(2+1) resonan multiphoton ionization of photolytically produced CH radical yields previously unobserved bands arising from two-photon transition to Rydberg states. Analysing of the spectrum of CH+, three new states ar...(2+1) resonan multiphoton ionization of photolytically produced CH radical yields previously unobserved bands arising from two-photon transition to Rydberg states. Analysing of the spectrum of CH+, three new states are identified. They are 8 d, 9 d and 10 d Rydberg states, respectively.展开更多
The two-photon resonance-enhanced multiphoton ionization spectrum between 285 and288.5 nm of the band of CF radical is reported. The band isrotationally analyzed, and the spectroscopic constants of the state are first...The two-photon resonance-enhanced multiphoton ionization spectrum between 285 and288.5 nm of the band of CF radical is reported. The band isrotationally analyzed, and the spectroscopic constants of the state are first derived:σ0 = 69566.38±0.52 cm-1, A’v= 46.4±0.3 cm-1, B’v= 2.565±0.017 cm-1, D’V= (8.6±1.2)×10-6cm-1.展开更多
文摘(2+1) resonan multiphoton ionization of photolytically produced CH radical yields previously unobserved bands arising from two-photon transition to Rydberg states. Analysing of the spectrum of CH+, three new states are identified. They are 8 d, 9 d and 10 d Rydberg states, respectively.
文摘The two-photon resonance-enhanced multiphoton ionization spectrum between 285 and288.5 nm of the band of CF radical is reported. The band isrotationally analyzed, and the spectroscopic constants of the state are first derived:σ0 = 69566.38±0.52 cm-1, A’v= 46.4±0.3 cm-1, B’v= 2.565±0.017 cm-1, D’V= (8.6±1.2)×10-6cm-1.
