Binuclear Copper (Ⅰ) Complex {Cu [ WS2P(C2H5O)2] (C10H8N2) } 2 was synthesized and characterized by elemental analysis, IR and X-ray diffraction analysis. The crystal belongs to triclinic system, space group P1 with ...Binuclear Copper (Ⅰ) Complex {Cu [ WS2P(C2H5O)2] (C10H8N2) } 2 was synthesized and characterized by elemental analysis, IR and X-ray diffraction analysis. The crystal belongs to triclinic system, space group P1 with Z = l, cell dimentions are a = 1. 0613 (5), b = 1. 0723 (3), c = 0. 9397 (2) um, a = 111. 11 (4), β = 115. 57(6), y = 85. 28(2)", V= 0. 8583(6) "nm3. The structure was refined to R = 0. 039 and Rw = 0. 042 for 2527 reflection with Ⅰ > 36(Ⅰ). The complex exists as a centrosymmetric dimer with a Cu-S-P-S-Cu-S-P-S chair eight-membered ring in which Cu atoms are bridged by di-AS-P-S groups.展开更多
文摘Binuclear Copper (Ⅰ) Complex {Cu [ WS2P(C2H5O)2] (C10H8N2) } 2 was synthesized and characterized by elemental analysis, IR and X-ray diffraction analysis. The crystal belongs to triclinic system, space group P1 with Z = l, cell dimentions are a = 1. 0613 (5), b = 1. 0723 (3), c = 0. 9397 (2) um, a = 111. 11 (4), β = 115. 57(6), y = 85. 28(2)", V= 0. 8583(6) "nm3. The structure was refined to R = 0. 039 and Rw = 0. 042 for 2527 reflection with Ⅰ > 36(Ⅰ). The complex exists as a centrosymmetric dimer with a Cu-S-P-S-Cu-S-P-S chair eight-membered ring in which Cu atoms are bridged by di-AS-P-S groups.
