In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperatur...In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperature swing can be equivalent to reducing maximum instantaneous phase copper loss in this paper.First,a two-level optimization aiming at minimizing maximum instantaneous phase copper loss at each electrical angle is proposed.Then,the optimization is transformed to a singlelevel optimization by introducing the auxiliary variable for easy solving.Considering that singleobjective optimization trades a great total copper loss for a small reduction of maximum phase copper loss,the optimization considering both instantaneous total copper loss and maximum phase copper loss is proposed,which has the same performance of temperature swing reduction but with lower total loss.In this way,the proposed control scheme can reduce maximum junction temperature by 11%.Both simulation and experimental results are presented to prove the effectiveness and superiority of the proposed control scheme for low-frequency temperature swing reduction.展开更多
For three phase four-wire active power filters （APFs）, several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor （UPF） and instantaneous act...For three phase four-wire active power filters （APFs）, several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor （UPF） and instantaneous active current （IAC） methods are analyzed and compared with each other. The interpretation of active and reactive currents in non-sinusoidal and unbalanced three-phase four-wire systems is given based on the generalized instantaneous reactive power theory. The performance and the characteristic are evaluated, and the application conditions of current reference generation strategies are concluded. Simulation results under different source voltages and loads verify the evaluation result.展开更多
The three-phase bridge inverter is used as the converter topology in the power controller for a 9 kW doubly salient permanent magnet （DSPM） motor. Compared with common three-phase bridge inverters, the proposed inve...The three-phase bridge inverter is used as the converter topology in the power controller for a 9 kW doubly salient permanent magnet （DSPM） motor. Compared with common three-phase bridge inverters, the proposed inverter works under more complicated conditions with different principles for special winding back EMFs, position signals of hall sensors, and the given mode of switches. The ideal steady driving principles of the inverter for the motor are given. The working state with asymmetric winding back EMFs, inaccurate position signals of hall sensors, and the changing input voltage is analyzed. Finally, experimental results vertify that the given anal ysis is correct.展开更多
Constructing heterojunction is an effective strategy to develop high-performance non-preciousmetal-based catalysts for electrochemical water splitting(WS).Herein,we design and prepare an N-doped-carbon-encapsulated Ni...Constructing heterojunction is an effective strategy to develop high-performance non-preciousmetal-based catalysts for electrochemical water splitting(WS).Herein,we design and prepare an N-doped-carbon-encapsulated Ni/MoO_(2) nano-needle with three-phase heterojunction(Ni/MoO_(2)@CN)for accelerating the WS under industrial alkaline condition.Density functional theory calculations reveal that the electrons are redistributed at the three-phase heterojunction interface,which optimizes the adsorption energy of H-and O-containing intermediates to obtain the best ΔG_(H*) for hydrogen evolution reaction(HER)and decrease the ΔG value of ratedetermining step for oxygen evolution reaction(OER),thus enhancing the HER/OER catalytic activity.Electrochemical results confirm that Ni/MoO_(2)@CN exhibits good activity for HER(ƞ_(-10)=33 mV,ƞ_(-1000)=267 mV)and OER(ƞ_(10)=250 mV,ƞ_(1000)=420 mV).It shows a low potential of 1.86 V at 1000 mA cm^(−2) for WS in 6.0 M KOH solution at 60℃ and can steadily operate for 330 h.This good HER/OER performance can be attributed to the three-phase heterojunction with high intrinsic activity and the self-supporting nano-needle with more active sites,faster mass diffusion,and bubbles release.This work provides a unique idea for designing high efficiency catalytic materials for WS.展开更多
A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert c...A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows： diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger （Ф 38×2 mm）, and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.展开更多
As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen e...As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen evolution reaction(HER),have become an emerging research direction and have gained increasing attention due to their advantages of environmental friendliness and sustainability.Various studies have been designed to accelerate sluggish kinetics but with limited results.Most of them promote the reaction by modulating the intrinsic properties of the catalyst,ignoring the synergistic effect of the reaction as a whole.Due to the introduction of gas,traditional liquid-solid two-phase reactions are no longer applicable to future research.Since gas-involved electrochemical reactions mostly occur at the junctions of gaseous reactants,liquid electrolytes and solid catalysts,the focus of future research on reaction kinetics should gradually shift to three-phase reaction interfaces.In this review,we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit,namely,the active site,mass diffusion and electron mass transfer.Subsequently,a series of modulation methods and relevant works are discussed in detail from the three improvement directions of‘exposing more active sites,promoting mass diffusion and accelerating electron transfer’.Definitively,we provide farsighted insights into the understanding and research of three-phase interfaces in the future and point out the possible development direction of future regulatory methods,hoping that this review can broaden the future applications of the three-phase interface,including but not limited to gas-involved electrochemical reactions.展开更多
Accurate characterization of fluid phase behavior is an important aspect of CO_(2) enhanced shale oil recovery.So far,however,there has been little discussion about the nanopore confinement effect,including adsorption...Accurate characterization of fluid phase behavior is an important aspect of CO_(2) enhanced shale oil recovery.So far,however,there has been little discussion about the nanopore confinement effect,including adsorption and capillarity on the phase equilibrium of water-oil-CO_(2) mixtures.In this study,an improved three-phase flash algorithm is proposed for calculating the phase behavior of water-oil-gas mixture on the basis of an extended Young-Laplace equation and a newly developed fugacity calculation model.The fugacity model can consider the effect of water-oil-gas adsorption on phase equilibrium.A water-Bakken oil-CO_(2) mixture is utilized to verify the accuracy of the flash algorithm and investigate the confinement effect.Results show that the confinement effect promotes the transfer of all components in the vapor phase to other phases,while the transfer of water,CO_(2),and lighter hydrocarbons is more significant.This leads to a large decrease,a large increase,and a small increase in the mole fraction of the vapor,oleic,and aqueous phases,respectively.When the confinement effect is considered,the density difference of vaporoleic phases decreases,and the interfacial tension of vapor-oleic phases decreases;however,the density difference of vapor-aqueous phases increases,the interfacial tension of vapor-aqueous phases still decreases.展开更多
We investigate the dynamic characteristics of oil-gas-water three-phase flow in terms of chaotic attractor comparison. In particular, we extract a statistic to characterize the dynamical difference in attractor probab...We investigate the dynamic characteristics of oil-gas-water three-phase flow in terms of chaotic attractor comparison. In particular, we extract a statistic to characterize the dynamical difference in attractor probability distribution. We first take time series from Logistic chaotic system with different parameters as examples to demonstrate the effectiveness of the method. Then we use this method to investigate the experimental signals from oil-gas-water three-phase flow. The results indicate that the extracted statistic is very sensitive to the change of flow parameters and can gain a quantitatively insight into the dynamic characteristics of different flow patterns.展开更多
Half-wavelength AC transmission(HWACT) is an ultra-long distance AC transmission technology, whose electrical distance is close to half-wavelength at the system power frequency. It is very important for the constructi...Half-wavelength AC transmission(HWACT) is an ultra-long distance AC transmission technology, whose electrical distance is close to half-wavelength at the system power frequency. It is very important for the construction and operation of HWACT to analyze its fault features and corresponding protection technology. In this paper, the steady-state voltage and current characteristics of the bus bar and fault point and the steady-state overvoltage distribution along the line will be analyzed when a three-phase symmetrical short-circuit fault occurs on an HWACT line. On this basis, the threephase fault characteristics for longer transmission lines are also studied.展开更多
A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit....A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.With the application of two-stage three-phase continuous power supply structure,the electrical characteristics exhibit new features differing from the existing traction system.In this work,the principle for voltage levels determining two-stage network is dissected in accordance with the requirements of traction network and electric locomotive.The equivalent model of three-phase traction system is built for deducing the formula of current distribution and voltage losses.Based on the chain network model of the traction network,a simulation model is established to analyze the electrical characteristics such as traction current distribution,voltage losses,system equivalent impedance,voltage distribution,voltage unbalance and regenerative energy utilization.In a few words,quite a lot traction current of about 99%is undertaken by long-section cable network.The proportion of system voltage losses is small attributed to the two-stage three-phase power supply structure,and the voltage unbal-ance caused by impedance asymmetry of traction network is less than 1‰.In addition,the utilization rate of regenerative energy for locomotive achieves a significant promotion of over 97%.展开更多
To study the flow characteristics of three-phase foam in gob area,different perfusion experiments in coal mine gob were designed and put forward in the paper.Through the observation of flow range,flow characteristics ...To study the flow characteristics of three-phase foam in gob area,different perfusion experiments in coal mine gob were designed and put forward in the paper.Through the observation of flow range,flow characteristics of three phase foam were analyzed with different flow rates.And,unsteady seepage process of three-phase foam was simulated with CFD software.Base on experiment and numerical simulation results,flow characteristics of three-phase foam and its major influence factors are discussed,and the optimal arrangement distribution of mine fire control drills is also determined.Research results show that the flow range and stacking height of three-phase foam in gob are significantly influenced by gravity.The vertical stacking height and horizontal diffusion distance of three-phase foam are also directly related to the flow volume of foam perfusion,the larger flow single hole perfusion volume,the higher stacking height and the longer diffusion distance could be obtained.展开更多
The present study aims at investigating the effect of temperature variation due to heat transfer between the formation and drilling fluids considering influx from the reservoir in the underbalanced drilling condition....The present study aims at investigating the effect of temperature variation due to heat transfer between the formation and drilling fluids considering influx from the reservoir in the underbalanced drilling condition. Gas-liquid-solid three-phase flow model considering transient thermal interaction with the formation was applied to simulate wellbore fluid to calculate the wellbore temperature and pressure and analyze the influence of different parameters on fluid pressure and temperature distribution in annulus. The results show that the non-isothermal three-phase flow model with thermal consideration gives more accurate prediction of bottom-hole pressure(BHP) compared to other models considering geothermal temperature. Viscous dissipation, the heat produced by friction between the rotating drilling-string and well wall and drill bit drilling, and influx of oil and gas from reservoir have significant impact on the distribution of fluid temperature in the wellbore, which in turn affects the BHP. Bottom-hole fluid temperature decreases with increasing liquid flow rate, circulation time, and specific heat of liquid and gas but it increases with increasing in gas flow rate. It was found that BHP is strongly depended on the gas and liquid flow rates but it has weak dependence on the circulation time and specific heat of liquid and gas. BHP increase with increasing liquid flow rate and decreases with increasing gas flow rate.展开更多
In this article,vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers subjected to blast load are studied.Higher-order ES-MITC3 element based on higher-order...In this article,vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers subjected to blast load are studied.Higher-order ES-MITC3 element based on higher-order shear deformation theory(HSDT)to achieve the governing equations.The sandwich plates with the ultra-light feature of the auxetic honeycomb core layer(negative Poisson’s ratio)and reinforced by two laminated three-phase skin layers.The obtained results in our work are compared with other previously published to confirm accuracy and reliability.In addition,the effects of parameters such as geometrical and material parameters on the vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers are fully investigated.展开更多
Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to i...Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to its low solubility in aqueous electrolytes.Herein,we propose phosphorus-activated Cu electrocatalysts to generate electron-deficient Cu sites on the catalyst surface to promote the adsorption of N_(2) molecules.The eNRR system is further modified using a gas diffusion electrode(GDE) coated with polytetrafluoroethylene(PTFE) to form an effective three-phase boundary of liquid water-gas N_(2)-solid catalyst to facilitate easy access of N_(2) to the catalytic sites.As a result,the new catalyst in the flow-type cell records a Faradaic efficiency of 13.15% and an NH_(3) production rate of 7.69 μg h^(-1) cm^(-2) at-0.2 V_(RHE),which represent 3.56 and 59.2 times increases from those obtained with a pristine Cu electrode in a typical electrolytic cell.This work represents a successful demonstration of dual modification strategies;catalyst modification and N_(2) supplying system engineering,and the results would provide a useful platform for further developments of electrocatalysts and reaction systems.展开更多
With the help of digital image processing technology, an automatic measurement method for the three-phase contact angles in the pore throats of the microfluidic model was established using the microfluidic water flood...With the help of digital image processing technology, an automatic measurement method for the three-phase contact angles in the pore throats of the microfluidic model was established using the microfluidic water flooding experiment videos as the data source. The results of the new method were verified through comparing with the manual measurement data.On this basis, the dynamic changes of the three-phase contact angles under flow conditions were clarified by the contact angles probability density curve and mean value change curve. The results show that, for water-wetting rocks, the mean value of the contact angles is acute angle during the early stage of the water flooding process, and it increases with the displacement time and becomes obtuse angle in the middle-late stage of displacement as the dominant force of oil phase gradually changes from viscous force to capillary force. The droplet flow in the remaining oil occurs in the central part of the pore throats, without three-phase contact angle. The contact angles for the porous flow and the columnar flow change slightly during the displacement and present as obtuse angles in view of mean values, which makes the remaining oil poorly movable and thus hard to be recovered. The mean value of the contact angle for the cluster flow tends to increase in the flooding process, which makes the remaining oil more difficult to be recovered. The contact angles for the membrane flow are mainly obtuse angles and reach the highest mean value in the late stage of displacement, which makes the remaining oil most difficult to be recovered. After displacement, the remaining oils under different flow regimes are just subjected to capillary force, with obtuse contact angles, and the wettability of the pore throat walls in the microfluidic model tends to be oil-wet under the action of crude oil.展开更多
A single-stage single-switch high- frequency electronic ballast topology is presented. The circuit topology is the integration of a buck power- factor-correction （PFC） converter and a class E resonant inverter with ...A single-stage single-switch high- frequency electronic ballast topology is presented. The circuit topology is the integration of a buck power- factor-correction （PFC） converter and a class E resonant inverter with only one active power switch. The buck converter is operated in discontinuous conduction mode and at a fixed switching frequency, and constant duty cycle to achieve high power factor and it can be controlled easily. Detailed analysis of the operation and characteristics of the circuit is provided. Simulation results satisfy present standard requirements.展开更多
The intermediate gearbox of a helicopter operates under splash lubrication.If the bearing produces metal particles due to insufficient lubrication or wear,whether it can be adsorbed by the metal particles signal at th...The intermediate gearbox of a helicopter operates under splash lubrication.If the bearing produces metal particles due to insufficient lubrication or wear,whether it can be adsorbed by the metal particles signal at the bottom of the gearbox and alarm directly affects the flight safety of the helicopter.Based on the CFD method,the factors affecting the accessibility of metal particles are analyzed by using the volume of fluid-discrete phase model(VOFDPM)coupling model,the RNG k-ɛturbulence model and the dynamic grid technology.Furthermore,the optimization research on the casing structure is conducted.Experimental results show that the accessibility of metal particles is optimal when the gear speed is 6000 rad/min or the immersion depth is 24 mm.The density of metal particles exhibits a nonlinear relationship with their accessibility,and the particle size has a relatively small impact on their accessibility without an order of magnitude change.展开更多
The Baijigou Mine fire in Ningxia Province,which broke out on October 24,2003,affected more than 108 m3 of the mine and was probably the largest underground fire in China in recent years. In addition to its size,the f...The Baijigou Mine fire in Ningxia Province,which broke out on October 24,2003,affected more than 108 m3 of the mine and was probably the largest underground fire in China in recent years. In addition to its size,the fire was also characterized by excessive air leakage and the potential for violent methane explosions. A series of new measures were taken to fight the fire,including sealing intake tunnels with water,injecting three-phase foam through boreholes,and flushing with a large volume of nitrogen. The fire was successfully extinguished and production re-sumed soon afterwards; not one single methane explosion occurred during fire-fighting and afterwards.展开更多
Due to the low porosity and low permeability in unconventional reservoirs,a large amount of crude oil is trapped in micro-to nano-sized pores and throats,which leads to low oil recovery.Nanofluids have great potential...Due to the low porosity and low permeability in unconventional reservoirs,a large amount of crude oil is trapped in micro-to nano-sized pores and throats,which leads to low oil recovery.Nanofluids have great potential to enhance oil recovery(EOR)in low permeability reservoirs.In this work,the regulating ability of a nanofluid at the oil/water/solid three-phase interface was explored.The results indicated that the nanofluid reduced the oil/water interfacial tension by two orders of magnitude,and the expansion modulus of oil/water interface was increased by 77% at equilibrium.In addition,the solid surface roughness was reduced by 50%,and the three-phase contact angle dropped from 135(oil-wet)to 48(water-wet).Combining the displacement experiments using a 2.5D reservoir micromodel and a microchannel model,the remaining oil mobilization and migration processes in micro-to nano-scale pores and throats were visualized.It was found that the nanofluid dispersed the remaining oil into small oil droplets and displaced them via multiple mechanisms in porous media.Moreover,the high strength interface film formed by the nanofluid inhibited the coalescence of oil droplets and improved the flowing ability.These results help to understand the EOR mechanisms of nanofluids in low permeability reservoirs from a visual perspective.展开更多
基金supported by the National Natural Science Foundation of China(No.62271109)。
文摘In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperature swing can be equivalent to reducing maximum instantaneous phase copper loss in this paper.First,a two-level optimization aiming at minimizing maximum instantaneous phase copper loss at each electrical angle is proposed.Then,the optimization is transformed to a singlelevel optimization by introducing the auxiliary variable for easy solving.Considering that singleobjective optimization trades a great total copper loss for a small reduction of maximum phase copper loss,the optimization considering both instantaneous total copper loss and maximum phase copper loss is proposed,which has the same performance of temperature swing reduction but with lower total loss.In this way,the proposed control scheme can reduce maximum junction temperature by 11%.Both simulation and experimental results are presented to prove the effectiveness and superiority of the proposed control scheme for low-frequency temperature swing reduction.
文摘For three phase four-wire active power filters （APFs）, several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor （UPF） and instantaneous active current （IAC） methods are analyzed and compared with each other. The interpretation of active and reactive currents in non-sinusoidal and unbalanced three-phase four-wire systems is given based on the generalized instantaneous reactive power theory. The performance and the characteristic are evaluated, and the application conditions of current reference generation strategies are concluded. Simulation results under different source voltages and loads verify the evaluation result.
文摘The three-phase bridge inverter is used as the converter topology in the power controller for a 9 kW doubly salient permanent magnet （DSPM） motor. Compared with common three-phase bridge inverters, the proposed inverter works under more complicated conditions with different principles for special winding back EMFs, position signals of hall sensors, and the given mode of switches. The ideal steady driving principles of the inverter for the motor are given. The working state with asymmetric winding back EMFs, inaccurate position signals of hall sensors, and the changing input voltage is analyzed. Finally, experimental results vertify that the given anal ysis is correct.
基金supported by the National Natural Science Foundation of China(21872040,22162004)the Hundred Talents Program of Guangxi Universities,the Excellent Scholars and Innovation Team of Guangxi Universities+1 种基金the Innovation Project of Guangxi Graduate Education(YCBZ2021011)the High-performance Computing Platform of Guangxi University.
文摘Constructing heterojunction is an effective strategy to develop high-performance non-preciousmetal-based catalysts for electrochemical water splitting(WS).Herein,we design and prepare an N-doped-carbon-encapsulated Ni/MoO_(2) nano-needle with three-phase heterojunction(Ni/MoO_(2)@CN)for accelerating the WS under industrial alkaline condition.Density functional theory calculations reveal that the electrons are redistributed at the three-phase heterojunction interface,which optimizes the adsorption energy of H-and O-containing intermediates to obtain the best ΔG_(H*) for hydrogen evolution reaction(HER)and decrease the ΔG value of ratedetermining step for oxygen evolution reaction(OER),thus enhancing the HER/OER catalytic activity.Electrochemical results confirm that Ni/MoO_(2)@CN exhibits good activity for HER(ƞ_(-10)=33 mV,ƞ_(-1000)=267 mV)and OER(ƞ_(10)=250 mV,ƞ_(1000)=420 mV).It shows a low potential of 1.86 V at 1000 mA cm^(−2) for WS in 6.0 M KOH solution at 60℃ and can steadily operate for 330 h.This good HER/OER performance can be attributed to the three-phase heterojunction with high intrinsic activity and the self-supporting nano-needle with more active sites,faster mass diffusion,and bubbles release.This work provides a unique idea for designing high efficiency catalytic materials for WS.
基金This work was supported by the National Basic Research Program of China (2005CB221205)
文摘A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows： diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger （Ф 38×2 mm）, and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.
基金supported by the National Natural Science Foundation of China(U21A20332,52103226,52202275,52203314,and 12204253)the Distinguished Young Scholars Fund of Jiangsu Province(BK20220061)the Fellowship of China Postdoctoral Science Foundation(2021 M702382)。
文摘As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen evolution reaction(HER),have become an emerging research direction and have gained increasing attention due to their advantages of environmental friendliness and sustainability.Various studies have been designed to accelerate sluggish kinetics but with limited results.Most of them promote the reaction by modulating the intrinsic properties of the catalyst,ignoring the synergistic effect of the reaction as a whole.Due to the introduction of gas,traditional liquid-solid two-phase reactions are no longer applicable to future research.Since gas-involved electrochemical reactions mostly occur at the junctions of gaseous reactants,liquid electrolytes and solid catalysts,the focus of future research on reaction kinetics should gradually shift to three-phase reaction interfaces.In this review,we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit,namely,the active site,mass diffusion and electron mass transfer.Subsequently,a series of modulation methods and relevant works are discussed in detail from the three improvement directions of‘exposing more active sites,promoting mass diffusion and accelerating electron transfer’.Definitively,we provide farsighted insights into the understanding and research of three-phase interfaces in the future and point out the possible development direction of future regulatory methods,hoping that this review can broaden the future applications of the three-phase interface,including but not limited to gas-involved electrochemical reactions.
基金The financial support from National Natural Science Foundation of China(52074319,U19B6003-02)Strategic Cooperation Technology Project of CNPC(ZLZX 2020-01-08)。
文摘Accurate characterization of fluid phase behavior is an important aspect of CO_(2) enhanced shale oil recovery.So far,however,there has been little discussion about the nanopore confinement effect,including adsorption and capillarity on the phase equilibrium of water-oil-CO_(2) mixtures.In this study,an improved three-phase flash algorithm is proposed for calculating the phase behavior of water-oil-gas mixture on the basis of an extended Young-Laplace equation and a newly developed fugacity calculation model.The fugacity model can consider the effect of water-oil-gas adsorption on phase equilibrium.A water-Bakken oil-CO_(2) mixture is utilized to verify the accuracy of the flash algorithm and investigate the confinement effect.Results show that the confinement effect promotes the transfer of all components in the vapor phase to other phases,while the transfer of water,CO_(2),and lighter hydrocarbons is more significant.This leads to a large decrease,a large increase,and a small increase in the mole fraction of the vapor,oleic,and aqueous phases,respectively.When the confinement effect is considered,the density difference of vaporoleic phases decreases,and the interfacial tension of vapor-oleic phases decreases;however,the density difference of vapor-aqueous phases increases,the interfacial tension of vapor-aqueous phases still decreases.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.41174109 and 61104148)the National Science and Technology Major Project of the Ministry of Science and Technology of China(Grant No.2011ZX05020-006)the Tianjin City High School Science and Technology Fund Planning Project,China(Grant No.20130718)
文摘We investigate the dynamic characteristics of oil-gas-water three-phase flow in terms of chaotic attractor comparison. In particular, we extract a statistic to characterize the dynamical difference in attractor probability distribution. We first take time series from Logistic chaotic system with different parameters as examples to demonstrate the effectiveness of the method. Then we use this method to investigate the experimental signals from oil-gas-water three-phase flow. The results indicate that the extracted statistic is very sensitive to the change of flow parameters and can gain a quantitatively insight into the dynamic characteristics of different flow patterns.
基金supported by National Key Research and Development Program of China(2016YFB0900100)
文摘Half-wavelength AC transmission(HWACT) is an ultra-long distance AC transmission technology, whose electrical distance is close to half-wavelength at the system power frequency. It is very important for the construction and operation of HWACT to analyze its fault features and corresponding protection technology. In this paper, the steady-state voltage and current characteristics of the bus bar and fault point and the steady-state overvoltage distribution along the line will be analyzed when a three-phase symmetrical short-circuit fault occurs on an HWACT line. On this basis, the threephase fault characteristics for longer transmission lines are also studied.
基金This research was supported by the Science and Technology Plan Project of Sichuan Province(No.21YYJC3324)the Science and Technology Plan Project of Sichuan Province(No.2022YFQ0104).
文摘A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.With the application of two-stage three-phase continuous power supply structure,the electrical characteristics exhibit new features differing from the existing traction system.In this work,the principle for voltage levels determining two-stage network is dissected in accordance with the requirements of traction network and electric locomotive.The equivalent model of three-phase traction system is built for deducing the formula of current distribution and voltage losses.Based on the chain network model of the traction network,a simulation model is established to analyze the electrical characteristics such as traction current distribution,voltage losses,system equivalent impedance,voltage distribution,voltage unbalance and regenerative energy utilization.In a few words,quite a lot traction current of about 99%is undertaken by long-section cable network.The proportion of system voltage losses is small attributed to the two-stage three-phase power supply structure,and the voltage unbal-ance caused by impedance asymmetry of traction network is less than 1‰.In addition,the utilization rate of regenerative energy for locomotive achieves a significant promotion of over 97%.
基金supported by the National Natural Science Foundation of China(Nos.51104154,51134020)Central Subordinate University Basic Scientific Research Foundation of China(No.2011QNA05)CUMT Innovation and Entrepreneurship Fund for Undergraduates of China(Nos.201403,201503)
文摘To study the flow characteristics of three-phase foam in gob area,different perfusion experiments in coal mine gob were designed and put forward in the paper.Through the observation of flow range,flow characteristics of three phase foam were analyzed with different flow rates.And,unsteady seepage process of three-phase foam was simulated with CFD software.Base on experiment and numerical simulation results,flow characteristics of three-phase foam and its major influence factors are discussed,and the optimal arrangement distribution of mine fire control drills is also determined.Research results show that the flow range and stacking height of three-phase foam in gob are significantly influenced by gravity.The vertical stacking height and horizontal diffusion distance of three-phase foam are also directly related to the flow volume of foam perfusion,the larger flow single hole perfusion volume,the higher stacking height and the longer diffusion distance could be obtained.
文摘The present study aims at investigating the effect of temperature variation due to heat transfer between the formation and drilling fluids considering influx from the reservoir in the underbalanced drilling condition. Gas-liquid-solid three-phase flow model considering transient thermal interaction with the formation was applied to simulate wellbore fluid to calculate the wellbore temperature and pressure and analyze the influence of different parameters on fluid pressure and temperature distribution in annulus. The results show that the non-isothermal three-phase flow model with thermal consideration gives more accurate prediction of bottom-hole pressure(BHP) compared to other models considering geothermal temperature. Viscous dissipation, the heat produced by friction between the rotating drilling-string and well wall and drill bit drilling, and influx of oil and gas from reservoir have significant impact on the distribution of fluid temperature in the wellbore, which in turn affects the BHP. Bottom-hole fluid temperature decreases with increasing liquid flow rate, circulation time, and specific heat of liquid and gas but it increases with increasing in gas flow rate. It was found that BHP is strongly depended on the gas and liquid flow rates but it has weak dependence on the circulation time and specific heat of liquid and gas. BHP increase with increasing liquid flow rate and decreases with increasing gas flow rate.
文摘In this article,vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers subjected to blast load are studied.Higher-order ES-MITC3 element based on higher-order shear deformation theory(HSDT)to achieve the governing equations.The sandwich plates with the ultra-light feature of the auxetic honeycomb core layer(negative Poisson’s ratio)and reinforced by two laminated three-phase skin layers.The obtained results in our work are compared with other previously published to confirm accuracy and reliability.In addition,the effects of parameters such as geometrical and material parameters on the vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers are fully investigated.
基金supported by the Climate Change Response Project (NRF-2019M1A2A2065612)the Brainlink Project (NRF2022H1D3A3A01081140)+3 种基金the NRF-2021R1A4A3027878 and the No. RS-2023-00212273 funded by the Ministry of Science and ICT of Korea via National Research Foundationresearch funds from Hanhwa Solutions Chemicals (1.220029.01)UNIST (1.190013.01)supported by the Institute for Basic Science (IBS-R019-D1)。
文摘Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to its low solubility in aqueous electrolytes.Herein,we propose phosphorus-activated Cu electrocatalysts to generate electron-deficient Cu sites on the catalyst surface to promote the adsorption of N_(2) molecules.The eNRR system is further modified using a gas diffusion electrode(GDE) coated with polytetrafluoroethylene(PTFE) to form an effective three-phase boundary of liquid water-gas N_(2)-solid catalyst to facilitate easy access of N_(2) to the catalytic sites.As a result,the new catalyst in the flow-type cell records a Faradaic efficiency of 13.15% and an NH_(3) production rate of 7.69 μg h^(-1) cm^(-2) at-0.2 V_(RHE),which represent 3.56 and 59.2 times increases from those obtained with a pristine Cu electrode in a typical electrolytic cell.This work represents a successful demonstration of dual modification strategies;catalyst modification and N_(2) supplying system engineering,and the results would provide a useful platform for further developments of electrocatalysts and reaction systems.
基金Supported by National Science and Technology Major Project of China (51674271)Major Technical Field Test of PetroChina (2019F-33)。
文摘With the help of digital image processing technology, an automatic measurement method for the three-phase contact angles in the pore throats of the microfluidic model was established using the microfluidic water flooding experiment videos as the data source. The results of the new method were verified through comparing with the manual measurement data.On this basis, the dynamic changes of the three-phase contact angles under flow conditions were clarified by the contact angles probability density curve and mean value change curve. The results show that, for water-wetting rocks, the mean value of the contact angles is acute angle during the early stage of the water flooding process, and it increases with the displacement time and becomes obtuse angle in the middle-late stage of displacement as the dominant force of oil phase gradually changes from viscous force to capillary force. The droplet flow in the remaining oil occurs in the central part of the pore throats, without three-phase contact angle. The contact angles for the porous flow and the columnar flow change slightly during the displacement and present as obtuse angles in view of mean values, which makes the remaining oil poorly movable and thus hard to be recovered. The mean value of the contact angle for the cluster flow tends to increase in the flooding process, which makes the remaining oil more difficult to be recovered. The contact angles for the membrane flow are mainly obtuse angles and reach the highest mean value in the late stage of displacement, which makes the remaining oil most difficult to be recovered. After displacement, the remaining oils under different flow regimes are just subjected to capillary force, with obtuse contact angles, and the wettability of the pore throat walls in the microfluidic model tends to be oil-wet under the action of crude oil.
文摘A single-stage single-switch high- frequency electronic ballast topology is presented. The circuit topology is the integration of a buck power- factor-correction （PFC） converter and a class E resonant inverter with only one active power switch. The buck converter is operated in discontinuous conduction mode and at a fixed switching frequency, and constant duty cycle to achieve high power factor and it can be controlled easily. Detailed analysis of the operation and characteristics of the circuit is provided. Simulation results satisfy present standard requirements.
基金supported by the Na‑tional Natural Science Foundation of China(No.52075241)the National Key Laboratory of Science and Technology on Helicopter Transmission(Nanjing University of Aeronau‑tics and Astronautics)(Nos.HTL-A-22K04 and HTL-O21G13).
文摘The intermediate gearbox of a helicopter operates under splash lubrication.If the bearing produces metal particles due to insufficient lubrication or wear,whether it can be adsorbed by the metal particles signal at the bottom of the gearbox and alarm directly affects the flight safety of the helicopter.Based on the CFD method,the factors affecting the accessibility of metal particles are analyzed by using the volume of fluid-discrete phase model(VOFDPM)coupling model,the RNG k-ɛturbulence model and the dynamic grid technology.Furthermore,the optimization research on the casing structure is conducted.Experimental results show that the accessibility of metal particles is optimal when the gear speed is 6000 rad/min or the immersion depth is 24 mm.The density of metal particles exhibits a nonlinear relationship with their accessibility,and the particle size has a relatively small impact on their accessibility without an order of magnitude change.
基金Project 50604014 supported by the National Natural Science Foundation of China
文摘The Baijigou Mine fire in Ningxia Province,which broke out on October 24,2003,affected more than 108 m3 of the mine and was probably the largest underground fire in China in recent years. In addition to its size,the fire was also characterized by excessive air leakage and the potential for violent methane explosions. A series of new measures were taken to fight the fire,including sealing intake tunnels with water,injecting three-phase foam through boreholes,and flushing with a large volume of nitrogen. The fire was successfully extinguished and production re-sumed soon afterwards; not one single methane explosion occurred during fire-fighting and afterwards.
基金The authors sincerely appreciate the financial support from the National Natural Science Foundation of China(No.52074249,51874261)Fundamental Research Funds for the Central Universities(2-9-2019-103).
文摘Due to the low porosity and low permeability in unconventional reservoirs,a large amount of crude oil is trapped in micro-to nano-sized pores and throats,which leads to low oil recovery.Nanofluids have great potential to enhance oil recovery(EOR)in low permeability reservoirs.In this work,the regulating ability of a nanofluid at the oil/water/solid three-phase interface was explored.The results indicated that the nanofluid reduced the oil/water interfacial tension by two orders of magnitude,and the expansion modulus of oil/water interface was increased by 77% at equilibrium.In addition,the solid surface roughness was reduced by 50%,and the three-phase contact angle dropped from 135(oil-wet)to 48(water-wet).Combining the displacement experiments using a 2.5D reservoir micromodel and a microchannel model,the remaining oil mobilization and migration processes in micro-to nano-scale pores and throats were visualized.It was found that the nanofluid dispersed the remaining oil into small oil droplets and displaced them via multiple mechanisms in porous media.Moreover,the high strength interface film formed by the nanofluid inhibited the coalescence of oil droplets and improved the flowing ability.These results help to understand the EOR mechanisms of nanofluids in low permeability reservoirs from a visual perspective.
