The purpose of this study is to explore the adsorption performance of meso-2,3-dimercaptosuccinic acid(DMSA)modified Fe3O4@SiO2 magnetic nanocomposite(Fe3O4@SiO2@DMSA)for Pb2+ions removal from aqueous solutions.The ef...The purpose of this study is to explore the adsorption performance of meso-2,3-dimercaptosuccinic acid(DMSA)modified Fe3O4@SiO2 magnetic nanocomposite(Fe3O4@SiO2@DMSA)for Pb2+ions removal from aqueous solutions.The effects of solution pH,initial concentration of Pb2+ions,contact time,and temperature on the amount of Pb2+adsorbed were investigated.Adsorption isotherms,adsorption kinetics,and thermodynamic analysis were also studied.The results showed that the maximum adsorption capacity of the Fe3O4@SiO2@DMSA composite is 50.5 mg/g at 298 K,which is higher than that of Fe3O4 and Fe3O4@SiO2 magnetic nanoparticles.The adsorption process agreed well with Langmuir adsorption isotherm models and pseudo second-order kinetics.The thermodynamic analysis revealed that the adsorption was spontaneous,endothermic and energetically driven in nature.展开更多
Water invasion is a common phenomenon in gas reservoirs with active edge-and-bottom aquifers.Due to high reservoir heterogeneity and production parameters,carbonate gas reservoirs feature exploitation obstacles and lo...Water invasion is a common phenomenon in gas reservoirs with active edge-and-bottom aquifers.Due to high reservoir heterogeneity and production parameters,carbonate gas reservoirs feature exploitation obstacles and low recovery factors.In this study,combined core displacement and nuclear magnetic resonance(NMR)experiments explored the reservoir gas−water two-phase flow and remaining microscopic gas distribution during water invasion and gas injection.Consequently,for fracture core,the water-phase relative permeability is higher and the co-seepage interval is narrower than that of three pore cores during water invasion,whereas the water-drive recovery efficiency at different invasion rates is the lowest among all cores.Gas injection is beneficial for reducing water saturation and partially restoring the gas-phase relative permeability,especially for fracture core.The remaining gas distribution and the content are related to the core properties.Compared with pore cores,the water invasion rate strongly influences the residual gas distribution in fracture core.The results enhance the understanding of the water invasion mechanism,gas injection to resume production and the remaining gas distribution,so as to improve the recovery factors of carbonate gas reservoirs.展开更多
基金Project(2013DFA51290)supported by International S&T Cooperation Program of China
文摘The purpose of this study is to explore the adsorption performance of meso-2,3-dimercaptosuccinic acid(DMSA)modified Fe3O4@SiO2 magnetic nanocomposite(Fe3O4@SiO2@DMSA)for Pb2+ions removal from aqueous solutions.The effects of solution pH,initial concentration of Pb2+ions,contact time,and temperature on the amount of Pb2+adsorbed were investigated.Adsorption isotherms,adsorption kinetics,and thermodynamic analysis were also studied.The results showed that the maximum adsorption capacity of the Fe3O4@SiO2@DMSA composite is 50.5 mg/g at 298 K,which is higher than that of Fe3O4 and Fe3O4@SiO2 magnetic nanoparticles.The adsorption process agreed well with Langmuir adsorption isotherm models and pseudo second-order kinetics.The thermodynamic analysis revealed that the adsorption was spontaneous,endothermic and energetically driven in nature.
基金Project(2016ZX05017)supported by the China National Science and Technology Major Project
文摘Water invasion is a common phenomenon in gas reservoirs with active edge-and-bottom aquifers.Due to high reservoir heterogeneity and production parameters,carbonate gas reservoirs feature exploitation obstacles and low recovery factors.In this study,combined core displacement and nuclear magnetic resonance(NMR)experiments explored the reservoir gas−water two-phase flow and remaining microscopic gas distribution during water invasion and gas injection.Consequently,for fracture core,the water-phase relative permeability is higher and the co-seepage interval is narrower than that of three pore cores during water invasion,whereas the water-drive recovery efficiency at different invasion rates is the lowest among all cores.Gas injection is beneficial for reducing water saturation and partially restoring the gas-phase relative permeability,especially for fracture core.The remaining gas distribution and the content are related to the core properties.Compared with pore cores,the water invasion rate strongly influences the residual gas distribution in fracture core.The results enhance the understanding of the water invasion mechanism,gas injection to resume production and the remaining gas distribution,so as to improve the recovery factors of carbonate gas reservoirs.
