The films of two x-shape oligo（thiophene）s, 3, 4-dibithienyl-2, 5-dithienylthiophene （7T） and 2, 5-dibithienyl-3, 4- ditrithienylthiophene （11T）, which are prepared by vacuum evaporation, have been investigated ...The films of two x-shape oligo（thiophene）s, 3, 4-dibithienyl-2, 5-dithienylthiophene （7T） and 2, 5-dibithienyl-3, 4- ditrithienylthiophene （11T）, which are prepared by vacuum evaporation, have been investigated as novel electron donor layers in two-layer photovoltaic cells. UV-Vis absorptions show red-shifted and broadened absorptions of the vacuumevaporated films as compared with those of the corresponding solutions and spin-coating films, which is beneficial for photovoltaic properties. X-ray diffraction （XRD） and differential scanning calorimetry （DSC） measurements show that the vacuum-evaporated films are almost amorphous. Two-layer photovoltaic cells have been realized by the thermal evaporation of 7T and llT as donors and N, N′-bis（1-ethylpropyl）-3, 4：9,10-perylene bis（tetracarboxyl diimide） （EP- PTC） as an acceptor. An energy conversion efficiency （ECE） of 0.18% of the cell based on 7T with an irradiation of white light at 100 mw/cm^2 has been demonstrated by the measurements of current （I）- voltage （V） curves of the cells to be higher than the ECE of the reference system based on donor dihexylterthienyl （H3T） that is linear and without α, β linkage.展开更多
基金Project supported by the State Key Development Program for Basic Research of China (Grant No 2002CB613401)the National Natural Science Foundation of China (Grant Nos 20474023 and 50673035)+2 种基金the Cooperation Research Project of National Natural Science Foundation of China and Korea Science and Engineering Foundation (Grant No 20611140613)the Research Project of Jilin Province (Grant Nos 20050504 and 20060702)the Research Project of Changchun City (Grant No 06GH03)
文摘The films of two x-shape oligo（thiophene）s, 3, 4-dibithienyl-2, 5-dithienylthiophene （7T） and 2, 5-dibithienyl-3, 4- ditrithienylthiophene （11T）, which are prepared by vacuum evaporation, have been investigated as novel electron donor layers in two-layer photovoltaic cells. UV-Vis absorptions show red-shifted and broadened absorptions of the vacuumevaporated films as compared with those of the corresponding solutions and spin-coating films, which is beneficial for photovoltaic properties. X-ray diffraction （XRD） and differential scanning calorimetry （DSC） measurements show that the vacuum-evaporated films are almost amorphous. Two-layer photovoltaic cells have been realized by the thermal evaporation of 7T and llT as donors and N, N′-bis（1-ethylpropyl）-3, 4：9,10-perylene bis（tetracarboxyl diimide） （EP- PTC） as an acceptor. An energy conversion efficiency （ECE） of 0.18% of the cell based on 7T with an irradiation of white light at 100 mw/cm^2 has been demonstrated by the measurements of current （I）- voltage （V） curves of the cells to be higher than the ECE of the reference system based on donor dihexylterthienyl （H3T） that is linear and without α, β linkage.
