The standard formation enthalpy of the glycine complex with erbium chloride was determined by using an isoperibolic calorimeter with the hydrochloric acid solution(2 mol/L) as a calorimetric solvent according a propos...The standard formation enthalpy of the glycine complex with erbium chloride was determined by using an isoperibolic calorimeter with the hydrochloric acid solution(2 mol/L) as a calorimetric solvent according a proposed thermochemical cycle. The following values were obtained: Δ r H θ m(298.15 K)=-3.331 kJ/mol Δ f H θ m(Er(Gly) 3Cl 3·3H 2O,s,298.15 K)=-3 632.0展开更多
The reaction enthalpy of coordination reaction of lanthanum chloride with Glycine is determined by solution calorimetry in an isoperibel reaction calorimeter. The calormetric solvent is the solution of hydrochloric ac...The reaction enthalpy of coordination reaction of lanthanum chloride with Glycine is determined by solution calorimetry in an isoperibel reaction calorimeter. The calormetric solvent is the solution of hydrochloric acid (2 mol· L－ 1), a new thermochemical cycle is designed. According to the results, the following date: (298.2 K)=－ 4.310 kJ· mol－ 1 (La(Gly)3Cl3· 5H2O, s, 298.2 K)=－ 4222.93 kJ· mol－ 1 were obtained.展开更多
The reaction enthalpy of solid-solid coordination reaction of L-Leucine with copper acetate is determined by solution calorimetry in an isoperibel reaction calorimeter. The calorimetric solvent is the solution of hydr...The reaction enthalpy of solid-solid coordination reaction of L-Leucine with copper acetate is determined by solution calorimetry in an isoperibel reaction calorimeter. The calorimetric solvent is the solution of hydrochloric acid（4 mol/L）, a new thermochemical cycle is designed. The values of ΔfHθm=15.64 kJ/mol, ΔfHθm（trans-Cu（L-Leu）2,s）=-1194.7 kJ/mol are evalcated.展开更多
文摘The standard formation enthalpy of the glycine complex with erbium chloride was determined by using an isoperibolic calorimeter with the hydrochloric acid solution(2 mol/L) as a calorimetric solvent according a proposed thermochemical cycle. The following values were obtained: Δ r H θ m(298.15 K)=-3.331 kJ/mol Δ f H θ m(Er(Gly) 3Cl 3·3H 2O,s,298.15 K)=-3 632.0
文摘The reaction enthalpy of coordination reaction of lanthanum chloride with Glycine is determined by solution calorimetry in an isoperibel reaction calorimeter. The calormetric solvent is the solution of hydrochloric acid (2 mol· L－ 1), a new thermochemical cycle is designed. According to the results, the following date: (298.2 K)=－ 4.310 kJ· mol－ 1 (La(Gly)3Cl3· 5H2O, s, 298.2 K)=－ 4222.93 kJ· mol－ 1 were obtained.
文摘The reaction enthalpy of solid-solid coordination reaction of L-Leucine with copper acetate is determined by solution calorimetry in an isoperibel reaction calorimeter. The calorimetric solvent is the solution of hydrochloric acid（4 mol/L）, a new thermochemical cycle is designed. The values of ΔfHθm=15.64 kJ/mol, ΔfHθm（trans-Cu（L-Leu）2,s）=-1194.7 kJ/mol are evalcated.
