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消旋山莨菪碱的电子轰击质谱研究 被引量:2
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作者 谢亚雄 朱雁 刘芳 《质谱学报》 EI CAS CSCD 2004年第B10期111-112,共2页
In this paper, raceanisodamine are analyzed by El mass spectrometry(EIMS),their characteristic fragment ions were obtained. The fragmentation mechanism on this component was discussed. The results showed the ring of r... In this paper, raceanisodamine are analyzed by El mass spectrometry(EIMS),their characteristic fragment ions were obtained. The fragmentation mechanism on this component was discussed. The results showed the ring of raceanisodamine was crazed and characteristic ions m/z261 and base peak m/z94 were produced by losing free group CH2CH2OH, then its alcoholysis can create some ploy-ring ions such as m/z140 and m/z 156. These fragment act as the characters of raceanisodamine. 展开更多
关键词 消旋山莨菪碱 电子轰击质谱 生物碱 裂解过程
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