Short carbon fiber preform reinforced geopolymer composites containing different contents of α-Al2O3 filler （Cr（a-Al2O3）/geopolymer composites） were fabricated, and the effects of heat treatment temperatures up t...Short carbon fiber preform reinforced geopolymer composites containing different contents of α-Al2O3 filler （Cr（a-Al2O3）/geopolymer composites） were fabricated, and the effects of heat treatment temperatures up to 1 200 ℃ on the thermal-mechanical properties were studied. The results show that the thermal shrinkage in the direction perpendicular to the lamination of the composites gradually increases with the increase of the heat treatment temperatures from room temperature （25 ℃ ） to 1000 ℃. However, the composites in the direction parallel to the lamination show an expansion behavior. Beyond 1 000℃, in the two directions the composites exhibit a larger degree of shrinkage due to the densification and crystallization. The mechanical properties of the composites show the minimum values in the temperature range from 600 to 800 ℃ as the hydration water of geopolymer matrix is lost. The addition of α-Al2O3 particle filler into the composites clearly increases the onset crystalline temperature of leucite （KAlSi2O6） from the amorphous geopolymer matrix. In addition, the addition of α-Al2O3 particles into the composites can not only help to keep volume stable at high temperatures but also effectively improve the mechanical properties of the composites subjected to thermal load to a certain extent. The main toughening mechanisms of the composites subjected to thermal load are attributed to fiber pulling-out.展开更多
根据掺杂稀土离子固体材料激光冷却四能级理论模型,冷却样品的背景吸收系数是影响样品激光冷却性能的关键参数.为了探究冷却样品(以Yb^(3+):LuLiF_(4)(LLF)为例)中背景吸收系数与温度的函数关系,设计了在低温条件下获取冷却晶体背景吸...根据掺杂稀土离子固体材料激光冷却四能级理论模型,冷却样品的背景吸收系数是影响样品激光冷却性能的关键参数.为了探究冷却样品(以Yb^(3+):LuLiF_(4)(LLF)为例)中背景吸收系数与温度的函数关系,设计了在低温条件下获取冷却晶体背景吸收系数的低温-激光诱导温度调制光谱(laser-induced temperature modulation spectrum,LITMoS)实验方案.依据热负载理论推导了低温条件下冷却效率的实验计算公式,并对热负载来源进行理论分析.分析结果表明,接触传导热负载是低温-LITMoS实验样品热负载的主要来源.实验方案中采用液氮低温恒温器和特殊设计的冷指结构去控制晶体的温度,利用时间阀门-差分荧光光谱测温法对晶体进行非接触式测温获得晶体的温降,并对实验设计方案进行了可行性分析,计算了对应波长下的样品冷却效率.结果表明,在低温条件下实验设计方案可以测量样品背景吸收系数与温度之间的函数关系,制冷效率的测试结果符合光学制冷理论模型的预测.展开更多
基金Project supported by the Science Fund for Distinguished Young Scholars of Heilongjiang Province, ChinaProject supported by the Program for Excellent Team in Harbin Institute of Technology
文摘Short carbon fiber preform reinforced geopolymer composites containing different contents of α-Al2O3 filler （Cr（a-Al2O3）/geopolymer composites） were fabricated, and the effects of heat treatment temperatures up to 1 200 ℃ on the thermal-mechanical properties were studied. The results show that the thermal shrinkage in the direction perpendicular to the lamination of the composites gradually increases with the increase of the heat treatment temperatures from room temperature （25 ℃ ） to 1000 ℃. However, the composites in the direction parallel to the lamination show an expansion behavior. Beyond 1 000℃, in the two directions the composites exhibit a larger degree of shrinkage due to the densification and crystallization. The mechanical properties of the composites show the minimum values in the temperature range from 600 to 800 ℃ as the hydration water of geopolymer matrix is lost. The addition of α-Al2O3 particle filler into the composites clearly increases the onset crystalline temperature of leucite （KAlSi2O6） from the amorphous geopolymer matrix. In addition, the addition of α-Al2O3 particles into the composites can not only help to keep volume stable at high temperatures but also effectively improve the mechanical properties of the composites subjected to thermal load to a certain extent. The main toughening mechanisms of the composites subjected to thermal load are attributed to fiber pulling-out.
文摘根据掺杂稀土离子固体材料激光冷却四能级理论模型,冷却样品的背景吸收系数是影响样品激光冷却性能的关键参数.为了探究冷却样品(以Yb^(3+):LuLiF_(4)(LLF)为例)中背景吸收系数与温度的函数关系,设计了在低温条件下获取冷却晶体背景吸收系数的低温-激光诱导温度调制光谱(laser-induced temperature modulation spectrum,LITMoS)实验方案.依据热负载理论推导了低温条件下冷却效率的实验计算公式,并对热负载来源进行理论分析.分析结果表明,接触传导热负载是低温-LITMoS实验样品热负载的主要来源.实验方案中采用液氮低温恒温器和特殊设计的冷指结构去控制晶体的温度,利用时间阀门-差分荧光光谱测温法对晶体进行非接触式测温获得晶体的温降,并对实验设计方案进行了可行性分析,计算了对应波长下的样品冷却效率.结果表明,在低温条件下实验设计方案可以测量样品背景吸收系数与温度之间的函数关系,制冷效率的测试结果符合光学制冷理论模型的预测.
