Due to its high strength,high density,high hardness and good penetration capabilities,Depleted uranium alloys have already shined in armor-piercing projectiles.There should also be a lot of room for improvement in the...Due to its high strength,high density,high hardness and good penetration capabilities,Depleted uranium alloys have already shined in armor-piercing projectiles.There should also be a lot of room for improvement in the application of fragment killing elements.Therefore,regarding the performance of the depleted uranium alloy to penetrate the target plate,further investigation is needed to analyze its advantages and disadvantages compared to tungsten alloy.To study the difference in penetration performance between depleted uranium alloy and tungsten alloy fragments,firstly,a theoretical analysis of the adiabatic shear sensitivity of DU and tungsten alloys was given from the perspective of material constitutive model.Then,taking the cylindrical fragment penetration target as the research object,the penetration process and velocity characteristics of the steel target plates penetrated by DU alloy fragment and tungsten alloy fragment were compared and analyzed,by using finite element software ANSYS/LS-DYNA and Lagrange algorithm.Lastly,the influence of different postures when impacting target and different fragment shapes on the penetration results is carried out in the research.The results show that in the penetration process of the DU and tungsten alloy fragments,the self-sharpening properties of the DU alloy can make the fragment head sharper and the penetrating ability enhance.Under the same conditions,the penetration capability of cylindrical fragment impacting target in vertical posture is better than that in horizontal posture,and the penetration capability of the spherical fragment is slightly better than that of cylindrical fragment.展开更多
There is need to determination of uranium concentration at ppb level in environmental matrices.Due to low sensitivity of FAAS,UV-Visible Spectroscopy is generally used as measurement technique.In this study,ion-imprin...There is need to determination of uranium concentration at ppb level in environmental matrices.Due to low sensitivity of FAAS,UV-Visible Spectroscopy is generally used as measurement technique.In this study,ion-imprinted polymers(IIP)were prepared for uranyl ion(imprint ion)by formation of ternary(salicylaldoxime and 4-vinylpyridine)complex in 2-methoxy ethanol(porogen)following copolymerization with methacrylic acid(MAA)as a functional monomer and ethylene glycol dimethacrylate(EGDMA)as crosslinking monomer using 2,2-azobisisobutyronitrile as initiator.The synthesized polymers were characterized by FTIR and TGA analysis.ArsenazoⅢin 3M HClO_4 was used as complexing agent in the measurement step.The optimal pH for preconcentration was found to be between 3.5~6.5values.The developed method was applied to uranium(Ⅵ)determination in natural water samples.展开更多
To improve the adsorption performance and simplify uranium separation from aqueous media in post-treatment processes,a magnetic CoFe_(2)O_(4)@rGO composite was synthesized by microwave-hydrothermal method.The results ...To improve the adsorption performance and simplify uranium separation from aqueous media in post-treatment processes,a magnetic CoFe_(2)O_(4)@rGO composite was synthesized by microwave-hydrothermal method.The results of XRD,Raman,TEM/HRTEM,FTIR,BET and VSM characterization show that spinel-type cobalt ferrite CoFe_(2)O_(4) nanoparticles ca.13.4 nm in size are dispersedly anchored on the graphene sheet,and the saturation magnetization of the nanocomposite is 46.7 mA/(m^(2)·g).The effects of different pH,initial concentration and other conditions on uranium adsorption capacity were investigated,and adsorption kinetics equations were fitted to determine the adsorption behaviour of uranium on CoFe_(2)O_(4)@rGO in simulated uranium-containing seawater.It was observed that the uranium adsorption capacity of CoFe_(2)O_(4)@rGO composite at pH=5 is 127.6 mg/g,which is 1.31 and 2.43 times that of rGO and pure CoFe_(2)O_(4).The adsorption process conforms to Langmuir and quasi-second-order kinetic model.The excellent adsorption performance of CoFe_(2)O_(4)@rGO makes it potentially useful in the treatment of uranium-polluted water.展开更多
The role of Fe/S ratios(ω, g/g) in the uranium bioleaching from a complex uranium ore by Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans consortium was investigated. The results showed good uranium e...The role of Fe/S ratios(ω, g/g) in the uranium bioleaching from a complex uranium ore by Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans consortium was investigated. The results showed good uranium extraction with over 90% at the Fe/S ratio of 5:0.5, 5:1 and 5:5, while poor extraction(<46%) at the Fe/S ratio of 5:0 and 5:10.Furthermore, the bacterial community analysis based on species-specific gyrB numbers indicated that, absent sulfur or excessive sulfur would be not conducive to the synergistic growth for A. ferrooxidans and A. thiooxidans, and then not conducive to the uranium dissolution. Meanwhile, the sulfur-oxidizers could play an important role in the process of uranium synergistic bioleaching by mixed bacterial consortia. Additionally, the characteristics of mineral residue was detected by SEM-EDS. The results showed appropriate sulfur dosage would change the structure and improve the porosity of passivation substance. Lastly, the uranium dissolution kinetics and biochemical reaction mechanism was analyzed. It indicated that the biochemical reaction coupling iron and sulfur had a pleiotropic effect on the uranium dissolution from the ore particles, appropriate Fe/S ratio is the key factor for uranium bioleaching by chemoautotrophic acidophiles.展开更多
In this paper it has been presented the ELF Survey Meter and its application for investigation of presence of electric and magnetic fields strength in uranium conversion facilities,especially to investigate the effect...In this paper it has been presented the ELF Survey Meter and its application for investigation of presence of electric and magnetic fields strength in uranium conversion facilities,especially to investigate the effect of electric and magnetic sources on the operation of electrical controllers like PLC instruments, electrical drivers and actuators which are sensitive to presence of electrical and magnetic fields and also the effect of high voltage power lines展开更多
Chatkal-Kurama region is characterized by igneous complexes of rocks with different composition. According to the existing data magmatism can be referred to 3 types:a) subductional（C<sub>1</sub>-C<sub&...Chatkal-Kurama region is characterized by igneous complexes of rocks with different composition. According to the existing data magmatism can be referred to 3 types:a) subductional（C<sub>1</sub>-C<sub>3</sub>）;b) orogenical（P<sub>1</sub>-T<sub>1</sub>）;and c) dyke（P<sub>2</sub>-T<sub>1</sub>-K）.Different ore deposits occurrences are connected with these rock complexes of Chatkal-Kurama region.展开更多
According to the experimental data, there is an intermediate substance that formed in the initial stage of oxidation reaction when water vapor is absorbed onto the metallic uranium. The minimum energy of UOH 2 wich C ...According to the experimental data, there is an intermediate substance that formed in the initial stage of oxidation reaction when water vapor is absorbed onto the metallic uranium. The minimum energy of UOH 2 wich C 2v configuration is obtained in the state of 5A 1 by B3LYP method of the density function theory (DFT), which is consistent with that by statics of atoms and molecules reaction (AMRS) and group theory. The results from calculations indicate that the adsorption of water vapor on the metallic uranium is an exothermic reaction and that the adsorbed amount decreases with the elevated temperatures. the adsorptive heat at 1 atm is -205.474 7 kJ.mol -1 , which indicates a typical chemical adsorption.展开更多
文摘Due to its high strength,high density,high hardness and good penetration capabilities,Depleted uranium alloys have already shined in armor-piercing projectiles.There should also be a lot of room for improvement in the application of fragment killing elements.Therefore,regarding the performance of the depleted uranium alloy to penetrate the target plate,further investigation is needed to analyze its advantages and disadvantages compared to tungsten alloy.To study the difference in penetration performance between depleted uranium alloy and tungsten alloy fragments,firstly,a theoretical analysis of the adiabatic shear sensitivity of DU and tungsten alloys was given from the perspective of material constitutive model.Then,taking the cylindrical fragment penetration target as the research object,the penetration process and velocity characteristics of the steel target plates penetrated by DU alloy fragment and tungsten alloy fragment were compared and analyzed,by using finite element software ANSYS/LS-DYNA and Lagrange algorithm.Lastly,the influence of different postures when impacting target and different fragment shapes on the penetration results is carried out in the research.The results show that in the penetration process of the DU and tungsten alloy fragments,the self-sharpening properties of the DU alloy can make the fragment head sharper and the penetrating ability enhance.Under the same conditions,the penetration capability of cylindrical fragment impacting target in vertical posture is better than that in horizontal posture,and the penetration capability of the spherical fragment is slightly better than that of cylindrical fragment.
基金the Scientific Investigate Projects of Firat University,Turkey(FF.14.10)
文摘There is need to determination of uranium concentration at ppb level in environmental matrices.Due to low sensitivity of FAAS,UV-Visible Spectroscopy is generally used as measurement technique.In this study,ion-imprinted polymers(IIP)were prepared for uranyl ion(imprint ion)by formation of ternary(salicylaldoxime and 4-vinylpyridine)complex in 2-methoxy ethanol(porogen)following copolymerization with methacrylic acid(MAA)as a functional monomer and ethylene glycol dimethacrylate(EGDMA)as crosslinking monomer using 2,2-azobisisobutyronitrile as initiator.The synthesized polymers were characterized by FTIR and TGA analysis.ArsenazoⅢin 3M HClO_4 was used as complexing agent in the measurement step.The optimal pH for preconcentration was found to be between 3.5~6.5values.The developed method was applied to uranium(Ⅵ)determination in natural water samples.
基金Project(19B126)supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(21772035)supported by the National Natural Science Foundation of China+1 种基金Projects(2018JJ3099,2019JJ40058)supported by the Provincial Natural Science Foundation of Hunan,ChinaProject supported by the Innovation and Entrepreneurship Training Program of Hunan Institute of Engineering,China。
文摘To improve the adsorption performance and simplify uranium separation from aqueous media in post-treatment processes,a magnetic CoFe_(2)O_(4)@rGO composite was synthesized by microwave-hydrothermal method.The results of XRD,Raman,TEM/HRTEM,FTIR,BET and VSM characterization show that spinel-type cobalt ferrite CoFe_(2)O_(4) nanoparticles ca.13.4 nm in size are dispersedly anchored on the graphene sheet,and the saturation magnetization of the nanocomposite is 46.7 mA/(m^(2)·g).The effects of different pH,initial concentration and other conditions on uranium adsorption capacity were investigated,and adsorption kinetics equations were fitted to determine the adsorption behaviour of uranium on CoFe_(2)O_(4)@rGO in simulated uranium-containing seawater.It was observed that the uranium adsorption capacity of CoFe_(2)O_(4)@rGO composite at pH=5 is 127.6 mg/g,which is 1.31 and 2.43 times that of rGO and pure CoFe_(2)O_(4).The adsorption process conforms to Langmuir and quasi-second-order kinetic model.The excellent adsorption performance of CoFe_(2)O_(4)@rGO makes it potentially useful in the treatment of uranium-polluted water.
基金Project(51804165) supported by the National Natural Science Foundation of ChinaProject(2018JJ3441) supported by the Natural Science Foundation of Hunan Province,China。
文摘The role of Fe/S ratios(ω, g/g) in the uranium bioleaching from a complex uranium ore by Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans consortium was investigated. The results showed good uranium extraction with over 90% at the Fe/S ratio of 5:0.5, 5:1 and 5:5, while poor extraction(<46%) at the Fe/S ratio of 5:0 and 5:10.Furthermore, the bacterial community analysis based on species-specific gyrB numbers indicated that, absent sulfur or excessive sulfur would be not conducive to the synergistic growth for A. ferrooxidans and A. thiooxidans, and then not conducive to the uranium dissolution. Meanwhile, the sulfur-oxidizers could play an important role in the process of uranium synergistic bioleaching by mixed bacterial consortia. Additionally, the characteristics of mineral residue was detected by SEM-EDS. The results showed appropriate sulfur dosage would change the structure and improve the porosity of passivation substance. Lastly, the uranium dissolution kinetics and biochemical reaction mechanism was analyzed. It indicated that the biochemical reaction coupling iron and sulfur had a pleiotropic effect on the uranium dissolution from the ore particles, appropriate Fe/S ratio is the key factor for uranium bioleaching by chemoautotrophic acidophiles.
文摘In this paper it has been presented the ELF Survey Meter and its application for investigation of presence of electric and magnetic fields strength in uranium conversion facilities,especially to investigate the effect of electric and magnetic sources on the operation of electrical controllers like PLC instruments, electrical drivers and actuators which are sensitive to presence of electrical and magnetic fields and also the effect of high voltage power lines
文摘Chatkal-Kurama region is characterized by igneous complexes of rocks with different composition. According to the existing data magmatism can be referred to 3 types:a) subductional（C<sub>1</sub>-C<sub>3</sub>）;b) orogenical（P<sub>1</sub>-T<sub>1</sub>）;and c) dyke（P<sub>2</sub>-T<sub>1</sub>-K）.Different ore deposits occurrences are connected with these rock complexes of Chatkal-Kurama region.
文摘According to the experimental data, there is an intermediate substance that formed in the initial stage of oxidation reaction when water vapor is absorbed onto the metallic uranium. The minimum energy of UOH 2 wich C 2v configuration is obtained in the state of 5A 1 by B3LYP method of the density function theory (DFT), which is consistent with that by statics of atoms and molecules reaction (AMRS) and group theory. The results from calculations indicate that the adsorption of water vapor on the metallic uranium is an exothermic reaction and that the adsorbed amount decreases with the elevated temperatures. the adsorptive heat at 1 atm is -205.474 7 kJ.mol -1 , which indicates a typical chemical adsorption.
