In this study, to meet the development and application requirements for high-strength and hightoughness energetic structural materials, a representative volume element of a TA15 matrix embedded with a TaZrNb sphere wa...In this study, to meet the development and application requirements for high-strength and hightoughness energetic structural materials, a representative volume element of a TA15 matrix embedded with a TaZrNb sphere was designed and fabricated via diffusion bonding. The mechanisms of the microstructural evolution of the TaZrNb/TA15 interface were investigated via SEM, EBSD, EDS, and XRD.Interface mechanical property tests and in-situ tensile tests were conducted on the sphere-containing structure, and an equivalent tensile-strength model was established for the structure. The results revealed that the TA15 titanium alloy and joint had high density and no pores or cracks. The thickness of the planar joint was approximately 50-60 μm. The average tensile and shear strengths were 767 MPa and 608 MPa, respectively. The thickness of the spherical joint was approximately 60 μm. The Zr and Nb elements in the joint diffused uniformly and formed strong bonds with Ti without forming intermetallic compounds. The interface exhibited submicron grain refinement and a concave-convex interlocking structure. The tensile fracture surface primarily exhibited intergranular fracture combined with some transgranular fracture, which constituted a quasi-brittle fracture mode. The shear fracture surface exhibited brittle fracture with regular arrangements of furrows. Internal fracture occurred along the spherical interface, as revealed by advanced in-situ X-ray microcomputed tomography. The experimental results agreed well with the theoretical predictions, indicating that the high-strength interface contributes to the overall strength and toughness of the sphere-containing structure.展开更多
Water is a critical factor affecting the mechanical properties of rocks, leading to their degradation. Understanding the creep mechanical behavior of deep roadway surrounding rock under the influence of underground wa...Water is a critical factor affecting the mechanical properties of rocks, leading to their degradation. Understanding the creep mechanical behavior of deep roadway surrounding rock under the influence of underground water is of great significance. Compression and creep experiments on sandstone with varying water contents were conducted using a deep soft rock five-linked rheological experiment system. The experimental conditions, including water content (0%, 0.8%, 1.6%, 2.4% and 3.3%) and confining pressure (0, 6, 9 and 12 MPa), were determined based on pressure-free water absorption tests and in-situ stress measurements. The experimental results show that the compressive strength, creep failure stress, and dilatancy stress of sandstone decrease exponentially with increasing water content, while they increase exponentially with confining pressure. The ratio of lateral to axial instantaneous strain increases nearly linearly with the increase of stress, and the lateral creep strain characteristics of the sample are more significant than the axial ones. The duration of the attenuation creep stage of sandstone decreases with increasing water content and increases with increasing confining pressure. The lateral strain enters the steady-state creep stage before the axial strain, and the onset time of the accelerated creep stage of lateral strain under the failure stress is earlier than that of axial strain. The long-term strength of sandstone was determined based on the lateral steady-state creep rate curve, showing a negative exponential relationship with water content and a positive exponential relationship with confining pressure. A method for determining the long-term strength of rocks based on the ratio of lateral strain to axial strain (μc) is proposed, which is independent of water content. The research results provide a reliable theoretical basis for the analysis of the long-term stability of roadways under the influence of groundwater and the early prediction of creep failure.展开更多
In order to study the effects of biochar-based organic fertilizer on the accumulation of the total flavonoid contents in dandelion after sowing,the experiment applied four levels of treatments of carbon-based organic ...In order to study the effects of biochar-based organic fertilizer on the accumulation of the total flavonoid contents in dandelion after sowing,the experiment applied four levels of treatments of carbon-based organic fertilizer(0.15,0.30,0.45,and 0.60 kg•m^(-2)),and the base fertilizer that only applied conventional chemical fertilizer was used as the control.The total flavonoid contents and physiological indices of dandelion in different growth periods were determined.The results showed that the accumulation of the total flavonoid contents in leaves and roots of dandelion improved significantly by applying biochar-based organic fertilizer(0.15,0.30,0.45,and 0.60 kg•m^(-2)),with the highest total flavonoid occurred in the 0.45 kg•m^(-2) biochar-based organic fertilizer treatment.Along with dandelion growing,the total flavonoid contents in leaves were first elevated,and then decreased,with the maximum reached at 95 days after sowing(anthesis).While the total flavonoid contents in roots were elevated constantly.The total flavonoid contents accumulation in dandelion were positively correlated with net photosynthetic rate,stomatal conductance,transpiration rate,soluble sugar content,soluble protein,nitrate nitrogen,and available potassium,while negatively correlated with intercellular CO_(2) concentration.展开更多
Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and...Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and tribological properties were investigated by laser cladding technique.Additionally,the effect of Si on the glass forming ability(GFA)of the layers was understood.Results show that an appropriate Si content can refine the microstructure of the FeCoNiBSiNb laser cladding layers and improve the mechanical and tribological properties.The hardness of the coating layer increases monotonically with the Si content.At the Si content of 4.8at%(x=0),the coating layer exhibits a relatively low hardness(734.2HV 0.1).Conversely,at the silicon content of 13.44at%(x=3),the coating layer exhibits the highest hardness(1106HV 0.1).The non-crystalline content and tensile strength exhibit an initial increase,followed by a subsequent decrease.At x=2,the coating exhibits its maximum fracture strength(2880 MPa).However,when x>2,the fracture strength of the coating decreases with an increase in x.Conversely,with an increase in Si content,the wear volume loss initially decreases and then increases.At a Si content of 10.56at%(x=2),the coating exhibits the highest non-crystalline content(42%),the highest tensile strength(2880 MPa),and the most favorable dry friction performance.展开更多
本文从专家推荐网站入手对学科网站进行研究,以气象学为例,通过检索ISI Current Contents Connect数据库,对学科网站的地理分布、语种分布、信息来源、出版者及关键词进行统计分析,总结出学科网站的一些特点。最后对目前学科网络信息资...本文从专家推荐网站入手对学科网站进行研究,以气象学为例,通过检索ISI Current Contents Connect数据库,对学科网站的地理分布、语种分布、信息来源、出版者及关键词进行统计分析,总结出学科网站的一些特点。最后对目前学科网络信息资源研究提出了自己的看法。展开更多
In order to analyze mechanism of casing damage,the uniaxial compression experiment and creep experiment of interbedded mudstone samples from Sanan development area of Daqing Oilfield under different water contents wer...In order to analyze mechanism of casing damage,the uniaxial compression experiment and creep experiment of interbedded mudstone samples from Sanan development area of Daqing Oilfield under different water contents were carried out.The changes of the mudstone's mechanical parameters and creep characteristics with the increment of water saturation were studied.The results indicate that the rock strength and elastic modulus decrease rapidly with the increment of water content,at the same time,the creep strain and creep strain rate of steady state increase with the increment of water content,and also the steady state creep strain rate is enhanced with the increment of deviatoric stress.Through the creep characteristic curves,a non-linear creep constitutive equation of mudstone considering the change of water contents is established,which will be used in future numerical analysis.展开更多
The effects of B2O3 addition on both the sintering behavior and microwave dielectric properties of CaO-B2O3-SiO2 （CBS） glass ceramics were investigated by Fourier transform infrared spectroscopy （FTIR）, X-ray diff...The effects of B2O3 addition on both the sintering behavior and microwave dielectric properties of CaO-B2O3-SiO2 （CBS） glass ceramics were investigated by Fourier transform infrared spectroscopy （FTIR）, X-ray diffractometry （XRD） and scanning electron microscopy （SEM）. The results show that the increasing amount of B203 causes the increase of the contents of [BO3], [BO4] and [SiO4], which deduces the increase of CaB204 and a-SiO2 and the decrease of CaSiO3 correspondingly. No new phase is observed throughout the entire experiments. A bulk density of 2.54 g/cm3, a thermal expansion coefficient value of 11.95× 10-6 ℃-1 （20-500℃）, a dielectric constant er value of 6.42 and a dielectric loss tanδ value of 0.000 9 （measured at 9.7 GHz） are obtained for CBS glass ceramics containing 35%-B203 （mass fraction） sintered at 850 ℃ for 15 min.展开更多
Energetic structural materials(ESMs)are a new type of structural materials with bearing and damage characteristics.In this work the microstructure,mechanical properties and energy release characteristics of multi-elem...Energetic structural materials(ESMs)are a new type of structural materials with bearing and damage characteristics.In this work the microstructure,mechanical properties and energy release characteristics of multi-element Ti-Zr-Ta alloys with good casting performance were studied.The microstructure of the Ti_(x)ZrTa alloys gradually change from BCC+HCP to single BCC structure with the increase of Ti.While the Ti_(2)Zr_(y)Ta alloys was still uniform and single BCC structure with the increase of Zr.The evolution of microstructure and composition then greatly affect the mechanical properties and energy-release characteristics of Ti-Zr-Ta alloys.The synergistic effect of dual phase structure increases the fracture strain of Ti_(x)ZrTa(x=0.2,0.5)with the Ti content decreases,while the fracture strain of Ti_(x)ZrTa(x=2.0,3.0,4.0)gradually increase with the Ti content increases caused by the annihilation of the obstacles for dislocation movement.And as Zr content increases,the fracture strain of Ti_(2)Zr_(y)Ta alloys decrease,then the oxidation reaction rate and fragmentation degree gradually increase.The higher oxidation rate and the lager exposed oxidation area jointly leads the higher releasing energy efficiency of Ti_(x)ZrTa alloys with low Ti content and Ti_(2)Zr_(y)Ta alloys with high Zr content.展开更多
Feedstuff intake plays key role in impacting the yield and quality of milk. In this study, we discussed the contents of trace metal elements in cow milk impacted by different feedstuffs. We detected the contents of Pb...Feedstuff intake plays key role in impacting the yield and quality of milk. In this study, we discussed the contents of trace metal elements in cow milk impacted by different feedstuffs. We detected the contents of Pb, Cd, As, Cu, Mg, Ca, Fe and Zn in different feedstuffs and milk by atomic absorption spectrophotometry. The determinations of Pb, Cd and As contents were by graphite furnace A_AS and Cu, Mg, Ca, Fe and Zn was by flame atomic absorption spectrometry. The results showed that Pb, Cd, As and Cu presented in feedstuffs, but Pb, Cd and As were lowly detected in milk samples, and Cu was not detected in milk samples. The content of Mg in concentrates was lower than that in forages. However, the content of Mg in milk from concentrate feed was higher than that in forage feed. This suggested that the utilization of Mg in concentrate feed was higher than that in forage feed. The contents of Ca and Zn were opposite to Mg, and the utilization of Ca and Zn in forage feed was higher than that in concentrate feed. There was no obviously change law of Fe in different feedstuffs and milk samples. The relationship between the contents of trace metal elements in milk to feedstuffs would provide a theoretical basis for dairy farming. It would be useful for improving the milk yield and milk quality of dairy production.展开更多
r-learning,which is based on e-learning and u-learning,is defined as a learning support system that intelligent robots serve verbal and nonverbal interactions on ubiquitous computing environment.In order to guarantee ...r-learning,which is based on e-learning and u-learning,is defined as a learning support system that intelligent robots serve verbal and nonverbal interactions on ubiquitous computing environment.In order to guarantee the advantages of r-learning contents with no limits of timc and place and with nonverbal interaction which are not in e-learning contents,in recent years,assessment criteria for r-learning contents are urgently rcquired.Therefore,the reliable and valid assessment criteria were developed for nonverbal interaction contents in r-learning,and its detailed research content is as follows.First,assessment criteria for nonverbal interaction in r-learning contents will be specified into gesture,facial expression,semi-verbal message,distance,physical contact and time.Second,the validity of the developed assessment criteria will be proved by statistics.Consequently,the assessment criteria for nonverbal interaction contents will be helpful when choosing the better r-learning content and producing the better r-learning content,and the reliability of school education is improved ultimately.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.12372351).
文摘In this study, to meet the development and application requirements for high-strength and hightoughness energetic structural materials, a representative volume element of a TA15 matrix embedded with a TaZrNb sphere was designed and fabricated via diffusion bonding. The mechanisms of the microstructural evolution of the TaZrNb/TA15 interface were investigated via SEM, EBSD, EDS, and XRD.Interface mechanical property tests and in-situ tensile tests were conducted on the sphere-containing structure, and an equivalent tensile-strength model was established for the structure. The results revealed that the TA15 titanium alloy and joint had high density and no pores or cracks. The thickness of the planar joint was approximately 50-60 μm. The average tensile and shear strengths were 767 MPa and 608 MPa, respectively. The thickness of the spherical joint was approximately 60 μm. The Zr and Nb elements in the joint diffused uniformly and formed strong bonds with Ti without forming intermetallic compounds. The interface exhibited submicron grain refinement and a concave-convex interlocking structure. The tensile fracture surface primarily exhibited intergranular fracture combined with some transgranular fracture, which constituted a quasi-brittle fracture mode. The shear fracture surface exhibited brittle fracture with regular arrangements of furrows. Internal fracture occurred along the spherical interface, as revealed by advanced in-situ X-ray microcomputed tomography. The experimental results agreed well with the theoretical predictions, indicating that the high-strength interface contributes to the overall strength and toughness of the sphere-containing structure.
基金Projects(52174096, 52304110) supported by the National Natural Science Foundation of China。
文摘Water is a critical factor affecting the mechanical properties of rocks, leading to their degradation. Understanding the creep mechanical behavior of deep roadway surrounding rock under the influence of underground water is of great significance. Compression and creep experiments on sandstone with varying water contents were conducted using a deep soft rock five-linked rheological experiment system. The experimental conditions, including water content (0%, 0.8%, 1.6%, 2.4% and 3.3%) and confining pressure (0, 6, 9 and 12 MPa), were determined based on pressure-free water absorption tests and in-situ stress measurements. The experimental results show that the compressive strength, creep failure stress, and dilatancy stress of sandstone decrease exponentially with increasing water content, while they increase exponentially with confining pressure. The ratio of lateral to axial instantaneous strain increases nearly linearly with the increase of stress, and the lateral creep strain characteristics of the sample are more significant than the axial ones. The duration of the attenuation creep stage of sandstone decreases with increasing water content and increases with increasing confining pressure. The lateral strain enters the steady-state creep stage before the axial strain, and the onset time of the accelerated creep stage of lateral strain under the failure stress is earlier than that of axial strain. The long-term strength of sandstone was determined based on the lateral steady-state creep rate curve, showing a negative exponential relationship with water content and a positive exponential relationship with confining pressure. A method for determining the long-term strength of rocks based on the ratio of lateral strain to axial strain (μc) is proposed, which is independent of water content. The research results provide a reliable theoretical basis for the analysis of the long-term stability of roadways under the influence of groundwater and the early prediction of creep failure.
基金Supported by the National Key Research and Development Project(2021YFD16009012021YFD1600902)。
文摘In order to study the effects of biochar-based organic fertilizer on the accumulation of the total flavonoid contents in dandelion after sowing,the experiment applied four levels of treatments of carbon-based organic fertilizer(0.15,0.30,0.45,and 0.60 kg•m^(-2)),and the base fertilizer that only applied conventional chemical fertilizer was used as the control.The total flavonoid contents and physiological indices of dandelion in different growth periods were determined.The results showed that the accumulation of the total flavonoid contents in leaves and roots of dandelion improved significantly by applying biochar-based organic fertilizer(0.15,0.30,0.45,and 0.60 kg•m^(-2)),with the highest total flavonoid occurred in the 0.45 kg•m^(-2) biochar-based organic fertilizer treatment.Along with dandelion growing,the total flavonoid contents in leaves were first elevated,and then decreased,with the maximum reached at 95 days after sowing(anthesis).While the total flavonoid contents in roots were elevated constantly.The total flavonoid contents accumulation in dandelion were positively correlated with net photosynthetic rate,stomatal conductance,transpiration rate,soluble sugar content,soluble protein,nitrate nitrogen,and available potassium,while negatively correlated with intercellular CO_(2) concentration.
文摘Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and tribological properties were investigated by laser cladding technique.Additionally,the effect of Si on the glass forming ability(GFA)of the layers was understood.Results show that an appropriate Si content can refine the microstructure of the FeCoNiBSiNb laser cladding layers and improve the mechanical and tribological properties.The hardness of the coating layer increases monotonically with the Si content.At the Si content of 4.8at%(x=0),the coating layer exhibits a relatively low hardness(734.2HV 0.1).Conversely,at the silicon content of 13.44at%(x=3),the coating layer exhibits the highest hardness(1106HV 0.1).The non-crystalline content and tensile strength exhibit an initial increase,followed by a subsequent decrease.At x=2,the coating exhibits its maximum fracture strength(2880 MPa).However,when x>2,the fracture strength of the coating decreases with an increase in x.Conversely,with an increase in Si content,the wear volume loss initially decreases and then increases.At a Si content of 10.56at%(x=2),the coating exhibits the highest non-crystalline content(42%),the highest tensile strength(2880 MPa),and the most favorable dry friction performance.
基金Project(2002CB412704) supported by the Major State Basic Research Development Program of China
文摘In order to analyze mechanism of casing damage,the uniaxial compression experiment and creep experiment of interbedded mudstone samples from Sanan development area of Daqing Oilfield under different water contents were carried out.The changes of the mudstone's mechanical parameters and creep characteristics with the increment of water saturation were studied.The results indicate that the rock strength and elastic modulus decrease rapidly with the increment of water content,at the same time,the creep strain and creep strain rate of steady state increase with the increment of water content,and also the steady state creep strain rate is enhanced with the increment of deviatoric stress.Through the creep characteristic curves,a non-linear creep constitutive equation of mudstone considering the change of water contents is established,which will be used in future numerical analysis.
基金Project(2007AA03Z0455) supported by the National High-Technology Research and Development Program of ChinaProject(BE2009168) supported by the Natural Science Foundation of Jiangsu Province in ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institution,China
文摘The effects of B2O3 addition on both the sintering behavior and microwave dielectric properties of CaO-B2O3-SiO2 （CBS） glass ceramics were investigated by Fourier transform infrared spectroscopy （FTIR）, X-ray diffractometry （XRD） and scanning electron microscopy （SEM）. The results show that the increasing amount of B203 causes the increase of the contents of [BO3], [BO4] and [SiO4], which deduces the increase of CaB204 and a-SiO2 and the decrease of CaSiO3 correspondingly. No new phase is observed throughout the entire experiments. A bulk density of 2.54 g/cm3, a thermal expansion coefficient value of 11.95× 10-6 ℃-1 （20-500℃）, a dielectric constant er value of 6.42 and a dielectric loss tanδ value of 0.000 9 （measured at 9.7 GHz） are obtained for CBS glass ceramics containing 35%-B203 （mass fraction） sintered at 850 ℃ for 15 min.
基金supported by the National Natural Science Foundation of China(Grant Nos.52171166,11972372 and U20A20231)supported by Sinoma Institute of Materials Research(Guang Zhou)Co.,Ltd。
文摘Energetic structural materials(ESMs)are a new type of structural materials with bearing and damage characteristics.In this work the microstructure,mechanical properties and energy release characteristics of multi-element Ti-Zr-Ta alloys with good casting performance were studied.The microstructure of the Ti_(x)ZrTa alloys gradually change from BCC+HCP to single BCC structure with the increase of Ti.While the Ti_(2)Zr_(y)Ta alloys was still uniform and single BCC structure with the increase of Zr.The evolution of microstructure and composition then greatly affect the mechanical properties and energy-release characteristics of Ti-Zr-Ta alloys.The synergistic effect of dual phase structure increases the fracture strain of Ti_(x)ZrTa(x=0.2,0.5)with the Ti content decreases,while the fracture strain of Ti_(x)ZrTa(x=2.0,3.0,4.0)gradually increase with the Ti content increases caused by the annihilation of the obstacles for dislocation movement.And as Zr content increases,the fracture strain of Ti_(2)Zr_(y)Ta alloys decrease,then the oxidation reaction rate and fragmentation degree gradually increase.The higher oxidation rate and the lager exposed oxidation area jointly leads the higher releasing energy efficiency of Ti_(x)ZrTa alloys with low Ti content and Ti_(2)Zr_(y)Ta alloys with high Zr content.
文摘Feedstuff intake plays key role in impacting the yield and quality of milk. In this study, we discussed the contents of trace metal elements in cow milk impacted by different feedstuffs. We detected the contents of Pb, Cd, As, Cu, Mg, Ca, Fe and Zn in different feedstuffs and milk by atomic absorption spectrophotometry. The determinations of Pb, Cd and As contents were by graphite furnace A_AS and Cu, Mg, Ca, Fe and Zn was by flame atomic absorption spectrometry. The results showed that Pb, Cd, As and Cu presented in feedstuffs, but Pb, Cd and As were lowly detected in milk samples, and Cu was not detected in milk samples. The content of Mg in concentrates was lower than that in forages. However, the content of Mg in milk from concentrate feed was higher than that in forage feed. This suggested that the utilization of Mg in concentrate feed was higher than that in forage feed. The contents of Ca and Zn were opposite to Mg, and the utilization of Ca and Zn in forage feed was higher than that in concentrate feed. There was no obviously change law of Fe in different feedstuffs and milk samples. The relationship between the contents of trace metal elements in milk to feedstuffs would provide a theoretical basis for dairy farming. It would be useful for improving the milk yield and milk quality of dairy production.
基金Project(2011)supported by the research grant of the Chungbuk National University,South Korea
文摘r-learning,which is based on e-learning and u-learning,is defined as a learning support system that intelligent robots serve verbal and nonverbal interactions on ubiquitous computing environment.In order to guarantee the advantages of r-learning contents with no limits of timc and place and with nonverbal interaction which are not in e-learning contents,in recent years,assessment criteria for r-learning contents are urgently rcquired.Therefore,the reliable and valid assessment criteria were developed for nonverbal interaction contents in r-learning,and its detailed research content is as follows.First,assessment criteria for nonverbal interaction in r-learning contents will be specified into gesture,facial expression,semi-verbal message,distance,physical contact and time.Second,the validity of the developed assessment criteria will be proved by statistics.Consequently,the assessment criteria for nonverbal interaction contents will be helpful when choosing the better r-learning content and producing the better r-learning content,and the reliability of school education is improved ultimately.
