The isobaric molar heat capacities o f nano Co 2 O 3 were determined by an adiabatic calo rimeter in the temper-ature range from 78to 350K.No phase t ransition takes place in this temperature range.The relationship of...The isobaric molar heat capacities o f nano Co 2 O 3 were determined by an adiabatic calo rimeter in the temper-ature range from 78to 350K.No phase t ransition takes place in this temperature range.The relationship of C p,m with respect to thermodynamic temperature T was established as C p,m =-11.998X 3 -9.6431X 2 +63.478X+81.291(J·K -1 ·mol -1 ),where X=(T-201.903)/121.535,the correlation coefficient R 2 =0.9996.Ac-cording to this relationship and the relationships between thermodynam ic functions,the thermodynamic functions of nano Co 2 O 3 relative to the standard temperatur e of 298.15K were derived based on the measured heat capacity data.The average grain size of the studied nano Co 2 O 3 sample was determined to be 12nm by TE M.展开更多
文摘The isobaric molar heat capacities o f nano Co 2 O 3 were determined by an adiabatic calo rimeter in the temper-ature range from 78to 350K.No phase t ransition takes place in this temperature range.The relationship of C p,m with respect to thermodynamic temperature T was established as C p,m =-11.998X 3 -9.6431X 2 +63.478X+81.291(J·K -1 ·mol -1 ),where X=(T-201.903)/121.535,the correlation coefficient R 2 =0.9996.Ac-cording to this relationship and the relationships between thermodynam ic functions,the thermodynamic functions of nano Co 2 O 3 relative to the standard temperatur e of 298.15K were derived based on the measured heat capacity data.The average grain size of the studied nano Co 2 O 3 sample was determined to be 12nm by TE M.
