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Surface alloy/GC电催化剂的制备与结构表征 被引量:6
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作者 陈声培 张麒 +1 位作者 黄桃 孙世刚 《精细化工》 EI CAS CSCD 北大核心 2003年第1期44-46,共3页
以玻碳为载体 ,通过电化学方法在其表面沉积催化物质研制表面合金纳米电催化剂 (Surfacealloy/GC)。运用电化学循环伏安 (CV)和扫描电镜 (SEM)等技术进行结构和性能表征。结果表明 ,在Surfacealloy/GC上氢的析出电位负移至 - 0 40V(SCE... 以玻碳为载体 ,通过电化学方法在其表面沉积催化物质研制表面合金纳米电催化剂 (Surfacealloy/GC)。运用电化学循环伏安 (CV)和扫描电镜 (SEM)等技术进行结构和性能表征。结果表明 ,在Surfacealloy/GC上氢的析出电位负移至 - 0 40V(SCE) ,与Pt电极相比负移约 15 0mV ,具有较高的电还原应用价值。另外 ,Surfacealloy/GC的氧化电位正移至 0 64V ,其稳定性明显高于电有机合成中常用的Pb、Sb、Cu等金属电极。SEM研究结果表明 ,所研制的Surfacealloy/GC电催化剂是一种由粒度约为 展开更多
关键词 surface alloy/gc电催化剂 制备 结构表征 碳载表面合金 电催化 SEM
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Cooperative effect of surface alloying and laser texturing on tribological performance of lubricated surfaces 被引量:5
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作者 万轶 熊党生 李建亮 《Journal of Central South University》 SCIE EI CAS 2010年第5期906-910,共5页
The cooperative effect of laser surface texturing(LST) and double glow plasma surface alloying on tribological performance of lubricated sliding contacts was investigated.A Nd:YAG laser was used to generate microdimpl... The cooperative effect of laser surface texturing(LST) and double glow plasma surface alloying on tribological performance of lubricated sliding contacts was investigated.A Nd:YAG laser was used to generate microdimples on steel surfaces. Dimples with the diameter of 150μm and the depth of 30-35μm distributed circumferentially on the disc surface.The alloying element Cr was sputtered to the laser texturing steel surface by double glow plasma technique.A deep diffusion layer with a thickness of 30μm and a high hardness of HV900 was formed in this alloy.Tribological experiments of three types of samples(smooth,texturing and texturing+alloying) were conducted with a ring-on-disc tribometer to simulate the face seal.It is found that,in comparison with smooth steel surfaces,the laser texturing samples significantly reduce the friction coefficient.Moreover,the lower wear rate of the sample treated with the two surface techniques is observed. 展开更多
关键词 laser surface texturing double glow plasma surface alloying technology carbon steel tribological performance lubricated surface
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Evaluation of surface roughness and optimization of cutting parameters in turning of AA2024 alloy under different cooling-lubrication conditions using RSM method 被引量:3
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作者 Seyed Hasan MUSAVI Behnam DAVOODI Behzad ESKANDARI 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第6期1714-1728,共15页
In the present study,the effect of reduction of cutting fluid consumption on the surface quality and tool wear was studied.Mathematical models were developed to predict the surface roughness using response surface met... In the present study,the effect of reduction of cutting fluid consumption on the surface quality and tool wear was studied.Mathematical models were developed to predict the surface roughness using response surface methodology(RSM).Analysis of variance(ANOVA)was used to investigate the significance of the developed regression models.The results showed that the coefficient of determination values(R^2)for the developed models was 97.46%for dry,89.32%for flood mode(FM),and 99.44%for MQL,showing the high accuracy of fitted models.Also,under the minimum quantity lubrication(MQL)condition,the surface roughness improved by 23%−44%and 19%−41%compared with dry and FM,respectively,and the SEM images of machined surface proved the statement.The prepared SEM images of tool rake face also showed a considerable decrease in adhesion wear.Built-up edge and built-up layer were the two main products of the adhesion wear,and energy-dispersive X-ray spectroscopy(EDX)analysis of specific points on the tool faces helped to discover the chemical compositions of adhered materials.By changing dry and FM to MQL mode,dominant mechanism of tool wear in machining aluminum alloy was significantly decreased.Breakage wear that led to early failure of cutting edge was also controlled by MQL technique. 展开更多
关键词 cooling-lubrication methods surface roughness minimum quantity lubrication response surface methodology AA2024 aluminum alloy
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Influence of volume percentage of NanoTiB2 particles on tribological&mechanical behaviour of 6061-T6 Al alloy nano-surface composite layer prepared via friction stir process 被引量:1
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作者 V.Kishan Aruri Devaraju K.Prasanna Lakshmi 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2017年第1期16-21,共6页
The aim of present study is to analyze the influence of volume percentage(vol.%) of nano-sized particles(TiB_2: average size is 35 nm) on microstructure, mechanical and tribological behavior of 6061-T6 Al alloy surfac... The aim of present study is to analyze the influence of volume percentage(vol.%) of nano-sized particles(TiB_2: average size is 35 nm) on microstructure, mechanical and tribological behavior of 6061-T6 Al alloy surface nano composite prepared via Friction stir process(FSP). The microstructure of the fabricated surface nanocomposites is examined using optical microscopy(OM) and scanning electron microscope(SEM) for distribution of TiB_2 nano reinforcement particles, thickness of nano composite layer formed on the Aluminum alloy substrate and fracture features. The depth of surface nano composite layer is measured as 3683.82 m m along the cross section of stir zone of nano composite perpendicular to FSP. It was observed that increase in volume percentage of TiB_2 particles, the microhardness is increased up to132 Hv and it is greater than as-received Al alloy's microhardness(104 Hv). It is also observed that at 4volume percentage higher tensile properties exhibited as compared with the 2 and 8 vol. %. It is found that high wear resistance exhibited at 4 volume percentage as-compared with the 2 and 8 vol. %. The observed wear and mechanical properties are interrelated with microstructure, fractography and worn morphology. 展开更多
关键词 Friction stir process Al alloy surface nano composites Tensile TRIBOLOGY
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Enhancement of wear resistance of Ti–6Al–4V alloy by picosecond laser surface micro texturing process 被引量:2
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作者 DINESH BABU P VIGNESH S +1 位作者 VIGNESH M BALAMURUGAN C 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第8期1836-1848,共13页
A pulsed,picosecond Nd:YAG laser with a wavelength of 532 nm is used to texture the surface of grade 5 titanium alloy(Ti–6Al–4V)for minimizing its wear rate.The wear properties of the base samples and laser surface ... A pulsed,picosecond Nd:YAG laser with a wavelength of 532 nm is used to texture the surface of grade 5 titanium alloy(Ti–6Al–4V)for minimizing its wear rate.The wear properties of the base samples and laser surface textured samples are analyzed by conducting wear tests under a sliding condition using pin-on-disk equipment.The wear tests are conducted based on the Box–Benhken design,and the interaction of the process parameters is analyzed using response surface methodology.The wear analysis is conducted by varying the load,rotating speed of the disc,and track diameter at room temperature with a sliding distance of 1500 m.The results demonstrate that the laser textured surfaces exhibited a lower coefficient of friction and good anti-wear properties as compared with the non-textured surfaces.A regression model is developed for the wear analysis of titanium alloy using the analysis of variance technique.It is also observed from the analysis that the applied load and sliding distance are the parameters that have the greatest effect on the wear behavior followed by the wear track diameter.The optimum operating conditions have been suggested based on the results obtained from the numerical optimization approach. 展开更多
关键词 titanium alloy surface texturing Box–Benhken design WEAR coefficient of friction optimization
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Surface evolution of Al-Si-Cu alloy in thermal shock under different heating speeds 被引量:1
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作者 LIU Lei ZHANG Hai-jun +7 位作者 LI Bo-yan YANG Zhong BAO Tong LI Jian-ping GUO Yong-chun XIA Feng YANGWei LI Hai-ying 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第10期2988-2998,共11页
In order to understand the initial surface damage of Al piston in unsteady thermal environment like knock combustion,T6 heat treated cast Al-Si-Cu alloy was thermal shocked under different heating speeds between room ... In order to understand the initial surface damage of Al piston in unsteady thermal environment like knock combustion,T6 heat treated cast Al-Si-Cu alloy was thermal shocked under different heating speeds between room temperature and 450°C by adjusting the environmental temperature.The surface evolution was mainly characterized in view of roughness,hardness,morphology,texture,phase and element distribution.Results indicated that both the roughness and hardness went up to the maximum and then decreased with rising heating speed.Micro-structure and phase analysis suggested that the interactions of solid phase transition and oxidation with enhancing thermal stress took responsible for the surface evolution. 展开更多
关键词 Al alloy PISTON thermal shock heating speed surface roughness
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Evolution of surface roughness of a cast Al-Si-Cu piston alloy during thermal exposure 被引量:1
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作者 BAO Tong LI Jian-ping +7 位作者 LIU Lei LI Hai-ying YANG Zhong WANG Jian-li GUO Yong-chun LI Bo-yan YANG Wei ZHENG Jia-qi 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第6期1645-1653,共9页
In the present work,samples of Al-Si-Cu piston alloy after T6 heat treatment were exposed for 2 h at temperatures ranging from 400 to 550°C.The evolution of surface roughness and microstructure of the alloy durin... In the present work,samples of Al-Si-Cu piston alloy after T6 heat treatment were exposed for 2 h at temperatures ranging from 400 to 550°C.The evolution of surface roughness and microstructure of the alloy during thermal exposure was studied by combination methods of roughness profiles,optical and scanning electron microscopy as well as XRD analysis.It is found that the roughness and mass of the alloy increase with the raise of the thermal exposure temperature,and the increasing rates of them are slow as the exposure temperature is below 500°C,but accelerates abruptly when the temperature is higher than 500°C.The variation of surface roughness of the alloy is closely related to phase transformation and oxidation during the thermal exposure. 展开更多
关键词 surface roughness thermal exposure Al-Si-Cu piston alloy MICROSTRUCTURE OXIDATION
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Calcium phosphate deposition on surface of porous and dense TiNi alloys in simulated body fluid 被引量:1
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作者 刘珏 刘超 +2 位作者 李婧 刘敏 阮建明 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第1期1-9,共9页
Porous and dense TiNi alloys were successfully fabricated by powder metallurgy(P/M) method, and to further improve their surface biocompatibility, surface modification techniques including grind using silicon-carbide(... Porous and dense TiNi alloys were successfully fabricated by powder metallurgy(P/M) method, and to further improve their surface biocompatibility, surface modification techniques including grind using silicon-carbide(SiC) paper, acid etching and alkali treatment were employed to produce either irregularly rough surface or micro-porous surface roughness. X-ray diffractometry(XRD), scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDX) attached to SEM were used to characterize surface structure and the Ca-P coatings. Effects of the above surface treatments on the surface morphology, apatite forming ability were systematically investigated. Results indicate that all the above surface treatments increase the apatite forming ability of TiNi alloys in varying degrees when soaked in simulated body fluid(SBF). More apatite coatings formed on TiNi samples sintered at 1050℃ and 1100℃ due to their high porosity and pure TiNi phase that is beneficial to heterogeneous nucleation. Furthermore, more uniform apatite was fabricated on the sample sintered from the mixture of Ni and Ti powders. 展开更多
关键词 calcium phosphate TiNi alloy surface treatment MICROSTRUCTURE simulated body fluid (SBF)
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Optimization of process parameters of aluminum alloy AA 2014-T6 friction stir welds by response surface methodology 被引量:7
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作者 Ramanjaneyulu KADAGANCHI Madhusudhan Reddy GANKIDI Hina GOKHALE 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2015年第3期209-219,共11页
The heat treatable aluminum-copper alloy AA2014 finds wide application in the aerospace and defence industry due to its high strength-toweight ratio and good ductility. Friction stir welding(FSW) process, an emerging ... The heat treatable aluminum-copper alloy AA2014 finds wide application in the aerospace and defence industry due to its high strength-toweight ratio and good ductility. Friction stir welding(FSW) process, an emerging solid state joining process, is suitable for joining this alloy compared to fusion welding processes. This work presents the formulation of a mathematical model with process parameters and tool geometry to predict the responses of friction stir welds of AA 2014-T6 aluminum alloy, viz yield strength, tensile strength and ductility. The most influential process parameters considered are spindle speed, welding speed, tilt angle and tool pin profile. A four-factor, five-level central composite design was used and a response surface methodology(RSM) was employed to develop the regression models to predict the responses.The mechanical properties, such as yield strength(YS), ultimate tensile strength(UTS) and percentage elongation(%El), are considered as responses. Method of analysis of variance was used to determine the important process parameters that affect the responses. Validation trials were carried out to validate these results. These results indicate that the friction stir welds of AA 2014-T6 aluminum alloy welded with hexagonal tool pin profile have the highest tensile strength and elongation, whereas the joints fabricated with conical tool pin profile have the lowest tensile strength and elongation. 展开更多
关键词 焊接工艺参数 搅拌摩擦焊 铝合金焊接 响应面分析法 抗拉强度 优化 焊接接头 屈服强度
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Forward hot extrusion forming process of 4-lobe aluminum alloy helical surface rotor
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作者 XIA Feng LI Hui +4 位作者 LIU Hou-gen ZHAO Bei-bei ZHANG Zhao-qiang LU Di-hua CHEN Jian-qiang 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第9期2307-2317,共11页
The 4-lobe aluminum alloy helical surface rotors are widely applied in industry,such as superchargers.Generally,the conventional manufacturing processes of aluminum alloy helical surface are time consuming and costly.... The 4-lobe aluminum alloy helical surface rotors are widely applied in industry,such as superchargers.Generally,the conventional manufacturing processes of aluminum alloy helical surface are time consuming and costly.To make the manufacturing processes more flexible and economical,the forward hot extrusion process is proposed to form the 4-lobe aluminum alloy helical surface rotors.In this work,we implement both simulations and experiments to the forming process of the helical surface,of which the material is 6063 aluminum alloy.The forward hot extrusion process is simulated with finite element method in DEFORM-3D.Based on the simulation method,the influences of different extrusion parameters,such as extrusion temperature,extrusion speed and extrusion ratio,on the extrusion process are studied.According to the numerical simulation results,the optimal case is chosen to carry out the experiment.Furthermore,the experimental results show that the surface is smooth;the toothed fill is full;the twist angle in the length direction is evenly distributed;the value of twist angle is roughly in line with the design angle,which is mainly due to the modified die structure,having a positive and significant effect on the increment of twist angle.Therefore,the twist angle has an increase of about 76%,which verifies the modified die structure. 展开更多
关键词 6063 aluminum alloy helical surface forward hot extrusion twist angle die structure
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Influence of surface finish and annealing treatment on oxidation behavior of Ti-48Al-8Cr-2Ag alloy
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作者 席艳君 刘泳俊 《Journal of Central South University》 SCIE EI CAS 2009年第4期541-545,共5页
The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy was investigated at 900 and 1 000 ℃, respectively in air. Thermal gravimetric analysis (TGA)... The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy was investigated at 900 and 1 000 ℃, respectively in air. Thermal gravimetric analysis (TGA) was conducted for the characterization of oxidation kinetics. The microstructures of oxide scales were studied by scanning electron microscopy (SEM) and transmission election microscopy (TEM) techniques. Unfavorable effect of the annealing treatment on the oxidation behavior of the coating was also investigated. The results indicate that the oxidation behavior of the alloy is influenced by surface finish and annealing treatment. The oxidation rate of ground sample is lower than that of the polished alloy at 1 000 ℃ in air. The former forms a scale of merely Al2O3, and the latter forms a scale of the mixture of Al2O3 and TiO2. Annealing can improve the formation of TiO2. 展开更多
关键词 Ti-48Al-8Cr-2Ag alloy COATING surface finish ANNEALING oxidation behavior
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Laser Surface Modification of Lean-alloyed Austenitic Stainless Steel for Corrosion Resistance
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作者 Chan W K Kwok C T +1 位作者 Chan M C Lo K H 《腐蚀与防护》 北大核心 2012年第S1期55-61,共7页
In order to reduce the cost of the austenitic stainless steels(ASSs),the expensive austenite former(nickel) is often substituted by manganese.However,manganese is generally seen to have a detrimental effect on the cor... In order to reduce the cost of the austenitic stainless steels(ASSs),the expensive austenite former(nickel) is often substituted by manganese.However,manganese is generally seen to have a detrimental effect on the corrosion resistance.In the present study,the feasibility of laser surface modification of a lean-alloyed ASS(FeCrMn) for enhancing pitting corrosion resistance was investigated.Laser surface modification of FeCrMn was successfully achieved by a 2.3 kW high power diode laser(HPDL).Cyclic polarization tests for FeCrMn after laser surface modification in 3.5% NaCl solution at 25 ℃ were performed by using a potentiostat.The pitting resistance of the laser-modified specimens was found to be significantly improved as reflected by the noble shift in pitting potential.This could be attributed to redistribution of manganese sulphide leading to a more homogenous and refined microstructure.Pitting corrosion resistance of the laser-treated FeCrMn followed by subsequent citric acid passivation was found to be further improved as reflected by the noble shift in pitting potential to 0.18 V. 展开更多
关键词 laser surface melting HPDL lean-alloyed austenite stainless steel pitting corrosion citric acid passivation
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Friction stir surfacing of cast A356 aluminiumesilicon alloy with boron carbide and molybdenum disulphide powders 被引量:2
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作者 R.SRINIVASU A.SAMBASIVA RAO +1 位作者 G.MADHUSUDHAN REDDY K.SRINIVASA RAO 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2015年第2期140-146,共7页
Good castability and high strength properties of Ale Si alloys are useful in defence applications like torpedoes,manufacture of Missile bodies,and parts of automobile such as engine cylinders and pistons.Poor wear res... Good castability and high strength properties of Ale Si alloys are useful in defence applications like torpedoes,manufacture of Missile bodies,and parts of automobile such as engine cylinders and pistons.Poor wear resistance of the alloys is major limitation for their use.Friction stir processing(FSP) is a recognized surfacing technique as it overcomes the problems of fusion route surface modification methods.Keeping in view of the requirement of improving wear resistance of cast aluminiumesilicon alloy,friction stir processing was attempted for surface modification with boron carbide(B4C) and molybdenum disulfide(Mo S2) powders.Metallography,micro compositional analysis,hardness and pin-on-disc wear testing were used for characterizing the surface composite coating.Microscopic study revealed breaking of coarse silicon needles and uniformly distributed carbides in the A356 alloy matrix after FSP.Improvement and uniformity in hardness was obtained in surface composite layer.Higher wear resistance was achieved in friction stir processed coating with carbide powders.Addition of solid lubricant Mo S2 powder was found to improve wear resistance of the base metal significantly. 展开更多
关键词 A356合金 二硫化钼 堆焊技术 硅合金 钼粉末 碳化硼 摩擦 铸铝
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Friction surfacing of hypereutectic Al-Si alloy on commercially pure aluminum : Effect of consumable rod heat treatment and heat input
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作者 BARARPOUR Seyedeh Marjan JAMSHIDI AVAL Hamed +1 位作者 JAMAATI Roohollah JAVIDANI Mousa 《Journal of Central South University》 CSCD 2024年第11期4082-4097,共16页
This study investigated the effect of pre-friction surfacing heat treatment of consumable rods and heat input during friction surfacing on the microstructure,mechanical properties,and wear resistance of hypereutectic ... This study investigated the effect of pre-friction surfacing heat treatment of consumable rods and heat input during friction surfacing on the microstructure,mechanical properties,and wear resistance of hypereutectic Al-Si alloy deposited on a commercially pure aluminum substrate.The results show that regardless of the consumable rod’s heat treatment conditions,the coating’s efficiency has increased with the increase in heat input,so the coating efficiency increases by 20%and 30%in the solid solution-treated rod and the artificially aged rod,respectively.By increasing the heat input,the average grain size in the coating fabricated by solid solution-treated rod and artificially aged rod increased from 0.1 to 0.9μm and from 0.2 to 1.3μm,respectively.At constant heat input,the average hardness and wear resistance of the coating created in the solid solution-treated rod are lower than those of the artificially aged rod.By decreasing heat input,the wear loss in the coating fabricated by solid solution-treated rod and artificially aged rod decreased by 10%and 20%,respectively,reaching 0.1 and 0.03μg/m. 展开更多
关键词 friction surfacing hypereutectic Al-Si alloy heat input microstructure wear resistance
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顶空固相微萃取-GC-MS/MS法监测地表水中7种有机溶剂 被引量:1
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作者 姚洋 杨燕 +2 位作者 张庆鹏 张胜平 刘晓芳 《化学研究与应用》 北大核心 2025年第4期1014-1018,共5页
建立顶空固相微萃取技术联合气相色谱三重四级杆质谱(GC-MS/MS)测定地表水中硝基苯、苯胺、甲基叔丁基醚、溴甲烷、溴乙烷、联苯和1,1,1-三氯乙烷7种常见溶剂残留检测方法的检测方法。采用顶空固相微萃取技术,选择聚丙烯酸酯涂层纤维地... 建立顶空固相微萃取技术联合气相色谱三重四级杆质谱(GC-MS/MS)测定地表水中硝基苯、苯胺、甲基叔丁基醚、溴甲烷、溴乙烷、联苯和1,1,1-三氯乙烷7种常见溶剂残留检测方法的检测方法。采用顶空固相微萃取技术,选择聚丙烯酸酯涂层纤维地表水样进行提取。提取液进样色谱质谱系统,外标法定量。硝基苯、苯胺、甲基叔丁基醚、溴甲烷、溴乙烷、联苯和1,1,1-三氯乙烷7种溶剂在质量浓度0.005~0.5μg·mL^(-1)范围内与相应的定量离子峰面积呈良好的线性关系,相关系数均大于0.995。检出限如下:硝基苯:0.00342μg·mL^(-1)、苯胺:0.00435μg·mL^(-1)、甲基叔丁基醚:0.00452μg·mL^(-1)、溴甲烷:0.00476μg·mL^(-1)、溴乙烷:0.00453μg·mL^(-1)、联苯:0.00456μg·mL^(-1)、1,1,1-三氯乙烷:0.00480μg·mL^(-1)。样品在不同水平浓度点的回收率在90.5%~110.3%之间,相对标准偏差在1.78%~4.58%之间(n=6)。该方法操作简单、快速,定性定量准确,适用于地表水中硝基苯等7种有机溶剂残留的监测,为保护地表水环境提供技术参考。 展开更多
关键词 顶空固相微萃取 gc-MS/MS 地表水 溶剂残留
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多氯联苯的气相色谱/质谱/质谱(GC/MS/MS)法测定 被引量:24
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作者 张景明 胡冠九 +1 位作者 周春宏 穆肃 《中国环境监测》 CAS CSCD 北大核心 2003年第3期5-8,共4页
采用气相色谱/质谱/质谱(GC/MS/MS)法测定多氯联苯(PCB),具有良好的灵敏度和选择性,在地表水样品检测时,样品只须进行简单的液液萃取-浓缩,不须任何净化过程即可上机分析,方法检出限低于ng/L级。
关键词 多氯联苯 气相色谱/质谱/质谱 地表水
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籽瓜多糖的提取分离及单糖组成的GC-MS分析 被引量:19
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作者 宋珅 赵保堂 +3 位作者 殷振雄 刘琴 梁俊玉 张继 《食品与发酵工业》 CAS CSCD 北大核心 2013年第5期238-245,共8页
用微波辅助萃取技术从籽瓜中提取籽瓜多糖,并用GC-MS分析其单糖组成。依据响应面设计(response surface methodology,RSM)原理,使用SAS(SAS Package)软件的中心组合设计建立提取数学模型,对影响籽瓜多糖得率的提取时间、微波功率、提取... 用微波辅助萃取技术从籽瓜中提取籽瓜多糖,并用GC-MS分析其单糖组成。依据响应面设计(response surface methodology,RSM)原理,使用SAS(SAS Package)软件的中心组合设计建立提取数学模型,对影响籽瓜多糖得率的提取时间、微波功率、提取温度和料液比4个因素进行优化组合。确定最优提取工艺参数为时间19.5min、温度62℃、料液比(g∶mL)1∶0.9、功率302 W。多糖得率为4.58%。对得到的籽瓜多糖进行了红外扫描,3 408、2928、1 408、1 645.08、1 074 cm-1都出现了糖类的特征吸收峰。GC-MS分析结果表明籽瓜多糖由鼠李糖、阿拉伯糖、木糖、甘露糖、葡萄糖、半乳糖六种单糖组成,摩尔比为4.48∶13.14∶4.16∶7.82∶10.1∶60.3。 展开更多
关键词 籽瓜多糖 微波提取 响应面法 gc-MS分析
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鼠曲草挥发油的提取及GC-MS分析 被引量:8
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作者 潘明 邓赟 +1 位作者 郭脉玺 刘慧杰 《食品工业科技》 CAS CSCD 北大核心 2009年第6期243-245,共3页
用水蒸气蒸馏法提取鼠曲草挥发油,采用minitab软件对鼠曲草挥发油的提取工艺进行响应面分析,利用气相色谱-质谱联用(GC-MS)对挥发油成分进行分析。结果表明:从鼠曲草挥发油中分离鉴定了25个组分,占总峰面积含量的98.69%,主要含长链脂肪... 用水蒸气蒸馏法提取鼠曲草挥发油,采用minitab软件对鼠曲草挥发油的提取工艺进行响应面分析,利用气相色谱-质谱联用(GC-MS)对挥发油成分进行分析。结果表明:从鼠曲草挥发油中分离鉴定了25个组分,占总峰面积含量的98.69%,主要含长链脂肪酸及其衍生物。主要挥发性成分的面积归一化法含量为:棕榈酸38.30%,亚油酸16.70%,亚油酸乙酯7.44%,肉豆蔻酸6.33%,油酸4.86%,硬脂酸2.28%,6,10,14-三甲基十五烷-2-酮2.83%,十五烷酸1.72%等。 展开更多
关键词 鼠曲草 挥发油 响应面法 气相-质谱联用分析
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玉米植物甾醇的精制、结构表征及GC-MS分析 被引量:3
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作者 陈红 王大为 +2 位作者 樊红秀 刘静雪 刘健影 《中国粮油学报》 EI CAS CSCD 北大核心 2015年第5期41-46,52,共7页
以玉米植物甾醇粗品为研究对象,应用响应面分析法,对植物甾醇的精制工艺条件进行研究,结果表明:液料比10∶1,结晶温度1℃,养晶时间3 h,甾醇得率为68.60%,甾醇纯度为95.68%,甾醇得率与理论预测值基本一致。采用红外光谱分析法和电镜扫描... 以玉米植物甾醇粗品为研究对象,应用响应面分析法,对植物甾醇的精制工艺条件进行研究,结果表明:液料比10∶1,结晶温度1℃,养晶时间3 h,甾醇得率为68.60%,甾醇纯度为95.68%,甾醇得率与理论预测值基本一致。采用红外光谱分析法和电镜扫描法对玉米植物甾醇进行表征。采用气相色谱质谱联用仪分析精制产品中玉米植物甾醇的组成,鉴定出菜油甾醇、豆甾醇和β-谷甾醇3种植物甾醇,质量分数分别为28.57%、6.18%和65.25%。 展开更多
关键词 粗甾醇 精制 响应面 结构表征 gc-MS分析
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优化GC检测欧李酒香气成分的萃取条件 被引量:13
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作者 陈臣 李艳 牟德华 《食品工业科技》 CAS CSCD 北大核心 2014年第6期81-86,共6页
香气物质的组成表征果酒的特色,利用响应面法优化顶空固相微萃取(HS-SPME)欧李果酒中香气物质的条件,使气相色谱法检测香气物质的结果更精确。本文采用HS-SPME结合GC-FID检测欧李发酵酒中的香气物质,在单因素实验的基础上,以加盐量、萃... 香气物质的组成表征果酒的特色,利用响应面法优化顶空固相微萃取(HS-SPME)欧李果酒中香气物质的条件,使气相色谱法检测香气物质的结果更精确。本文采用HS-SPME结合GC-FID检测欧李发酵酒中的香气物质,在单因素实验的基础上,以加盐量、萃取温度、萃取时间为影响因素,出峰面积为响应值,运用Box-Benhnken中心组合实验设计原理进行响应面分析,优化了HS-SPME的萃取条件。结果表明,HS-SPME萃取欧李发酵酒中香气成分的适宜条件为:加盐量0.226g/mL、萃取温度29℃、萃取时间36min。该条件下萃取,结合GC-FID测得欧李发酵酒中32种香气成分,对其中10种进行了定性和定量分析,含量较高的有:异戊醇110.734mg/L、己酸乙酯11.568mg/L、异丁醇8.7725mg/L、苯乙醇47.178mg/L、乙酸异戊酯15.655mg/L、丙醇1.7032mg/L。 展开更多
关键词 HS—SPME 响应面优化 gc—FID 欧李发酵酒 香气成分
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