The utilization of perovskite oxide materials as catalysts for the photodegradation of organic pollutants in water is a promising and rapidly advancing field.In this study,a series of La_(1−x)Ba_(x)CoO_(3)(x=0.2,0.3,0...The utilization of perovskite oxide materials as catalysts for the photodegradation of organic pollutants in water is a promising and rapidly advancing field.In this study,a series of La_(1−x)Ba_(x)CoO_(3)(x=0.2,0.3,0.4,0.5,0.6)catalysts with varying Ba doping ratios were synthesized using the citric acid complexation-hydrothermal synthesis combined method for the degradation of phenol under visible light irradiation.Among the synthesized catalysts,La_(0.5)Ba_(0.5)CoO_(3) exhibited the highest photocatalytic activity.In addition,the photocatalytic mechanism for La_(0.5)Ba_(0.5)CoO_(3) perovskite degradation of phenol was also discussed.The synthesized catalysts were characterized using XRD,SEM,FT-IR,XPS,MPMS and other characterization techniques.The results revealed that the diffraction peak intensity of La_(1−x)Ba_(x)CoO_(3) increased with higher Ba doping ratios,and the La_(0.4)Ba_(0.6)CoO_(3) exhibited the strongest diffraction peaks.The catalyst particle sizes ranged from 10 to 50 nm,and the specific surface area decreased with increasing Ba content.Additionally,the paramagnetic properties of La_(0.5)Ba_(0.5)CoO_(3) were similar to that of La_(0.4)Ba_(0.6)CoO_(3).The experimental results suggested that the incorporation of Ba could significantly improve the catalytic performance of La_(1−x)Ba_(x)CoO_(3) perovskites,promote electron transfer and favor to the generation of hydroxyl radicals(•OH),leading to the efficiently degradation of phenol.展开更多
以海上甚高频(Very High Frequency,VHF)宽带数据通信网络为研究对象,结合海上通信环境的特有属性,利用电磁波相关理论,在合理选用和优化现有独立分散数学模型的基础上,设计完整而简洁的海上VHF通信传输损耗模型、确定有效可行的海上VH...以海上甚高频(Very High Frequency,VHF)宽带数据通信网络为研究对象,结合海上通信环境的特有属性,利用电磁波相关理论,在合理选用和优化现有独立分散数学模型的基础上,设计完整而简洁的海上VHF通信传输损耗模型、确定有效可行的海上VHF通信传输损耗计算流程。对影响传输损耗的相关物理因素进行建模,给出相应的计算结果,并分析其与传输损耗间的关系。计算结果表明:随着传输距离增加,海上VHF通信传输损耗的增长幅度在不同的距离区段内具有不同的波动特征。计算结果有助于在具有较少的先验信息的条件下快捷地计算出海上VHF通信传输损耗,为提升海上无线通信质量、设计并建立海上VHF宽带数据通信系统提供技术支撑。展开更多
为改进传统的海上甚高频(Very High Frequency,VHF)的模拟通信方式,实现海上通信现代化,针对国际灯塔与航标协会(International Association of Lighthouse Authorities,IALA)和国际海事组织(International Maritime Organization,IMO)...为改进传统的海上甚高频(Very High Frequency,VHF)的模拟通信方式,实现海上通信现代化,针对国际灯塔与航标协会(International Association of Lighthouse Authorities,IALA)和国际海事组织(International Maritime Organization,IMO)提出的VHF数据通信系统(VHF Data Exchange System,VDES)研究计划,建立基于正交频分复用(Orthogonal Frequency Division Multiplexing,OFDM)的数据传输模型.海上无线信道的多径时延的确定是建立OFDM系统的关键,因此通过建立海上无线信道的多径传播模型分析和计算海上无线信道的多径时延.通过实验证明,该方法能够获得较低的误码率,有效实现海上VHF数据通信.展开更多
基金The Fundamental Research Program for Young Scientists of Shanxi Province(Project No.202103021223294)The Fundamental Research Program of Shanxi Province(Project No.202203021211203)+1 种基金The Start-up Fund for Doctorate Scientific Research Project of Taiyuan University of Science and Technology(Project No.20232124)The Innovation and Entrepreneurship Training Program for Undergraduate,Taiyuan University of Science and Technology(Project No.DCX2024162).
文摘The utilization of perovskite oxide materials as catalysts for the photodegradation of organic pollutants in water is a promising and rapidly advancing field.In this study,a series of La_(1−x)Ba_(x)CoO_(3)(x=0.2,0.3,0.4,0.5,0.6)catalysts with varying Ba doping ratios were synthesized using the citric acid complexation-hydrothermal synthesis combined method for the degradation of phenol under visible light irradiation.Among the synthesized catalysts,La_(0.5)Ba_(0.5)CoO_(3) exhibited the highest photocatalytic activity.In addition,the photocatalytic mechanism for La_(0.5)Ba_(0.5)CoO_(3) perovskite degradation of phenol was also discussed.The synthesized catalysts were characterized using XRD,SEM,FT-IR,XPS,MPMS and other characterization techniques.The results revealed that the diffraction peak intensity of La_(1−x)Ba_(x)CoO_(3) increased with higher Ba doping ratios,and the La_(0.4)Ba_(0.6)CoO_(3) exhibited the strongest diffraction peaks.The catalyst particle sizes ranged from 10 to 50 nm,and the specific surface area decreased with increasing Ba content.Additionally,the paramagnetic properties of La_(0.5)Ba_(0.5)CoO_(3) were similar to that of La_(0.4)Ba_(0.6)CoO_(3).The experimental results suggested that the incorporation of Ba could significantly improve the catalytic performance of La_(1−x)Ba_(x)CoO_(3) perovskites,promote electron transfer and favor to the generation of hydroxyl radicals(•OH),leading to the efficiently degradation of phenol.
文摘以海上甚高频(Very High Frequency,VHF)宽带数据通信网络为研究对象,结合海上通信环境的特有属性,利用电磁波相关理论,在合理选用和优化现有独立分散数学模型的基础上,设计完整而简洁的海上VHF通信传输损耗模型、确定有效可行的海上VHF通信传输损耗计算流程。对影响传输损耗的相关物理因素进行建模,给出相应的计算结果,并分析其与传输损耗间的关系。计算结果表明:随着传输距离增加,海上VHF通信传输损耗的增长幅度在不同的距离区段内具有不同的波动特征。计算结果有助于在具有较少的先验信息的条件下快捷地计算出海上VHF通信传输损耗,为提升海上无线通信质量、设计并建立海上VHF宽带数据通信系统提供技术支撑。
文摘为改进传统的海上甚高频(Very High Frequency,VHF)的模拟通信方式,实现海上通信现代化,针对国际灯塔与航标协会(International Association of Lighthouse Authorities,IALA)和国际海事组织(International Maritime Organization,IMO)提出的VHF数据通信系统(VHF Data Exchange System,VDES)研究计划,建立基于正交频分复用(Orthogonal Frequency Division Multiplexing,OFDM)的数据传输模型.海上无线信道的多径时延的确定是建立OFDM系统的关键,因此通过建立海上无线信道的多径传播模型分析和计算海上无线信道的多径时延.通过实验证明,该方法能够获得较低的误码率,有效实现海上VHF数据通信.
