Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide(MoS_(2)).MoS_(2)-based composites are usually used for the electromagnetic wave(EMW)absorber,but the effect of di...Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide(MoS_(2)).MoS_(2)-based composites are usually used for the electromagnetic wave(EMW)absorber,but the effect of different phases on the EMW absorbing performance,such as 1T and 2H phase,is still not studied.In this work,micro-1T/2H MoS_(2) is achieved via a facile one-step hydrother-mal route,in which the 1T phase is induced by the intercalation of guest molecules and ions.The EMW absorption mechanism of single MoS_(2) is revealed by presenting a comparative study between 1T/2H MoS_(2) and 2H MoS_(2).As a result,1T/2H MoS_(2) with the matrix loading of 15%exhibits excellent microwave absorption property than 2H MoS_(2).Furthermore,taking the advantage of 1T/2H MoS_(2),a flexible EMW absorbers that ultrathin 1T/2H MoS_(2)grown on the carbon fiber also performs outstanding performance only with the matrix loading of 5%.This work offers necessary reference to improve microwave absorption performance by phase engineering and design a new type of flexible electromagnetic wave absorption material to apply for the portable microwave absorption electronic devices.展开更多
Cobalt nickel bimetallic oxides(NiCo_(2)O_(4))have received numerous attentions in terms of their controllable morphology,high temperature,corrosion resistance and strong electromagnetic wave(EMW)absorption capability...Cobalt nickel bimetallic oxides(NiCo_(2)O_(4))have received numerous attentions in terms of their controllable morphology,high temperature,corrosion resistance and strong electromagnetic wave(EMW)absorption capability.However,broadening the absorption bandwidth is still a huge challenge for NiCo_(2)O_(4)-based absorbers.Herein,the unique NiCo_(2)O_(4)@C core-shell microcubes with hollow structures were fabricated via a facile sacrificial template strategy.The concentration of oxygen vacancies and morphologies of the three-dimensional(3D)cubic hollow core-shell NiCo_(2)O_(4)@C framework were effectively optimized by adjusting the calcination temperature.The specially designed 3D framework structure facilitated the multiple reflections of incident electromagnetic waves and provided rich interfaces between multiple components,generating significant interfacial polarization losses.Dipole polarizations induced by oxygen vacancies could further enhance the attenuation ability for the incident EM waves.The optimized NiCo_(2)O_(4)@C hollow microcubes exhibit superior EMW absorption capability with minimum RL(RLmin)of-84.45 dB at 8.4 GHz for the thickness of 3.0 mm.Moreover,ultrabroad effective absorption bandwidth(EAB)as large as 12.48 GHz(5.52-18 GHz)is obtained.This work is believed to illuminate the path to synthesis of high-performance cobalt nickel bimetallic oxides for EMW absorbers with excellent EMW absorption capability,especially in broadening effective absorption bandwidth.展开更多
Electromagnetic wave(EMW)absorbing materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control.And in order to cope with the complex electroma...Electromagnetic wave(EMW)absorbing materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control.And in order to cope with the complex electromagnetic environment,the design of multifunctional and multiband high efficiency EMW absorbers remains a tremendous challenge.In this work,we designed a three-dimensional porous structure via the salt melt synthesis strategy to optimize the impedance matching of the absorber.Also,through interfacial engineering,a molybdenum carbide transition layer was introduced between the molybdenum selenide nanoparticles and the three-dimensional porous carbon matrix to improve the absorption behavior of the absorber.The analysis indicates that the number and components of the heterogeneous interfaces have a significant impact on the EMW absorption performance of the absorber due to mechanisms such as interfacial polarization and conduction loss introduced by interfacial engineering.Wherein,the prepared MoSe_(2)/MoC/PNC composites showed excellent EMW absorption performance in C,X,and Ku bands,especially exhibiting a reflection loss of−59.09 dB and an effective absorption bandwidth of 6.96 GHz at 1.9 mm.The coordination between structure and components endows the absorber with strong absorption,broad bandwidth,thin thickness,and multi-frequency absorption characteristics.Remarkably,it can effectively reinforce the marine anticorrosion property of the epoxy resin coating on Q235 steel substrate.This study contributes to a deeper understanding of the relationship between interfacial engineering and the performance of EMW absorbers,and provides a reference for the design of multifunctional,multiband EMW absorption materials.展开更多
An equivalent-circuit model is used to analyse the improvement of the wave absorbing performance of the lossy frequency selective surface（FSS） absorber by using a magnetic substrate,showing that it is possible to wi...An equivalent-circuit model is used to analyse the improvement of the wave absorbing performance of the lossy frequency selective surface（FSS） absorber by using a magnetic substrate,showing that it is possible to widen the wave absorbing bandwidth.Three pieces of magnetic substrates are prepared.According to the complex permittivity and permeability,the reflectivity of the corresponding absorber is calculated by the finite difference time-domain（FDTD） method,and the bandwidth of the reflectivity below 10 dB is optimized by genetic algorithm.The calculated results indicate that the wave absorbing performance is significantly improved by increasing the complex permeability of the substrate;the reflectivity bandwidth below 10 dB of the single layer FSS absorber can reach 3.6-18 GHz with a thickness of 5 mm,which is wider than that with a dielectric substrate.The density of the FSS absorber is only 0.92 g/cm 3.Additionally,the absorption band can be further widened by inserting a second lossy FSS.Finally,a double layer lossy FSS absorber with a magnetic substrate is fabricated based on the design result.The experimental result is consistent with the design one.展开更多
A set of experiments is carried out in a towing tank to study the effects of the curvature of perforated plates on the wave reflection coefficient （Cr）. The curvature of a perforated plate can be changed by rotating...A set of experiments is carried out in a towing tank to study the effects of the curvature of perforated plates on the wave reflection coefficient （Cr）. The curvature of a perforated plate can be changed by rotating a reference perforated plate about its origin point according to the parabolic equation y=-x2 A plunger-type wave maker is used to generate regular waves. The reflection coefficients are calculated using Goda and Suzuki’s （1976） method. The results are compared with those of vertical or sloped passive wave absorbers. The comparison shows that a perforated plate with a curved profile is highly efficient in terms of reducing the wave reflection coefficient. A correlation is established to estimate the reflection coefficient of curved perforated plates as a function of both flow and geometry characteristics.展开更多
For active wave absorbers in force-control mode,the optimal feedback(control)force provided by the control system depends on the hydrodynamic forces.This work investigates a piston-type wave absorber with different dr...For active wave absorbers in force-control mode,the optimal feedback(control)force provided by the control system depends on the hydrodynamic forces.This work investigates a piston-type wave absorber with different draft-to-water depth ratios,focusing on the frequency-dependent hydrodynamic coefficients,wave absorption efficiency,wave absorber displacement and velocity,and control force.Analytical results were derived based on potential flow theory,confirming that regular incident waves can be fully absorbed by the piston-type active wave absorber at any draft ratio by optimizing the control force.The results for the wave tank with a typical water depth of 3 m were studied in detail.The draft ratio has a strong influence on the hydrodynamic coefficients.At the maximum wave absorption efficiency,the displacement and velocity amplitudes are sensitive to the draft ratio in the low-frequency region,increase with decreasing draft ratio,and are independent of the mass of the wave absorber.The control force required can be extremely large for a draft ratio greater than 1/3.The control force increases significantly as the draft ratio increases.The mass of the wave absorber has a weak influence on the control force.A time-domain numerical method based on the boundary element method was developed to verify the analytical solutions.Perfect agreements between the analytical solutions and the numerical results were obtained.展开更多
基金the National Natural Science Foundation of China(No.51672222)Joint Fund Project-Enterprise-Shaanxi Coal Joint Fund Project(2019JLM-32)+2 种基金Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(CX202054)the Graduate innovation team of Northwestern Polytechnical Universitythe Analysis and Testing Center of Northwestern Polytechnical University for their technical assistance in SEM(Verios G4).
文摘Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide(MoS_(2)).MoS_(2)-based composites are usually used for the electromagnetic wave(EMW)absorber,but the effect of different phases on the EMW absorbing performance,such as 1T and 2H phase,is still not studied.In this work,micro-1T/2H MoS_(2) is achieved via a facile one-step hydrother-mal route,in which the 1T phase is induced by the intercalation of guest molecules and ions.The EMW absorption mechanism of single MoS_(2) is revealed by presenting a comparative study between 1T/2H MoS_(2) and 2H MoS_(2).As a result,1T/2H MoS_(2) with the matrix loading of 15%exhibits excellent microwave absorption property than 2H MoS_(2).Furthermore,taking the advantage of 1T/2H MoS_(2),a flexible EMW absorbers that ultrathin 1T/2H MoS_(2)grown on the carbon fiber also performs outstanding performance only with the matrix loading of 5%.This work offers necessary reference to improve microwave absorption performance by phase engineering and design a new type of flexible electromagnetic wave absorption material to apply for the portable microwave absorption electronic devices.
基金This work was supported by Natural Science Foundation of Shandong Province(ZR2022ME089)National Natural Science Foundation of China(52207249)Yantai Basic Research Project(2022JCYJ04).
文摘Cobalt nickel bimetallic oxides(NiCo_(2)O_(4))have received numerous attentions in terms of their controllable morphology,high temperature,corrosion resistance and strong electromagnetic wave(EMW)absorption capability.However,broadening the absorption bandwidth is still a huge challenge for NiCo_(2)O_(4)-based absorbers.Herein,the unique NiCo_(2)O_(4)@C core-shell microcubes with hollow structures were fabricated via a facile sacrificial template strategy.The concentration of oxygen vacancies and morphologies of the three-dimensional(3D)cubic hollow core-shell NiCo_(2)O_(4)@C framework were effectively optimized by adjusting the calcination temperature.The specially designed 3D framework structure facilitated the multiple reflections of incident electromagnetic waves and provided rich interfaces between multiple components,generating significant interfacial polarization losses.Dipole polarizations induced by oxygen vacancies could further enhance the attenuation ability for the incident EM waves.The optimized NiCo_(2)O_(4)@C hollow microcubes exhibit superior EMW absorption capability with minimum RL(RLmin)of-84.45 dB at 8.4 GHz for the thickness of 3.0 mm.Moreover,ultrabroad effective absorption bandwidth(EAB)as large as 12.48 GHz(5.52-18 GHz)is obtained.This work is believed to illuminate the path to synthesis of high-performance cobalt nickel bimetallic oxides for EMW absorbers with excellent EMW absorption capability,especially in broadening effective absorption bandwidth.
基金the Surface Project of Local Development in Science and Technology Guided by Central Government(No.2021ZYD0041)Natural Science Foundation of Shandong Province(No.ZR2019YQ24)+2 种基金Taishan Scholars and Young Experts Program of Shandong Province(No.tsqn202103057)the Qingchuang Talents Induction Program of Shandong Higher Education Institution(Research and Innovation Team of Structural-Functional Polymer Composites)Special Financial of Shandong Province(Structural Design of High-efficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Talent Teams).
文摘Electromagnetic wave(EMW)absorbing materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control.And in order to cope with the complex electromagnetic environment,the design of multifunctional and multiband high efficiency EMW absorbers remains a tremendous challenge.In this work,we designed a three-dimensional porous structure via the salt melt synthesis strategy to optimize the impedance matching of the absorber.Also,through interfacial engineering,a molybdenum carbide transition layer was introduced between the molybdenum selenide nanoparticles and the three-dimensional porous carbon matrix to improve the absorption behavior of the absorber.The analysis indicates that the number and components of the heterogeneous interfaces have a significant impact on the EMW absorption performance of the absorber due to mechanisms such as interfacial polarization and conduction loss introduced by interfacial engineering.Wherein,the prepared MoSe_(2)/MoC/PNC composites showed excellent EMW absorption performance in C,X,and Ku bands,especially exhibiting a reflection loss of−59.09 dB and an effective absorption bandwidth of 6.96 GHz at 1.9 mm.The coordination between structure and components endows the absorber with strong absorption,broad bandwidth,thin thickness,and multi-frequency absorption characteristics.Remarkably,it can effectively reinforce the marine anticorrosion property of the epoxy resin coating on Q235 steel substrate.This study contributes to a deeper understanding of the relationship between interfacial engineering and the performance of EMW absorbers,and provides a reference for the design of multifunctional,multiband EMW absorption materials.
文摘An equivalent-circuit model is used to analyse the improvement of the wave absorbing performance of the lossy frequency selective surface（FSS） absorber by using a magnetic substrate,showing that it is possible to widen the wave absorbing bandwidth.Three pieces of magnetic substrates are prepared.According to the complex permittivity and permeability,the reflectivity of the corresponding absorber is calculated by the finite difference time-domain（FDTD） method,and the bandwidth of the reflectivity below 10 dB is optimized by genetic algorithm.The calculated results indicate that the wave absorbing performance is significantly improved by increasing the complex permeability of the substrate;the reflectivity bandwidth below 10 dB of the single layer FSS absorber can reach 3.6-18 GHz with a thickness of 5 mm,which is wider than that with a dielectric substrate.The density of the FSS absorber is only 0.92 g/cm 3.Additionally,the absorption band can be further widened by inserting a second lossy FSS.Finally,a double layer lossy FSS absorber with a magnetic substrate is fabricated based on the design result.The experimental result is consistent with the design one.
文摘A set of experiments is carried out in a towing tank to study the effects of the curvature of perforated plates on the wave reflection coefficient （Cr）. The curvature of a perforated plate can be changed by rotating a reference perforated plate about its origin point according to the parabolic equation y=-x2 A plunger-type wave maker is used to generate regular waves. The reflection coefficients are calculated using Goda and Suzuki’s （1976） method. The results are compared with those of vertical or sloped passive wave absorbers. The comparison shows that a perforated plate with a curved profile is highly efficient in terms of reducing the wave reflection coefficient. A correlation is established to estimate the reflection coefficient of curved perforated plates as a function of both flow and geometry characteristics.
文摘For active wave absorbers in force-control mode,the optimal feedback(control)force provided by the control system depends on the hydrodynamic forces.This work investigates a piston-type wave absorber with different draft-to-water depth ratios,focusing on the frequency-dependent hydrodynamic coefficients,wave absorption efficiency,wave absorber displacement and velocity,and control force.Analytical results were derived based on potential flow theory,confirming that regular incident waves can be fully absorbed by the piston-type active wave absorber at any draft ratio by optimizing the control force.The results for the wave tank with a typical water depth of 3 m were studied in detail.The draft ratio has a strong influence on the hydrodynamic coefficients.At the maximum wave absorption efficiency,the displacement and velocity amplitudes are sensitive to the draft ratio in the low-frequency region,increase with decreasing draft ratio,and are independent of the mass of the wave absorber.The control force required can be extremely large for a draft ratio greater than 1/3.The control force increases significantly as the draft ratio increases.The mass of the wave absorber has a weak influence on the control force.A time-domain numerical method based on the boundary element method was developed to verify the analytical solutions.Perfect agreements between the analytical solutions and the numerical results were obtained.
