Constitutive behavior of nickel-titanium shape memory alloy （Ni-Ti SMA） under hot deformation was investigated by means of the compression tests and the linear fitting method. Based on the true stres-strain curves o...Constitutive behavior of nickel-titanium shape memory alloy （Ni-Ti SMA） under hot deformation was investigated by means of the compression tests and the linear fitting method. Based on the true stres-strain curves of Ni-Ti SMA under compression at the strain rates of 0.001-1 s land at the temperatures ranging from 600 to 1 000 ℃, the constitutive equation of Ni-Ti SMA with respect to the Zener-Hollomon parameter was established according to the high stress level and the low stress level at various temperatures so as to more accurately describe the deformation behavior of Ni-Ti SMA during hot working. Dynamic recovery and dynamic recrystallization of Ni-Ti SMA occur under hot compression, which lays the theoretical foundation for understanding the constitutive behavior of Ni-Ti SMA.展开更多
An innovative approach to increase structural survivability of concrete and maintain structural durability of concrete was developed in case of earthquakes and typhoons. This approach takes advantage of the superelast...An innovative approach to increase structural survivability of concrete and maintain structural durability of concrete was developed in case of earthquakes and typhoons. This approach takes advantage of the superelastic effect of shape memory alloy(SMA) and the cohering characteristic of repairing adhesive. These SMA wires and brittle fibers containing adhesives were embedded into concrete beams during concrete casting to form smart reinforced concrete beams. The self-repairing capacity of smart concrete beams was investigated by three-point bending tests. The experimental results show that SMA wires add self-restoration capacity,the concrete beams recover almost completely after incurring an extremely large deflection and the cracks are closed almost completely by the recovery forces of SMA wires. The number or areas of SMA wires has no influence on the tendency of deformation during loading and the tendency of reversion by the superelasticity. The adhesives released from the broken-open fibers fill voids and cracks. The repaired damage enables continued function and prevents further degradation.展开更多
In order to present the microstructures of dynamic recrystallization(DRX) in different deformation zones of hot extruded NiTi shape memory alloy(SMA) pipe coupling,a simulation approach combining finite element method...In order to present the microstructures of dynamic recrystallization(DRX) in different deformation zones of hot extruded NiTi shape memory alloy(SMA) pipe coupling,a simulation approach combining finite element method(FEM) with cellular automaton(CA) was developed and the relationship between the macroscopic field variables and the microscopic internal variables was established.The results show that there exists a great distinction among the microstructures in different zones of pipe coupling because deformation histories of these regions are diverse.Large plastic deformation may result in fine recrystallized grains,whereas the recrystallized grains may grow very substantially if there is a rigid translation during the deformation,even if the final plastic strain is very large.As a consequence,the deformation history has a significant influence on the evolution path of the DRX as well as the final microstructures of the DRX,including the morphology,the mean grain size and the recrystallization fraction.展开更多
The hysteresis characteristic is the major deficiency in the positioning control of magnetic shape memory alloy actuator. A Prandtl-Ishlinskii model was developed to characterize the hysteresis of magnetic shape memor...The hysteresis characteristic is the major deficiency in the positioning control of magnetic shape memory alloy actuator. A Prandtl-Ishlinskii model was developed to characterize the hysteresis of magnetic shape memory alloy actuator. Based on the proposed Prandtl-Ishlinskii model, the inverse Prandtl-Ishlinskii model was established as a feedforward controller to compensate the hysteresis of the magnetic shape memory alloy actuator. For further improving of the positioning precision of the magnetic shape memory alloy actuator, a hybrid control method with hysteresis nonlinear model in feedforward loop was proposed. The control method is separated into two parts: a feedforward loop with inverse Prandtl-Ishlinskii model and a feedback loop with neural network controller. To validate the validity of the proposed control method, a series of simulations and experiments were researched. The simulation and experimental results demonstrate that the maximum error rate of open loop controller based on inverse PI model is 1.72%, the maximum error rate of the hybrid controller based on inverse PI model is 1.37%.展开更多
In the present study,the thermal,mechanical,and biological properties of xAg/Ti-30Ta(x=0,0.41,0.82 and 2.48 at%)shape memory alloys(SMAs)were investigated.The study was conducted using optical and scanning electron mi...In the present study,the thermal,mechanical,and biological properties of xAg/Ti-30Ta(x=0,0.41,0.82 and 2.48 at%)shape memory alloys(SMAs)were investigated.The study was conducted using optical and scanning electron microscopy(SEM),X-ray diffractometry(XRD),compression test,and shape memory testing.The xAg/Ti-Ta was made using a powder metallurgy technique and microwave-sintering process.The results revealed that the addition of Ag has a significant effect on the pore size and shape,whereas the smallest pore size of 11μm was found with the addition of 0.41 at%along with a relative density of 72%.The fracture stress and strain increased with the addition of Ag,reaching the minimum values around 0.41 at%Ag.Therefore,this composition showed the maximum stress and strain at fracture region.Moreover,0.82 Ag/Ti-Ta shows more excellent corrosion resistance and biocompatibility than other percentages,obtaining almost the same behaviour of the pure Ti and Ti-6Al-4V alloys,which can be recommended for their promising and potential response for biomaterial applications.展开更多
Titanium(Ti)and nickel(Ni)elemental powders were blended by ball milling and the ball milled powders were employed to fabricate TiNi shape memory alloy(SMA)foams by spacer sintering.Effect of ball milling time on phas...Titanium(Ti)and nickel(Ni)elemental powders were blended by ball milling and the ball milled powders were employed to fabricate TiNi shape memory alloy(SMA)foams by spacer sintering.Effect of ball milling time on phase constitutes of the sintered TiNi alloy foams was studied by X-ray diffraction(XRD)analysis.Scanning electron microscopy(SEM)was used to characterize the porous structure,and compressive tests were carried out to evaluate the mechanical properties of the foams.Results indicate that porosities of the TiNi alloy foams can be controlled by using the spacer sintering method,and the porosities show a significant effect on the mechanical properties and shape memory effect(SME).展开更多
The stability and microstructure of Ni Ti Nb based shape memory alloys were investigated after alloyed with elements Zr, Cr and V. In artificial seawater (3.5%NaCl) and physiological solution (5%NaCl+0.1%H 2O 2), the ...The stability and microstructure of Ni Ti Nb based shape memory alloys were investigated after alloyed with elements Zr, Cr and V. In artificial seawater (3.5%NaCl) and physiological solution (5%NaCl+0.1%H 2O 2), the results show that the alloying elements influence the corrosion behavior of Ni Ti Nb alloys. Generally, Zr improves the corrosion resistance of Ni Ti Nb alloy, Cr reduces its corrosion resistance and V does not change the property. In order to investigate the reason of the difference,the relation of the phase components and corrosion resistance of Ni Ti Nb based shape memory alloys were studied by element analysis and SEM.展开更多
The mechanical properties and cutting performance of the designed Cu Al Mn Zn Ti B shape memory alloy were studied by tensile test and microstructure observation. Using X-ray diffractometry, differential scanning calo...The mechanical properties and cutting performance of the designed Cu Al Mn Zn Ti B shape memory alloy were studied by tensile test and microstructure observation. Using X-ray diffractometry, differential scanning calorimetry(DSC) and semi-quantitative shape memory effect test, the microstructure and shape memory effect were analyzed. It is found that lots of βphase and few α phase are formed in the quenching of Cu-7.5Al-9.7Mn-3.4Zn-0.3Ti-0.14B(mass fraction, %) alloy, a great deal of martensite and few α phase are formed in the aging alloy, while the annealing alloy is composed of a great deal of α phase and few βphase. The tensile strength and elongation of the annealed alloy are 649 MPa and 17.1%, respectively. Some tiny and dispersion distributed second phase particles are generated in Ti and B precipitates, greatly improving the alloy machinability.展开更多
The stress strain curves of two CuZnAl shape memory alloys which have the martensitic transformation temperatures of 50 ℃ and -10 ℃ respectively, were measured by using electronic material tester after treated by di...The stress strain curves of two CuZnAl shape memory alloys which have the martensitic transformation temperatures of 50 ℃ and -10 ℃ respectively, were measured by using electronic material tester after treated by different heat-treatment conditions. The results show that the area enclosed by hysteresis loop of the CuZnAl shape memory alloy in martensitic state is much larger than that of the alloy in austenitic state with super-elasticity at room temperature. Therefore, the former has better vibration attenuation effect. After being oil-quenched, water-quenched, and step-quenched, the CuZnAl alloy takes on more stable shape memory effect,better super-plasticity and superelasticity (pseudoelasticity). A CuZnAl shape memory alloy damper was designed, produced and installed to a 2-layer frame structure. In addition, the vibration experiments were made by dynamic data collecting analysis meter. The velocity of vibration attenuation of frame structure with CuZnAl shape memory alloy damper is much faster than that without it. And with the help of CuZnAl shape memory alloy damper, the attenuation period reduces to 1/10 of the original.展开更多
It is known that pure Co undergoes martensitic transformation from γ phase (fcc) to ε phase (hcp) by the movement of a/6<112> Shockley partial dislocations at around 400 ℃, however, there have been few system...It is known that pure Co undergoes martensitic transformation from γ phase (fcc) to ε phase (hcp) by the movement of a/6<112> Shockley partial dislocations at around 400 ℃, however, there have been few systematic works on the SM effect in Co and Co-based alloys. In this study, the fcc/hcp rnartensitic transformation and the SM effect were investigated in Co-A1 binary alloys(mole fraction of Al=0-16%). The γ/ε rnartensitic transformation temperatures were found from the DSC measurements to decrease with increasing Al content, while the transformation temperature hystereses were observed to increase from 60℃ at x(Al)=0 to 150℃ at x(Al) = 16%. The SM effect evaluated by a conventional bending test was enhanced by the addition of Al over 4% (mole fraction) and Co-Al alloys containing over 10%(mole fraction) exhibit a good SM effect associated with the hcpfee → reverse transformation above 200℃. The SM effect was significantly improved by precipitation of β (I32) phase and the max[real shape recovery strain of 2.2 % was obtained, which can be explained by precipitation hardening. The crystallographic orientations between the β, εand γ phases were also determined. Finally, the magnetic properties were investigated and it was found that the Curie temperature and saturation magnetization of Co-14% Al(mole fraction) are 690℃ and 120 emu/g, respectively. It is concluded that the Co-A1 alloys hold promise as new high-temperature and ferromagnetic SM alloys.展开更多
Recently, minimally invasive surgeries using guide-wire, catheter, stent etc. have spread rapidly as the diagnosis and the medical treatment for a cancer, a disease in a circulatory organ etc. Currently, further maneu...Recently, minimally invasive surgeries using guide-wire, catheter, stent etc. have spread rapidly as the diagnosis and the medical treatment for a cancer, a disease in a circulatory organ etc. Currently, further maneuverability and functionability of those devices are strongly desired in order to be used widely and safely. Although Ti-Ni shape memory alloys have been used in medical devices such orthodontic wire, guide-wire, it has been suspected that Ni is allergenic and carcinogenic to the human body. Thus the development of Ni-free shape memory alloys has been strongly required. Recently, several Ni-free beta-titanium alloys such as Ti-Mo-Al, Ti-Mo-Ga, Ti-Nb-Al have been developed as new-type shape memory alloys. We have been studying Ti-Mo based beta-titanium alloys and Ti-Mo-Sn alloy has constantly super elasticity of 3%.The purpose of present study is to propose the micro catheter with thin wall and high flexibility using To-Mo-Sn alloys tube on the basis of its mechanical properties.展开更多
Shape memory alloys (SMAs) are well-known as high damping materials. Recently,we have reported that the Cu-Al-Mn SMAs show a high internal friction as well as the other SMAs such as Ni-Ti, Cu-Zn-Al SMAs. Since the Cu-...Shape memory alloys (SMAs) are well-known as high damping materials. Recently,we have reported that the Cu-Al-Mn SMAs show a high internal friction as well as the other SMAs such as Ni-Ti, Cu-Zn-Al SMAs. Since the Cu-Al-Mn-based SMAs possess an excellent cold-workability, a strong recrystallization texture can be formed by thermomechanical treatment. The present authors demonstrated that the texture control is considerably effective for improving the SM properties and especially, in the Cu-Al-Mn-Ni SMAs with a strong {112}<110> recrystallization texture, a large pseudoelastic (PE) of about 7% can be obtained. Such a texture control is expected to enhance the damping capacity in the Cu-Al-Mn-based SMAs as well as PE. In this study, the effect of texture on the internal friction in Cu-Al-Mn and Cu-Al-Mn-Ni SMAs was investigated by tensile testing mode of Dynamic Mechanical Spectrometer (DMS). In sheet specimens with the {112}<110> texture, value of dynamic damping tanφ depends on the loading direction and an excellent damping capacity of tanφ= 0.1 can be obtained at the rolling direction in the martensite phase condition. Moreover, these Cu-Al-Mn-based SMAs show a high tensile strength over 600 MPa in the martensite phase. The present Cu-Al-Mn-based SMAs should have a great potential as the damping materials.展开更多
It is well known that the morphologies of the α’ martensite formed from the γ phase in ferrous alloys are classified into five types of lath, butterfly, （225）A type plate,lenticular and thin-plate. Among those α...It is well known that the morphologies of the α’ martensite formed from the γ phase in ferrous alloys are classified into five types of lath, butterfly, （225）A type plate,lenticular and thin-plate. Among those α’ martensites, only the thin-plate martensite,which is characterized by containing a high density of transformation twins, has a potential of exhibiting a perfect shape memory （SM） effect.Recently the present authors found in Fe-Ni-Si alloys that the thin-plate martensite is formed by the introduction of fine and coherent γ’-（Ni,Fe）3Si particles with a L12 ordered structure in the austenite matrix due to ausaging. In the present study, the SM properties of the ausaged Fe-Ni-Si alloys with the thin-plate martensite are investigated by a conventional bending-test. The effects of the addition of Co to the Fe-Ni-Si alloys on the martensitic transformation and the SM properties are also investigated. It is shown that while the ausaged Fe-Ni-Si ternary alloys exhibit an imperfect SM effect due to reverse transformation from stress-induced thin-plate martensite to austenite, the SM properties are improved by the addition of Co. An almost perfect SM effect is confirmed in the Fe-Ni-Si-Co alloys by heating to 1 100 ℃ after deformation at -196 ℃.展开更多
基金Project(51071056) supported by the National Natural Science Foundation of ChinaProjects(HEUCFR1132, HEUCF121712)supported by the Fundamental Research Funds for the Central Universities of China
文摘Constitutive behavior of nickel-titanium shape memory alloy （Ni-Ti SMA） under hot deformation was investigated by means of the compression tests and the linear fitting method. Based on the true stres-strain curves of Ni-Ti SMA under compression at the strain rates of 0.001-1 s land at the temperatures ranging from 600 to 1 000 ℃, the constitutive equation of Ni-Ti SMA with respect to the Zener-Hollomon parameter was established according to the high stress level and the low stress level at various temperatures so as to more accurately describe the deformation behavior of Ni-Ti SMA during hot working. Dynamic recovery and dynamic recrystallization of Ni-Ti SMA occur under hot compression, which lays the theoretical foundation for understanding the constitutive behavior of Ni-Ti SMA.
基金Project(50538020) supported by the National Natural Science Foundation of ChinaProject(20070421050) supported by China Postdoctoral Science Foundation
文摘An innovative approach to increase structural survivability of concrete and maintain structural durability of concrete was developed in case of earthquakes and typhoons. This approach takes advantage of the superelastic effect of shape memory alloy(SMA) and the cohering characteristic of repairing adhesive. These SMA wires and brittle fibers containing adhesives were embedded into concrete beams during concrete casting to form smart reinforced concrete beams. The self-repairing capacity of smart concrete beams was investigated by three-point bending tests. The experimental results show that SMA wires add self-restoration capacity,the concrete beams recover almost completely after incurring an extremely large deflection and the cracks are closed almost completely by the recovery forces of SMA wires. The number or areas of SMA wires has no influence on the tendency of deformation during loading and the tendency of reversion by the superelasticity. The adhesives released from the broken-open fibers fill voids and cracks. The repaired damage enables continued function and prevents further degradation.
基金Projects(51305091,51475101)supported by the National Natural Science Foundation of ChinaProject(20132304120025)supported by Specialized Research Fund for the Doctoral Program of Higher Education,China
文摘In order to present the microstructures of dynamic recrystallization(DRX) in different deformation zones of hot extruded NiTi shape memory alloy(SMA) pipe coupling,a simulation approach combining finite element method(FEM) with cellular automaton(CA) was developed and the relationship between the macroscopic field variables and the microscopic internal variables was established.The results show that there exists a great distinction among the microstructures in different zones of pipe coupling because deformation histories of these regions are diverse.Large plastic deformation may result in fine recrystallized grains,whereas the recrystallized grains may grow very substantially if there is a rigid translation during the deformation,even if the final plastic strain is very large.As a consequence,the deformation history has a significant influence on the evolution path of the DRX as well as the final microstructures of the DRX,including the morphology,the mean grain size and the recrystallization fraction.
基金Project(51105170) supported by the National Natural Science Foundation of ChinaProject supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Ministry of Education,China
文摘The hysteresis characteristic is the major deficiency in the positioning control of magnetic shape memory alloy actuator. A Prandtl-Ishlinskii model was developed to characterize the hysteresis of magnetic shape memory alloy actuator. Based on the proposed Prandtl-Ishlinskii model, the inverse Prandtl-Ishlinskii model was established as a feedforward controller to compensate the hysteresis of the magnetic shape memory alloy actuator. For further improving of the positioning precision of the magnetic shape memory alloy actuator, a hybrid control method with hysteresis nonlinear model in feedforward loop was proposed. The control method is separated into two parts: a feedforward loop with inverse Prandtl-Ishlinskii model and a feedback loop with neural network controller. To validate the validity of the proposed control method, a series of simulations and experiments were researched. The simulation and experimental results demonstrate that the maximum error rate of open loop controller based on inverse PI model is 1.72%, the maximum error rate of the hybrid controller based on inverse PI model is 1.37%.
基金Project(Q.J130000.2524.12H60)supported by the Ministry of Higher Education of Malaysia and Universiti Teknologi Malaysia。
文摘In the present study,the thermal,mechanical,and biological properties of xAg/Ti-30Ta(x=0,0.41,0.82 and 2.48 at%)shape memory alloys(SMAs)were investigated.The study was conducted using optical and scanning electron microscopy(SEM),X-ray diffractometry(XRD),compression test,and shape memory testing.The xAg/Ti-Ta was made using a powder metallurgy technique and microwave-sintering process.The results revealed that the addition of Ag has a significant effect on the pore size and shape,whereas the smallest pore size of 11μm was found with the addition of 0.41 at%along with a relative density of 72%.The fracture stress and strain increased with the addition of Ag,reaching the minimum values around 0.41 at%Ag.Therefore,this composition showed the maximum stress and strain at fracture region.Moreover,0.82 Ag/Ti-Ta shows more excellent corrosion resistance and biocompatibility than other percentages,obtaining almost the same behaviour of the pure Ti and Ti-6Al-4V alloys,which can be recommended for their promising and potential response for biomaterial applications.
文摘Titanium(Ti)and nickel(Ni)elemental powders were blended by ball milling and the ball milled powders were employed to fabricate TiNi shape memory alloy(SMA)foams by spacer sintering.Effect of ball milling time on phase constitutes of the sintered TiNi alloy foams was studied by X-ray diffraction(XRD)analysis.Scanning electron microscopy(SEM)was used to characterize the porous structure,and compressive tests were carried out to evaluate the mechanical properties of the foams.Results indicate that porosities of the TiNi alloy foams can be controlled by using the spacer sintering method,and the porosities show a significant effect on the mechanical properties and shape memory effect(SME).
文摘The stability and microstructure of Ni Ti Nb based shape memory alloys were investigated after alloyed with elements Zr, Cr and V. In artificial seawater (3.5%NaCl) and physiological solution (5%NaCl+0.1%H 2O 2), the results show that the alloying elements influence the corrosion behavior of Ni Ti Nb alloys. Generally, Zr improves the corrosion resistance of Ni Ti Nb alloy, Cr reduces its corrosion resistance and V does not change the property. In order to investigate the reason of the difference,the relation of the phase components and corrosion resistance of Ni Ti Nb based shape memory alloys were studied by element analysis and SEM.
基金Project(51271203)supported by the National Natural Science Foundation of ChinaProject(CX2012B037)supported by Hunan Provincial Innovation Foundation for Postgraduate,China+1 种基金Project(2013zzts017)supported by the Graduate Degree Thesis Innovation Foundation of Central South University,ChinaProject(2012bjjxj015)supported by the Excellent Doctor Degree Thesis Support Foundation of Central South University,China
文摘The mechanical properties and cutting performance of the designed Cu Al Mn Zn Ti B shape memory alloy were studied by tensile test and microstructure observation. Using X-ray diffractometry, differential scanning calorimetry(DSC) and semi-quantitative shape memory effect test, the microstructure and shape memory effect were analyzed. It is found that lots of βphase and few α phase are formed in the quenching of Cu-7.5Al-9.7Mn-3.4Zn-0.3Ti-0.14B(mass fraction, %) alloy, a great deal of martensite and few α phase are formed in the aging alloy, while the annealing alloy is composed of a great deal of α phase and few βphase. The tensile strength and elongation of the annealed alloy are 649 MPa and 17.1%, respectively. Some tiny and dispersion distributed second phase particles are generated in Ti and B precipitates, greatly improving the alloy machinability.
文摘The stress strain curves of two CuZnAl shape memory alloys which have the martensitic transformation temperatures of 50 ℃ and -10 ℃ respectively, were measured by using electronic material tester after treated by different heat-treatment conditions. The results show that the area enclosed by hysteresis loop of the CuZnAl shape memory alloy in martensitic state is much larger than that of the alloy in austenitic state with super-elasticity at room temperature. Therefore, the former has better vibration attenuation effect. After being oil-quenched, water-quenched, and step-quenched, the CuZnAl alloy takes on more stable shape memory effect,better super-plasticity and superelasticity (pseudoelasticity). A CuZnAl shape memory alloy damper was designed, produced and installed to a 2-layer frame structure. In addition, the vibration experiments were made by dynamic data collecting analysis meter. The velocity of vibration attenuation of frame structure with CuZnAl shape memory alloy damper is much faster than that without it. And with the help of CuZnAl shape memory alloy damper, the attenuation period reduces to 1/10 of the original.
文摘It is known that pure Co undergoes martensitic transformation from γ phase (fcc) to ε phase (hcp) by the movement of a/6<112> Shockley partial dislocations at around 400 ℃, however, there have been few systematic works on the SM effect in Co and Co-based alloys. In this study, the fcc/hcp rnartensitic transformation and the SM effect were investigated in Co-A1 binary alloys(mole fraction of Al=0-16%). The γ/ε rnartensitic transformation temperatures were found from the DSC measurements to decrease with increasing Al content, while the transformation temperature hystereses were observed to increase from 60℃ at x(Al)=0 to 150℃ at x(Al) = 16%. The SM effect evaluated by a conventional bending test was enhanced by the addition of Al over 4% (mole fraction) and Co-Al alloys containing over 10%(mole fraction) exhibit a good SM effect associated with the hcpfee → reverse transformation above 200℃. The SM effect was significantly improved by precipitation of β (I32) phase and the max[real shape recovery strain of 2.2 % was obtained, which can be explained by precipitation hardening. The crystallographic orientations between the β, εand γ phases were also determined. Finally, the magnetic properties were investigated and it was found that the Curie temperature and saturation magnetization of Co-14% Al(mole fraction) are 690℃ and 120 emu/g, respectively. It is concluded that the Co-A1 alloys hold promise as new high-temperature and ferromagnetic SM alloys.
文摘Recently, minimally invasive surgeries using guide-wire, catheter, stent etc. have spread rapidly as the diagnosis and the medical treatment for a cancer, a disease in a circulatory organ etc. Currently, further maneuverability and functionability of those devices are strongly desired in order to be used widely and safely. Although Ti-Ni shape memory alloys have been used in medical devices such orthodontic wire, guide-wire, it has been suspected that Ni is allergenic and carcinogenic to the human body. Thus the development of Ni-free shape memory alloys has been strongly required. Recently, several Ni-free beta-titanium alloys such as Ti-Mo-Al, Ti-Mo-Ga, Ti-Nb-Al have been developed as new-type shape memory alloys. We have been studying Ti-Mo based beta-titanium alloys and Ti-Mo-Sn alloy has constantly super elasticity of 3%.The purpose of present study is to propose the micro catheter with thin wall and high flexibility using To-Mo-Sn alloys tube on the basis of its mechanical properties.
文摘Shape memory alloys (SMAs) are well-known as high damping materials. Recently,we have reported that the Cu-Al-Mn SMAs show a high internal friction as well as the other SMAs such as Ni-Ti, Cu-Zn-Al SMAs. Since the Cu-Al-Mn-based SMAs possess an excellent cold-workability, a strong recrystallization texture can be formed by thermomechanical treatment. The present authors demonstrated that the texture control is considerably effective for improving the SM properties and especially, in the Cu-Al-Mn-Ni SMAs with a strong {112}<110> recrystallization texture, a large pseudoelastic (PE) of about 7% can be obtained. Such a texture control is expected to enhance the damping capacity in the Cu-Al-Mn-based SMAs as well as PE. In this study, the effect of texture on the internal friction in Cu-Al-Mn and Cu-Al-Mn-Ni SMAs was investigated by tensile testing mode of Dynamic Mechanical Spectrometer (DMS). In sheet specimens with the {112}<110> texture, value of dynamic damping tanφ depends on the loading direction and an excellent damping capacity of tanφ= 0.1 can be obtained at the rolling direction in the martensite phase condition. Moreover, these Cu-Al-Mn-based SMAs show a high tensile strength over 600 MPa in the martensite phase. The present Cu-Al-Mn-based SMAs should have a great potential as the damping materials.
文摘It is well known that the morphologies of the α’ martensite formed from the γ phase in ferrous alloys are classified into five types of lath, butterfly, （225）A type plate,lenticular and thin-plate. Among those α’ martensites, only the thin-plate martensite,which is characterized by containing a high density of transformation twins, has a potential of exhibiting a perfect shape memory （SM） effect.Recently the present authors found in Fe-Ni-Si alloys that the thin-plate martensite is formed by the introduction of fine and coherent γ’-（Ni,Fe）3Si particles with a L12 ordered structure in the austenite matrix due to ausaging. In the present study, the SM properties of the ausaged Fe-Ni-Si alloys with the thin-plate martensite are investigated by a conventional bending-test. The effects of the addition of Co to the Fe-Ni-Si alloys on the martensitic transformation and the SM properties are also investigated. It is shown that while the ausaged Fe-Ni-Si ternary alloys exhibit an imperfect SM effect due to reverse transformation from stress-induced thin-plate martensite to austenite, the SM properties are improved by the addition of Co. An almost perfect SM effect is confirmed in the Fe-Ni-Si-Co alloys by heating to 1 100 ℃ after deformation at -196 ℃.
