Zeolite ZSM-5 has been synthesized with the organosilicon compound γ-aminopropyl triethoxylsilane as structure-directing agent using the composition 10SiO2: Al2O3: 3-5Na2O: 0. 1-0.5R: 40-100H2O(molar ratios). First o...Zeolite ZSM-5 has been synthesized with the organosilicon compound γ-aminopropyl triethoxylsilane as structure-directing agent using the composition 10SiO2: Al2O3: 3-5Na2O: 0. 1-0.5R: 40-100H2O(molar ratios). First of all, γ-aminopropyl triethoxylsilane was quaternarized with bromoethane and ethyl alcohol. XRD, TG, DTA and SEM were used to characterize the sample. The investigation proves that the organosilicon compound resides intact at the channel intersections, and that the silicon atom In this species is located in a framework position. Prehydrolysis of the organosilane precursor is necessary for zeolite formation.展开更多
The title compound [N(CH 3) 4] 4 [H 5PMo 5V 9O 42 ] ·3.5H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X ray analysis. The cluster anion is a bicapped Keggin poly...The title compound [N(CH 3) 4] 4 [H 5PMo 5V 9O 42 ] ·3.5H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X ray analysis. The cluster anion is a bicapped Keggin polyanion, two vanadium atoms are distributed at two capping metal atom positions. The crystal is monoclinic, space group C2/c with a=1.284 8(4) nm, b=2.366 4(4) nm, c=2.113 6(4) nm, β= 90.69(2)° , V=6.425(4) nm 3, Z=4, D c=2.07 g\5cm -3 , R=0.066, R w=0.069, S=1.33, \{(Δ/σ) max =\}0 04, \{(Δρ) max =\}91 e·nm -3 .展开更多
The organically templated titanium phosphate [Ti 3P 6O 27 H 5] · [C 2H 9N 2] 5·2 [H 3O] has been synthesized by solvothermal method and its structure was determined by single crystal X ray diffraction. The c...The organically templated titanium phosphate [Ti 3P 6O 27 H 5] · [C 2H 9N 2] 5·2 [H 3O] has been synthesized by solvothermal method and its structure was determined by single crystal X ray diffraction. The crystal crystallizes in a orthorhombic system of the enantiomorphic space group P 2 12 12 1 , with a = 1.018 0(6) nm , b =1.589 9(9) nm, c =2.322 7(12) nm, V =3.759 4(4) nm 3, Z =4, D c= 1.96 g/cm 3 , F (000)= 2 296 , R =0.048 6, ωR 2=0.125 7. The title compound contains chiral spirals formed from macroanionic chains of titanium oxygen octahedra bonded together by phosphate tetrahedral. These spirals are interconnected through hydrogen bonding in a manner to form unusual tunnels along the [001] direction in which H 2N(CH 2) 2NH 3 + cations are included. Second harmonics are generated in powdered sample. [WT5HZ]展开更多
This paper mainly elaborated the recent developments of the studies on the new type zeohite molecular sieve host-nanoguest composite materials composing of molecular sieve chaimels or cages encapsulated nanoscale mate...This paper mainly elaborated the recent developments of the studies on the new type zeohite molecular sieve host-nanoguest composite materials composing of molecular sieve chaimels or cages encapsulated nanoscale materials from the point of nanochemistry and material science,and the trends of development in this field. As the research of the properties of this kind of materials are gomg on. it is possible that this kind of host-guest nanocomposite materials will be usd in some fields. such as science and high technology fields. as the new type of ptical. electrical and magnetic materials in the level of molecular assembly. This paper contains the following contents:hosts and guests; the sizes and shapes of guests; the optical, electrical and magnetic properties of the materials; the syntheses and characterizations of the materials; the applications of the materials and forecast.展开更多
Tris(bipyridine)ruthenium(Ⅱ)(Ru(bpy) 2+ 3) was incorporated into mesoporous silicate MCM 48. X ray diffraction and emission spectroscopy were used to investigate the products, Ru(bpy) 2+ 3/MCM 48. The emission spectr...Tris(bipyridine)ruthenium(Ⅱ)(Ru(bpy) 2+ 3) was incorporated into mesoporous silicate MCM 48. X ray diffraction and emission spectroscopy were used to investigate the products, Ru(bpy) 2+ 3/MCM 48. The emission spectra show that the wavelength of maximum intensity( λ max ) for Ru(bpy) 2+ 3 increases with the increase of Ru(bpy) 2+ 3 loading level in MCM 48. The photoluminescent property of Ru(bpy) 2+ 3/MCM 48 was investigated. It was observed that the wavelength maximum intensity( λ max ) for Ru(bpy) 2+ 3/MCM 48 was red shifted when acetone vapor was introduced. [WT5HZ]展开更多
文摘Zeolite ZSM-5 has been synthesized with the organosilicon compound γ-aminopropyl triethoxylsilane as structure-directing agent using the composition 10SiO2: Al2O3: 3-5Na2O: 0. 1-0.5R: 40-100H2O(molar ratios). First of all, γ-aminopropyl triethoxylsilane was quaternarized with bromoethane and ethyl alcohol. XRD, TG, DTA and SEM were used to characterize the sample. The investigation proves that the organosilicon compound resides intact at the channel intersections, and that the silicon atom In this species is located in a framework position. Prehydrolysis of the organosilane precursor is necessary for zeolite formation.
文摘The title compound [N(CH 3) 4] 4 [H 5PMo 5V 9O 42 ] ·3.5H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X ray analysis. The cluster anion is a bicapped Keggin polyanion, two vanadium atoms are distributed at two capping metal atom positions. The crystal is monoclinic, space group C2/c with a=1.284 8(4) nm, b=2.366 4(4) nm, c=2.113 6(4) nm, β= 90.69(2)° , V=6.425(4) nm 3, Z=4, D c=2.07 g\5cm -3 , R=0.066, R w=0.069, S=1.33, \{(Δ/σ) max =\}0 04, \{(Δρ) max =\}91 e·nm -3 .
文摘The organically templated titanium phosphate [Ti 3P 6O 27 H 5] · [C 2H 9N 2] 5·2 [H 3O] has been synthesized by solvothermal method and its structure was determined by single crystal X ray diffraction. The crystal crystallizes in a orthorhombic system of the enantiomorphic space group P 2 12 12 1 , with a = 1.018 0(6) nm , b =1.589 9(9) nm, c =2.322 7(12) nm, V =3.759 4(4) nm 3, Z =4, D c= 1.96 g/cm 3 , F (000)= 2 296 , R =0.048 6, ωR 2=0.125 7. The title compound contains chiral spirals formed from macroanionic chains of titanium oxygen octahedra bonded together by phosphate tetrahedral. These spirals are interconnected through hydrogen bonding in a manner to form unusual tunnels along the [001] direction in which H 2N(CH 2) 2NH 3 + cations are included. Second harmonics are generated in powdered sample. [WT5HZ]
文摘This paper mainly elaborated the recent developments of the studies on the new type zeohite molecular sieve host-nanoguest composite materials composing of molecular sieve chaimels or cages encapsulated nanoscale materials from the point of nanochemistry and material science,and the trends of development in this field. As the research of the properties of this kind of materials are gomg on. it is possible that this kind of host-guest nanocomposite materials will be usd in some fields. such as science and high technology fields. as the new type of ptical. electrical and magnetic materials in the level of molecular assembly. This paper contains the following contents:hosts and guests; the sizes and shapes of guests; the optical, electrical and magnetic properties of the materials; the syntheses and characterizations of the materials; the applications of the materials and forecast.
文摘Tris(bipyridine)ruthenium(Ⅱ)(Ru(bpy) 2+ 3) was incorporated into mesoporous silicate MCM 48. X ray diffraction and emission spectroscopy were used to investigate the products, Ru(bpy) 2+ 3/MCM 48. The emission spectra show that the wavelength of maximum intensity( λ max ) for Ru(bpy) 2+ 3 increases with the increase of Ru(bpy) 2+ 3 loading level in MCM 48. The photoluminescent property of Ru(bpy) 2+ 3/MCM 48 was investigated. It was observed that the wavelength maximum intensity( λ max ) for Ru(bpy) 2+ 3/MCM 48 was red shifted when acetone vapor was introduced. [WT5HZ]
