yb^3＋：Er^3＋ co-doped oxy-fluoride ceramics glass has been prepared. The mechanism of up-conversion emissions about Er^3＋ was discussed, and the temperature properties of green up-conversion fluorescence between 30...yb^3＋：Er^3＋ co-doped oxy-fluoride ceramics glass has been prepared. The mechanism of up-conversion emissions about Er^3＋ was discussed, and the temperature properties of green up-conversion fluorescence between 303 and 823 K were investigated. The results show that the sensitivity of this sample reaches its maximum value, about 0.0047 K^-1, when the temperature is 383 K, indicating that this kind of sample can be used as high temperature and high sensitivity optical temperature sensor.展开更多
The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence propert...The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence properties and the drift of chromaticity coordinates(CIE) of the(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors and the color conversion glass ceramics were studied in the sintering temperature range from 600℃ to 800℃. The luminous intensity and internal quantum yield(QY) of the blue-green phosphors and glass ceramics decreased with the sintering temperature increasing. When the sintering temperature increased beyond 750℃, the phosphors and the color conversion glass ceramics almost had no peak in photoluminescence(PL) and excitation(PLE) spectra. The results showed that the blue-green phosphors had poor thermal stability at higher temperature. The lattice structure of the phosphors was destroyed by the glass matrix and the Ce^3+ in the phosphors was oxidized to Ce^4+, which further caused a decrease in luminescent properties of the color conversion glass ceramics.展开更多
The effects of BaCu（B2Os） （BCB） addition on the microstructure, phase formation, and microwave dielectric proper- ties of BasNb4015-BaWO4 ceramic are investigated. As a sintering aid, BaCu（B2Os） ceramic could ef...The effects of BaCu（B2Os） （BCB） addition on the microstructure, phase formation, and microwave dielectric proper- ties of BasNb4015-BaWO4 ceramic are investigated. As a sintering aid, BaCu（B2Os） ceramic could effectively lower the sintering temperature of BasNb4015-BaWO4 ceramic from 1100 ℃ to 950 ℃ due to the liquid-phase effect. Meanwhile, BaCu（B2Os） addition effectively improves the densification of BasNb4015-BaWO4 ceramic and significantly influences the microwave dielectric properties. X-ray diffraction analysis reveals that BasNb4015 and BaWO4 coexist with no crystal phase of BaCu（B2Os） in the sintered ceramics. The BasNb4015-BaWO4 ceramics with 1.0 wt% BaCu（B2Os） sintered at 950 ℃ for 2 h presents good microwave dielectric properties of er = 19.0, high Q× f of 33802 GHz and low vf of 2.5 ppm/℃.展开更多
An optical temperature sensor based on infrared-to-visible upconversion emission in Er ^(3+)/Yb ^(3+)co−doped Bi3TiNbØ9(BTN)ceramics is reported.The fluorescence intensity ratio of the green upconversion photolum...An optical temperature sensor based on infrared-to-visible upconversion emission in Er ^(3+)/Yb ^(3+)co−doped Bi3TiNbØ9(BTN)ceramics is reported.The fluorescence intensity ratio of the green upconversion photoluminescence(UC−PL)around 524 nm and 545 nm depends on temperature.The operating temperature range and the maximum sensitivity of Er ^(3+)/Yb ^(3+)co−doped Bi_(3)TiNbO_(9) ceramics are 123–693 K and 0.0032 K^(−1),respectively.BTN:Er3+/Yb3+ceramic has good thermal,physical and chemical stability,great UC−PL intensity and low cost fabrication.The results imply that Er ^(3+)/Yb ^(3+)co−doped Bi3TiNbO9 ceramic is promising for applications in wide-temperature-range sensors.展开更多
The strong temperature dependence of dielectric and piezoelectric properties is a big'bottleneck'for practical applications of KNN-based piezoceramics.In order to resolve this problem,Ca_(0.5)Sr_(0.5)TiO_(3)(C...The strong temperature dependence of dielectric and piezoelectric properties is a big'bottleneck'for practical applications of KNN-based piezoceramics.In order to resolve this problem,Ca_(0.5)Sr_(0.5)TiO_(3)(CST)is doped into(Na_(0.53)K_(0.4)0_(7)Li_(0.063))Nb0.937Sb0.063O3(NKLNS)ceramics.The thermal stability of s11E and k31 in the temperature range from−50℃to 200℃for ceramics with 1.0 and 1.5 mol%CST is raised in comparison with ceramics without CST.Ceramics with 1.5 mol%CST exhibit high piezoelectric properties(d33=202 pC/N,kp=44%)and low dielectric loss(2%)at room temperature.The excellent piezoelectric properties,which are comparable to conventional PZT ceramics,indicate that these ceramics are promising candidates for lead-free piezoelectric applications.展开更多
Quaternary carbide Ti3NiAl2C ceramics has been investigated as a potential nuclear fusion structural material,and it has advantages in certain aspects compared with Ti2AlC,Ti3AlC2,and Ti3SiC2 structural materials.In t...Quaternary carbide Ti3NiAl2C ceramics has been investigated as a potential nuclear fusion structural material,and it has advantages in certain aspects compared with Ti2AlC,Ti3AlC2,and Ti3SiC2 structural materials.In this paper,quaternary carbide Ti3NiAl2C ceramics is pressurized to investigate its structural,mechanical,electronic properties,and Debye temperature.Quaternary carbide Ti3NiAl2C ceramics still maintains a cubic structure under pressure(0–110 GPa).At zero pressure,quaternary carbide Ti3NiAl2C ceramics only has three bonds:Ti–Al,Ni–Al,and Ti–C.However,at pressures of 20 GPa,30 GPa,40 GPa,60 GPa,and 70 GPa,new Ti–Ni,Ti–Ti,Al–Al,Ti–Al,and Ti–Ti bonds form.When the pressure reaches 20 GPa,the covalent bonds change to metallic bonds.The volume of quaternary carbide Ti3NiAl2C ceramics can be compressed to 72%of its original volume at most.Pressurization can improve the mechanical strength and ductility of quaternary carbide Ti3NiAl2C ceramics.At 50–60 GPa,its mechanical strength can be comparable to pure tungsten,and the material changes from brittleness to ductility.However,the degree of anisotropy of quaternary carbide Ti3NiAl2C ceramics increases with the increasing pressure.In addition,we also investigated the Debye temperature,density,melting point,hardness,and wear resistance of quaternary carbide Ti3NiAl2C ceramics under pressure.展开更多
Based on Clausius-Mosotti equation and Debye relaxation theory, the dielectric model of yttria ceramics was developed according to the dielectric loss mechanism. The dielectric properties of yttria ceramics were predi...Based on Clausius-Mosotti equation and Debye relaxation theory, the dielectric model of yttria ceramics was developed according to the dielectric loss mechanism. The dielectric properties of yttria ceramics were predicted at high temperature. The temperature dependence and frequency dependence of dielectric constant and dielectric loss were discussed, respectively. As the result, the data calculated by theoretical dielectric model are in agreement with experimental data.展开更多
Development and application of ferrite materials for low temperature co-fired ceramic （LTCC） technology are dis- cussed, specifically addressing several typical ferrite materials such as M-type barium ferrite, NiCuZ...Development and application of ferrite materials for low temperature co-fired ceramic （LTCC） technology are dis- cussed, specifically addressing several typical ferrite materials such as M-type barium ferrite, NiCuZn ferrite, YIG ferrite, and lithium ferrite. In order to permit co-firing with a silver internal electrode in LTCC process, the sintering temperature of ferrite materials should be less than 950 ℃. These ferrite materials are research focuses and are applied in many ways in electronics.展开更多
An experimental and numerical study on the temperature field induced in the ultra-high frequency induction heating is carried out.With an aim of predicting the thermal history of the workpiece,the influence factors of...An experimental and numerical study on the temperature field induced in the ultra-high frequency induction heating is carried out.With an aim of predicting the thermal history of the workpiece,the influence factors of temperature field,such as the induction frequency,the dimension of coil and the gap between coil and workpiece,are investigated considering temperature-dependent material properties by using FLUX 2Dsoftware.The temperature field characteristic in ultra-high induction heating is obtained and discussed.The numerical values are compared with the experimental results.A good agreement between them is observed with 7.9% errors.展开更多
Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PMN-PT)piezoelectric ceramics have excellent piezoelectric properties and are used in a wide range of applications.Adjusting the solid solution ratios of PMN/PT and different conce...Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PMN-PT)piezoelectric ceramics have excellent piezoelectric properties and are used in a wide range of applications.Adjusting the solid solution ratios of PMN/PT and different concentrations of elemental doping are the main methods to modulate their piezoelectric coefficients.The combination of these controllable conditions leads to an exponential increase of possible compositions in ceramics,which makes it not easy to extend the sample data by additional experimental or theoretical calculations.In this paper,a physics-embedded machine learning method is proposed to overcome the difficulties in obtaining piezoelectric coefficients and Curie temperatures of Sm-doped PMN-PT ceramics with different components.In contrast to all-data-driven model,physics-embedded machine learning is able to learn nonlinear variation rules based on small datasets through potential correlation between ferroelectric properties.Based on the model outputs,the positions of morphotropic phase boundary(MPB)with different Sm doping amounts are explored.We also find the components with the best piezoelectric property and comprehensive performance.Moreover,we set up a database according to the obtained results,through which we can quickly find the optimal components of Sm-doped PMN-PT ceramics according to our specific needs.展开更多
Proton conducting ceramic cells(PCCs)are an attractive emerging technology operating in the intermediate temperature range of 500 to 700℃.In this work,we evaluate the production of hydrogen at intermediate temperatur...Proton conducting ceramic cells(PCCs)are an attractive emerging technology operating in the intermediate temperature range of 500 to 700℃.In this work,we evaluate the production of hydrogen at intermediate temperatures by proton conducting ceramic cell electrolysis(PCCEL).We demonstrate a highperformance steam electrolysis owing to a composite positrode based on BaGd_(0.8)La_(0.2)Co_(2)O_(6-δ)(BGLC1082)and BaZr0.5Ce0.4Y0.1O3-δ(BZCY541).The high reliability of PCCEL is demonstrated for 1680 h at a current density as high as-0.8 A cm^(-2)close to the thermoneutral cell voltage at 600℃.The electrolysis cell showed a specific energy consumption ranging from 54 to 66 kW h kg^(-1)that is comparable to state-of-the-art low temperature electrolysis technologies,while showing hydrogen production rates systematically higher than commercial solid oxide ceramic cells(SOCs).Compared to SOCs,the results verified the higher performances of PCCs at the relevant operating temperatures,due to the lower activation energy for proton transfer comparing with oxygen ion conduction.However,because of the p-type electronic conduction in protonic ceramics,the energy conversion rate of PCCs is relatively lower in steam electrolysis.The faradaic efficiency of the PCC in electrolysis mode can be increased at lower operating temperatures and in endothermic conditions,making PCCEL a technology of choice to valorize high temperature waste heat from industrial processes into hydrogen.To increase the faradaic efficiency by optimizing the materials,the cell design,or the operating strategy is a key challenge to address for future developments of PCCEL in order to achieve even more superior techno-economic merits.展开更多
In this paper, the preparation of 0.08BiGaO3–0.90BaTiO3–0.02LiNbO3 is investigated at pressure 3.8 GPa and temperature 1100–1200？C. Experimental results indicate that not only is the sintered rate more effective, ...In this paper, the preparation of 0.08BiGaO3–0.90BaTiO3–0.02LiNbO3 is investigated at pressure 3.8 GPa and temperature 1100–1200？C. Experimental results indicate that not only is the sintered rate more effective, but also the sintered temperature is lower under high pressure and high temperature than those of under normal pressure. It is thought that the adscititious pressure plays the key role in this process, which is discussed in detail. The composition and the structure of the as-prepared samples are recorded by XRD patterns. The result shows that the phases of Ba TiO3, BaBiO（2.77）, and Ba2Bi4Ti5O（18） with piezoelectric ceramic performance generate in the sintered samples. Furthermore, the surface morphology characteristics of the typical samples are also investigated using a scanning electron microscope. It indicates that the grain size and surface structure of the samples are closely related to the sintering temperature and sintering time. It is hoped that this study can provide a new train of thought for the preparation of lead-free piezoelectric ceramics with excellent performance.展开更多
Regenerated gratings seeded by type-I gratings are shown to withstand temperatures beyond 1000 ℃. The method of regeneration offers a new approach to increasing temperature resistance of stable fibre Bragg and other ...Regenerated gratings seeded by type-I gratings are shown to withstand temperatures beyond 1000 ℃. The method of regeneration offers a new approach to increasing temperature resistance of stable fibre Bragg and other gratings. These ultra-high temperature （UHT） gratings extend the applicability of silicate based components to high temperature applications such as monitoring of smelters and vehicle and aircraft engines to high power fibre lasers.展开更多
CuO added Pb0.92Sr0.06Ba0.02（Mg1/3Nb2/3）0.25（Ti0.53Zr0.47）0.75O3 ceramics were studied to prepare high-quality multilayer piezoelectric actuators with pure Ag electrodes at 900 ℃. CuO addition not only reduced th...CuO added Pb0.92Sr0.06Ba0.02（Mg1/3Nb2/3）0.25（Ti0.53Zr0.47）0.75O3 ceramics were studied to prepare high-quality multilayer piezoelectric actuators with pure Ag electrodes at 900 ℃. CuO addition not only reduced the sintering temperature significantly from 1260 ℃ to 900 ℃ but also improved the ceramic density to 7.742 g/cm3. The 0.7 wt.% CuO added ceramic sintered at 900 ℃ shows the remnant polarization （Pr） of 40 μC/cm2, 0.28% strain at 40 kV/cm, and the piezoelectric coefficient （d33） of 630 pC/N. This ceramic shows a strong relaxor characteristic with a Curie temperature of 200 ℃. Furthermore, the 0.7 wt.% CuO added ceramic and pure Ag electrodes were co-fired at 900 ℃ to prepare a high-quality multilayer piezoelectric actuator with a d33 of over 450 pC/N per ceramic layer.展开更多
It is found that the core-shell structured grains are easy to produce for fine grain doped BaTiO3 ceramics in the sintering process. We study the influence of the core-shell structure on the Curie-Weiss temperature an...It is found that the core-shell structured grains are easy to produce for fine grain doped BaTiO3 ceramics in the sintering process. We study the influence of the core-shell structure on the Curie-Weiss temperature and dielectric properties of BaTiO3 ceramics by using effective medium approximation （EMA）. Considering the second approximation, the dielectric properties of fine grain doped BaTiO3 ceramics are consistent with experimental data.展开更多
Ce^(3+)and Dy^(3+)co-doped oxyfluoride glasses and glass ceramics containing CeF3 nanocrystals are prepared in a reducing atmosphere.XRD measurements and the calculated lattice parameters suggest that Dy^(3+)ions are ...Ce^(3+)and Dy^(3+)co-doped oxyfluoride glasses and glass ceramics containing CeF3 nanocrystals are prepared in a reducing atmosphere.XRD measurements and the calculated lattice parameters suggest that Dy^(3+)ions are incorporated with precipitated CeF3 nanocrystals along with a rise in the Dy^(3+)concentration or an increase in the annealing temperature.The glass ceramics emit white light close to the CIE coordinates of(0.3,0.3),derived from a combination of Ce^(3+)and Dy^(3+)emission.The CIE chromaticity coordinates of the Ce^(3+)and Dya+codoped glass ceramics can be tuned by varying the ratio of Ce^(3+)/Dy^(3+),while the luminescence intensity can be enhanced by heat treatment above 620℃.展开更多
In this paper, a novel antenna is proposed for high-temperature testing, which can make the high-temperature pressure characteristics of a wireless passive ceramic pressure sensor demonstrated at up to a temperature o...In this paper, a novel antenna is proposed for high-temperature testing, which can make the high-temperature pressure characteristics of a wireless passive ceramic pressure sensor demonstrated at up to a temperature of 600℃. The design parameters of the antenna are similar to those of the sensor, which will increase the coupling strength between the sensor and testing antenna. The antenna is fabricated in thick film integrated technology, and the properties of the alumina ceramic and silver ensure the feasibility of the antenna in high-temperature environments. The sensor, coupled with the ceramic antenna, is investigated using a high-temperature pressure testing platform. The experimental measurement results show that the pressure signal in a harsh environment can be detected by the frequency diversity of the sensor.展开更多
In this paper, we present a compact low-temperature co-fired ceramic（LTCC） dual-band antenna by using the electromagnetic coupling effect concept for global positioning system（GPS） and universal mobile telecommuni...In this paper, we present a compact low-temperature co-fired ceramic（LTCC） dual-band antenna by using the electromagnetic coupling effect concept for global positioning system（GPS） and universal mobile telecommunication system（UMTS） applications. The overall dimension of the antenna is 8.6 mm × 13.0 mm × 1.1 mm. It consists of double meander lines and a via hole line. The top meander line operates at the upper band, and the bottom radiating patch is designed for the lower band. The via-hole line is employed to connect the double meander lines. Because of the effect of the coupled line,total dimension of the proposed antenna is greatly reduced. With the 2.5： voltage standing wave ratio（VSWR） impedance bandwidth definition, the lower and upper bands have the bandwidths of 110 MHz and 150 MHz, respectively. The proposed antenna is successfully designed, simulated, and analyzed by a high frequency structure simulator（HFSS）. And the antenna is manufactured by using the 0.95Zn2SiO4-0.05 CaTiO3ceramics（εr = 7.1, tanδ = 0.00038） that is prepared by ourselves. The results show that the antenna is compact, efficient, and of near omnidirectional radiation pattern.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 10804015 )the Science Foundation of the Education Department of Liaoning Province of China (Grant No. 2009A417)
文摘yb^3＋：Er^3＋ co-doped oxy-fluoride ceramics glass has been prepared. The mechanism of up-conversion emissions about Er^3＋ was discussed, and the temperature properties of green up-conversion fluorescence between 303 and 823 K were investigated. The results show that the sensitivity of this sample reaches its maximum value, about 0.0047 K^-1, when the temperature is 383 K, indicating that this kind of sample can be used as high temperature and high sensitivity optical temperature sensor.
基金Project supported by the Science and Technology Planning Project of Zhejiang Province,China(Grant No.2018C01046)Enterprise-funded Latitudinal Research Projects,China(Grant Nos.J2016-141,J2017-171,J2017-293,and J2017-243)
文摘The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence properties and the drift of chromaticity coordinates(CIE) of the(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors and the color conversion glass ceramics were studied in the sintering temperature range from 600℃ to 800℃. The luminous intensity and internal quantum yield(QY) of the blue-green phosphors and glass ceramics decreased with the sintering temperature increasing. When the sintering temperature increased beyond 750℃, the phosphors and the color conversion glass ceramics almost had no peak in photoluminescence(PL) and excitation(PLE) spectra. The results showed that the blue-green phosphors had poor thermal stability at higher temperature. The lattice structure of the phosphors was destroyed by the glass matrix and the Ce^3+ in the phosphors was oxidized to Ce^4+, which further caused a decrease in luminescent properties of the color conversion glass ceramics.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51372031,61171047,51132003,and 61271038)the Program for New Century Excellent Talents in University,China(Grant No.NCET-12-0090)Science Fund from the Science and Technology Department of Sichuan Province,China(Grant No.2013GZX0144)
文摘The effects of BaCu（B2Os） （BCB） addition on the microstructure, phase formation, and microwave dielectric proper- ties of BasNb4015-BaWO4 ceramic are investigated. As a sintering aid, BaCu（B2Os） ceramic could effectively lower the sintering temperature of BasNb4015-BaWO4 ceramic from 1100 ℃ to 950 ℃ due to the liquid-phase effect. Meanwhile, BaCu（B2Os） addition effectively improves the densification of BasNb4015-BaWO4 ceramic and significantly influences the microwave dielectric properties. X-ray diffraction analysis reveals that BasNb4015 and BaWO4 coexist with no crystal phase of BaCu（B2Os） in the sintered ceramics. The BasNb4015-BaWO4 ceramics with 1.0 wt% BaCu（B2Os） sintered at 950 ℃ for 2 h presents good microwave dielectric properties of er = 19.0, high Q× f of 33802 GHz and low vf of 2.5 ppm/℃.
基金by the National Natural Science Foundation of China under Grant No 10704021the Natural Scientific Research Innovation Foundation at the Harbin Institute of Technology(2009055).
文摘An optical temperature sensor based on infrared-to-visible upconversion emission in Er ^(3+)/Yb ^(3+)co−doped Bi3TiNbØ9(BTN)ceramics is reported.The fluorescence intensity ratio of the green upconversion photoluminescence(UC−PL)around 524 nm and 545 nm depends on temperature.The operating temperature range and the maximum sensitivity of Er ^(3+)/Yb ^(3+)co−doped Bi_(3)TiNbO_(9) ceramics are 123–693 K and 0.0032 K^(−1),respectively.BTN:Er3+/Yb3+ceramic has good thermal,physical and chemical stability,great UC−PL intensity and low cost fabrication.The results imply that Er ^(3+)/Yb ^(3+)co−doped Bi3TiNbO9 ceramic is promising for applications in wide-temperature-range sensors.
基金by the National Natural Science Foundation of China under Grant No 50802038the Technology Research Foundation of Shandong Province under Grant No 2008GG10003011.
文摘The strong temperature dependence of dielectric and piezoelectric properties is a big'bottleneck'for practical applications of KNN-based piezoceramics.In order to resolve this problem,Ca_(0.5)Sr_(0.5)TiO_(3)(CST)is doped into(Na_(0.53)K_(0.4)0_(7)Li_(0.063))Nb0.937Sb0.063O3(NKLNS)ceramics.The thermal stability of s11E and k31 in the temperature range from−50℃to 200℃for ceramics with 1.0 and 1.5 mol%CST is raised in comparison with ceramics without CST.Ceramics with 1.5 mol%CST exhibit high piezoelectric properties(d33=202 pC/N,kp=44%)and low dielectric loss(2%)at room temperature.The excellent piezoelectric properties,which are comparable to conventional PZT ceramics,indicate that these ceramics are promising candidates for lead-free piezoelectric applications.
基金Project supported by Fujian Science&Technology Innovation Laboratory for Energy Devices of China(21C-LAB)(Grant No.21C-OP-202013)the National Natural Science Foundation of China(Grant No.12064027)+1 种基金the International Science and Technology Cooperation Program of China(Grant No.2015DFA61800)the Scientific Research Fund of Jiangxi Provincial Education Department,China(Grant No.GJJ180973).
文摘Quaternary carbide Ti3NiAl2C ceramics has been investigated as a potential nuclear fusion structural material,and it has advantages in certain aspects compared with Ti2AlC,Ti3AlC2,and Ti3SiC2 structural materials.In this paper,quaternary carbide Ti3NiAl2C ceramics is pressurized to investigate its structural,mechanical,electronic properties,and Debye temperature.Quaternary carbide Ti3NiAl2C ceramics still maintains a cubic structure under pressure(0–110 GPa).At zero pressure,quaternary carbide Ti3NiAl2C ceramics only has three bonds:Ti–Al,Ni–Al,and Ti–C.However,at pressures of 20 GPa,30 GPa,40 GPa,60 GPa,and 70 GPa,new Ti–Ni,Ti–Ti,Al–Al,Ti–Al,and Ti–Ti bonds form.When the pressure reaches 20 GPa,the covalent bonds change to metallic bonds.The volume of quaternary carbide Ti3NiAl2C ceramics can be compressed to 72%of its original volume at most.Pressurization can improve the mechanical strength and ductility of quaternary carbide Ti3NiAl2C ceramics.At 50–60 GPa,its mechanical strength can be comparable to pure tungsten,and the material changes from brittleness to ductility.However,the degree of anisotropy of quaternary carbide Ti3NiAl2C ceramics increases with the increasing pressure.In addition,we also investigated the Debye temperature,density,melting point,hardness,and wear resistance of quaternary carbide Ti3NiAl2C ceramics under pressure.
文摘Based on Clausius-Mosotti equation and Debye relaxation theory, the dielectric model of yttria ceramics was developed according to the dielectric loss mechanism. The dielectric properties of yttria ceramics were predicted at high temperature. The temperature dependence and frequency dependence of dielectric constant and dielectric loss were discussed, respectively. As the result, the data calculated by theoretical dielectric model are in agreement with experimental data.
基金Project supported by the National Basic Research Program of China(Grant No.2012CB933100)the National Natural Science Foundation of China(Grant Nos.51132003,61021061,and 61171047)the Second Item of Strongpoint Industry of Guangdong Province,China(Grant No.2012A090100001)
文摘Development and application of ferrite materials for low temperature co-fired ceramic （LTCC） technology are dis- cussed, specifically addressing several typical ferrite materials such as M-type barium ferrite, NiCuZn ferrite, YIG ferrite, and lithium ferrite. In order to permit co-firing with a silver internal electrode in LTCC process, the sintering temperature of ferrite materials should be less than 950 ℃. These ferrite materials are research focuses and are applied in many ways in electronics.
基金Supported by the National Science and Technology Major Project of China(2012ZX04003081)
文摘An experimental and numerical study on the temperature field induced in the ultra-high frequency induction heating is carried out.With an aim of predicting the thermal history of the workpiece,the influence factors of temperature field,such as the induction frequency,the dimension of coil and the gap between coil and workpiece,are investigated considering temperature-dependent material properties by using FLUX 2Dsoftware.The temperature field characteristic in ultra-high induction heating is obtained and discussed.The numerical values are compared with the experimental results.A good agreement between them is observed with 7.9% errors.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.52272116 and 12002400)the Natural Science Foundation of Shandong Province (Grant No.ZR2021ME096)the Youth Innovation Team Project of Shandong Provincial Education Department (Grant No.2019KJJ012)。
文摘Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PMN-PT)piezoelectric ceramics have excellent piezoelectric properties and are used in a wide range of applications.Adjusting the solid solution ratios of PMN/PT and different concentrations of elemental doping are the main methods to modulate their piezoelectric coefficients.The combination of these controllable conditions leads to an exponential increase of possible compositions in ceramics,which makes it not easy to extend the sample data by additional experimental or theoretical calculations.In this paper,a physics-embedded machine learning method is proposed to overcome the difficulties in obtaining piezoelectric coefficients and Curie temperatures of Sm-doped PMN-PT ceramics with different components.In contrast to all-data-driven model,physics-embedded machine learning is able to learn nonlinear variation rules based on small datasets through potential correlation between ferroelectric properties.Based on the model outputs,the positions of morphotropic phase boundary(MPB)with different Sm doping amounts are explored.We also find the components with the best piezoelectric property and comprehensive performance.Moreover,we set up a database according to the obtained results,through which we can quickly find the optimal components of Sm-doped PMN-PT ceramics according to our specific needs.
基金The China Scholarship Council is acknowledged for the doctoral scholarship of Haoyu Zheng(201806160173)The German Federal Ministry for Education and Research is acknowledged for funding via the Project ARCADE(03SF0580A)。
文摘Proton conducting ceramic cells(PCCs)are an attractive emerging technology operating in the intermediate temperature range of 500 to 700℃.In this work,we evaluate the production of hydrogen at intermediate temperatures by proton conducting ceramic cell electrolysis(PCCEL).We demonstrate a highperformance steam electrolysis owing to a composite positrode based on BaGd_(0.8)La_(0.2)Co_(2)O_(6-δ)(BGLC1082)and BaZr0.5Ce0.4Y0.1O3-δ(BZCY541).The high reliability of PCCEL is demonstrated for 1680 h at a current density as high as-0.8 A cm^(-2)close to the thermoneutral cell voltage at 600℃.The electrolysis cell showed a specific energy consumption ranging from 54 to 66 kW h kg^(-1)that is comparable to state-of-the-art low temperature electrolysis technologies,while showing hydrogen production rates systematically higher than commercial solid oxide ceramic cells(SOCs).Compared to SOCs,the results verified the higher performances of PCCs at the relevant operating temperatures,due to the lower activation energy for proton transfer comparing with oxygen ion conduction.However,because of the p-type electronic conduction in protonic ceramics,the energy conversion rate of PCCs is relatively lower in steam electrolysis.The faradaic efficiency of the PCC in electrolysis mode can be increased at lower operating temperatures and in endothermic conditions,making PCCEL a technology of choice to valorize high temperature waste heat from industrial processes into hydrogen.To increase the faradaic efficiency by optimizing the materials,the cell design,or the operating strategy is a key challenge to address for future developments of PCCEL in order to achieve even more superior techno-economic merits.
基金Project supported by the National Natural Science Foundation of China(Grant No.51172089)the Natural Science Foundation of Education Department of Guizhou Province,China(Grant Nos.KY[2013]183 and LH[2015]7232)the Research Fund for the Doctoral Program of Tongren University,China(Grant No.DS1302)
文摘In this paper, the preparation of 0.08BiGaO3–0.90BaTiO3–0.02LiNbO3 is investigated at pressure 3.8 GPa and temperature 1100–1200？C. Experimental results indicate that not only is the sintered rate more effective, but also the sintered temperature is lower under high pressure and high temperature than those of under normal pressure. It is thought that the adscititious pressure plays the key role in this process, which is discussed in detail. The composition and the structure of the as-prepared samples are recorded by XRD patterns. The result shows that the phases of Ba TiO3, BaBiO（2.77）, and Ba2Bi4Ti5O（18） with piezoelectric ceramic performance generate in the sintered samples. Furthermore, the surface morphology characteristics of the typical samples are also investigated using a scanning electron microscope. It indicates that the grain size and surface structure of the samples are closely related to the sintering temperature and sintering time. It is hoped that this study can provide a new train of thought for the preparation of lead-free piezoelectric ceramics with excellent performance.
基金supported by the Australian Research Council (ARC) Discovery Project.
文摘Regenerated gratings seeded by type-I gratings are shown to withstand temperatures beyond 1000 ℃. The method of regeneration offers a new approach to increasing temperature resistance of stable fibre Bragg and other gratings. These ultra-high temperature （UHT） gratings extend the applicability of silicate based components to high temperature applications such as monitoring of smelters and vehicle and aircraft engines to high power fibre lasers.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51472118,51602156,52177072,and 11274174)the Fundamental Research Funds for the Central Universities,China(Grant Nos.30916011104 and 30916011208)
文摘CuO added Pb0.92Sr0.06Ba0.02（Mg1/3Nb2/3）0.25（Ti0.53Zr0.47）0.75O3 ceramics were studied to prepare high-quality multilayer piezoelectric actuators with pure Ag electrodes at 900 ℃. CuO addition not only reduced the sintering temperature significantly from 1260 ℃ to 900 ℃ but also improved the ceramic density to 7.742 g/cm3. The 0.7 wt.% CuO added ceramic sintered at 900 ℃ shows the remnant polarization （Pr） of 40 μC/cm2, 0.28% strain at 40 kV/cm, and the piezoelectric coefficient （d33） of 630 pC/N. This ceramic shows a strong relaxor characteristic with a Curie temperature of 200 ℃. Furthermore, the 0.7 wt.% CuO added ceramic and pure Ag electrodes were co-fired at 900 ℃ to prepare a high-quality multilayer piezoelectric actuator with a d33 of over 450 pC/N per ceramic layer.
基金supported by the Natural Science Foundation of Shanxi Province,China(Grant No.2012011028-2)
文摘It is found that the core-shell structured grains are easy to produce for fine grain doped BaTiO3 ceramics in the sintering process. We study the influence of the core-shell structure on the Curie-Weiss temperature and dielectric properties of BaTiO3 ceramics by using effective medium approximation （EMA）. Considering the second approximation, the dielectric properties of fine grain doped BaTiO3 ceramics are consistent with experimental data.
基金Supported by the National Natural Science Foundation of China(No 50902120)the Research Fund of the Doctoral Program of Higher Education of China(No 20100101120025)+1 种基金Science and Technology Innovative Research Team of Zhejiang Province(No 2009 R50010)Program for Changjiang Scholars and Innovative Research Team in University.
文摘Ce^(3+)and Dy^(3+)co-doped oxyfluoride glasses and glass ceramics containing CeF3 nanocrystals are prepared in a reducing atmosphere.XRD measurements and the calculated lattice parameters suggest that Dy^(3+)ions are incorporated with precipitated CeF3 nanocrystals along with a rise in the Dy^(3+)concentration or an increase in the annealing temperature.The glass ceramics emit white light close to the CIE coordinates of(0.3,0.3),derived from a combination of Ce^(3+)and Dy^(3+)emission.The CIE chromaticity coordinates of the Ce^(3+)and Dya+codoped glass ceramics can be tuned by varying the ratio of Ce^(3+)/Dy^(3+),while the luminescence intensity can be enhanced by heat treatment above 620℃.
基金Project supported by the National Natural Science Foundation for Distinguished Young Scholars,China(Grant No.51425505)the National Natural Science Foundation of China(Grant No.61471324)+1 种基金the Program for the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi Province,China(Grant No.2013-077)the Graduate Students Outstanding Innovation Project of Shanxi Province,China(Grant No.20143020)
文摘In this paper, a novel antenna is proposed for high-temperature testing, which can make the high-temperature pressure characteristics of a wireless passive ceramic pressure sensor demonstrated at up to a temperature of 600℃. The design parameters of the antenna are similar to those of the sensor, which will increase the coupling strength between the sensor and testing antenna. The antenna is fabricated in thick film integrated technology, and the properties of the alumina ceramic and silver ensure the feasibility of the antenna in high-temperature environments. The sensor, coupled with the ceramic antenna, is investigated using a high-temperature pressure testing platform. The experimental measurement results show that the pressure signal in a harsh environment can be detected by the frequency diversity of the sensor.
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20133718120009)the Natural Science Foundation of Shandong Provence,China(Grant Nos.ZR2013FQ002 and ZR2014FQ006)+2 种基金the China Postdoctoral Science Foundation(Grant No.2014M551935)the Qingdao Municipality Postdoctoral Science Foundation,Chinathe Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talents,China(Grant Nos.2013RCJJ042 and 2014RCJJ052)
文摘In this paper, we present a compact low-temperature co-fired ceramic（LTCC） dual-band antenna by using the electromagnetic coupling effect concept for global positioning system（GPS） and universal mobile telecommunication system（UMTS） applications. The overall dimension of the antenna is 8.6 mm × 13.0 mm × 1.1 mm. It consists of double meander lines and a via hole line. The top meander line operates at the upper band, and the bottom radiating patch is designed for the lower band. The via-hole line is employed to connect the double meander lines. Because of the effect of the coupled line,total dimension of the proposed antenna is greatly reduced. With the 2.5： voltage standing wave ratio（VSWR） impedance bandwidth definition, the lower and upper bands have the bandwidths of 110 MHz and 150 MHz, respectively. The proposed antenna is successfully designed, simulated, and analyzed by a high frequency structure simulator（HFSS）. And the antenna is manufactured by using the 0.95Zn2SiO4-0.05 CaTiO3ceramics（εr = 7.1, tanδ = 0.00038） that is prepared by ourselves. The results show that the antenna is compact, efficient, and of near omnidirectional radiation pattern.
