Polymeric surfactants were prepared by ultrasonic copolymerization of carboxy methyl cellulose (CMC) and alkyl poly(etheroxy) acrylate. The adsorption mechanism of CMC based polymeric surfactants at silica gel/water i...Polymeric surfactants were prepared by ultrasonic copolymerization of carboxy methyl cellulose (CMC) and alkyl poly(etheroxy) acrylate. The adsorption mechanism of CMC based polymeric surfactants at silica gel/water interface was studied by the adsorption isotherms,IR difference spectra. The results show that the adsorptive amount goes up steadily with the increasing of copolymer concentration. Because of multicontact adsorption of copolymers at the surface of silica gel, the strong interaction between copolymers and surface of silica gel (such as hydrogen bond), large amount of polymeric surfactants adsorbs on silica gel. The pH value of copolymer solution plays a great role on adsorption, which indicates that the electrostatic action is the main adsorption mechanism of CMC based polymeric surfactants.展开更多
The micellar conformation of polymeric surfactants based on carboxy methyl cellulose in aqueous solution was studied by dynamic laser scattering and environmental scanning electron microscope. The results show that di...The micellar conformation of polymeric surfactants based on carboxy methyl cellulose in aqueous solution was studied by dynamic laser scattering and environmental scanning electron microscope. The results show that different polymeric surfactants have different micellar conformation. The micelles formed by copolymer A3, B7 and B9 are spheroidal or ellipsoidal. While copolymer A9 which is more hydrophilic forms rod like micelles. At high concentration the micelles in aqueous solution would aggregate and form network structure further. The dependence of micelle size distribution function F(R) on scattering vector confirms again that the micelles of A9 is not like spherical, while the independence of F(R) on scattering angles means B9 molecules forming sphere like micelles.展开更多
第33届国际纯粹与应用化学学会高分子讨论会(33rd IUPAC International Symposium on Macromolecules)于1990年7月8日至7月13日在加拿大蒙特利尔举行。44个国家和地区近3000名学者参加了讨论会。中国代表10人,其中成都科技大学徐僖教授...第33届国际纯粹与应用化学学会高分子讨论会(33rd IUPAC International Symposium on Macromolecules)于1990年7月8日至7月13日在加拿大蒙特利尔举行。44个国家和地区近3000名学者参加了讨论会。中国代表10人,其中成都科技大学徐僖教授和广州中山大学李卓美教授是大会特邀报告人。此外,不少中国留学生参加了会议。会议交流论文1627篇,其中大会报告6篇,高分子材料48个专题组822篇。展开更多
文摘Polymeric surfactants were prepared by ultrasonic copolymerization of carboxy methyl cellulose (CMC) and alkyl poly(etheroxy) acrylate. The adsorption mechanism of CMC based polymeric surfactants at silica gel/water interface was studied by the adsorption isotherms,IR difference spectra. The results show that the adsorptive amount goes up steadily with the increasing of copolymer concentration. Because of multicontact adsorption of copolymers at the surface of silica gel, the strong interaction between copolymers and surface of silica gel (such as hydrogen bond), large amount of polymeric surfactants adsorbs on silica gel. The pH value of copolymer solution plays a great role on adsorption, which indicates that the electrostatic action is the main adsorption mechanism of CMC based polymeric surfactants.
文摘The micellar conformation of polymeric surfactants based on carboxy methyl cellulose in aqueous solution was studied by dynamic laser scattering and environmental scanning electron microscope. The results show that different polymeric surfactants have different micellar conformation. The micelles formed by copolymer A3, B7 and B9 are spheroidal or ellipsoidal. While copolymer A9 which is more hydrophilic forms rod like micelles. At high concentration the micelles in aqueous solution would aggregate and form network structure further. The dependence of micelle size distribution function F(R) on scattering vector confirms again that the micelles of A9 is not like spherical, while the independence of F(R) on scattering angles means B9 molecules forming sphere like micelles.
文摘第33届国际纯粹与应用化学学会高分子讨论会(33rd IUPAC International Symposium on Macromolecules)于1990年7月8日至7月13日在加拿大蒙特利尔举行。44个国家和地区近3000名学者参加了讨论会。中国代表10人,其中成都科技大学徐僖教授和广州中山大学李卓美教授是大会特邀报告人。此外,不少中国留学生参加了会议。会议交流论文1627篇,其中大会报告6篇,高分子材料48个专题组822篇。
