利用共沉淀法制备了四组分的Cu Zn Al Mn和Cu Zn Al Ce催化剂以及三组分的Cu Zn Al催化剂。利用组成H2/CO/CO2/N2=66/27/3/4(体积比)的富CO原料气对催化剂进行了活性评价,并研究了温度、压力和空速等反应条件对催化剂活性的影响。结果...利用共沉淀法制备了四组分的Cu Zn Al Mn和Cu Zn Al Ce催化剂以及三组分的Cu Zn Al催化剂。利用组成H2/CO/CO2/N2=66/27/3/4(体积比)的富CO原料气对催化剂进行了活性评价,并研究了温度、压力和空速等反应条件对催化剂活性的影响。结果发现添加适量的锰助剂能显著提高催化剂的活性和热稳定性。利用SEM和XRD方法进行了催化剂的结构和形貌表征,同样表明锰助剂可以起到阻止CuO晶粒长大和促进CuO分散作用。利用富CO2的生物质原料气体积比为H2/CO/CO2/N2=50/25/20/5对Cu Zn Al Mn催化剂进行的评价表明:Cu Zn Al Mn催化剂上CO/CO2加氢合成甲醇的甲醇产率和选择性均有下降,在试验范围内,甲醇产率下降11%～25%,选择性为93%～95%。展开更多
This paper introduces the effect of dolomite and limestone on waste tyre pyrolysis When waste tyre was pyrolyzed in 700?℃, the derived gases was passed through the catalyst zone in which the temperature was controlle...This paper introduces the effect of dolomite and limestone on waste tyre pyrolysis When waste tyre was pyrolyzed in 700?℃, the derived gases was passed through the catalyst zone in which the temperature was controlled at 700?℃, 800?℃and 900?℃, respectively It is found that both dolomite and limestone affect the product distribution of tyre pyrolysis with erhancing gas yield and effective absorption of H 2S The effect of these catalysts on tar cracking is obvious at 900?℃, however, the life of catalyst is short The product yields are about 40% for gas, 30% for liquid and 30% for char in the presence of dolomite and limestone The result indicates that multi use of the pyrolysed product is highly recommended [WT5H1]展开更多
文摘利用共沉淀法制备了四组分的Cu Zn Al Mn和Cu Zn Al Ce催化剂以及三组分的Cu Zn Al催化剂。利用组成H2/CO/CO2/N2=66/27/3/4(体积比)的富CO原料气对催化剂进行了活性评价,并研究了温度、压力和空速等反应条件对催化剂活性的影响。结果发现添加适量的锰助剂能显著提高催化剂的活性和热稳定性。利用SEM和XRD方法进行了催化剂的结构和形貌表征,同样表明锰助剂可以起到阻止CuO晶粒长大和促进CuO分散作用。利用富CO2的生物质原料气体积比为H2/CO/CO2/N2=50/25/20/5对Cu Zn Al Mn催化剂进行的评价表明:Cu Zn Al Mn催化剂上CO/CO2加氢合成甲醇的甲醇产率和选择性均有下降,在试验范围内,甲醇产率下降11%～25%,选择性为93%～95%。
文摘This paper introduces the effect of dolomite and limestone on waste tyre pyrolysis When waste tyre was pyrolyzed in 700?℃, the derived gases was passed through the catalyst zone in which the temperature was controlled at 700?℃, 800?℃and 900?℃, respectively It is found that both dolomite and limestone affect the product distribution of tyre pyrolysis with erhancing gas yield and effective absorption of H 2S The effect of these catalysts on tar cracking is obvious at 900?℃, however, the life of catalyst is short The product yields are about 40% for gas, 30% for liquid and 30% for char in the presence of dolomite and limestone The result indicates that multi use of the pyrolysed product is highly recommended [WT5H1]
