The post structure aligned carbon nanotube(ACNT) film was prepared by CVD. it was a ultra-hydrophobic film with a higher contact angle(166°) and lower sliding angle(less than 3°). The post structure ACNT fil...The post structure aligned carbon nanotube(ACNT) film was prepared by CVD. it was a ultra-hydrophobic film with a higher contact angle(166°) and lower sliding angle(less than 3°). The post structure ACNT film showed discrete pillar composed of carbon nanotubes, these pillar formed microstructure in the film, which affected both the contact angle and the sliding angle.展开更多
Wettability is a very important property governed by both the chemical composition and the geometrical structure of solid surfaces. Super-hydrophobic surface[with water contact angle(CA) larger than 150°] have be...Wettability is a very important property governed by both the chemical composition and the geometrical structure of solid surfaces. Super-hydrophobic surface[with water contact angle(CA) larger than 150°] have been extensively investigated due to their importance for industrial applications. In the present study, we describe a rather simple method for synthesizing separated alignments of polymer nanopole films, which has super-hydrophobic property with water a contact angle as high as 152.0°. Nanostructures that induce the large fraction of air on the surface cause this unique property.展开更多
A new photochromic complex of Keggin type tungstophosphate acid/polyvinyl pyrrolidone system was prepared, and its thin films was made by the dipping method. Their photochromic properties were investigated by FTIR, UV...A new photochromic complex of Keggin type tungstophosphate acid/polyvinyl pyrrolidone system was prepared, and its thin films was made by the dipping method. Their photochromic properties were investigated by FTIR, UV Vis spectra. The salts were formed by the combination of the ion based on the N atoms in the polymeric molecules and H + of the acids. The UV Vis spectra showed that this type of system had an excellent photochromic behavior. The g values of ESR spectra for the one electron blues were the characteristic of tetragonal W(Ⅴ) complex in colored thin film. It was indicated that the charge could be transferred between the anion and cation under irradiation of UV light and the result in the oxidation of the cation and the reduction of the anion.展开更多
文摘The post structure aligned carbon nanotube(ACNT) film was prepared by CVD. it was a ultra-hydrophobic film with a higher contact angle(166°) and lower sliding angle(less than 3°). The post structure ACNT film showed discrete pillar composed of carbon nanotubes, these pillar formed microstructure in the film, which affected both the contact angle and the sliding angle.
文摘Wettability is a very important property governed by both the chemical composition and the geometrical structure of solid surfaces. Super-hydrophobic surface[with water contact angle(CA) larger than 150°] have been extensively investigated due to their importance for industrial applications. In the present study, we describe a rather simple method for synthesizing separated alignments of polymer nanopole films, which has super-hydrophobic property with water a contact angle as high as 152.0°. Nanostructures that induce the large fraction of air on the surface cause this unique property.
文摘A new photochromic complex of Keggin type tungstophosphate acid/polyvinyl pyrrolidone system was prepared, and its thin films was made by the dipping method. Their photochromic properties were investigated by FTIR, UV Vis spectra. The salts were formed by the combination of the ion based on the N atoms in the polymeric molecules and H + of the acids. The UV Vis spectra showed that this type of system had an excellent photochromic behavior. The g values of ESR spectra for the one electron blues were the characteristic of tetragonal W(Ⅴ) complex in colored thin film. It was indicated that the charge could be transferred between the anion and cation under irradiation of UV light and the result in the oxidation of the cation and the reduction of the anion.
