The hyperfine red phosphors,NaEu(MoO4)2,were synthesized by hydrothermal and subsequent heat-treatment processes.The NaEu(MoO4)2 phosphors show regular elliptical morphologies,and the particle sizes of 0.25～0.3 μm.T...The hyperfine red phosphors,NaEu(MoO4)2,were synthesized by hydrothermal and subsequent heat-treatment processes.The NaEu(MoO4)2 phosphors show regular elliptical morphologies,and the particle sizes of 0.25～0.3 μm.The excitation spectra located at short-wavelength UV region belong to the interweave broad charge transfer bands of Mo6+-O2-and Eu3+-O2-,and the three sharp lines around 395 nm,465 nm and 535 nm are ascribed to the Eu3+ 4f excitation transitions.All of the samples can be excited with near-UV 395 nm light and exhibit the characteristic red emission of Eu3+ 5D0→7F2transition.The relative red emission intensities of the optimum phosphors reach two-fold as compared with that of the commercial phosphors.The submicro-phosphors may be applied as red phosphors for white light emitting diodes.展开更多
目前,钙钛矿太阳能电池(perovskite solar cell,PSC)的效率(25.8%)已经可以与硅基太阳能电池相媲美,但是长期稳定性不高是其开展商业化应用亟需解决的问题之一.电化学聚合作为一种制备电活性导电聚合物薄膜的方法,可以有效降低材料和器...目前,钙钛矿太阳能电池(perovskite solar cell,PSC)的效率(25.8%)已经可以与硅基太阳能电池相媲美,但是长期稳定性不高是其开展商业化应用亟需解决的问题之一.电化学聚合作为一种制备电活性导电聚合物薄膜的方法,可以有效降低材料和器件制备的成本;同时,化学交联的电聚合薄膜具有较好的稳定性,能有效提高器件的稳定性.总结了将交联的电聚合薄膜作为空穴传输层(hole transporting layer,HTL)或电子传输层(electron transporting layer,ETL)来开发稳定和高效的钙钛矿太阳能电池,并论述了电聚合薄膜在钙钛矿太阳能电池未来的研究重点.展开更多
文摘The hyperfine red phosphors,NaEu(MoO4)2,were synthesized by hydrothermal and subsequent heat-treatment processes.The NaEu(MoO4)2 phosphors show regular elliptical morphologies,and the particle sizes of 0.25～0.3 μm.The excitation spectra located at short-wavelength UV region belong to the interweave broad charge transfer bands of Mo6+-O2-and Eu3+-O2-,and the three sharp lines around 395 nm,465 nm and 535 nm are ascribed to the Eu3+ 4f excitation transitions.All of the samples can be excited with near-UV 395 nm light and exhibit the characteristic red emission of Eu3+ 5D0→7F2transition.The relative red emission intensities of the optimum phosphors reach two-fold as compared with that of the commercial phosphors.The submicro-phosphors may be applied as red phosphors for white light emitting diodes.
基金supported by the National Key Basic Research Program of China(973)(2006CB202605)National High-Tech Research and Development Program of China(863)(2007AA05Z439)National Natural Science Foundation of China(20973183)~~
基金supported by the National Natural Science Foundation of China(Nos.91227104,21271176,21472196,21501183,and21521062)the National Basic Research 973 program of China(No.S 2011CB932301 and 2011CB808402)the"Hundred Talent"Program and the Strategic Priority Research Program(No.XDB 12010400)of the Chinese Academy of Sciences
基金supported by the National Key Basic Research Program of China(973)(2006CB202605)High-Tech Research and Development Program of China(983)(2007AA05Z439)National Natural Science Foundation of China(20973183)~~
基金supported by the National Natural Science Foundation of China(20873162)State Key Laboratory of Pollution Control and Resource Reuse Foundation of China(PCRRF09006)~~
