The determinations of rate constant ,activation energy and equilibrium constant of complexation reaction between CuTBP,CoTBP and imidazole ,pyridine ,2-methyprdine and 2,4-dimethypridine with spectrophotography were s...The determinations of rate constant ,activation energy and equilibrium constant of complexation reaction between CuTBP,CoTBP and imidazole ,pyridine ,2-methyprdine and 2,4-dimethypridine with spectrophotography were studied in this paper.The influences of basicity of ligand and space sterically hindered on the complexation reaction were discussed and the changes of ultraviolet-visible spectra of complexation reaction were given.展开更多
文摘The determinations of rate constant ,activation energy and equilibrium constant of complexation reaction between CuTBP,CoTBP and imidazole ,pyridine ,2-methyprdine and 2,4-dimethypridine with spectrophotography were studied in this paper.The influences of basicity of ligand and space sterically hindered on the complexation reaction were discussed and the changes of ultraviolet-visible spectra of complexation reaction were given.
