Metal-organic frameworks(MOFs),a family of highly porous materials possessing huge surface areas and feasible chemical tunability,are emerging as critical functional materials to solve the growing challenges associate...Metal-organic frameworks(MOFs),a family of highly porous materials possessing huge surface areas and feasible chemical tunability,are emerging as critical functional materials to solve the growing challenges associated with energy-water systems,such as water scarcity issues.In this contribution,the roles of MOFs are highlighted in electrochemical-based water applications(i.e.,reactions,sensing,and separations),where MOF-based functional materials exhibit outstanding performances in detecting/removing pollutants,recovering resources,and harvesting energies from different water sources.Compared with the pristine MOFs,the efficiency and/or selectivity can be further enhanced via rational structural modulation of MOFs(e.g.,partial metal substitution)or integration of MOFs with other functional materials(e.g.,metal clusters and reduced graphene oxide).Several key factors/properties that affect the performances of MOF-based materials are also reviewed,including electronic structures,nanoconfined effects,stability,conductivity,and atomic structures.The advancement in the fundamental understanding of these key factors is expected to shed light on the functioning mechanisms of MOFs(e.g.,charge transfer pathways and guest-host interactions),which will subsequently accelerate the integration of precisely designed MOFs into electrochemical architectures to achieve highly effective water remediation with optimized selectivity and long-term stability.展开更多
The anoxia of coastal water has already been a serious problem all over the word.Nanobubbles are proved to have great applications in water remediation because they could effectively increase the oxygen content and de...The anoxia of coastal water has already been a serious problem all over the word.Nanobubbles are proved to have great applications in water remediation because they could effectively increase the oxygen content and degrade organic matters in water.But the existing methods to produce nanobubbles are complicated and high cost to operate,especially in deep sea.In this paper,we presented a low-cost method,hydraulic air compression(HAC),to produce a large number of nanobubbles and proved that nanoscale gas bubbles could be produced by HAC for the first time.Nanoparticle tracking analysis was used to measure the size and concentration of produced nanobubbles.It indicated that the concentration of nanobubbles would increase as the downpipe height increases.Degassed measurements proved that produced“nanoparticles”are gas nanobubbles indeed.More dissolved oxygen in water would provide the source for larger number of nanobubble formation.Those results are expected to be very helpful for water remediation in ocean in the future.展开更多
基金supported by the start-up package and COES Institutional Research Incentive Program at the Florida Institute of Technology.
文摘Metal-organic frameworks(MOFs),a family of highly porous materials possessing huge surface areas and feasible chemical tunability,are emerging as critical functional materials to solve the growing challenges associated with energy-water systems,such as water scarcity issues.In this contribution,the roles of MOFs are highlighted in electrochemical-based water applications(i.e.,reactions,sensing,and separations),where MOF-based functional materials exhibit outstanding performances in detecting/removing pollutants,recovering resources,and harvesting energies from different water sources.Compared with the pristine MOFs,the efficiency and/or selectivity can be further enhanced via rational structural modulation of MOFs(e.g.,partial metal substitution)or integration of MOFs with other functional materials(e.g.,metal clusters and reduced graphene oxide).Several key factors/properties that affect the performances of MOF-based materials are also reviewed,including electronic structures,nanoconfined effects,stability,conductivity,and atomic structures.The advancement in the fundamental understanding of these key factors is expected to shed light on the functioning mechanisms of MOFs(e.g.,charge transfer pathways and guest-host interactions),which will subsequently accelerate the integration of precisely designed MOFs into electrochemical architectures to achieve highly effective water remediation with optimized selectivity and long-term stability.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11874379,11575281,and U1532260)the Knowledge Innovation Program of the Chinese Academy of Sciences(Grant Nos.KJZD-EW-M03and QYZDJ-SSW-SLH019)。
文摘The anoxia of coastal water has already been a serious problem all over the word.Nanobubbles are proved to have great applications in water remediation because they could effectively increase the oxygen content and degrade organic matters in water.But the existing methods to produce nanobubbles are complicated and high cost to operate,especially in deep sea.In this paper,we presented a low-cost method,hydraulic air compression(HAC),to produce a large number of nanobubbles and proved that nanoscale gas bubbles could be produced by HAC for the first time.Nanoparticle tracking analysis was used to measure the size and concentration of produced nanobubbles.It indicated that the concentration of nanobubbles would increase as the downpipe height increases.Degassed measurements proved that produced“nanoparticles”are gas nanobubbles indeed.More dissolved oxygen in water would provide the source for larger number of nanobubble formation.Those results are expected to be very helpful for water remediation in ocean in the future.
