The title compound was synthesized by a one pot synthesis method with ethanolamine ,ketone and dichloroacetyl chloride. The product was characterization by IR, 1 HNMR,UV, and elementary analysis.
Because of their low electrical conductivity,sluggish ion diffusion,and poor stability,conventional electrode materials are not able to meet the growing demands of energy storage and portable devices.Graphene assemble...Because of their low electrical conductivity,sluggish ion diffusion,and poor stability,conventional electrode materials are not able to meet the growing demands of energy storage and portable devices.Graphene assembled films(GAFs)formed from graphene nanosheets have an ultrahigh conductivity,a unique 2D network structure,and exceptional mechanical strength,which give them the potential to solve these problems.However,a systematic understanding of GAFs as an advanced electrode material is lacking.This review focuses on the use of GAFs in electrochemistry,providing a comprehensive analysis of their synthesis methods,surface/structural characteristics,and physical properties,and thus understand their structure-property relationships.Their advantages in batteries,supercapacitors,and electrochemical sensors are systematically evaluated,with an emphasis on their excellent electrical conductivity,ion transport kinetics,and interfacial stability.The existing problems in these devices,such as chemical inertness and mechanical brittleness,are discussed and potential solutions are proposed,including defect engineering and hybrid structures.This review should deepen our mechanistic understanding of the use of GAFs in electrochemical systems and provide actionable strategies for developing stable,high-performance electrode materials.展开更多
In order to realize the photocatalysis of TiO2 in the sunlight and directly apply it to waste water treatment, the Gd-doped TiO2 nanofibre was synthesized using two-step synthesis method as follows: Firstly, potassium...In order to realize the photocatalysis of TiO2 in the sunlight and directly apply it to waste water treatment, the Gd-doped TiO2 nanofibre was synthesized using two-step synthesis method as follows: Firstly, potassium carbonate, titanium dioxide and proper gadolinium oxide （dopant） were calcined in the muffle at high temperature and the doped gadolinium K2Ti4O9 fibres were obtained; secondly, the fibre was heated using glycerol as solvent until Gd-doped TiO2 nanofibres were obtained. The synthesized samples were characterized using scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The results show that Gd-doped TiO2 nanofibre heat-treated by glycerol solvent can inhibit the agglomeration, so the grain diameter of the fibre is smaller than that without heat-treated with glycerol. Meanwhile, the diameter of the fibre decreases with the increase of the heating temperature and time. 97% 98% of Gd-doped TiO2 nanofibre is anatase. The photocatalysis results showed that the photocatalysis activity of Gd-doped TiO2 nanofibre is just a little lower than that of TiO2 powder.展开更多
Microwave synthesis method was applied to the fast preparation of LiCoO2. The structure of the synthesized oxides was analyzed by using X-ray diffraction. Only single-phase LiCoO2 was obtained. Electrochemical behavio...Microwave synthesis method was applied to the fast preparation of LiCoO2. The structure of the synthesized oxides was analyzed by using X-ray diffraction. Only single-phase LiCoO2 was obtained. Electrochemical behaviors of LiCoO2 were investigated by charge-discharge cycling properties in the voltage range of 3.004.35 V（（vs Li）.） The results show that the prepared LiCoO2 powders calcinated at 900 ℃ for 120 min exhibit an initial charge and discharge capacity of 168 and 162 mA·h·g-1 at 0.1C current rate, respectively, as compared to 159 and 154 (mA·h·g-1) of LiCoO2 synthesized by conventional means. In addition, more than 95% of the capacity is retained （even） after 10 cycles. But with the increase of calcinating time, its electrochemical properties deteriorate. Compared with the conventional method, the microwave heating method is simple, fast, and with high energy efficiency.展开更多
This paper addresses a unified approach of the PID controller design for low as well as high order unstable processes with time delay.The design method is based on the direct synthesis(DS)approach to achieve the enhan...This paper addresses a unified approach of the PID controller design for low as well as high order unstable processes with time delay.The design method is based on the direct synthesis(DS)approach to achieve the enhanced load disturbance rejection.To improve the servo response,a two-degree of freedom control scheme has been considered.A suitable guideline has been provided to select the desired reference model in the DS scheme.The direct synthesis controller has been approximated to the PID controller using the frequency response matching method.A consistently better performance has been obtained in comparison with the recently reported methods.展开更多
文摘The title compound was synthesized by a one pot synthesis method with ethanolamine ,ketone and dichloroacetyl chloride. The product was characterization by IR, 1 HNMR,UV, and elementary analysis.
基金the National Natural Science Foundation of China(22279097)the Key R&D Program of Hubei Province(2023BAB103)the PhD Scientific Research and Innovation Foundation of The Education Department of Hainan Province Joint Project of Sanya Yazhou Bay Science and Technology City(HSPHDSRF-2024-03-022)。
文摘Because of their low electrical conductivity,sluggish ion diffusion,and poor stability,conventional electrode materials are not able to meet the growing demands of energy storage and portable devices.Graphene assembled films(GAFs)formed from graphene nanosheets have an ultrahigh conductivity,a unique 2D network structure,and exceptional mechanical strength,which give them the potential to solve these problems.However,a systematic understanding of GAFs as an advanced electrode material is lacking.This review focuses on the use of GAFs in electrochemistry,providing a comprehensive analysis of their synthesis methods,surface/structural characteristics,and physical properties,and thus understand their structure-property relationships.Their advantages in batteries,supercapacitors,and electrochemical sensors are systematically evaluated,with an emphasis on their excellent electrical conductivity,ion transport kinetics,and interfacial stability.The existing problems in these devices,such as chemical inertness and mechanical brittleness,are discussed and potential solutions are proposed,including defect engineering and hybrid structures.This review should deepen our mechanistic understanding of the use of GAFs in electrochemical systems and provide actionable strategies for developing stable,high-performance electrode materials.
文摘In order to realize the photocatalysis of TiO2 in the sunlight and directly apply it to waste water treatment, the Gd-doped TiO2 nanofibre was synthesized using two-step synthesis method as follows: Firstly, potassium carbonate, titanium dioxide and proper gadolinium oxide （dopant） were calcined in the muffle at high temperature and the doped gadolinium K2Ti4O9 fibres were obtained; secondly, the fibre was heated using glycerol as solvent until Gd-doped TiO2 nanofibres were obtained. The synthesized samples were characterized using scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The results show that Gd-doped TiO2 nanofibre heat-treated by glycerol solvent can inhibit the agglomeration, so the grain diameter of the fibre is smaller than that without heat-treated with glycerol. Meanwhile, the diameter of the fibre decreases with the increase of the heating temperature and time. 97% 98% of Gd-doped TiO2 nanofibre is anatase. The photocatalysis results showed that the photocatalysis activity of Gd-doped TiO2 nanofibre is just a little lower than that of TiO2 powder.
文摘Microwave synthesis method was applied to the fast preparation of LiCoO2. The structure of the synthesized oxides was analyzed by using X-ray diffraction. Only single-phase LiCoO2 was obtained. Electrochemical behaviors of LiCoO2 were investigated by charge-discharge cycling properties in the voltage range of 3.004.35 V（（vs Li）.） The results show that the prepared LiCoO2 powders calcinated at 900 ℃ for 120 min exhibit an initial charge and discharge capacity of 168 and 162 mA·h·g-1 at 0.1C current rate, respectively, as compared to 159 and 154 (mA·h·g-1) of LiCoO2 synthesized by conventional means. In addition, more than 95% of the capacity is retained （even） after 10 cycles. But with the increase of calcinating time, its electrochemical properties deteriorate. Compared with the conventional method, the microwave heating method is simple, fast, and with high energy efficiency.
文摘This paper addresses a unified approach of the PID controller design for low as well as high order unstable processes with time delay.The design method is based on the direct synthesis(DS)approach to achieve the enhanced load disturbance rejection.To improve the servo response,a two-degree of freedom control scheme has been considered.A suitable guideline has been provided to select the desired reference model in the DS scheme.The direct synthesis controller has been approximated to the PID controller using the frequency response matching method.A consistently better performance has been obtained in comparison with the recently reported methods.
