Significant progress has recently been made in enhancing the power conversion efficiency(PCE)of perovskite solar cells(PSCs).The electron transport layer(ETL),as an essential component of PSCs,significantly influences...Significant progress has recently been made in enhancing the power conversion efficiency(PCE)of perovskite solar cells(PSCs).The electron transport layer(ETL),as an essential component of PSCs,significantly influences the performance of devices.Traditional spin-coating method for preparing the ETL fails to fully cover the cusp of FTO transparent conductive glass substrate,leading to direct contact between perovskite film and FTO substrate,which induces charge recombination and reduces the performance of PSCs.To address this issue,an in-situ growth method was proposed to prepare conformal SnO_(2) films on FTO glass substrates in this study.The resulting SnO_(2) films are not only dense and uniform,fully covering the cusp of the FTO glass substrates and reducing the contact area between the FTO substrates and the perovskite films,but also facilitating the formation of perovskite films with large grain sizes.Moreover,the conformal SnO_(2) films can improve the charge extraction at the SnO_(2)/perovskite interface,reduce the trap density and trap-assisted recombination in PSCs,and thus enhance the PCE of PSCs.Through comparative experiments,it is found that the PSCs with in-situ grown SnO_(2) films show an improved PCE of 21.97%,which significantly increased compared to that with spin-coated SnO_(2) films(20.93%).All above data demonstrate that the as-prepared SnO_(2) film can serve as an ideal ETL.It is worth mentioning that this method avoids the use of corrosive hydrochloric acid and toxic thioglycolic acid,and it can also be extended to ITO flexible transparent conductive substrates in the future.展开更多
基金Space Application System of China Manned Space Program。
文摘Significant progress has recently been made in enhancing the power conversion efficiency(PCE)of perovskite solar cells(PSCs).The electron transport layer(ETL),as an essential component of PSCs,significantly influences the performance of devices.Traditional spin-coating method for preparing the ETL fails to fully cover the cusp of FTO transparent conductive glass substrate,leading to direct contact between perovskite film and FTO substrate,which induces charge recombination and reduces the performance of PSCs.To address this issue,an in-situ growth method was proposed to prepare conformal SnO_(2) films on FTO glass substrates in this study.The resulting SnO_(2) films are not only dense and uniform,fully covering the cusp of the FTO glass substrates and reducing the contact area between the FTO substrates and the perovskite films,but also facilitating the formation of perovskite films with large grain sizes.Moreover,the conformal SnO_(2) films can improve the charge extraction at the SnO_(2)/perovskite interface,reduce the trap density and trap-assisted recombination in PSCs,and thus enhance the PCE of PSCs.Through comparative experiments,it is found that the PSCs with in-situ grown SnO_(2) films show an improved PCE of 21.97%,which significantly increased compared to that with spin-coated SnO_(2) films(20.93%).All above data demonstrate that the as-prepared SnO_(2) film can serve as an ideal ETL.It is worth mentioning that this method avoids the use of corrosive hydrochloric acid and toxic thioglycolic acid,and it can also be extended to ITO flexible transparent conductive substrates in the future.
