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Research status and application of artificial intelligence large models in the oil and gas industry
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作者 LIU He REN Yili +6 位作者 LI Xin DENG Yue WANG Yongtao CAO Qianwen DU Jinyang LIN Zhiwei WANG Wenjie 《Petroleum Exploration and Development》 SCIE 2024年第4期1049-1065,共17页
This article elucidates the concept of large model technology,summarizes the research status of large model technology both domestically and internationally,provides an overview of the application status of large mode... This article elucidates the concept of large model technology,summarizes the research status of large model technology both domestically and internationally,provides an overview of the application status of large models in vertical industries,outlines the challenges and issues confronted in applying large models in the oil and gas sector,and offers prospects for the application of large models in the oil and gas industry.The existing large models can be briefly divided into three categories:large language models,visual large models,and multimodal large models.The application of large models in the oil and gas industry is still in its infancy.Based on open-source large language models,some oil and gas enterprises have released large language model products using methods like fine-tuning and retrieval augmented generation.Scholars have attempted to develop scenario-specific models for oil and gas operations by using visual/multimodal foundation models.A few researchers have constructed pre-trained foundation models for seismic data processing and interpretation,as well as core analysis.The application of large models in the oil and gas industry faces challenges such as current data quantity and quality being difficult to support the training of large models,high research and development costs,and poor algorithm autonomy and control.The application of large models should be guided by the needs of oil and gas business,taking the application of large models as an opportunity to improve data lifecycle management,enhance data governance capabilities,promote the construction of computing power,strengthen the construction of“artificial intelligence+energy”composite teams,and boost the autonomy and control of large model technology. 展开更多
关键词 foundation model large language mode visual large model multimodal large model large model of oil and gas industry pre-training fine-tuning
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Logit-based exit choice model of evacuation in rooms with internal obstacles and multiple exits 被引量:12
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作者 郭仁拥 黄海军 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第3期101-107,共7页
A logit-based discrete choice model is proposed to study the exit choice behaviour of evacuees in rooms with internal obstacles and multiple exits. Several factors influencing the exit choice behaviour, including the ... A logit-based discrete choice model is proposed to study the exit choice behaviour of evacuees in rooms with internal obstacles and multiple exits. Several factors influencing the exit choice behaviour, including the information obtained by evacuees, the tendency of following others, the visibility and familiarity of exits and the physical conditions of nearby exits, are considered. Evacuees are allowed to re-select their target exits for minimizing the perceived disutility during evacuation process. Numerical results from applying the model to cellular automata simulation of evacuation are presented and the effects of some model parameters on evacuation time are investigated. 展开更多
关键词 exit choice EVACUATION logit-based discrete choice cellular automata
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Preparation and Properties of PBXs Based on FOX-7 in Controlled Fragmentation Warhead Application 被引量:3
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作者 Karim K Elsharkawy Lin Guo Ahmed M Enew 《含能材料》 EI CAS CSCD 北大核心 2018年第10期843-849,共7页
Polymer bonded explosive(PBX)formulations were successfully prepared in the laboratory scale containing 1,1-diamino-2,2-dinitroethene(FOX-7)and hexogen(RDX)as brisant high explosives and different binder types of poly... Polymer bonded explosive(PBX)formulations were successfully prepared in the laboratory scale containing 1,1-diamino-2,2-dinitroethene(FOX-7)and hexogen(RDX)as brisant high explosives and different binder types of polyurethane(PU)based on glycidyl azide polymer(GAP) and hydroxyl-terminated polybutadiene(HTPB) as an energetic and inert polymeric binder respectively.Casting technique was used for the preparation of different PBX formulations based on FOX-7/RDX and PU(GAP/HTPB)with 14% binder.The sensitivity to different initial impulses and performance characteristics of the explosive and lethal zone of the tested controlled fragmentation warhead by the fragmentation warhead assessment test(arena test)were studied,in which the arena test was carried out with a controlled fragmentation warhead made from Ck45 steel,with dimensions(100 mm length,30 mm outer diameter and 3 mm thickness).Results show that PBXGF4 has lower sensitivity to impact and heat than those of PBXGR4 by 188.4% and 3.2% respectively.Its friction sensitivity is the same as that of PBXGR4.It has better performance,in which detonation velocity increases by 2.1% and brisance increases by 0.5% when compared with those of PBXGR4.It was concluded that PBXGF4 which based on FOX-7 bonded with PU/GAP matrix has good characteristics as PBX,specially in the sensitivity to impact and can be applied for replacing PBXs based on RDX in the advanced PBXs for low sensitive fragmentation warheads. 展开更多
关键词 polymer bonded explosive(PBX) CONTROLLED fragmentation WARHEAD 1 1-diamino-2 2-dinitroethene(FOX-7) hexo-gen(RDX) preparation sensitivity performance characterization ARENA test
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Modelling Study to Compare the Flow and Heat Transfer Characteristics of Low-Power Hydrogen,Nitrogen and Argon Arc-Heated Thrusters 被引量:5
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作者 王海兴 陈熙 +3 位作者 潘文霞 A.B.MURPHY 耿金越 贾少霞 《Plasma Science and Technology》 SCIE EI CAS CSCD 2010年第6期692-701,共10页
A modelling study is performed to compare the plasma flow and heat transfer characteristics of low-power arc-heated thrusters (arcjets) for three different propellants: hydrogen, nitrogen and argon. The all-speed S... A modelling study is performed to compare the plasma flow and heat transfer characteristics of low-power arc-heated thrusters (arcjets) for three different propellants: hydrogen, nitrogen and argon. The all-speed SIMPLE algorithm is employed to solve the governing equations, which take into account the effects of compressibility, Lorentz force and Joule heating, as well as the temperature- and pressure-dependence of the gas properties. The temperature, velocity and Mach number distributions calculated within the thruster nozzle obtained with different propellant gases are compared for the same thruster structure, dimensions, inlet-gas stagnant pressure and arc currents. The temperature distributions in the solid region of the anode-nozzle wall are also given. It is found that the flow and energy conversion processes in the thruster nozzle show many similar features for all three propellants. For example, the propellant is heated mainly in the near-cathode and constrictor region, with the highest plasma temperature appearing near the cathode tip; the flow transition from the subsonic to supersonic regime occurs within the constrictor region; the highest axial velocity appears inside the nozzle; and most of the input propellant flows towards the thruster exit through the cooler gas region near the anode-nozzle wall. However, since the properties of hydrogen, nitrogen and argon, especially their molecular weights, specific enthMpies and thermal conductivities, are different, there are appreciable differences in arcjet performance. For example, compared to the other two propellants, the hydrogen arcjet thruster shows a higher plasma temperature in the arc region, and higher axial velocity but lower temperature at the thruster exit. Correspondingly, the hydrogen arcjet thruster has the highest specific impulse and arc voltage for the same inlet stagnant pressure and arc current. The predictions of the modelling are compared favourably with available experimental results. 展开更多
关键词 low-power arcjet plasma flow and heat transfer numerical modelling propellant-type effects
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Analysis and Simulation of Evolution Induced Catastrophe 被引量:5
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作者 BAI Yilong XIA Mengfen +2 位作者 KE Fujiu LU Chunsheng LING Zhong 《Chinese Physics Letters》 SCIE CAS CSCD 1993年第3期155-158,共4页
A model of evolution induced catastrophe(EIC)characterized by a nonlocal interaction is proposed.The general feature of the model is its two bias states:explosively catastrophic and globally stable,both consisting in ... A model of evolution induced catastrophe(EIC)characterized by a nonlocal interaction is proposed.The general feature of the model is its two bias states:explosively catastrophic and globally stable,both consisting in a cascade of locally unstable states.A one-dimensional analysis reveals a transition region from globally stable to catastrophe.A two-dimensional simulation gives a thin fractal fracture profile similar to that observed and also a possible spectrum of fracture fractal.All these are different from percolation.Hence,the EIC model may represent a prototype of natural processes. 展开更多
关键词 globally FRACTAL LOCALLY
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Existence of Formal Conservation Laws of a Variable-Coefficient Korteweg-de Vries Equation from Fluid Dynamics and Plasma Physics via Symbolic Computation 被引量:2
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作者 张春义 李娟 +2 位作者 孟祥花 许韬 高以天 《Chinese Physics Letters》 SCIE CAS CSCD 2008年第3期878-880,共3页
Employing the method which can be used to demonstrate the infinite conservation laws for the standard Kortewegde Vries (KdV) equation, we prove that the variable-coeFficient KdV equation under the Painlevé test... Employing the method which can be used to demonstrate the infinite conservation laws for the standard Kortewegde Vries (KdV) equation, we prove that the variable-coeFficient KdV equation under the Painlevé test condition also possesses the formal conservation laws. 展开更多
关键词 NONLINEAR EVOLUTION-EQUATIONS SOLITARY WAVES MATHEMATICAL APPROACH POSITONIC SOLUTIONS KDV EQUATION DUSTY PLASMA MODEL TRANSFORMATION SOLITONS DEVRIES
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Sensitivity Test and Data Analysis for Storage Reliability Assessment of Explosive Initiator 被引量:2
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作者 洪东跑 赵宇 《Defence Technology(防务技术)》 SCIE EI CAS 2010年第2期119-125,共7页
The explosive initiator is one kind of sensitivity products with long life and high reliability.In order to improve the storage reliability assessment,the method of storage reliability assessment for explosive initiat... The explosive initiator is one kind of sensitivity products with long life and high reliability.In order to improve the storage reliability assessment,the method of storage reliability assessment for explosive initiator was proposed based on time series model using the sensitivity test data.In the method,the up and down test was used to estimate the distribution parameters of threshold.And an approach to design the up and down test was present to draw better estimations.Furthermore,the method of shrinkage estimation was introduced to get a better estimation of scale parameter by combining the sample information with prior information.The simulation result shows that the shrinkage estimation is better than traditional estimation under certain conditions.With the distribution parameters estimations,the time series models were used to describe the changing trends of distribution parameters along with storage time.Then for a fixed storage time,the distribution parameters were predicted based on the models.Finally,the confidence interval of storage reliability was obtained by fiducial inference.The illustrative example shows that the method is available for storage reliability assessment of the explosive initiator with high reliability. 展开更多
关键词 system engineering storage reliability explosive initiator up and down test time series model shrinkage estimation
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Analysis of Arc Characteristics and Flow Field in Arc Chamber of High-Voltage SF_6 Auto-Expansion Circuit Breaker 被引量:2
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作者 张俊民 陈长 《Plasma Science and Technology》 SCIE EI CAS CSCD 2008年第5期594-599,共6页
A new magnetic hydro-dynamics model for nozzle arc emphasizing the interaction of arc with PTFE (polytetrafluorethylene) vapour is established based on the conservation equations. The interruption of auto-expansion ... A new magnetic hydro-dynamics model for nozzle arc emphasizing the interaction of arc with PTFE (polytetrafluorethylene) vapour is established based on the conservation equations. The interruption of auto-expansion circuit breaker is simulated numerically by finite element method and the influence of PTFE vapour on the arc is analysed with this model. The results reveal that the flow field inside the arc chamber is determined by the arc current, the arcing time, the nozzle arc and the clogging of its thermal boundary. The establishment of quenching pressure relies on both SF6 gas and PTFE vapour that absorbed arc energy in the nozzle. The PTFE vapour leads to an increase in the pressure of nozzle arc obviously, and a decrease in the temperature of arc. But it enhances the temperature of arc at zero current and slows down the decreasing rate of arc temperature as the current decreases. 展开更多
关键词 PTFE vapour arc characteristics SF6 auto-expansion circuit breaker numerical analysis nozzle ablation
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Effects of H on Electronic Structure and Ideal Tensile Strength of W: A First-Principles Calculation 被引量:3
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作者 刘悦林 周洪波 +2 位作者 金硕 张颖 吕广宏 《Chinese Physics Letters》 SCIE CAS CSCD 2010年第12期162-165,共4页
We investigate the structure, energetics, and the ideal tensile strength of tungsten (W) with hydrogen (H) using a first-principles method. Both density of states (DOS) and the electron localization function (... We investigate the structure, energetics, and the ideal tensile strength of tungsten (W) with hydrogen (H) using a first-principles method. Both density of states (DOS) and the electron localization function (ELF) reveal the underlying physical mechanism that the tetrahedral interstitial H is the most energetically favorable. The firstprinciples computational tensile test (FPCTT) shows that the ideal tensile strength is 29.1 GPa at the strain of 14% along the [001] direction for the intrinsic W, while it decreases to 27.1 GPa at the strain of 12% when one impurity H atom is embedded into the bulk W. These results provide a useful reference to understand W as a plasma facing material in the nuclear fusion Tokamak. 展开更多
关键词 Condensed matter: electrical magnetic and optical Condensed matter: structural mechanical & thermal
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Comparative analysis of the arc characteristics inside the convergingdiverging and cylindrical plasma torches 被引量:1
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作者 Jianghong SUN Surong SUN +2 位作者 Haixing WANG Chong NIU Tao ZHU 《Plasma Science and Technology》 SCIE EI CAS CSCD 2020年第3期79-89,共11页
A two-temperature thermal non-equilibrium model is used to simulate and compare the arc characteristics within the converging-diverging and traditional cylindrical plasma torches.The modeling results show that the pre... A two-temperature thermal non-equilibrium model is used to simulate and compare the arc characteristics within the converging-diverging and traditional cylindrical plasma torches.The modeling results show that the presence of the constrictor within the converging-diverging torch makes the evolution characteristics of the arc significantly different from that of cylindrical torch.Compared with a cylindrical geometrical torch,a much higher plasma flow velocity and relatively longer high temperature region can be generated and maintained inside the converging-diverging torch.In the constrictor of converging-diverging torch,the normalized radius of arc column increases and the degree of thermodynamic equilibrium of the plasma is significantly improved with the increase of axial distance.The radial momentum balance analysis shows that for the cylindrical torch,the pressure gradient that drives the arc expansion and the Lorentz force that drives the arc contraction dominate the radial evolution of the arc.While at the converging and constrictor region of a converging-diverging plasma torch,the radial gas dynamic forces in arc fringes pointing toward the arc center enhance the mixing of the cold gas of boundary layer with the high temperature gas of the arc center,increasing the average gas temperature and decreasing the thickness of cold boundary layer,thereby facilitating the formation of diffusion type arc anode attachment at the diverging section of torch. 展开更多
关键词 plasma TORCH THERMODYNAMIC NON-EQUILIBRIUM ARC characteristics
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Electronic structures and magnetoelectric properties of tetragonal BaFeO_3:an ab initio density functional theory study 被引量:1
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作者 冯宏剑 刘发民 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第5期1874-1880,共7页
First-principles calculations have been performed to investigate the ground state electronic properties of BaFeO3 (BFO). Local spin density approximation (LSDA) plus U (LSDA+U) treatment modified the metallic b... First-principles calculations have been performed to investigate the ground state electronic properties of BaFeO3 (BFO). Local spin density approximation (LSDA) plus U (LSDA+U) treatment modified the metallic behaviour to insulated one with a band gap of 4.12eV. The spontaneous polarization was found to be 89.3μC/cm^2 with Berry phase scheme in terms of the modern theory of polarization. Fe-3d eg were split into two singlet states (dz2 and dx2-v2), and Fe-3d t2g were split into one doublet states(dze and dyz) and one singlet states(dzy) after Fe and O displaced along the c axis. Meanwhile the occupation numbers of dx2, dxz, dyz and OT pz (on the top of Fe) were increased at the expense of those in xy plane. Our results showed that it was the sensitivity of hybridization to ferroelectric distortions, not just the total change of hybridization, that produced the possibility of ferroelectricity. Moreover, the increasing occupation numbers of OT pz and Fe dz2 favoured the 180° coupling between Fe-3d eg and Fe-3d t2g, leading to ferromagnetic ordering, which has been confirmed by the increase of magnetic moment by 0.13μB per formula unit in the polarized direction. Hence, the magnetization can be altered by the reversal of external electric field. 展开更多
关键词 MULTIFERROIC density functional theory density of states band structures
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Dynamical and Geometric Phases of a Two Energy-Level Bose-Einstein Condensate Interacting with a Laser Field 被引量:1
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作者 于肇贤 焦志勇 +1 位作者 金硕 王继锁 《Chinese Physics Letters》 SCIE CAS CSCD 2007年第2期330-332,共3页
By using of the invariant theory, we study a two energy-level Bose-Einstein condensate interacting with a timedependent laser field, the dynamical and geometric phases are given respectively. The Aharonov-Anandan phas... By using of the invariant theory, we study a two energy-level Bose-Einstein condensate interacting with a timedependent laser field, the dynamical and geometric phases are given respectively. The Aharonov-Anandan phase is also obtained under the cyclical evolution. 展开更多
关键词 ADIABATIC APPROXIMATION BERRYS PHASE ATOMS GAS PHOTONS
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Optimization and design of pigments for heat-insulating coatings 被引量:1
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作者 王广海 张跃 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第12期520-525,共6页
This paper reports that heat insulating property of infrared reflective coatings is obtained through the use of pigments which diffuse near-infrared thermal radiation. Suitable structure and size distribution of pigme... This paper reports that heat insulating property of infrared reflective coatings is obtained through the use of pigments which diffuse near-infrared thermal radiation. Suitable structure and size distribution of pigments would attain maximum diffuse infrared radiation and reduce the pigment volume concentration required. The optimum structure and size range of pigments for reflective infrared coatings are studied by using Kubelka-Munk theory, Mie model and independent scattering approximation. Taking titania particle as the pigment embedded in an inorganic coating, the computational results show that core-shell particles present excellent scattering ability, more so than solid and hollow spherical particles. The optimum radius range of core-shell particles is around 0.3 - 1.6 μm. ~rthermore, the influence of shell thickness on optical parameters of the coating is also obvious and the optimal thickness of shell is 100-300 nm. 展开更多
关键词 COATING engineering ceramics SCATTERING PIGMENTS
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Structure distortion, optical and electrical properties of ZnO thin films co-doped with Al and Sb by sol-gel spin coating 被引量:1
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作者 钟文武 刘发民 +3 位作者 蔡鲁刚 周传仓 丁芃 张嬛 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第10期515-519,共5页
ZnO thin films co-doped with A1 and Sb with different concentrations and a fixed molar ratio of AlCl3 to SbCl3 at 1:2, are prepared by a sol-gel spin-coating method on glass annealed at 550 ℃ for 2 h in air. The x-r... ZnO thin films co-doped with A1 and Sb with different concentrations and a fixed molar ratio of AlCl3 to SbCl3 at 1:2, are prepared by a sol-gel spin-coating method on glass annealed at 550 ℃ for 2 h in air. The x-ray diffraction results confirm that the ZnO thin films co-doped with Al distortion, and the biaxial stresses are 1.03× 10^8. 3.26× 10^8 and Sb are of wurtzite hexagonal ZnO with a very small 5.23 × 10^8, and 6.97× 10^8 Pa, corresponding to those of the ZnO thin films co-doped with Al and Sb in concentrations of 1.5, 3.0, 4.5, 6.0 at% respectively. The optical properties reveal that the ZnO thin films co-doped with Al and Sb have obviously enhanced transmittance in the visible region. The electrical properties show that ZnO thin film co-doped with Al and Sb in a concentration of 1.5 at% has a lowest resistivity of 2.5 Ω·cm. 展开更多
关键词 ZnO thin films co-doped with Al and Sb sol-gel spin-coating method structure distortion optical and electrical properties
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Design and Trafficability Study of Flexible Wheel for Planetary Exploration Rover 被引量:1
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作者 李雯 高峰 徐国艳 《Journal of Beijing Institute of Technology》 EI CAS 2007年第3期279-283,共5页
To reduce sending costs, a flexible wheel configuration is proposed. The wheel is made of titanium alloy (Ti-6Al-4V) in consideration of the planetary environment factors (i. e. strong radiation, big temperature di... To reduce sending costs, a flexible wheel configuration is proposed. The wheel is made of titanium alloy (Ti-6Al-4V) in consideration of the planetary environment factors (i. e. strong radiation, big temperature differences, high vacuum), and mass constraint of launch vehicle. The advantages of the proposed wheel involves the potential for: ① small sending volume and mass, ② large deployed area and volume to reduce wheel loading, ③ a damping effect to smooth motion on rough terrain. To study the trafficability and tractive performance of the wheel concept, the drawbar pull and driven torque were calculated based on simplified model of terramechanics formulations. The results show that the wheel possesses sufficient drawbar pull to negotiate all types of soil stratums listed in this contribution. 展开更多
关键词 planetary rover flexible wheel wheel-soil interaction TRAFFICABILITY
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Flow characterization and dilution effects of N_2 and CO_2 on premixed CH_4/air flames in a swirl-stabilized combustor 被引量:1
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作者 韩乐 蔡国飙 +2 位作者 王海兴 Renou Bruno Boukhalfa Abdelkrim 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第3期382-395,共14页
Numerically-aided experimental studies are conducted on a swirl-stabilized combustor to investigate the dilution effects on flame stability, flame structure, and pollutant emissions of premixed CH4/air flames. Our goa... Numerically-aided experimental studies are conducted on a swirl-stabilized combustor to investigate the dilution effects on flame stability, flame structure, and pollutant emissions of premixed CH4/air flames. Our goal is to provide a systematic assessment on combustion characteristics in diluted regimes for its application to environmentally-friendly approaches such as biogas combustion and exhanst-gas recirculation technology. Two main diluting species, N2 and CO2, are tested at various dilution rates. The results obtained by means of optical diagnostics show that five main flame regimes can be observed for Nz-diluted flames by changing excess air and dilution rate. CO2-diluted flames follow the same pattern evolution except that all the domains are shifted to lower excess air. Both N2 and CO2 dilution affect the lean blow- out (LBO) limits negatively. This behavior can be counter-balanced by reactant preheating which is able to broaden the flammability domain of the diluted flames. Flame reactivity is degraded by increasing dilution rate. Meanwhile, flames are thickened in the presence of both diluting species. NOx emissions are significantly reduced with dilution and proved to be relevant to flame stability diagrams: slight augmentation in NOx emission profiles is related to transitional flame states where instability occurs. Although dilution results in increase in CO emissions at certain levels, optimal dilution rates can still be proposed to achieve an ideal compromise. 展开更多
关键词 dilution effect premixed combustion swirl flow optical diagnostics
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Ab initio study on phase transition and magnetism of BiFeO_3 under pressure 被引量:1
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作者 冯宏剑 刘发民 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第4期1574-1577,共4页
In this paper the first-principles calculations within local spin density approximation (LSDA)+U show that BiFeO3 experiences a mixed phase state with P4mm structure being the intermediate phase before the pressure... In this paper the first-principles calculations within local spin density approximation (LSDA)+U show that BiFeO3 experiences a mixed phase state with P4mm structure being the intermediate phase before the pressure of phase transition is reached. The critical pressure for the insulator-metal transition (IMT) is found to be about 50 GPa. A pressure induced crossover of high-spin states and low-spin states is observed close to the IMT pressure in R3c structure. The LSDA+U calculations account well for the mechanism of the IMT and crossover of spin states predicted in recent experiment (Ref.[1]). 展开更多
关键词 density functional theory phase transition BIFEO3
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Two Classes of Solvable Subgroups of SL(3, C) and Application for Differential Equations in C 被引量:1
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作者 ZHANG Shao-fei LI Hui-zhen 《Chinese Quarterly Journal of Mathematics》 CSCD 2010年第1期30-36,共7页
Structures of two classes of solvable subgroups in SL(3, C) are given in this paper, and the integrability of the 3-order Fuchsian equation which is integrable in the sense that its monodromy group is solvable is di... Structures of two classes of solvable subgroups in SL(3, C) are given in this paper, and the integrability of the 3-order Fuchsian equation which is integrable in the sense that its monodromy group is solvable is discussed. 展开更多
关键词 Fuehsian system solvable group general linear group special linear group monodromy group INTEGRABILITY
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Synthesis and photoluminescence properties of Nd_2O_3 nanoparticles modified by sodium bis(2-ethylhexyl) sulfosuccinate 被引量:1
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作者 任建华 赵同刚 +3 位作者 刘建华 孔娟 贺加欣 郭林 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第12期4669-4672,共4页
This paper reports that Nd2O3 nanoparticles modified by AOT(sodium bis(2-ethylhexyl) sulfosuccinate) were prepared using microemulsion method in the system of water and propanol/AOT/toluene. Transmission electron ... This paper reports that Nd2O3 nanoparticles modified by AOT(sodium bis(2-ethylhexyl) sulfosuccinate) were prepared using microemulsion method in the system of water and propanol/AOT/toluene. Transmission electron microscopy shows that the Nd2O3 nanoparticles take the shape of sphere with 18 nm and 31 nm with different preparation. The organic sol of Nd2O3 nanoparticles is very stable at room temperature. X-ray diffraction results show that the product has hexagonal phase structure. Two ultraviolet emission band at 344 nm and 361 nm corresponding to the transition of ^4 D3/2→4 I9/2 and 2P3/2→^4I 11/2 or ^4D 3/2→ ^4 I 13/2 were observed. 展开更多
关键词 Nd2O3 nanocrystals photoluminescence spectrum surface modification
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Preparation,structure and ferromagnetic properties of the nanocrystalline Ti_(1-x)Mn_xO_2 thin films grown by radio frequency magnetron co-sputtering 被引量:1
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作者 丁芃 刘发民 +1 位作者 杨新安 李建奇 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第2期721-725,共5页
This paper reported that the Mn-doped TiO2 films were prepared by radio frequency (RF) magnetron cosputtering. X-ray diffraction measurements indicate that the samples are easy to form the futile structure, and the ... This paper reported that the Mn-doped TiO2 films were prepared by radio frequency (RF) magnetron cosputtering. X-ray diffraction measurements indicate that the samples are easy to form the futile structure, and the sizes of the crystal grains grow big and big as the Mn concentration increases. X-ray photoemlssion spectroscopy measurements and high resolution transmission electron microscope photographs confirm that the manganese ions have been effectively doped into the TiO2 crystal when the Mn concentration is lower than 21%. The magnetic property measurements show that the Ti1-xMnxO2 (x = 0.21) films are ferromagnetic at room temperature, and the saturation magnetization, coercivity, and saturation field are 16.0 emu/cm^3, 167.5 × 80 A/m and 3740 × 80 A/m at room temperature, respectively. The room-temperature ferromagnetism of the films can be attributed to the new futile Ti1-xMnxO2 structure formed by the substitution of Mn^4+ for Ti^4+ into the TiO2 crystal .lattice, and could be explained by O vacancy (Vo)-enhanced ferromagnetism model. 展开更多
关键词 RF magnetron sputtering Mn-doped TiO2 films room-temperature ferromagnetic properties
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