This paper proposes a novel modified uni-traveling-carrier photodiode(MUTC-PD)featuring an electric field regulation layer:a p-type doped thin layer inserted behind the PD’s n-doped cliff layer.This electric field re...This paper proposes a novel modified uni-traveling-carrier photodiode(MUTC-PD)featuring an electric field regulation layer:a p-type doped thin layer inserted behind the PD’s n-doped cliff layer.This electric field regulation layer enhances the PD’s performance by not only reducing and smoothing the electric field intensity in the collector layer,allowing photo-generated electrons to transit at peak drift velocity,but also improving the electric field intensity in the depleted absorber layer and optimizing the photo-generated carriers’saturated transit performance.Additionally,the transport characteristics of the peak drift velocity of photogenerated electrons in the device’s collection layer can be used to optimize its parasitic characteristics.The electron’s peak drift velocity compensates for the lost transit time.Thus improving the 3 dB bandwidth of the PD’s photo response.Finally obtains a MUTC-PD with a 3 dB bandwidth of 68 GHz at a responsivity of 0.502 A/W,making it suitable for 100 Gbit/s optical receivers.展开更多
A novel substrate integrated microstrip to ultra-thin cavity filter transition operating in the W-band is proposed in this letter.The structure is a new method of connecting microstrip circuits and waveguide filters,a...A novel substrate integrated microstrip to ultra-thin cavity filter transition operating in the W-band is proposed in this letter.The structure is a new method of connecting microstrip circuits and waveguide filters,and this new structure enables a planar integrated transition from microstrip lines to ultra-thin cavity filters,thereby reducing the size of the transition structure and achieving miniaturization.The structure includes a conventional tapered microstrip transition structure,which guides the electromagnetic field from the microstrip line to the reduced-height dielectric-filled waveguide,and an air-filled matching cavity which is placed between the dielectric-filled waveguide and the ultra-thin cavity filter.The heights of the microstrip line,the dielectric-filled waveguide and the ultra-thin cavity filter are the same,enabling seamless integration within a planar radio-frequency(RF)circuit.To facilitate testing,mature finline transition structures are integrated at both ends of the microstrip line during fabrications.The simulation results of the fabricated microstrip to ultra-thin cavity filter transition with the finline transition structure,with a passband of 91.5-96.5 GHz,has an insertion loss of less than 1.9 dB and a return loss lower than-20 dB.And the whole structure has also been measured which achieves an insertion loss less than 2.6 dB and a return loss lower than-15 dB within the filter's passband,including the additional insertion loss introduced by the finline transitions.Finally,a W-band compact up-conversion module is designed,and the test results show that after using the proposed structure,the module achieves 95 dBc suppression of the 84 GHz local oscillator.It is also demonstrated that the structure proposed in this letter achieves miniaturization of the system integration without compromising the filter performance.展开更多
High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production meth...High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.展开更多
Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an excep...Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an exceptionalspecific capacitance of 190.8 mAh·g^(-1)at 1 A·g^(-1),greatly higher than the corresponding monometallic sulfides MnS(31.7 mAh·g^(-1))and Co_(3)S_(4)(86.7 mAh·g^(-1)).Impressively,the as-assembled MnCo_(2)S_(4)||porous carbon(PC)hybridsupercapacitor(HSC),showed an outstanding energy density of 76.88 Wh·kg^(-1)at a power density of 374.5 W·kg^(-1),remarkable cyclic performance with a capacity retention of 86.8% after 10000 charge-discharge cycles at 5 A·g^(-1),and excellent Coulombic efficiency of 99.7%.展开更多
Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown tha...Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown that this structure gives it exceptional physical properties that exceed those of cubic diamond,making it highly promising for groundbreaking applications in superhard cutting tools,wide-bandgap semiconductor devices,and materials for extreme environments.As a result,the controllable synthesis of hexagonal diamond has emerged as a cutting-edge research focus in materials science.This review briefly outlines the progress in this area,with a focus on the mechanisms governing its key synthesis conditions,its intrinsic physical properties,and its potential applications in various fields.展开更多
As a representative transition metal dichalcogenides(TMD),NiTe_(2)has an ultra-fast optical response,high carrier mobility,and excellent environmental stability.It has a broad application prospect in the fields of ene...As a representative transition metal dichalcogenides(TMD),NiTe_(2)has an ultra-fast optical response,high carrier mobility,and excellent environmental stability.It has a broad application prospect in the fields of ener-gy,biomedicine,optoelectronic devices,and so on.At present,there have been scant reports on the application of NiTe_(2)in the field of ultrafast photonics.In this work,NiTe_(2)was synthesized by chemical vapor deposition(CVD)and integrated with a tapered optical fiber to achieve mode-locking in an erbium-doped fiber laser(EDFL)and a thu-lium-doped fiber laser(TDFL).The mode-locked EDFL exhibited a pulse width of 678 fs and an output power of 3.92 mW.The pulse width of mode-locked TDFL was estimated to have a pulse width of 694 fs with an output power of 21.64 mW.These results demonstrate that NiTe_(2)is an effective saturable absorber material with potential applica-tions in the field of ultrafast optics.展开更多
The use of lithium-sulfur(Li-S)batteries is limited by sulfur redox reactions involving multi-phase transformations,especially at low-temperatures.To address this issue,we report a material(FCNS@NCFs)consisting of nit...The use of lithium-sulfur(Li-S)batteries is limited by sulfur redox reactions involving multi-phase transformations,especially at low-temperatures.To address this issue,we report a material(FCNS@NCFs)consisting of nitrogen-doped carbon fibers loaded with a ternary metal sulf-ide((Fe,Co,Ni)_(9)S_(8))for use as the sulfur host in Li-S batteries.This materi-al was prepared using transfer blot filter paper as the carbon precursor,thiourea as the source of nitrogen and sulfur,and FeCl_(3)·6H_(2)O,CoCl_(2)·6H_(2)O and NiCl_(2)·6H_(2)O as the metal ion sources.It was synthesized by an impreg-nation method followed by calcination.The nitrogen doping significantly in-creased the conductivity of the host,and the metal sulfides have excellent catalytic activities.Theoretical calculations,and adsorption and deposition experiments show that active sites on the surface of FCNS@NCFs selectively adsorb polysulfides,facilitate rapid adsorption and conversion,prevent cathode passivation and inhib-it the polysulfide shuttling.The FCNS@NCFs used as the sulfur host has excellent electrochemical properties.Its initial dis-charge capacity is 1639.0 mAh g^(−1) at 0.2 C and room temperature,and it remains a capacity of 1255.1 mAh g^(−1) after 100 cycles.At−20~C,it has an initial discharge capacity of 1578.5 mAh g^(−1) at 0.2 C,with a capacity of 867.5 mAh g^(−1) after 100 cycles.Its excellent performance at both ambient and low temperatures suggests a new way to produce high-performance low-temper-ature Li-S batteries.展开更多
Herein,an FMS/CC composite was successfully fabricated by depositing FeMoS_(4)onto a pristine carbon fiber cloth(CC)substrate via a facile two-step hydrothermal method.The amorphous nature of the FMS/CC compos-ite end...Herein,an FMS/CC composite was successfully fabricated by depositing FeMoS_(4)onto a pristine carbon fiber cloth(CC)substrate via a facile two-step hydrothermal method.The amorphous nature of the FMS/CC compos-ite endows it with abundant catalytically active sites,thereby accelerating the reduction of I_(3)^(-).More importantly,the dye-sensitized solar cells(DSSCs)prepared by scraping it on flexible titanium mesh with low resistance had low series resistance(Rs).Electrochemical characterizations revealed that the DSSCs employing the FMS/CC counter electrode achieved a power conversion efficiency(PCE)of ca.9.51%(surpassing the ca.8.15%efficiency of the Pt counter electrode),open-circuit voltage(Voc)of ca.0.79 V,short-circuit current density(Jsc)of ca.18.31 mA·cm^(-2),and fill factor(FF)of ca.0.65.Moreover,after 100 times of cyclic voltammetry(CV)test,the CV curve remained unchanged,indicating the excellent stability of FMS/CC in the electrolyte containing I_(3)^(-)/I^(-).展开更多
The ductile-to-brittle transition temperature(DBTT)of high strength steels can be optimized by tailoring microstructure and crystallographic orientation characteristics,where the start cooling temperature plays a key ...The ductile-to-brittle transition temperature(DBTT)of high strength steels can be optimized by tailoring microstructure and crystallographic orientation characteristics,where the start cooling temperature plays a key role.In this work,X70 steels with different start cooling temperatures were prepared through thermo-mechanical control process.The quasi-polygonal ferrite(QF),granular bainite(GB),bainitic ferrite(BF)and martensite-austenite constituents were formed at the start cooling temperatures of 780℃(C1),740℃(C2)and 700℃(C3).As start cooling temperature decreased,the amount of GB decreased,the microstructure of QF and BF increased.Microstructure characteristics of the three samples,such as high-angle grain boundaries(HAGBs),MA constituents and crystallographic orientation,also varied with the start cooling temperatures.C2 sample had the lowest DBTT value(−86℃)for its highest fraction of HAGBs,highest content of<110>oriented grains and lowest content of<001>oriented grains parallel to TD.The high density of{332}<113>and low density of rotated cube{001}<110>textures also contributed to the best impact toughness of C2 sample.In addition,a modified model was used in this paper to quantitatively predict the approximate DBTT value of steels.展开更多
During the electromagnetic railgun launch process,high temperature and high current conditions can lead to armature wear,affecting armature/rail contact and degrading launch performance.This paper starts with the anal...During the electromagnetic railgun launch process,high temperature and high current conditions can lead to armature wear,affecting armature/rail contact and degrading launch performance.This paper starts with the analysis of the metal liquid film formation at the armature/rail contact interface.1D and 3D models are developed based on the characteristic relational equation obtained from the melt liquid film model.These models incorporate thermodynamic equilibrium phase diagram,transient heat and mass transfer model,copper-aluminum alloy reaction model,nonlinear electrical conductivity relational equation and nonlinear thermal conductivity relational equation to analyze the temperature distribution and copper-aluminum intermetallic compounds(Cu-Al IMCs)formation in the melt liquid film.The wear mechanism and influence law of armature are explained in detail from different perspectives to un-derstand and predict the transition and gouging phenomena at the contact interface.The model's validity is confirmed by the results of electromagnetic launch experiments,providing insights for future structure design and material selection of the armature and rail.展开更多
The electricity-hydrogen integrated energy system(EH-IES)enables synergistic operation of electricity,heat,and hydrogen subsystems,supporting renewable energy integration and efficient multi-energy utilization in futu...The electricity-hydrogen integrated energy system(EH-IES)enables synergistic operation of electricity,heat,and hydrogen subsystems,supporting renewable energy integration and efficient multi-energy utilization in future low carbon societies.However,uncertainties from renewable energy and load variability threaten system safety and economy.Conventional chance-constrained programming(CCP)ensures reliable operation by limiting risk.However,increasing source-load uncertainties that can render CCP models infeasible and exacerbate operational risks.To address this,this paper proposes a risk-adjustable chance-constrained goal programming(RACCGP)model,integrating CCP and goal programming to balance risk and cost based on system risk assessment.An intelligent nonlinear goal programming method based on the state transition algorithm(STA)is developed,along with an improved discretized step transformation,to handle model nonlinearity and enhance computational efficiency.Experimental results show that the proposed model reduces costs while controlling risk compared to traditional CCP,and the solution method outperforms average sample sampling in efficiency and solution quality.展开更多
Recent advancements have led to the synthesis of various new metal-containing explosives,particularly energetic metal-organic frameworks(EMOFs),which feature high-energy ligands within well-ordered crystalline structu...Recent advancements have led to the synthesis of various new metal-containing explosives,particularly energetic metal-organic frameworks(EMOFs),which feature high-energy ligands within well-ordered crystalline structures.These explosives exhibit significant advantages over traditional compounds,including higher density,greater heats of detonation,improved mechanical hardness,and excellent thermal stability.To effectively evaluate their detonation performance,it is crucial to have a reliable method for predicting detonation heat,velocity,and pressure.This study leverages experimental data and outputs from the leading commercial computer code to identify suitable decomposition pathways for different metal oxides,facilitating straightforward calculations for the detonation performance of alkali metal salts,and metal coordination compounds,along with EMOFs.The new model enhances predictive reliability for detonation velocities,aligning more closely with experimental results,as evi-denced by a root mean square error(RMSE)of 0.68 km/s compared to 1.12 km/s for existing methods.Furthermore,it accommodates a broader range of compounds,including those containing Sr,Cd,and Ag,and provides predictions for EMOFs that are more consistent with computer code outputs than previous predictive models.展开更多
High temperature Raman spectra was recorded in this paper.The phase transition of β BaB 2O 4(BBO),a widely used crystal and potassium lithium niobate (KLN)crystal,a newly crystal was studied by the Raman spectra.The ...High temperature Raman spectra was recorded in this paper.The phase transition of β BaB 2O 4(BBO),a widely used crystal and potassium lithium niobate (KLN)crystal,a newly crystal was studied by the Raman spectra.The phase transition temperature of BBO from β BaB 2O 4 to α BaB 2O 4 was confirmed to be about 927℃ and 500℃ of KLN from ferro electric phase to para electric phase.It was observed that the change of the distribution of Ba 2+ and the change of the structure of [B 3O 6] 3- rings were important symbols of the phase transition of BBO.The finger peak (629cm -1 )belonged to [B 3O 6] 3- rings still existed when the temperature was up to 1400K.This indicated that the basic growing unit of BBO was[B 3O 6] 3- rings not atoms.The phase transition of KLN was mainly due to the position shifting of all the particles at the transition point.The movement of Li + ions had great influence on the vibration modes in the crystal. The relation between the phase transition and the efficiency of frequency doubling was also studied.It was often observed that when the power of the incident light was increased to a certain degree,the conversion efficiency was no longer increased.This mainly because the phase transition temperature of the crystal was lower and phase transition occurred in the crystal.展开更多
The convection in melt crystal growth influences the crystal integrity deeply.During space crystal growth,the buoyancy driven convection has been eliminated for the microgravity environment,therefroe,surface tension d...The convection in melt crystal growth influences the crystal integrity deeply.During space crystal growth,the buoyancy driven convection has been eliminated for the microgravity environment,therefroe,surface tension driven convection (Marangoni Convection) become the main convection form.But the Marangoni convection forms,starting condition,development process and its influence on crystal growth are still unclear now.At the present time,Many studies focused on simulating liquid Marangoni convection or numerical simulation.However,few studies concerned on real melt,especially on oxide melt. In this paper,an in situ observation is carried out to study the start and development of Marangoni convection of Bi 12 SiO 20 melt in a 2mm diameter loop like platinum crucible.The different states of steady convection and the transition from steady to oscillatory convection are observed.The critical Marangoni number is obtained as 22433 and it agreed with a dependence Ma c=2884Pr 0.638 for high Prandtl number melt.The authors also obtained a dependence of convection oscillatory frequency on melt temperature.It increases with temperature rising.展开更多
文摘This paper proposes a novel modified uni-traveling-carrier photodiode(MUTC-PD)featuring an electric field regulation layer:a p-type doped thin layer inserted behind the PD’s n-doped cliff layer.This electric field regulation layer enhances the PD’s performance by not only reducing and smoothing the electric field intensity in the collector layer,allowing photo-generated electrons to transit at peak drift velocity,but also improving the electric field intensity in the depleted absorber layer and optimizing the photo-generated carriers’saturated transit performance.Additionally,the transport characteristics of the peak drift velocity of photogenerated electrons in the device’s collection layer can be used to optimize its parasitic characteristics.The electron’s peak drift velocity compensates for the lost transit time.Thus improving the 3 dB bandwidth of the PD’s photo response.Finally obtains a MUTC-PD with a 3 dB bandwidth of 68 GHz at a responsivity of 0.502 A/W,making it suitable for 100 Gbit/s optical receivers.
基金Supported by the Fundamental Research Funds for the Central Universities(ZYGX2021J008)。
文摘A novel substrate integrated microstrip to ultra-thin cavity filter transition operating in the W-band is proposed in this letter.The structure is a new method of connecting microstrip circuits and waveguide filters,and this new structure enables a planar integrated transition from microstrip lines to ultra-thin cavity filters,thereby reducing the size of the transition structure and achieving miniaturization.The structure includes a conventional tapered microstrip transition structure,which guides the electromagnetic field from the microstrip line to the reduced-height dielectric-filled waveguide,and an air-filled matching cavity which is placed between the dielectric-filled waveguide and the ultra-thin cavity filter.The heights of the microstrip line,the dielectric-filled waveguide and the ultra-thin cavity filter are the same,enabling seamless integration within a planar radio-frequency(RF)circuit.To facilitate testing,mature finline transition structures are integrated at both ends of the microstrip line during fabrications.The simulation results of the fabricated microstrip to ultra-thin cavity filter transition with the finline transition structure,with a passband of 91.5-96.5 GHz,has an insertion loss of less than 1.9 dB and a return loss lower than-20 dB.And the whole structure has also been measured which achieves an insertion loss less than 2.6 dB and a return loss lower than-15 dB within the filter's passband,including the additional insertion loss introduced by the finline transitions.Finally,a W-band compact up-conversion module is designed,and the test results show that after using the proposed structure,the module achieves 95 dBc suppression of the 84 GHz local oscillator.It is also demonstrated that the structure proposed in this letter achieves miniaturization of the system integration without compromising the filter performance.
基金Natural Science Foundation of Shanghai(24ZR1400800)he Natural Science Foundation of China(U23A20685,52073058,91963204)+1 种基金the National Key R&D Program of China(2021YFB3701400)Shanghai Sailing Program(23YF1400200)。
文摘High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.
文摘Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an exceptionalspecific capacitance of 190.8 mAh·g^(-1)at 1 A·g^(-1),greatly higher than the corresponding monometallic sulfides MnS(31.7 mAh·g^(-1))and Co_(3)S_(4)(86.7 mAh·g^(-1)).Impressively,the as-assembled MnCo_(2)S_(4)||porous carbon(PC)hybridsupercapacitor(HSC),showed an outstanding energy density of 76.88 Wh·kg^(-1)at a power density of 374.5 W·kg^(-1),remarkable cyclic performance with a capacity retention of 86.8% after 10000 charge-discharge cycles at 5 A·g^(-1),and excellent Coulombic efficiency of 99.7%.
基金the National Natural Science Foundation of China(12274170 and 52225203)。
文摘Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown that this structure gives it exceptional physical properties that exceed those of cubic diamond,making it highly promising for groundbreaking applications in superhard cutting tools,wide-bandgap semiconductor devices,and materials for extreme environments.As a result,the controllable synthesis of hexagonal diamond has emerged as a cutting-edge research focus in materials science.This review briefly outlines the progress in this area,with a focus on the mechanisms governing its key synthesis conditions,its intrinsic physical properties,and its potential applications in various fields.
基金Supported by Guangdong Basic and Applied Basic Research Fund,China(2024A1515012429)。
文摘As a representative transition metal dichalcogenides(TMD),NiTe_(2)has an ultra-fast optical response,high carrier mobility,and excellent environmental stability.It has a broad application prospect in the fields of ener-gy,biomedicine,optoelectronic devices,and so on.At present,there have been scant reports on the application of NiTe_(2)in the field of ultrafast photonics.In this work,NiTe_(2)was synthesized by chemical vapor deposition(CVD)and integrated with a tapered optical fiber to achieve mode-locking in an erbium-doped fiber laser(EDFL)and a thu-lium-doped fiber laser(TDFL).The mode-locked EDFL exhibited a pulse width of 678 fs and an output power of 3.92 mW.The pulse width of mode-locked TDFL was estimated to have a pulse width of 694 fs with an output power of 21.64 mW.These results demonstrate that NiTe_(2)is an effective saturable absorber material with potential applica-tions in the field of ultrafast optics.
基金partially supported by National Natural Science Foundation of China(52172250)Institute of Process Engineering(IPE)Project for Frontier Basic Research(QYJC-2023-06)。
文摘The use of lithium-sulfur(Li-S)batteries is limited by sulfur redox reactions involving multi-phase transformations,especially at low-temperatures.To address this issue,we report a material(FCNS@NCFs)consisting of nitrogen-doped carbon fibers loaded with a ternary metal sulf-ide((Fe,Co,Ni)_(9)S_(8))for use as the sulfur host in Li-S batteries.This materi-al was prepared using transfer blot filter paper as the carbon precursor,thiourea as the source of nitrogen and sulfur,and FeCl_(3)·6H_(2)O,CoCl_(2)·6H_(2)O and NiCl_(2)·6H_(2)O as the metal ion sources.It was synthesized by an impreg-nation method followed by calcination.The nitrogen doping significantly in-creased the conductivity of the host,and the metal sulfides have excellent catalytic activities.Theoretical calculations,and adsorption and deposition experiments show that active sites on the surface of FCNS@NCFs selectively adsorb polysulfides,facilitate rapid adsorption and conversion,prevent cathode passivation and inhib-it the polysulfide shuttling.The FCNS@NCFs used as the sulfur host has excellent electrochemical properties.Its initial dis-charge capacity is 1639.0 mAh g^(−1) at 0.2 C and room temperature,and it remains a capacity of 1255.1 mAh g^(−1) after 100 cycles.At−20~C,it has an initial discharge capacity of 1578.5 mAh g^(−1) at 0.2 C,with a capacity of 867.5 mAh g^(−1) after 100 cycles.Its excellent performance at both ambient and low temperatures suggests a new way to produce high-performance low-temper-ature Li-S batteries.
文摘Herein,an FMS/CC composite was successfully fabricated by depositing FeMoS_(4)onto a pristine carbon fiber cloth(CC)substrate via a facile two-step hydrothermal method.The amorphous nature of the FMS/CC compos-ite endows it with abundant catalytically active sites,thereby accelerating the reduction of I_(3)^(-).More importantly,the dye-sensitized solar cells(DSSCs)prepared by scraping it on flexible titanium mesh with low resistance had low series resistance(Rs).Electrochemical characterizations revealed that the DSSCs employing the FMS/CC counter electrode achieved a power conversion efficiency(PCE)of ca.9.51%(surpassing the ca.8.15%efficiency of the Pt counter electrode),open-circuit voltage(Voc)of ca.0.79 V,short-circuit current density(Jsc)of ca.18.31 mA·cm^(-2),and fill factor(FF)of ca.0.65.Moreover,after 100 times of cyclic voltammetry(CV)test,the CV curve remained unchanged,indicating the excellent stability of FMS/CC in the electrolyte containing I_(3)^(-)/I^(-).
基金Project(2018XK2301) supported by the Change-Zhu-Tan National Independent Innavation Demonstration Zone Special Program,China。
文摘The ductile-to-brittle transition temperature(DBTT)of high strength steels can be optimized by tailoring microstructure and crystallographic orientation characteristics,where the start cooling temperature plays a key role.In this work,X70 steels with different start cooling temperatures were prepared through thermo-mechanical control process.The quasi-polygonal ferrite(QF),granular bainite(GB),bainitic ferrite(BF)and martensite-austenite constituents were formed at the start cooling temperatures of 780℃(C1),740℃(C2)and 700℃(C3).As start cooling temperature decreased,the amount of GB decreased,the microstructure of QF and BF increased.Microstructure characteristics of the three samples,such as high-angle grain boundaries(HAGBs),MA constituents and crystallographic orientation,also varied with the start cooling temperatures.C2 sample had the lowest DBTT value(−86℃)for its highest fraction of HAGBs,highest content of<110>oriented grains and lowest content of<001>oriented grains parallel to TD.The high density of{332}<113>and low density of rotated cube{001}<110>textures also contributed to the best impact toughness of C2 sample.In addition,a modified model was used in this paper to quantitatively predict the approximate DBTT value of steels.
文摘During the electromagnetic railgun launch process,high temperature and high current conditions can lead to armature wear,affecting armature/rail contact and degrading launch performance.This paper starts with the analysis of the metal liquid film formation at the armature/rail contact interface.1D and 3D models are developed based on the characteristic relational equation obtained from the melt liquid film model.These models incorporate thermodynamic equilibrium phase diagram,transient heat and mass transfer model,copper-aluminum alloy reaction model,nonlinear electrical conductivity relational equation and nonlinear thermal conductivity relational equation to analyze the temperature distribution and copper-aluminum intermetallic compounds(Cu-Al IMCs)formation in the melt liquid film.The wear mechanism and influence law of armature are explained in detail from different perspectives to un-derstand and predict the transition and gouging phenomena at the contact interface.The model's validity is confirmed by the results of electromagnetic launch experiments,providing insights for future structure design and material selection of the armature and rail.
基金Project(2022YFC2904502)supported by the National Key Research and Development Program of ChinaProject(62273357)supported by the National Natural Science Foundation of China。
文摘The electricity-hydrogen integrated energy system(EH-IES)enables synergistic operation of electricity,heat,and hydrogen subsystems,supporting renewable energy integration and efficient multi-energy utilization in future low carbon societies.However,uncertainties from renewable energy and load variability threaten system safety and economy.Conventional chance-constrained programming(CCP)ensures reliable operation by limiting risk.However,increasing source-load uncertainties that can render CCP models infeasible and exacerbate operational risks.To address this,this paper proposes a risk-adjustable chance-constrained goal programming(RACCGP)model,integrating CCP and goal programming to balance risk and cost based on system risk assessment.An intelligent nonlinear goal programming method based on the state transition algorithm(STA)is developed,along with an improved discretized step transformation,to handle model nonlinearity and enhance computational efficiency.Experimental results show that the proposed model reduces costs while controlling risk compared to traditional CCP,and the solution method outperforms average sample sampling in efficiency and solution quality.
基金the research committee at Malek Ashtar University of Technology (MUT) for their invaluable support of this project
文摘Recent advancements have led to the synthesis of various new metal-containing explosives,particularly energetic metal-organic frameworks(EMOFs),which feature high-energy ligands within well-ordered crystalline structures.These explosives exhibit significant advantages over traditional compounds,including higher density,greater heats of detonation,improved mechanical hardness,and excellent thermal stability.To effectively evaluate their detonation performance,it is crucial to have a reliable method for predicting detonation heat,velocity,and pressure.This study leverages experimental data and outputs from the leading commercial computer code to identify suitable decomposition pathways for different metal oxides,facilitating straightforward calculations for the detonation performance of alkali metal salts,and metal coordination compounds,along with EMOFs.The new model enhances predictive reliability for detonation velocities,aligning more closely with experimental results,as evi-denced by a root mean square error(RMSE)of 0.68 km/s compared to 1.12 km/s for existing methods.Furthermore,it accommodates a broader range of compounds,including those containing Sr,Cd,and Ag,and provides predictions for EMOFs that are more consistent with computer code outputs than previous predictive models.
文摘High temperature Raman spectra was recorded in this paper.The phase transition of β BaB 2O 4(BBO),a widely used crystal and potassium lithium niobate (KLN)crystal,a newly crystal was studied by the Raman spectra.The phase transition temperature of BBO from β BaB 2O 4 to α BaB 2O 4 was confirmed to be about 927℃ and 500℃ of KLN from ferro electric phase to para electric phase.It was observed that the change of the distribution of Ba 2+ and the change of the structure of [B 3O 6] 3- rings were important symbols of the phase transition of BBO.The finger peak (629cm -1 )belonged to [B 3O 6] 3- rings still existed when the temperature was up to 1400K.This indicated that the basic growing unit of BBO was[B 3O 6] 3- rings not atoms.The phase transition of KLN was mainly due to the position shifting of all the particles at the transition point.The movement of Li + ions had great influence on the vibration modes in the crystal. The relation between the phase transition and the efficiency of frequency doubling was also studied.It was often observed that when the power of the incident light was increased to a certain degree,the conversion efficiency was no longer increased.This mainly because the phase transition temperature of the crystal was lower and phase transition occurred in the crystal.
文摘The convection in melt crystal growth influences the crystal integrity deeply.During space crystal growth,the buoyancy driven convection has been eliminated for the microgravity environment,therefroe,surface tension driven convection (Marangoni Convection) become the main convection form.But the Marangoni convection forms,starting condition,development process and its influence on crystal growth are still unclear now.At the present time,Many studies focused on simulating liquid Marangoni convection or numerical simulation.However,few studies concerned on real melt,especially on oxide melt. In this paper,an in situ observation is carried out to study the start and development of Marangoni convection of Bi 12 SiO 20 melt in a 2mm diameter loop like platinum crucible.The different states of steady convection and the transition from steady to oscillatory convection are observed.The critical Marangoni number is obtained as 22433 and it agreed with a dependence Ma c=2884Pr 0.638 for high Prandtl number melt.The authors also obtained a dependence of convection oscillatory frequency on melt temperature.It increases with temperature rising.
