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湘赣地洼型煤田中岩浆岩的岩石学及地球化学特征
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作者 童玉明 邱明 《地球化学》 CAS 1982年第4期357-366,共10页
Commonly seen in Mesozoic coal fields of Diwa type in Hunan and Jiangxi are basic, intermediate and acidic intrusive and volcanic rocks. The sequence of magmatism is from acidic to basic. The rocks show a tendency to ... Commonly seen in Mesozoic coal fields of Diwa type in Hunan and Jiangxi are basic, intermediate and acidic intrusive and volcanic rocks. The sequence of magmatism is from acidic to basic. The rocks show a tendency to become younger in age from west to east. Biotite granite porphyry-quartz diorite porphyrite, diorite porphyrite-diabase, diabase-porphyrite and spilite are the main rock types. These rocks are geochemically eharacterized by an evolutionary sequence from acidic to basic and by the enrichment in alkaline elements (except for biotite granite porphyry which has undergone intense alteration). In the acidic rocks K2O> Na2O whereas in the basic rocks K2O < Na2O. All the rocks are rich in non-ferrous metals and rare dements. The majority of the magmatic rocks were emplaced during the most intensive pariod of Diwa development. The rocks generally run parallel with the strike of coal basins. They were emplaced mostly along the layers or cut across coal seams. The above data on tectono-magmatic activity in coal fields of Diwa type lend great support to Prof. Chert Guoda's proposal that the history of crustal evolution is divided into three major stages -- geosyncline, platform snd Diwa. 展开更多
关键词 煤田 岩浆岩 岩石学 地球化学
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氧弹燃烧-催化极谱法测定煤中痕量硒 被引量:2
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作者 谢建鹰 《理化检验(化学分册)》 CAS CSCD 北大核心 1991年第5期292-293,共2页
测硒的样品,一般采用混合酸消化处理。然而,对于煤样,以此方式处理则比较困难。文献利用氧弹燃烧预处理、导数荧光法测定煤中痕量硒。在此基础上,本工作将煤样经氧弹燃烧处理后,无须分离而用催化极谱法直接测定样品中痕量硒。方法简便,... 测硒的样品,一般采用混合酸消化处理。然而,对于煤样,以此方式处理则比较困难。文献利用氧弹燃烧预处理、导数荧光法测定煤中痕量硒。在此基础上,本工作将煤样经氧弹燃烧处理后,无须分离而用催化极谱法直接测定样品中痕量硒。方法简便,灵敏度高,加标回收率为87~110%,测定下限为0.1×10-4% Se。试验部分一仪器与主要试剂 JP-2A型示波极谱仪(成都仪器厂产) 采用三电极系统:滴汞电极、饱和甘汞电极和铂电极。 展开更多
关键词 测定 氧弹燃烧 催化极谱法
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煤中痕量铊的测定
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作者 谢建鹰 《中国环境监测》 CAS CSSCI CSCD 北大核心 1993年第1期56-58,共3页
正如其它一些稀散元素一样,铊也常有时伴生富集于煤中.尽管近年发表的铊测定方面文章较多,但作者未见有应用于煤中这方面的报道.结晶紫、孔雀石绿。
关键词 测定
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