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Nonlinear and Variable Structure Excitation Controller for Power System Stability 被引量:5
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作者 王奔 Ronnie Belmans 《Journal of Southwest Jiaotong University(English Edition)》 2006年第4期339-347,共9页
A new nonlinear variable structure excitation controller is proposed. Its design combines the differential geometry theory and the variable structure controlling theory. The mathematical model in the form of "an affm... A new nonlinear variable structure excitation controller is proposed. Its design combines the differential geometry theory and the variable structure controlling theory. The mathematical model in the form of "an affme nonlinear system" is set up for the control of a large-scale power system. The static and dynamic performances of the nonlinear variable structure controller are simulated. The response of system with the controller proposed is compared to that of the nonlinear optimal controller when the system is subjected to a variety of disturbances. Simulation results show that the nonlinear variable structure excitation controller gives more satisfactorily static and dynamic performance and better robustness. 展开更多
关键词 Excitation control Nonlinear control variable structure control Dynamic performance Power system
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Structure identification of an uncertain network coupled with complex-variable chaotic systems via adaptive impulsive control 被引量:1
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作者 刘丹峰 吴召艳 叶青伶 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第4期183-190,共8页
In this paper, structure identification of an uncertain network coupled with complex-variable chaotic systems is in- vestigated. Both the topological structure and the system parameters can be unknown and need to be i... In this paper, structure identification of an uncertain network coupled with complex-variable chaotic systems is in- vestigated. Both the topological structure and the system parameters can be unknown and need to be identified. Based on impulsive stability theory and the Lyapunov function method, an impulsive control scheme combined with an adaptive strategy is adopted to design effective and universal network estimators. The restriction on the impulsive interval is relaxed by adopting an adaptive strategy. Further, the proposed method can monitor the online switching topology effectively. Several numerical simulations are provided to illustrate the effectiveness of the theoretical results. 展开更多
关键词 structure identification NETWORK complex-variable chaotic system impulsive control
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Variable separation solutions and new solitary wave structures to the (l+l)-dimensional Ito system
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作者 徐昌智 何宝钢 张解放 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第1期1-7,共7页
A variable separation approach is proposed and extended to the (1+1)-dimensional physics system. The variable separation solution of (1-F1)-dimensional Ito system is obtained. Some special types of solutions such... A variable separation approach is proposed and extended to the (1+1)-dimensional physics system. The variable separation solution of (1-F1)-dimensional Ito system is obtained. Some special types of solutions such as non-propagating solitary wave solution, propagating solitary wave solution and looped soliton solution are found by selecting the arbitrary function appropriately. 展开更多
关键词 (1+1)-dimensional Ito system variable separation approach new solitary wave structures
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Design of Neural Network Variable Structure Reentry Control System for Reusable Launch Vehicle 被引量:3
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作者 呼卫军 周军 《Defence Technology(防务技术)》 SCIE EI CAS 2008年第3期191-197,共7页
A flight control system is designed for a reusable launch vehicle with aerodynamic control surfaces and reaction control system based on a variable-structure control and neural network theory.The control problems of c... A flight control system is designed for a reusable launch vehicle with aerodynamic control surfaces and reaction control system based on a variable-structure control and neural network theory.The control problems of coupling among the channels and the uncertainty of model parameters are solved by using the method.High precise and robust tracking of required attitude angles can be achieved in complicated air space.A mathematical model of reusable launch vehicle is presented first,and then a controller of flight system is presented.Base on the mathematical model,the controller is divided into two parts:variable-structure controller and neural network module which is used to modify the parameters of controller.This control system decouples the lateraldirectional tunnels well with a neural network sliding mode controller and provides a robust and de-coupled tracking for mission angle profiles.After this a control allocation algorithm is employed to allocate the torque moments to aerodynamic control surfaces and thrusters.The final simulation shows that the control system has a good accurate,robust and de-coupled tracking performance.The stable state error is less than 1°,and the overshoot is less than 5%. 展开更多
关键词 飞行技术 自动控制 运输器 神经网络
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Variable Structure Proportional Navigation for Homing Missile 被引量:2
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作者 宋建梅 张天桥 《Journal of Beijing Institute of Technology》 EI CAS 2000年第3期296-301,共6页
The purpose of this paper is to design control loop and guidance loop for the homing missile, to prove that the modified variable structure proportional navigation (VSPN) can be used in passive homing guidance system,... The purpose of this paper is to design control loop and guidance loop for the homing missile, to prove that the modified variable structure proportional navigation (VSPN) can be used in passive homing guidance system, and to compare the VSPN with the proportional navigation (PN). Angular rate and linear acceleration are fed back to improve the stability and robust of autopilot, VSPN and PN are compared in mathematics simulation of homing missile in attacking tanks and helicopters. The damp and the stability of the missile body are increased. The VSPN cuts down the overload of guidance phase dramatically, makes the ballistic trajectory straighter than PN and leads to smaller missdistance. The VSPN can be used for passive homing guidance system, and is especially suitable for attacking helicopter. 展开更多
关键词 homing missile variable structure proportional navigation (VSPN) proportional navigation (PN)
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Model Reference Variable Structure Autopilot Design for Homing Missile 被引量:1
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作者 宋建梅 《Journal of Beijing Institute of Technology》 EI CAS 2001年第4期364-369,共6页
To design the control system for some homing missile so that the autopilot can transfer guidance command correctly and be robust to disturbances, such as the measurement noises and parameter variation caused by areody... To design the control system for some homing missile so that the autopilot can transfer guidance command correctly and be robust to disturbances, such as the measurement noises and parameter variation caused by areodynamic floating. The model reference adaptive control was combined with the variable structure control to design a model reference variable structure (MRVS) control system whose control structure is simple and can be realized easily. The simulation results indicate that MRVS can complete the task of transferring guidance command and suppress the distrubances effectively. 展开更多
关键词 model reference variable structure variable structure control AUTOPILOT
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Variable-top stem biomass equations at tree-level generated by a simultaneous density-integral system for second growth forests of roble, raulí,and coigüe in Chile
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作者 Carlos Valenzuela Eduardo Acuna +3 位作者 Alicia Ortega Geronimo Quinonez-Barraza Jose Corral-Rivas Jorge Cancino 《Journal of Forestry Research》 SCIE CAS CSCD 2019年第3期993-1010,共18页
Variable-top stem biomass models at the tree level for second growth forests of roble (Nothofagus obliqua), rauli(Nothofagus alpina), and coigüe (Nothofagus dombeyi) were fitted by a simultaneous density-integral... Variable-top stem biomass models at the tree level for second growth forests of roble (Nothofagus obliqua), rauli(Nothofagus alpina), and coigüe (Nothofagus dombeyi) were fitted by a simultaneous density-integral system, which combines a stem taper model and a wood basic density model. For each model, an autoregressive structure of order 2 and a power equation of residual variance were incorporated to reduce residual autocorrelation and heteroscedasticity, respectively. By using dummy variables in the regression analysis, zonal effects on the parameters in the variable-top stem biomass equations were detected in roble. Consequently, equations for clusters of zones were obtained. These equations presented significant parameters and a high precision in both fitting and validation processes (i.e., CV<11.5% and CVp<11.9%, respectively), demonstrating that they are unbiased. The advantage of these types of functions is that they provide estimates of volume and biomass of sections of the stem, defined between any two points of the stem in the three species. Thus, depending on the final use of the wood and the dimensions of the tree, a stem fraction can be quantified in units of volume and the remaining fraction in units of weight. 展开更多
关键词 AUTOCORRELATION Density-integral DUMMY variables AUTOREGRESSIVE error structure HETEROSCEDASTICITY
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VARIABLE STRUCTURE MODEL-FOLLOWING ADAPTIVE CONTROL DESIGN FOR ROBOT MANIPULATORS
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作者 Zhao Dongbiao Zhu Jianying (Department of Mechanical Engineering ,NUAA29 Yudao Street ,Nanjing 210016 ,P.R.China) 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 1994年第1期85-91,共7页
The increasing demand on robotic system performance leads to the use of advanced control strategies. A variable structure model-following adaptive control design is presented for the nonlinear robot manipulator sys... The increasing demand on robotic system performance leads to the use of advanced control strategies. A variable structure model-following adaptive control design is presented for the nonlinear robot manipulator systems, when subjected to fast and wide ranges of unknown-but-bounded parameter variations and disturbances. The design does not require any knowledge of a nonlinear robotic system. The system is robust and insensitive to the parameter variation, disturbances, as well as to the unmodeled dynamics. This insensitive property enables the elimination of interactions among the various joints of the robotic manipulator. In the closed loop, the robotic system asymptotically converges to the reference trajectory with a Prescribed transient resPOnse. The problem of chattering is discussed with the introduction of the special approaches: boundary layer, smoothing law, and nonlinear compensation. 展开更多
关键词 ROBOTS 1 model reference ADAPTIVE control robustness variable structure CONTROL
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Remote Control Guidance Law Design Using Variable Structure Control
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作者 孟秀云 王奇 《Journal of Beijing Institute of Technology》 EI CAS 2006年第1期81-84,共4页
A method of sliding mode variable structure control for the missile body being a time varying system is presented. A remote control guidance law is designed. The method has strong robustness to target' s maneuver. To... A method of sliding mode variable structure control for the missile body being a time varying system is presented. A remote control guidance law is designed. The method has strong robustness to target' s maneuver. To reduce the chattering phenomena, quasi-sliding mode variable structure control method is used. Simulation results show that the proposed method has small miss distance for any kind of maneuvering targets and requires small control energy. 展开更多
关键词 remote control guidance law variable structure control sliding mode reaching mode
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Population structure,age and growth rates of conifer species and their relation to environmental variables at Malam Jabba,Swat District,Pakistan
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作者 Arsalan Muhammad Faheem Siddiqui +2 位作者 Moinuddin Ahmed Syed Shahid Shaukat Alamdar Hussain 《Journal of Forestry Research》 SCIE CAS CSCD 2020年第2期429-441,共13页
This study focuses on age,growth rate and diameter distribution of pine forests in the Malam Jabba area,Swat District,Pakistan.Wood core samples were taken from twenty stands.Picea smithiana was the oldest at 234 year... This study focuses on age,growth rate and diameter distribution of pine forests in the Malam Jabba area,Swat District,Pakistan.Wood core samples were taken from twenty stands.Picea smithiana was the oldest at 234 years with a 112-cm diameter.Abies pindrow was 125 years with an 80-cm diameter while the oldest Pinus wallichiana was 122 years with 75-cm diameter.The fastest overall growth rate of 1.5±0.1 year/cm was for P.wallichiana on a west-facing aspect,while the slowest 5.8±2.6 year/cm growth was P.smithiana on an eastfacing exposure.P.wallichiana and A.pindrow exhibited marked differences in growth rates over a 5-year period.The highest growth was by P.wallichiana from 1966 to 2006.A.pindrow showed less growth over the same years,such pattern simultaneously reverse from 1911 to 1965.The relationship between diameter and age,diameter and growth rate and age and growth rate were correlated.P.wallichiana and A.pindrow ages were correlated with diameter and growth rates.P.smithiana age was positive correlated with diameter.Generally,topographic and edaphic factors did not show significant correlations with growth rates,although some appreciable correlations were recorded.The growth of P.wallichiana was correlated with elevation while A.pindrow was correlated with maximum water retaining capacity.Diameter and age produced uneven size classes and many size gaps,which could be the result of anthropogenic disturbances. 展开更多
关键词 Dendrochronology Environmental variables Conifer species Forest structure Age classes
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A Variable Structure Model Reference Adaptive Control
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作者 Yao Yu (School of Astronautics) 《哈尔滨工业大学学报》 EI CAS CSCD 北大核心 1990年第3期62-70,共9页
A variable structure model reference adaptive control problem for the nonlinear system is studied in this paper. First, according to the relative degree concept of th nonlinear control system an error equation between... A variable structure model reference adaptive control problem for the nonlinear system is studied in this paper. First, according to the relative degree concept of th nonlinear control system an error equation between the outputs of the reference model and the controlled plant is derived. Then, by using the variable structrue control method, an algorithm of variable structure model reference adaptive control is deduced on the basis of a new concept of reaching law. The definition of the SISO system is introduced into the MIMO nonlinear system. Finally, as an example, a pendulum nonlinear control system is simulated to demonstrated the effectiveness of the method. The results show that the method has some advantages: the design is simple, intuitive and easy to be realized in engineering. Besides, it is of practical significance for the synthesis of nonlinear control systems. 展开更多
关键词 变结构控制 自适应控制 非线性系统 相关度 变结构模型
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Prolongation structure of the variable coefficient KdV equation
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作者 杨云青 陈勇 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第1期76-81,共6页
The prolongation structure methodologies of Wahlquist-Estabrook [Wahlquist H D and Estabrook F B 1975 J. Math. Phys. 16 1] for nonlinear differential equations are applied to a variable-coefficient KdV equation. Based... The prolongation structure methodologies of Wahlquist-Estabrook [Wahlquist H D and Estabrook F B 1975 J. Math. Phys. 16 1] for nonlinear differential equations are applied to a variable-coefficient KdV equation. Based on the obtained prolongation structure, a Lie algebra with five parameters is constructed. Under certain conditions, a Lie algebra representation and three kinds of Lax pairs for the variable coefficient KdV equation are derived. 展开更多
关键词 prolongation structure variable-coefficient KdV equation Lax pairs
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考虑流固耦合的斜拉管桥结构压电阻尼减震控制研究
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作者 代建波 马祥祥 +1 位作者 汪浩 刘冬 《水利与建筑工程学报》 2025年第1期7-15,共9页
为减小流固耦合的斜拉管桥结构的地震响应,基于压电陶瓷的逆压电效应等特点,设计了一种新型压电摩擦阻尼器,并以某单塔双跨多索双管道斜拉管桥为例,建立考虑流固耦合的斜拉管桥结构有限元模型,探讨阻尼器在斜拉管桥结构中的最优安装位... 为减小流固耦合的斜拉管桥结构的地震响应,基于压电陶瓷的逆压电效应等特点,设计了一种新型压电摩擦阻尼器,并以某单塔双跨多索双管道斜拉管桥为例,建立考虑流固耦合的斜拉管桥结构有限元模型,探讨阻尼器在斜拉管桥结构中的最优安装位置及减震控制效果。结果表明:设计的新型压电变摩擦阻尼器具有良好的工作性能,阻尼力与驱动电压之间呈现较好的线性关系,建立的阻尼力-驱动电压本构模型可以用于管桥结构的压电减震控制;阻尼索在算例斜拉管桥上的最佳减震效果安装位置L为42.875 m,对应的阻尼器最佳倾斜角为41.4°;压电阻尼器在最佳安装位置,阻尼系数为50 kN·s/m时,管桥结构的位移控制效果为13.5%,加速度控制效果为33.9%。随着阻尼系数的增大,明显提高了减震效果。 展开更多
关键词 斜拉管桥结构 压电变摩擦阻尼器 流固耦合 减震率 减震控制
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双层准零刚度隔振系统吸引子迁移控制特性
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作者 马召召 余永华 +2 位作者 杨庆超 周瑞平 柴凯 《力学学报》 北大核心 2025年第3期730-739,共10页
非线性隔振系统普遍存在多稳态吸引子共存现象,运行在不同吸引子上时则具有不同的隔振效果.为保证非线性隔振系统处于最优的隔振状态,以双层准零刚度隔振(two-stage quasi-zero stiffness vibration isolation,TQZS VI)系统为对象,对其... 非线性隔振系统普遍存在多稳态吸引子共存现象,运行在不同吸引子上时则具有不同的隔振效果.为保证非线性隔振系统处于最优的隔振状态,以双层准零刚度隔振(two-stage quasi-zero stiffness vibration isolation,TQZS VI)系统为对象,对其吸引子迁移控制特性展开分析.首先,建立了TQZS VI系统动力学模型,采用参数延拓跟踪方法和并行胞映射方法分别揭示了TQZS VI系统全局分岔特性和吸引子共存特性,在不同激励力幅值作用下TQZS VI系统具有显著的分岔特性,包括周期运动(周期1,2和3等)以及混沌运动.然后,基于吸引子迁移控制理论,采用经典指数趋近律提出了一种基于滑模变结构的吸引子迁移控制方法,其无需建立非线性控制项且目标轨道函数传输域具备全局性.最后,采用所提出的吸引子迁移控制方法构建了TQZS VI系统迁移控制项,并揭示了TQZS VI系统在不同目标轨道以及吸引子之间的迁移控制特性.结果表明,基于滑模变结构的吸引子迁移控制方法能够有效控制TQZS VI系统的运动状态,可为非线性隔振系统状态控制和减振降噪提供一种新思路. 展开更多
关键词 非线性隔振 准零刚度 吸引子 滑模变结构 迁移控制
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新型边界增强变截面空心BCC点阵结构的耐撞性分析
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作者 李博 刘华 +2 位作者 张显涛 罗敏 杨先锋 《载人航天》 北大核心 2025年第2期202-211,共10页
针对点阵结构在实际应用中所面临的边界条件和实际尺寸及阵列数限制的问题,提出了一种新型变截面空心点阵设计思路以提高结构的能量吸收能力。通过在变截面空心点阵边界处添加金属片单元,设计了新型增强型变截面空心点阵材料;基于选区... 针对点阵结构在实际应用中所面临的边界条件和实际尺寸及阵列数限制的问题,提出了一种新型变截面空心点阵设计思路以提高结构的能量吸收能力。通过在变截面空心点阵边界处添加金属片单元,设计了新型增强型变截面空心点阵材料;基于选区激光熔融工艺制备了316L不锈钢变截面空心点阵和增强型变截面空心点阵结构;通过准静态压缩试验及基于LsDyna的仿真分析,对各变截面空心点阵结构的力学性能和吸能特性展开研究。基于试验验证的有限元模型进行了点阵结构性能参数化分析,揭示了边界金属片单元布置方式对增强型点阵结构的能量吸收影响规律。结果表明:金属片单元布置在垂直于加载平面的点阵棱边,可显著增强其能量吸收能力且具有良好的载荷均匀性。 展开更多
关键词 点阵结构 变截面设计 边界设计 数值模拟 能量吸收
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变序结构集优化问题的适定性
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作者 刘越庆 徐义红 《应用数学》 北大核心 2025年第1期182-190,共9页
本文研究具有变序结构集优化问题的适定性.基于广义变下序关系(variable generalized lower less relation),给出了集优化问题的三种适定性概念.引进了近似解映射,讨论了该映射的性质.给出了具有变序结构集优化问题的三种适定性的充分条... 本文研究具有变序结构集优化问题的适定性.基于广义变下序关系(variable generalized lower less relation),给出了集优化问题的三种适定性概念.引进了近似解映射,讨论了该映射的性质.给出了具有变序结构集优化问题的三种适定性的充分条件.举例说明了文中的主要结果. 展开更多
关键词 适定性 集优化 共辐射集 变序结构
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变截面弹体斜侵彻两层间隔钢靶弹道特性
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作者 蒋腾 武海军 +3 位作者 邓希旻 全鑫 董恒 黄风雷 《兵工学报》 北大核心 2025年第2期190-205,共16页
为研究变截面弹体斜侵彻两层间隔钢靶时结构特征对弹道特性的影响规律,开展椭圆等截面、椭圆变截面弹体在1020 m/s初速、5°着角条件下斜侵彻两层间隔钢靶实验,结合数值模拟对比圆等截面、椭圆等截面、圆变截面和椭圆变截面弹体在... 为研究变截面弹体斜侵彻两层间隔钢靶时结构特征对弹道特性的影响规律,开展椭圆等截面、椭圆变截面弹体在1020 m/s初速、5°着角条件下斜侵彻两层间隔钢靶实验,结合数值模拟对比圆等截面、椭圆等截面、圆变截面和椭圆变截面弹体在斜侵彻钢靶过程中的弹道轨迹、速度、偏转角、纵向位移和纵向加速度的变化情况,揭示变截面弹体结构特征影响弹道稳定性的物理机制。研究结果表明:当弹体初始撞击速度较大、弹肩处横截面面积一致及变截面角度在0°~2.5°范围内时,不同横截面形状和变截面角度弹体在斜侵彻两层间隔钢靶过程中的速度变化差异很小;对于变截面弹体,可以通过改变变截面结构特征找到一个使得弹体贯穿首层靶板后纵向位移基本为零的临界变截面角度;不同横截面形状的变截面弹体受变截面角度对贯穿钢靶后纵向运动、姿态偏转的敏感程度不同,横截面形状的长短轴之比越大,变截面角度对偏转角速度的影响越大;变截面角度会影响弹体穿靶过程中的受力方向,可能导致弹体受力出现反转现象。相关研究对变截面弹体结构特征参数的优化、变截面弹体斜侵彻两层间隔钢靶弹道特性预测具有较好的指导价值。 展开更多
关键词 变截面弹体 结构特征 弹道特性 斜侵彻 间隔钢靶
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一种具有大承载能力的封闭孔隙式橡胶牵引球铰设计
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作者 杨哲 孙海燕 +4 位作者 谭方 杨军 程海涛 刘文松 彭超义 《轨道交通材料》 2025年第2期47-50,共4页
针对大载荷工况应用条件下的橡胶牵引球铰,结合橡胶牵引球铰径向载荷工况复杂、偏转角度较大的受力特点,提出一种封闭孔隙式结构设计的橡胶牵引球铰。在满足高承载特性要求、实现变刚度性能的同时,保持了与常规球铰一致的外观、安装方... 针对大载荷工况应用条件下的橡胶牵引球铰,结合橡胶牵引球铰径向载荷工况复杂、偏转角度较大的受力特点,提出一种封闭孔隙式结构设计的橡胶牵引球铰。在满足高承载特性要求、实现变刚度性能的同时,保持了与常规球铰一致的外观、安装方法和维护需求。结构上通过橡胶球铰硫化体、两瓣硬止挡和整体外套等部分的组装设计实现内部封装,保证球铰整体外观完整度。两瓣硬止挡在球铰内部提供变刚度性能,变刚度调整不需要更改硫化模具,设计上具有一定灵活性。采用Abaqus+Endurica仿真分析计算疲劳性能,并通过实际的疲劳试验,验证了该封闭孔隙式结构橡胶牵引球铰的可靠性,为后续高承载能力、变刚度性能要求的橡胶牵引球铰设计提供了思路。 展开更多
关键词 橡胶牵引球铰 封闭孔隙式结构 高承载能力 变刚度性能
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基于响应面法和仿真计算的轴箱轴承结构参数优化
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作者 李治桦 黄志辉 +2 位作者 唐嘉诚 彭越阳 陈丙硕 《铁道机车车辆》 北大核心 2025年第2期86-94,共9页
为了提高某1 435/1 520 mm变轨距转向架车轴左侧轴箱轴承在宽轨运行时的疲劳寿命,在不改变原有轴箱轴承安装接口尺寸的条件下,研究轴承不同结构参数交互作用对疲劳寿命的影响并优化其结构参数。考虑轴承实际工作情况,通过Romax建立轴承... 为了提高某1 435/1 520 mm变轨距转向架车轴左侧轴箱轴承在宽轨运行时的疲劳寿命,在不改变原有轴箱轴承安装接口尺寸的条件下,研究轴承不同结构参数交互作用对疲劳寿命的影响并优化其结构参数。考虑轴承实际工作情况,通过Romax建立轴承仿真模型获取滚子与内、外滚道间的接触载荷,采用Lundberg-Palmgren理论计算不同轨距车轴左右两侧轴箱轴承的疲劳寿命,基于Design-Expert对宽轨时车轴左侧轴箱轴承的结构参数进行优化,提高其疲劳寿命。建立了疲劳寿命与结构参数间的响应面模型,分析各结构参数交互作用对疲劳寿命的影响,获得轴承疲劳寿命最长时的结构参数。提高了轴承疲劳寿命的安全冗余,可为变轨距转向架轴箱轴承结构参数的选取提供参考。 展开更多
关键词 变轨距转向架 轴箱轴承 Lundberg-Palmgren理论 疲劳寿命 结构参数 响应面法
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地塞米松棕榈酸酯分子结构中红外/变温中红外光谱
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作者 李穆婵 柴嘉欣 +3 位作者 吉一帆 雷晓静 徐元媛 于宏伟 《上海计量测试》 2025年第1期39-45,共7页
探究了地塞米松棕榈酸酯分子结构及热变性研究。分别开展地塞米松棕榈酸酯分子结构中红外(MIR)光谱及变温MIR光谱实验。结果发现:地塞米松棕榈酸酯分子结构的红外吸收模式主要为:ν_(O-H)(包括:ν_(O-H-游离)、ν_(O-H-二聚体)、ν_(O-H... 探究了地塞米松棕榈酸酯分子结构及热变性研究。分别开展地塞米松棕榈酸酯分子结构中红外(MIR)光谱及变温MIR光谱实验。结果发现:地塞米松棕榈酸酯分子结构的红外吸收模式主要为:ν_(O-H)(包括:ν_(O-H-游离)、ν_(O-H-二聚体)、ν_(O-H-多聚体)、ν_(asCH_(2))、ν_(sCH_(2))、ν_(C=O)(包括:ν_(C=O-1)和ν_(C=O-2))、ν_(C=C)(包括:ν_(C=C-1)、ν_(C=C-2)和ν_(C=C-3))、δ_(CH_(2))、δ_(asCH_(3))、δ_(sCH_(3))、ν_(C-O)/ν_(C-F)(包括:ν_(C-O-1)/ν_(C-F-1)、ν_(C-O-2)/ν_(C-F-2)、ν_(C-O-3)/ν_(C-F-3)、ν_(C-O-4)/ν_(C-F-4)和ν_(C-O-5)/ν_(C-F-5))和ρ_(CH_(2))。在热扰动因素下,地塞米松棕榈酸酯分子结构由晶体态转变为熔融态,其主要官能团对应的吸收频率及强度均有明显的改变,其中333~338 K是一个临界温度区间。MIR/变温MIR光谱开展地塞米松棕榈酸酯分子结构及热变性研究,具有重要的应用研究价值。 展开更多
关键词 地塞米松棕榈酸酯 中红外光谱 变温中红外光谱 结构 热变性
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