针对风力发电机组频发的火灾事故,首先从人-机-环-管角度出发,通过统计分析近20年来全球81起风力发电机组火灾事故案例,得到了21项风力发电机组火灾事故的影响因素;然后通过事故树分析(fault tree analysis,FTA)法演绎推理得到了风力发...针对风力发电机组频发的火灾事故,首先从人-机-环-管角度出发,通过统计分析近20年来全球81起风力发电机组火灾事故案例,得到了21项风力发电机组火灾事故的影响因素;然后通过事故树分析(fault tree analysis,FTA)法演绎推理得到了风力发电机组火灾事故各基本事件的逻辑关系,并根据结构重要度进行了火灾事故致因的定性分析;接着采用模糊层次分析(fuzzy analytic hierarchy process,FAHP)法,将事故树的基本事件从人、机、环、管4个方面整合,构建出风力发电机组火灾事故致因评价指标体系,并以结构重要度系数的顺序为模糊判断矩阵的赋值依据,进行了火灾事故致因的定量分析;最后,根据综合分析结果提出了风力发电机组火灾事故的对策措施。结果表明:机和环境的不安全因素是引发火灾事故的主要致因;电气设备故障和雷击是最主要因素。该研究成果可为风力发电机组的火灾防治提供理论参考。展开更多
The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2...The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.展开更多
基金The Ministry of Science and Higher Education of the Russian Federation(Agreement with Zelinsky Institute of Organic Chemistry RAS No 075-15-2020-803).
文摘The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.
