The effects of reaction conditions on the direct synthesis of dimethylcarbonate(DMC) from carbon dioxide and methanol in the presence of magnesium methoxide have been studied. The results indicate that the introductio...The effects of reaction conditions on the direct synthesis of dimethylcarbonate(DMC) from carbon dioxide and methanol in the presence of magnesium methoxide have been studied. The results indicate that the introduction of iodomethane increases the yield of DMC efficiently and lowers the reaction temperature. The addition of water absorption agents also brings about the increase of DMC yield. The reaction conversion can be enhanced under the nitrogen atmosphere.展开更多
文摘The effects of reaction conditions on the direct synthesis of dimethylcarbonate(DMC) from carbon dioxide and methanol in the presence of magnesium methoxide have been studied. The results indicate that the introduction of iodomethane increases the yield of DMC efficiently and lowers the reaction temperature. The addition of water absorption agents also brings about the increase of DMC yield. The reaction conversion can be enhanced under the nitrogen atmosphere.