固体核磁共振谱仪是目前研究固体和软物质材料结构和动力学的有力工具,在近年的工作中,在固体核磁共振谱仪上系统构建了用于高分子材料结构与动力学检测的系列多尺度核磁共振（nuclear magnetic resonance,NMR）实验技术,丰富和完善了NM...固体核磁共振谱仪是目前研究固体和软物质材料结构和动力学的有力工具,在近年的工作中,在固体核磁共振谱仪上系统构建了用于高分子材料结构与动力学检测的系列多尺度核磁共振（nuclear magnetic resonance,NMR）实验技术,丰富和完善了NMR谱仪的实验功能并拓展了其应用范围。这项工作充分发挥了NMR的潜在功能,提高了仪器的利用效率。通过制定完善的谱仪操作规程、实验室管理及学生的培训制度,保证了仪器的安全高效运行和学生实验能力的培养。通过积极对外开放交流,推动国内固体NMR在各学科领域的应用。展开更多
A new ligand N,N′-bis(2-methelene-1,10-phenanthroline)-3,6-dioxa-1,8-octaneethylenediamine(L) and the corresponding complexes LaL, LaL(Phe), and LaL( Try) were synthesized. The interaction of the complexes with calf ...A new ligand N,N′-bis(2-methelene-1,10-phenanthroline)-3,6-dioxa-1,8-octaneethylenediamine(L) and the corresponding complexes LaL, LaL(Phe), and LaL( Try) were synthesized. The interaction of the complexes with calf thymus DNA was studied by means of electronic absorbance spectra, flurescence spectra, circula r dichroic spectra and viscosity experiments. All the results indicate that the complexes may interact mainly with calf thymus DNA by intercalation and coordina tion binding.展开更多
文摘固体核磁共振谱仪是目前研究固体和软物质材料结构和动力学的有力工具,在近年的工作中,在固体核磁共振谱仪上系统构建了用于高分子材料结构与动力学检测的系列多尺度核磁共振（nuclear magnetic resonance,NMR）实验技术,丰富和完善了NMR谱仪的实验功能并拓展了其应用范围。这项工作充分发挥了NMR的潜在功能,提高了仪器的利用效率。通过制定完善的谱仪操作规程、实验室管理及学生的培训制度,保证了仪器的安全高效运行和学生实验能力的培养。通过积极对外开放交流,推动国内固体NMR在各学科领域的应用。
文摘A new ligand N,N′-bis(2-methelene-1,10-phenanthroline)-3,6-dioxa-1,8-octaneethylenediamine(L) and the corresponding complexes LaL, LaL(Phe), and LaL( Try) were synthesized. The interaction of the complexes with calf thymus DNA was studied by means of electronic absorbance spectra, flurescence spectra, circula r dichroic spectra and viscosity experiments. All the results indicate that the complexes may interact mainly with calf thymus DNA by intercalation and coordina tion binding.
