High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production meth...High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.展开更多
In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to character...In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.展开更多
A two-step leaching method in combination of acid and ethylene diaminetetraacetic acid disodium （EDTA-Na2） was applied to extract metals such as Cd, Cu, Fe, Pb and Zn from a zinc smelting slag. The results show that...A two-step leaching method in combination of acid and ethylene diaminetetraacetic acid disodium （EDTA-Na2） was applied to extract metals such as Cd, Cu, Fe, Pb and Zn from a zinc smelting slag. The results show that the extraction rates of Cd, Cu, Fe and Zn in slag reach 88.3%, 54.1%, 69.6% and 54.7%, respectively, while the extraction rate of Pb is only 0.05% leached with 1.25 mol/L sulfuric acid under the conditions of the ratio of slag to liquid of 100 g/L, 65 ℃ and 120 r/min for 2 h. However, Pb extraction rate from 1.25 mol/L sulfuric acid leached residue reaches as high as 66.5% by using 0.1 mol/L EDTA-Na2 solution. The results indicate that two-step sequential extraction procedure combining 1.25 mol/L sulfuric acid and 0.1 mol/L EDTA-Na2 solution can extensively extract Cd, Cu, Fe, Pb and Zn from zinc smelting slag.展开更多
For input saturated Hammerstein systems, the two-step predictive control strategy is adopted. The first step calculates the desired intermediate variable applying unconstrained linear modal and predictive control. The...For input saturated Hammerstein systems, the two-step predictive control strategy is adopted. The first step calculates the desired intermediate variable applying unconstrained linear modal and predictive control. The second step obtains the real-time control action by solving algebraic equation and desaturation. The case of immeasurable state is considered where the observer gain matrix is solved by Sylvester equation. The sufficient closed-loop stability condition is given and the designing and tuning algorithm for the domain of attraction is proposed. The theoretical results are validated by an example.展开更多
A two-step information extraction method is presented to capture the specific index-related information more accurately.In the first step,the overall process variables are separated into two sets based on Pearson corr...A two-step information extraction method is presented to capture the specific index-related information more accurately.In the first step,the overall process variables are separated into two sets based on Pearson correlation coefficient.One is process variables strongly related to the specific index and the other is process variables weakly related to the specific index.Through performing principal component analysis(PCA)on the two sets,the directions of latent variables have changed.In other words,the correlation between latent variables in the set with strong correlation and the specific index may become weaker.Meanwhile,the correlation between latent variables in the set with weak correlation and the specific index may be enhanced.In the second step,the two sets are further divided into a subset strongly related to the specific index and a subset weakly related to the specific index from the perspective of latent variables using Pearson correlation coefficient,respectively.Two subsets strongly related to the specific index form a new subspace related to the specific index.Then,a hybrid monitoring strategy based on predicted specific index using partial least squares(PLS)and T2statistics-based method is proposed for specific index-related process monitoring using comprehensive information.Predicted specific index reflects real-time information for the specific index.T2statistics are used to monitor specific index-related information.Finally,the proposed method is applied to Tennessee Eastman(TE).The results indicate the effectiveness of the proposed method.展开更多
NASICON-type structured NaTi2(PO4)3 has been regarded as a promising anode material for non-aqueous and aqueous Na-ion batteries,whereas its sodium storage performance was greatly restricted by its inherent inferior e...NASICON-type structured NaTi2(PO4)3 has been regarded as a promising anode material for non-aqueous and aqueous Na-ion batteries,whereas its sodium storage performance was greatly restricted by its inherent inferior electronic conductivity.In the present work,a two-step carbon modification method using prefabricated carbon spheres as support and phenolic resin as carbon source was proposed to prepare advanced NaTi2(PO4)3/C.The as-prepared composite with carbon spheres displayed a much higher reversible capacity(126.7 mA?h/g vs 106.7 mA?h/g at 0.5C)than the control sample without carbon spheres.Superior rate capability with discharge capacities of 115.1,95.5,80.8 mAh/g at 1C,10C,20C,respectively and long-term cycling stability with capacity retention of 92.4%after 1000 cycles at 5C were also observed.Owing to the designing of two-step carbon modification,although the as-prepared sample shows much smaller surface area,it possesses much better conductive network and more uniform particle distribution,resulting in higher electronic conductivity and faster ionic conductivity,thereby superior sodium storage ability at high rate.展开更多
Finite element modeling methods of steel-concrete composite structure with overlap slab were investigated. A two-step finite element method was presented. It was applied to analyze an extra long span composite bridge....Finite element modeling methods of steel-concrete composite structure with overlap slab were investigated. A two-step finite element method was presented. It was applied to analyze an extra long span composite bridge. The conversion of structure system and the mechanical behavior of the bridge were analyzed with two different construction methods. The stresses of steel beams, precast slabs and in-situ-place concrete under the total load were compared. The results show that steel-concrete composite structure with overlap slab has many advantages, the construction method that the top in-situ concrete and the concrete in construction joints are cast respectively is rather reasonable than the one that the top in-situ concrete and the concrete in construction joints are cast at the same time, and the two-step finite element method is affective to such large-scale structures.展开更多
基金Natural Science Foundation of Shanghai(24ZR1400800)he Natural Science Foundation of China(U23A20685,52073058,91963204)+1 种基金the National Key R&D Program of China(2021YFB3701400)Shanghai Sailing Program(23YF1400200)。
文摘High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.
基金Project(51378510) supported by the National Natural Science Foundation of China。
文摘In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.
基金Project(2011SK3262) supported by Science and Technology Program of Hunan Province,China
文摘A two-step leaching method in combination of acid and ethylene diaminetetraacetic acid disodium （EDTA-Na2） was applied to extract metals such as Cd, Cu, Fe, Pb and Zn from a zinc smelting slag. The results show that the extraction rates of Cd, Cu, Fe and Zn in slag reach 88.3%, 54.1%, 69.6% and 54.7%, respectively, while the extraction rate of Pb is only 0.05% leached with 1.25 mol/L sulfuric acid under the conditions of the ratio of slag to liquid of 100 g/L, 65 ℃ and 120 r/min for 2 h. However, Pb extraction rate from 1.25 mol/L sulfuric acid leached residue reaches as high as 66.5% by using 0.1 mol/L EDTA-Na2 solution. The results indicate that two-step sequential extraction procedure combining 1.25 mol/L sulfuric acid and 0.1 mol/L EDTA-Na2 solution can extensively extract Cd, Cu, Fe, Pb and Zn from zinc smelting slag.
文摘For input saturated Hammerstein systems, the two-step predictive control strategy is adopted. The first step calculates the desired intermediate variable applying unconstrained linear modal and predictive control. The second step obtains the real-time control action by solving algebraic equation and desaturation. The case of immeasurable state is considered where the observer gain matrix is solved by Sylvester equation. The sufficient closed-loop stability condition is given and the designing and tuning algorithm for the domain of attraction is proposed. The theoretical results are validated by an example.
基金Projects(61374140,61673173)supported by the National Natural Science Foundation of ChinaProjects(222201717006,222201714031)supported by the Fundamental Research Funds for the Central Universities,China
文摘A two-step information extraction method is presented to capture the specific index-related information more accurately.In the first step,the overall process variables are separated into two sets based on Pearson correlation coefficient.One is process variables strongly related to the specific index and the other is process variables weakly related to the specific index.Through performing principal component analysis(PCA)on the two sets,the directions of latent variables have changed.In other words,the correlation between latent variables in the set with strong correlation and the specific index may become weaker.Meanwhile,the correlation between latent variables in the set with weak correlation and the specific index may be enhanced.In the second step,the two sets are further divided into a subset strongly related to the specific index and a subset weakly related to the specific index from the perspective of latent variables using Pearson correlation coefficient,respectively.Two subsets strongly related to the specific index form a new subspace related to the specific index.Then,a hybrid monitoring strategy based on predicted specific index using partial least squares(PLS)and T2statistics-based method is proposed for specific index-related process monitoring using comprehensive information.Predicted specific index reflects real-time information for the specific index.T2statistics are used to monitor specific index-related information.Finally,the proposed method is applied to Tennessee Eastman(TE).The results indicate the effectiveness of the proposed method.
基金Projects(21671200,21571189)supported by the National Natural Science Foundation of ChinaProjects(2016TP1007,2017TP1001)supported by the Hunan Provincial Science and Technology Plan Project of China+1 种基金Project(2017CL17)supported by the Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province,ChinaProject(2016CXS009)supported by Innovation-Driven Project of Central South University,China
文摘NASICON-type structured NaTi2(PO4)3 has been regarded as a promising anode material for non-aqueous and aqueous Na-ion batteries,whereas its sodium storage performance was greatly restricted by its inherent inferior electronic conductivity.In the present work,a two-step carbon modification method using prefabricated carbon spheres as support and phenolic resin as carbon source was proposed to prepare advanced NaTi2(PO4)3/C.The as-prepared composite with carbon spheres displayed a much higher reversible capacity(126.7 mA?h/g vs 106.7 mA?h/g at 0.5C)than the control sample without carbon spheres.Superior rate capability with discharge capacities of 115.1,95.5,80.8 mAh/g at 1C,10C,20C,respectively and long-term cycling stability with capacity retention of 92.4%after 1000 cycles at 5C were also observed.Owing to the designing of two-step carbon modification,although the as-prepared sample shows much smaller surface area,it possesses much better conductive network and more uniform particle distribution,resulting in higher electronic conductivity and faster ionic conductivity,thereby superior sodium storage ability at high rate.
基金Project(2001G022) supported by the Science and Technology Development Program of Railways Department, China
文摘Finite element modeling methods of steel-concrete composite structure with overlap slab were investigated. A two-step finite element method was presented. It was applied to analyze an extra long span composite bridge. The conversion of structure system and the mechanical behavior of the bridge were analyzed with two different construction methods. The stresses of steel beams, precast slabs and in-situ-place concrete under the total load were compared. The results show that steel-concrete composite structure with overlap slab has many advantages, the construction method that the top in-situ concrete and the concrete in construction joints are cast respectively is rather reasonable than the one that the top in-situ concrete and the concrete in construction joints are cast at the same time, and the two-step finite element method is affective to such large-scale structures.
