Metal-organic framework(MOF)nanostructures have emerged as a prominent class of materials in the advancement of electrochemical sensors.The rational design of bimetallic MOF-functionalized microelectrode is of importa...Metal-organic framework(MOF)nanostructures have emerged as a prominent class of materials in the advancement of electrochemical sensors.The rational design of bimetallic MOF-functionalized microelectrode is of importance for improv-ing the electrochemical performance but still in great challenge.In this work,the bimetallic FeCo-MOF nanostructures were assembled onto a gold disk ultramicroelectrode(Au UME,5.2μm in diameter)via an in-situ electrodeposition method,which enhanced the sensitive detection of epinephrine(EP).The in-situ electrodeposited FeCo-MOF exhibited a character-istic nanoflower-like morphology and was uniformly dispersed on the Au UME.The FeCo-MOF/Au UME demonstrated excellent electrochemical performance on the detection of EP with a high sensitivity of 36.93μA·μmol^(-1)·L·cm^(-2)and a low detection limit of 1.28μmol·L^(-1).It can be attributed to the nonlinear diffusion of EP onto the ultra-micro working substrate,coupled with synergistical catalytic activity of the bimetallic Fe,Co within MOF structure.Furthermore,the FeCo-MOF/Au UME has been successful applied to the analysis of EP in human serum samples,yielding high recovery rates.These results not only contribute to the expansion of the research area of electrochemical sensors,but also provide novel insights and directions into the development of high-performance MOF-based electrochemical sensors.展开更多
了解磁结构对于深入探究磁性材料中的磁行为及其相关现象具有至关重要的意义。四维扫描透射电子显微镜(four⁃dimensional scanning transmission electron microscopy,4D⁃STEM)技术的出现,为定量分析磁场提供了一种全新的技术手段,特别...了解磁结构对于深入探究磁性材料中的磁行为及其相关现象具有至关重要的意义。四维扫描透射电子显微镜(four⁃dimensional scanning transmission electron microscopy,4D⁃STEM)技术的出现,为定量分析磁场提供了一种全新的技术手段,特别是通过精确定位衍射盘的位置,来解析磁场在纳米尺度上的分布情况。本文介绍了一款集成了多种衍射盘定位算法的Python程序包,并通过对实验数据的分析,探讨了该程序包中核心算法的性能及其适用场景。展开更多
基金support from the National Key Research and Development Program of China(2021YFB3201400,2021YFB3201401,2020YFC1908602)the National Natural Science Foundation of China(21904001 and 61774159)+1 种基金the Anhui Provincial Natural Science Foundation(2008085QF288)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Anhui Province(2020LCX032).
文摘Metal-organic framework(MOF)nanostructures have emerged as a prominent class of materials in the advancement of electrochemical sensors.The rational design of bimetallic MOF-functionalized microelectrode is of importance for improv-ing the electrochemical performance but still in great challenge.In this work,the bimetallic FeCo-MOF nanostructures were assembled onto a gold disk ultramicroelectrode(Au UME,5.2μm in diameter)via an in-situ electrodeposition method,which enhanced the sensitive detection of epinephrine(EP).The in-situ electrodeposited FeCo-MOF exhibited a character-istic nanoflower-like morphology and was uniformly dispersed on the Au UME.The FeCo-MOF/Au UME demonstrated excellent electrochemical performance on the detection of EP with a high sensitivity of 36.93μA·μmol^(-1)·L·cm^(-2)and a low detection limit of 1.28μmol·L^(-1).It can be attributed to the nonlinear diffusion of EP onto the ultra-micro working substrate,coupled with synergistical catalytic activity of the bimetallic Fe,Co within MOF structure.Furthermore,the FeCo-MOF/Au UME has been successful applied to the analysis of EP in human serum samples,yielding high recovery rates.These results not only contribute to the expansion of the research area of electrochemical sensors,but also provide novel insights and directions into the development of high-performance MOF-based electrochemical sensors.
文摘了解磁结构对于深入探究磁性材料中的磁行为及其相关现象具有至关重要的意义。四维扫描透射电子显微镜(four⁃dimensional scanning transmission electron microscopy,4D⁃STEM)技术的出现,为定量分析磁场提供了一种全新的技术手段,特别是通过精确定位衍射盘的位置,来解析磁场在纳米尺度上的分布情况。本文介绍了一款集成了多种衍射盘定位算法的Python程序包,并通过对实验数据的分析,探讨了该程序包中核心算法的性能及其适用场景。
