Ni-WC composite coating was obtained by using composite electrodeposition technique. The behavior of Ni-WC composite coating used as cathode material for hydro gen evolution reaction (HER) in a medium of 0.1 mol .L-1H...Ni-WC composite coating was obtained by using composite electrodeposition technique. The behavior of Ni-WC composite coating used as cathode material for hydro gen evolution reaction (HER) in a medium of 0.1 mol .L-1H2SO4+0.5mol.L-1 Na2SO4 was inverstigated. The experimental results show that the catalytic activity of Ni-WC composite electrode for HER in weak acidic medium is appearently higher than that of the electrode plated with Ni and is increased with the increasing of WC content in the coating. As compared with Ni plated electrode, the increase in catalytic activity of the composite electrode for HER should be attributed to the dispersion of WC particles in the Ni deposit, since the mechanism of HER for the two kinds of electrodes is the same.Owing to the incorporation of WC particles in Ni deposit, the standard activation free enthalpy for HER is decreased, and the defects and dislocations in the crystal sturcture of the composite coating are increased. This is equivalent to the addition of catalysis accelerator WC in the catalyst Ni.展开更多
本文是[1]的续篇。关于问题的含义以及有关概念与结果,都请参看该文,这里不再重复。本文讨论一种称为分组格的特殊可补格,得到了关于分组格按同型关系分类的一些初步结果。设 L 为一可补格,若存在 n 个子可补格 L1,…,Ln 适合:（i）每一...本文是[1]的续篇。关于问题的含义以及有关概念与结果,都请参看该文,这里不再重复。本文讨论一种称为分组格的特殊可补格,得到了关于分组格按同型关系分类的一些初步结果。设 L 为一可补格,若存在 n 个子可补格 L1,…,Ln 适合:（i）每一 Li都含有0、I 以外的元。展开更多
文摘Ni-WC composite coating was obtained by using composite electrodeposition technique. The behavior of Ni-WC composite coating used as cathode material for hydro gen evolution reaction (HER) in a medium of 0.1 mol .L-1H2SO4+0.5mol.L-1 Na2SO4 was inverstigated. The experimental results show that the catalytic activity of Ni-WC composite electrode for HER in weak acidic medium is appearently higher than that of the electrode plated with Ni and is increased with the increasing of WC content in the coating. As compared with Ni plated electrode, the increase in catalytic activity of the composite electrode for HER should be attributed to the dispersion of WC particles in the Ni deposit, since the mechanism of HER for the two kinds of electrodes is the same.Owing to the incorporation of WC particles in Ni deposit, the standard activation free enthalpy for HER is decreased, and the defects and dislocations in the crystal sturcture of the composite coating are increased. This is equivalent to the addition of catalysis accelerator WC in the catalyst Ni.
