The reaction of FeCo2 （CO）9(μ3-S ) with O [P（SCH2）2]2 ligand in mixed solvents of hexane and dichloromethane at 50℃ leads to the compound FeCo2 （CO）7 （μ3）-S) （O [P（SCH2）2]2）. The compound has been chara...The reaction of FeCo2 （CO）9(μ3-S ) with O [P（SCH2）2]2 ligand in mixed solvents of hexane and dichloromethane at 50℃ leads to the compound FeCo2 （CO）7 （μ3）-S) （O [P（SCH2）2]2）. The compound has been characterized by element analysis, IR, 1H NMR, MS spectfa and a single crystal X-ray structure determination.Its structure consists, of a distorted tetrthedral core FeCo2S in which the Co（1）, Co（2）, Fe, and S atoms occupy a vertex of the tetrahedron respectively, and the P atoms of O [P（SCH2）2]2 bonded to two Co atoms in their axial positions.展开更多
The title compound Fe3（CO）8（C6H5NC）（μ3-S）2 （Ⅰ） was synthesized bythe reaction of C6H5NCS with Fe3（CO）12 at room temperature. The crystal andmolecular structure of the title compound were determined by sing...The title compound Fe3（CO）8（C6H5NC）（μ3-S）2 （Ⅰ） was synthesized bythe reaction of C6H5NCS with Fe3（CO）12 at room temperature. The crystal andmolecular structure of the title compound were determined by single ctystal diffratttionmethod- Crystal data: monoclinic, space group P21/C, a=12．718（4）A, b=26.164（10）A,c=l3.741（7）A, β=117.18（2） °, V=4067（2）A3, Z=8, Dc=1．825 g/cm3. The structure wassolved by direct method and difference Fourier synthesis, and refined by full-matrix Leastsquares with anisotropic thermal paramaters, using 1990 observed reflections [Ⅰ＞3σ（Ⅰ）].The final residual factor was R＝0．076, Rw＝0．082. The substituted ligand （C6H5NC）in Fe3（CO）8（C6H5NC）（μ3-S）2 is connected to the Fe（3） atom of the distorted tetragonalpyramid Fe3S2 framework.展开更多
文摘The reaction of FeCo2 （CO）9(μ3-S ) with O [P（SCH2）2]2 ligand in mixed solvents of hexane and dichloromethane at 50℃ leads to the compound FeCo2 （CO）7 （μ3）-S) （O [P（SCH2）2]2）. The compound has been characterized by element analysis, IR, 1H NMR, MS spectfa and a single crystal X-ray structure determination.Its structure consists, of a distorted tetrthedral core FeCo2S in which the Co（1）, Co（2）, Fe, and S atoms occupy a vertex of the tetrahedron respectively, and the P atoms of O [P（SCH2）2]2 bonded to two Co atoms in their axial positions.
文摘The title compound Fe3（CO）8（C6H5NC）（μ3-S）2 （Ⅰ） was synthesized bythe reaction of C6H5NCS with Fe3（CO）12 at room temperature. The crystal andmolecular structure of the title compound were determined by single ctystal diffratttionmethod- Crystal data: monoclinic, space group P21/C, a=12．718（4）A, b=26.164（10）A,c=l3.741（7）A, β=117.18（2） °, V=4067（2）A3, Z=8, Dc=1．825 g/cm3. The structure wassolved by direct method and difference Fourier synthesis, and refined by full-matrix Leastsquares with anisotropic thermal paramaters, using 1990 observed reflections [Ⅰ＞3σ（Ⅰ）].The final residual factor was R＝0．076, Rw＝0．082. The substituted ligand （C6H5NC）in Fe3（CO）8（C6H5NC）（μ3-S）2 is connected to the Fe（3） atom of the distorted tetragonalpyramid Fe3S2 framework.
