This paper investigates process parameter effects on microstructure and mechanical properties of the tubes processed via recently developed friction assisted tube straining(FATS)method.For this purpose,design of exper...This paper investigates process parameter effects on microstructure and mechanical properties of the tubes processed via recently developed friction assisted tube straining(FATS)method.For this purpose,design of experiment was used to arrange finite element analyses and experimental tests.Numerical and experimental tests were executed by changing rotary speed,feed rate and die angle.Taguchi design results show that increasing feed rate and decreasing rotary speed enhance Zener-Hollomon(Z)parameter and decrease average grain size,while die angle has no considerable effect.Increasing Z value reduces grain size and enhances flow stress of the processed samples,while the experiment with the highest Z value refines initial microstructure from 40 to 8μm and increases flow stress by 5 times.展开更多
This study presents a machine learning-based method for predicting fragment velocity distribution in warhead fragmentation under explosive loading condition.The fragment resultant velocities are correlated with key de...This study presents a machine learning-based method for predicting fragment velocity distribution in warhead fragmentation under explosive loading condition.The fragment resultant velocities are correlated with key design parameters including casing dimensions and detonation positions.The paper details the finite element analysis for fragmentation,the characterizations of the dynamic hardening and fracture models,the generation of comprehensive datasets,and the training of the ANN model.The results show the influence of casing dimensions on fragment velocity distributions,with the tendencies indicating increased resultant velocity with reduced thickness,increased length and diameter.The model's predictive capability is demonstrated through the accurate predictions for both training and testing datasets,showing its potential for the real-time prediction of fragmentation performance.展开更多
High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production meth...High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.展开更多
1)Bifidobacterium longum subsp.iuvenis(Modesto et al.IJSEM.2023,73:6013;Type strain:NCC 5000 T=CCOS 2034 T=LMG 32752^(T))Etymology:iu’ve.nis.L.gen.masc./fem.n.iuvenis,of child,because the type strain was isolated fro...1)Bifidobacterium longum subsp.iuvenis(Modesto et al.IJSEM.2023,73:6013;Type strain:NCC 5000 T=CCOS 2034 T=LMG 32752^(T))Etymology:iu’ve.nis.L.gen.masc./fem.n.iuvenis,of child,because the type strain was isolated from a 2 year old Bangladeshi child.长双歧杆菌幼儿亚种.展开更多
Recent advances in additive manufacturing have enabled the construction of metallic lattice structures with tailored mechanical and functional properties.One potential application of metallic lattice struc-tures is in...Recent advances in additive manufacturing have enabled the construction of metallic lattice structures with tailored mechanical and functional properties.One potential application of metallic lattice struc-tures is in the impact load mitigation where an external kinetic energy is absorbed by the deformation/crushing of lattice cells.This has motivated a growing number of experimental and numerical studies,recently,on the crushing behavior of additively produced lattice structures.The present study overviews the dynamic and quasi-static crushing behavior of additively produced Ti64,316L,and AlSiMg alloy lattice structures.The first part of the study summarizes the main features of two most commonly used additive processing techniques for lattice structures,namely selective-laser-melt(SLM)and electro-beam-melt(EBM),along with a description of commonly observed process induced defects.In the second part,the deformation and strain rate sensitivities of the selected alloy lattices are outlined together with the most widely used dynamic test methods,followed by a part on the observed micro-structures of the SLM and EBM-processed Ti64,316L and AlSiMg alloys.Finally,the experimental and numerical studies on the quasi-static and dynamic compression behavior of the additively processed Ti64,316L,and AlSiMg alloy lattices are reviewed.The results of the experimental and numerical studies of the dynamic properties of various types of lattices,including graded,non-uniform strut size,hollow,non-uniform cell size,and bio-inspired,were tabulated together with the used dynamic testing methods.The dynamic tests have been noted to be mostly conducted in compression Split Hopkinson Pressure Bar(SHPB)or Taylor-and direct-impact tests using the SHPB set-up,in all of which relatively small-size test specimens were tested.The test specimen size effect on the compression behavior of the lattices was further emphasized.It has also been shown that the lattices of Ti64 and AlSiMg alloys are relatively brittle as compared with the lattices of 316L alloy.Finally,the challenges associated with modelling lattice structures were explained and the micro tension tests and multi-scale modeling techniques combining microstructural characteristics with macroscopic lattice dynamics were recommended to improve the accuracy of the numerical simulations of the dynamic compression deformations of metallic lattice structures.展开更多
The deformation behavior of hot-rolled AZ31 magnesium(Mg)alloy sheet was analyzed when subjected to uniaxial tension along its normal direction at temperatures ranging from 100 to 400℃and strain rates ranging from 0....The deformation behavior of hot-rolled AZ31 magnesium(Mg)alloy sheet was analyzed when subjected to uniaxial tension along its normal direction at temperatures ranging from 100 to 400℃and strain rates ranging from 0.5 to 100 mm/min.Based on the stress−strain curves and the dynamic material model,the hot processing map was established,which demonstrates that the power dissipation factor(η)is the most sensitive to strain rate at 400℃via absorption of dislocations.At 400℃,sample at 0.5 mm/min possessesηof 0.89 because of its lower kernel average misorientation(KAM)value of 0.51,while sample at 100 mm/min possessesηof 0.46 with a higher KAM value of 1.147.In addition,the flow stress presents a slight decrease of 25.94 MPa at 10 mm/min compared to that at 100 mm/min and 100℃.The reasons are twofold:a special~34°texture component during 100℃-100 mm/min favoring the activation of basal slip,and dynamic recrystallization(DRX)also providing softening effect to some extent by absorbing dislocations.Difference in activation of basal slip among twin laminas during 100℃-100 mm/min results in deformation inhomogeneity within the grains,which generates stress that helps matrix grains tilt to a direction favorable to basal slip,forming the special~34°texture component.展开更多
Waveform regulator in charge is a method that can realize multi-source detonation wave superposition through a single point detonation.The method does not need to weaken the strength of shell,and relies on the high st...Waveform regulator in charge is a method that can realize multi-source detonation wave superposition through a single point detonation.The method does not need to weaken the strength of shell,and relies on the high stress generated by superposition to cut shell into regular fragments.Additionally,it can be combined with different initiation methods to alter the fragmentation outcomes.In this study,aiming at the fracture strain of metal cylindrical shell driven by explosive charge with waveform regulator,theoretical analysis was first adopted to obtain the prediction model of the fracture strain of cylindrical shell with waveform regulator and the model of the axial distribution of the stress concentration factor.On this basis,both theoretical analysis and numerical models were utilized to investigate the effect of waveform regulator on the initial velocity of fragments.Finally,experiments were conducted to validate the fracture strain prediction model for cylindrical shell with waveform regulator.The research results show that the collision angles of the detonation waves at different axial positions are different,which leads to the stress concentration factor on the shell presenting a trend of gradually decreasing,then sharply increasing,and then rapidly decreasing along the axial direction.Additionally,the changes in the slot spacing and the thickness of outer charge will also affect the stress concentration factor,and the influence of outer charge thickness is relatively large.The smaller the ratio of charge volume to waveform regulator volume,the larger the axial sparse wave intensity and the more the fragment initial velocity decrease.From the initiation end to the non-initiation end,the failure modes of the shell sequentially change from pure shear,to mixed tensile-shear,and finally to pure tensile failure.The experimental results are in good agreement with the calculated results of the fracture strain model,and the maximum relative error is less than 10%,which indicates that the fracture strain prediction model of the cylindrical shell with waveform regulator established in this paper by considering the increase of elastic energy per unit volume caused by stress concentration on the shell is reliable.展开更多
This study investigates the shear mechanical responses and debonding failure mechanisms of anchoring systems comprising three anisotropic media and two anisotropic interfaces under controlled boundary conditions of co...This study investigates the shear mechanical responses and debonding failure mechanisms of anchoring systems comprising three anisotropic media and two anisotropic interfaces under controlled boundary conditions of constant normal load(F_(s)),constant normal stiffness(K),and shear rate(v).A systematic analysis of shear mechanical properties,the evolution of maximum principal strain field,and damage characteristics along shear failure surface is presented.Results from direct shear tests demonstrate that initial shear slip diminishes with increasing F_(s)and K,attributed to the normal constraint strengthening effect,while an increase in v enhances initial shear slip due to attenuated deformation coordination and stress transfer.As F_(s)increases from 7.5 to 120 kN,K from 0 to 12 MPa/mm,and v from 0.1 to 2 mm/min,the peak shear load increases by 210.32%and 80.16%with rising F_(s)and K,respectively,while decreases by 38.57%with increasing v.Correspondingly,the shear modulus exhibits,respectively,a 135.29%and 177.06%increase with rising F_(s)and K,and a 37.03%decrease with larger v.Initial shear dilation is identified as marking the formation of shear failure surface along anisotropic interfaces,resulting from the combined shear actions at the resin bolt interface,where resin undergoes shear by bolt surface protrusions,and the resin-rock interface,where mutual shear occurs between resin and rock.With increasing F_(s)and K and decreasing v,the location of the shear failure surface shifts from the resin-rock interface to the resin-bolt interface,accompanied by a transition in failure mode from tensile rupture of resin to shear off at the resin surface.展开更多
This study proposed a new and more flexible S-shaped rock damage evolution model from a phenomenological perspective based on an improved Logistic function to describe the characteristics of the rock strain softening ...This study proposed a new and more flexible S-shaped rock damage evolution model from a phenomenological perspective based on an improved Logistic function to describe the characteristics of the rock strain softening and damage process.Simultaneously,it established a constitutive model capable of describing the entire process of rock pre-peak compaction and post-peak strain softening deformation,considering the nonlinear effects of the initial compaction stage of rocks,combined with damage mechanics theory and effective medium theory.In addition,this research verified the rationality of the constructed damage constitutive model using results from uniaxial and conventional triaxial compression tests on Miluo granite,yellow sandstone,mudstone,and glutenite.The results indicate that based on the improved Logistic function,the theoretical damage model accurately describes the entire evolution of damage characteristics during rock compression deformation,from maintenance through gradual onset,accelerated development to deceleration and termination,in a simple and unified expression.At the same time,the constructed constitutive model can accurately simulate the stress-strain process of different rock types under uniaxial and conventional triaxial compression,and the theoretical model curve closely aligns with experimental data.Compared to existing constitutive models,the proposed model has significant advantages.The damage model parameters a,r and β have clear physical meanings and interact competitively,where the three parameters collectively determine the shape of the theoretical stress−strain curve.展开更多
Dynamic compression experiments were conducted on red sandstone utilizing a split Hopkinson pressure bar(SHPB)to study the loading rate and high temperatures on their mechanically deformed properties and ultimate fail...Dynamic compression experiments were conducted on red sandstone utilizing a split Hopkinson pressure bar(SHPB)to study the loading rate and high temperatures on their mechanically deformed properties and ultimate failure modes,and to analyze the correlation between the strain rate,temperature,peak strength,and ultimate failure modes.The results show that the mass decreases with the increase of treatment temperature,and the pattern of the stress−strain curves is not impacted by the increase of impact velocity.Under a fixed temperature,the higher the impact velocity,the higher the strain rate and dynamical compression strength,indicating a strain rate hardening effect for red sandstone.With an increasing treatment temperature,the strain rate gradually increases when the impact loading remains unchanged,suggesting a rise in the deformability of red sandstone under high-temperature environment.Raise in both impact velocity and treatment temperature leads to an intensification of the damage features of the red sandstone.Similarly,higher strain rates lead to the intensification of the final damage mode of red sandstone regardless of the change in treatment temperature.Moreover,a dynamic damage constitutive model that considers the impacts of strain rate and temperature is proposed based on experimental results.展开更多
The geostress and rock blasting in underground engineering may greatly affect the stress thresholds of surrounding rock.In this study,pre-damage impact tests were first conducted on granite under varying confining pre...The geostress and rock blasting in underground engineering may greatly affect the stress thresholds of surrounding rock.In this study,pre-damage impact tests were first conducted on granite under varying confining pressures(5,10 and 15 MPa)and numbers of impacts(1,5,10 and 15 impacts).Then,uniaxial compression tests were undertaken on the pre-damaged granite to study the evolution of stress thresholds using the crack volume strain method and acoustic emission method.The crack damage stresses determined by the two methods were compared.Additionally,based on the rise time amplitude and average frequency,the evolution law of microcracks inside rock specimens was revealed,and an improved acoustic emission method was proposed.The results indicated that as the number of impacts increased,the crack closure stress,crack damage stress,and peak stress of granite specimens initially rose and then declined,while they continuously increased with the confining pressure.The proportion of shear cracks first declined and then rose with greater number of impacts and decreased with higher confining pressure,and that of tensile cracks showed the opposite trend.The improved acoustic emission method was more accurate in identifying the crack damage stress.展开更多
Water is a critical factor affecting the mechanical properties of rocks, leading to their degradation. Understanding the creep mechanical behavior of deep roadway surrounding rock under the influence of underground wa...Water is a critical factor affecting the mechanical properties of rocks, leading to their degradation. Understanding the creep mechanical behavior of deep roadway surrounding rock under the influence of underground water is of great significance. Compression and creep experiments on sandstone with varying water contents were conducted using a deep soft rock five-linked rheological experiment system. The experimental conditions, including water content (0%, 0.8%, 1.6%, 2.4% and 3.3%) and confining pressure (0, 6, 9 and 12 MPa), were determined based on pressure-free water absorption tests and in-situ stress measurements. The experimental results show that the compressive strength, creep failure stress, and dilatancy stress of sandstone decrease exponentially with increasing water content, while they increase exponentially with confining pressure. The ratio of lateral to axial instantaneous strain increases nearly linearly with the increase of stress, and the lateral creep strain characteristics of the sample are more significant than the axial ones. The duration of the attenuation creep stage of sandstone decreases with increasing water content and increases with increasing confining pressure. The lateral strain enters the steady-state creep stage before the axial strain, and the onset time of the accelerated creep stage of lateral strain under the failure stress is earlier than that of axial strain. The long-term strength of sandstone was determined based on the lateral steady-state creep rate curve, showing a negative exponential relationship with water content and a positive exponential relationship with confining pressure. A method for determining the long-term strength of rocks based on the ratio of lateral strain to axial strain (μc) is proposed, which is independent of water content. The research results provide a reliable theoretical basis for the analysis of the long-term stability of roadways under the influence of groundwater and the early prediction of creep failure.展开更多
Flexible microporous metal rubber(FMP-MR)is widely used in national defense applications,yet its mechanical behavior under high-speed impact conditions remains insufficiently explored.In this study,dynamic and static ...Flexible microporous metal rubber(FMP-MR)is widely used in national defense applications,yet its mechanical behavior under high-speed impact conditions remains insufficiently explored.In this study,dynamic and static experiments were conducted to systematically investigate the mechanical response of metal-wrapped microporous materials under impact loading that spanned 10~6 orders of magnitude.By combining a high-precision numerical model with a spatial contact point search algorithm,the spatio–temporal contact characteristics of the complex network structure in FMP-MR were systematically analyzed.Furthermore,the mapping mechanism from turn topology and mesoscopic friction behavior to macroscopic mechanical properties was comprehensively explored.The results showed that compared with quasi-static loading,FMP-MR under high-speed impact exhibited higher energy absorption efficiency due to high-strain-rate inertia effect.Therefore,the peak stress increased by 141%,and the maximum energy dissipation increased by 300%.Consequently,the theory of dynamic friction locking effect was innovatively proposed.The theory explains that the close synergistic effect of sliding friction and plastic dissipation promoted by the stable interturn-locked embedded structure is the essential reason for the excellent dynamic mechanical properties of FMP-MR under dynamic loading conditions.Briefly,based on the in-depth investigation of the mechanical response and energy dissipation mechanism of FMP-MR under impact loads,this study provides a solid theoretical basis for further expanding the application range of FMP-MR and optimizing its performance.展开更多
The commercial ZK 60 magnesium alloy with extruded state experienced aging heat treatment(T 6)was dynamically loaded at strain rate of 3000 s−1 by means of the split Hopkinson pressure bar(SHPB)in this paper.Transmiss...The commercial ZK 60 magnesium alloy with extruded state experienced aging heat treatment(T 6)was dynamically loaded at strain rate of 3000 s−1 by means of the split Hopkinson pressure bar(SHPB)in this paper.Transmission electron microscopy(TEM)observations showed that the precipitatedβ′_(1) phases partially dissolved(spheroidized)with blurred interfaces within 160μs at 3000 s^(−1).The average length and diameter of the rod-shapedβ′_(1) phase particles were 48.5 and 9.8 nm after the T 6 heat treatment;while the average diameter of the sphericalβ′_(1) phases changed to 8.8 nm after loading.The deformedβ′_(1) phase generated larger lattice distortion energy than Mg matrix under high strain rate loading.Therefore,the difference of free energy(the driving force of dissolution)between theβ′_(1) phase and the matrix increased,making the instantaneous dissolution of theβ′_(1) phase thermodynamically feasible.The dissolution(spheroidization)of theβ′_(1) phase particles was kinetically promoted because the diffusion rate of the solute Zn atoms was accelerated by combined actions of adiabatic temperature rise,high density of dislocations(vacancies)and high deviatoric stresses during high strain rate loading.The increase in hardness of ZK 60-T 6 alloy could be attributed to solid solution strengthening,dislocation strengthening and second phase particle strengthening.展开更多
The vibration pretreatment-microwave curing process is an efficient,low energy consumption,and high-quality out-of-autoclave curing process for carbon fiber resin matrix composites.This study aims to investigate the i...The vibration pretreatment-microwave curing process is an efficient,low energy consumption,and high-quality out-of-autoclave curing process for carbon fiber resin matrix composites.This study aims to investigate the impact of vibration pretreatment temperature on the fiber weight content,microscopic morphology and mechanical properties of the composite laminates by using optical digital microscopy,universal tensile testing machine and thermo-gravimetric analyzer.Additionally,the combined mode of Bragg fiber grating sensor and temperature measurement fiber was employed to explore the effect of vibration pretreatment on the strain process during microwave curing.The study results revealed that the change in vibration pretreatment temperature had a slight impact on the fiber weight content when the vibration acceleration remained constant.The metallographic and interlaminar strength of the specimen formed at a vibration pretreatment temperature of 80℃ demonstrated a porosity of 0.414% and a 10.69% decrease in interlaminar shear strength compared to autoclave curing.Moreover,the introduction of the vibration energy field during the microwave curing process led to a significant reduction in residual strain in both the 0°and 90°fiber directions,when the laminate was cooled to 60℃.展开更多
In recent years,rockburst have gained significant attention as a crucial topic in rock engineering.Strain andfault-slip rockburst are two common types that occur frequently and cause substantial damage.The objective o...In recent years,rockburst have gained significant attention as a crucial topic in rock engineering.Strain andfault-slip rockburst are two common types that occur frequently and cause substantial damage.The objective of thisreview is to conduct a comprehensive study on the experiments and failure mechanisms of strain and fault-slip rockburst.Firstly,the article analyzes the evolving trends in experimental research on rockburst in the past decade,highlightingmechanical properties and failure modes as the primary research focuses in understanding rockburst mechanisms.Subsequently,it provides an overview of the experimental techniques and methods employed for studying both types ofrockburst.Then,with a focus on the mechanical properties and failure modes,the article conducts an extensive analysisof the failure mechanisms associated with strain and fault-slip rockburst.By analyzing experimental data and observingthe failure characteristics of samples,it discusses the variations and common features exhibited by these two types ofrockburst under various test conditions.This analysis is of paramount importance in revealing the causes of rockburstformation and development,as well as in predicting rockburst trends and assessing associated risks.Lastly,thelimitations of current rockburst experiments and future research directions are discussed,followed by a comprehensivesummary of the entire article.展开更多
In order to investigate the mechanical response behavior of the gas obturator of the breech mechanism,made of polychloroprene rubber(PCR), uniaxial compression experiments were carried out by using a universal testing...In order to investigate the mechanical response behavior of the gas obturator of the breech mechanism,made of polychloroprene rubber(PCR), uniaxial compression experiments were carried out by using a universal testing machine and a split Hopkinson pressure bar(SHPB), obtaining stress-strain responses at different temperatures and strain rates. The results revealed that, in comparison to other polymers, the gas obturator material exhibited inconspicuous strain softening and hardening effects;meanwhile, the mechanical response was more affected by the strain rate than by temperature. Subsequently, a succinct viscoelastic damage constitutive model was developed based on the ZWT model, including ten undetermined parameters, formulated with incorporating three parallel components to capture the viscoelastic response at high strain rate and further enhanced by integrating a three-parameter Weibull function to describe the damage. Compared to the ZWT model, the modified model could effectively describe the mechanical response behavior of the gas obturator material at high strain rates. This research laid a theoretical foundation for further investigation into the influence of chamber sealing issues on artillery firing.展开更多
Platinum(Pt)-based noble metal catalysts(PGMs)are the most widely used commercial catalysts,but they have the problems of high cost,low reserves,and susceptibility to small-molecule toxicity.Transition metal oxides(TM...Platinum(Pt)-based noble metal catalysts(PGMs)are the most widely used commercial catalysts,but they have the problems of high cost,low reserves,and susceptibility to small-molecule toxicity.Transition metal oxides(TMOs)are regarded as potential substitutes for PGMs because of their stability in oxidizing environments and excellent catalytic performance.In this study,comprehensive investigation into the influence of elastic strains on the adsorption energies of carbon(C),hydrogen(H)and oxygen(O)on TMOs was conducted.Based on density functional theory(DFT)calculations,these effects in both tetragonal structures(PtO_(2),PdO_(2))and hexagonal structures(ZnO,CdO),along with their respective transition metals were systematically explored.It was identified that the optimal adsorption sites on metal oxides pinpointed the top of oxygen or the top of metal atom,while face-centered cubic(FCC)and hexagonal close-packed(HCP)holes were preferred for the transition metals.Furthermore,under the influence of elastic strains,the results demonstrated significant disparities in the adsorption energies of H and O between oxides and transition metals.Despite these differences,the effect of elastic strains on the adsorption energies of C,H and O on TMOs mirrored those on transition metals:adsorption energies increased under compressive strains,indicating weaker adsorption,and decreased under tension strains,indicating stronger adsorption.This behavior was rationalized based on the d-band model for adsorption atop a metallic atom or the p-band model for adsorption atop an oxygen atom.Consequently,elastic strains present a promising avenue for tailoring the catalytic properties of TMOs.展开更多
借助扫描电镜和透射电镜对尼罗罗非鱼(Oreochromis niloticus)、奥利亚罗非鱼(O.aureus)、奥尼罗非鱼(O.niloticus×O.aureus)和吉富罗非鱼(GIFT Strain in Nile Tilapia,O.niloticus)成熟精子的超微结构进行了比较研究。...借助扫描电镜和透射电镜对尼罗罗非鱼(Oreochromis niloticus)、奥利亚罗非鱼(O.aureus)、奥尼罗非鱼(O.niloticus×O.aureus)和吉富罗非鱼(GIFT Strain in Nile Tilapia,O.niloticus)成熟精子的超微结构进行了比较研究。结果显示,4种罗非鱼精子均为有鞭毛精子,无顶体,尾部轴丝9±2型。尼罗罗非鱼精子植入窝陷入核深度最浅,线粒体个数和平均直径分别为5-9个、(0.36±0.10)μm,鞭毛侧鳍平均翼长为(0.29±0.11)μm;奥利亚罗非鱼精子核内染色质着色程度最深,植入窝陷入核深度约1/3,线粒体个数和平均直径分别为3-10个、(0.40±0.17)μm,鞭毛侧鳍平均翼长为(0.32±0.12)μm;奥尼罗非鱼精子核内染色质着色程度较浅,植入窝陷入核深度约1/3,线粒体个数和平均直径分别为5-7个、(0.32±0.09)μm,鞭毛侧鳍平均翼长(0.26±0.09)μm;吉富罗非鱼精子核内染色质着色最浅,植入窝陷入核最深,约占2/3,线粒体个数和平均直径分别为5-10个、(0.37±0.08)μm,中段存在大量中空囊泡,鞭毛侧鳍平均翼长为(0.15±0.03)μm,与其它三种罗非鱼精子鞭毛平均侧鳍翼长比较具显著性差异(P〈0.05)。展开更多
文摘This paper investigates process parameter effects on microstructure and mechanical properties of the tubes processed via recently developed friction assisted tube straining(FATS)method.For this purpose,design of experiment was used to arrange finite element analyses and experimental tests.Numerical and experimental tests were executed by changing rotary speed,feed rate and die angle.Taguchi design results show that increasing feed rate and decreasing rotary speed enhance Zener-Hollomon(Z)parameter and decrease average grain size,while die angle has no considerable effect.Increasing Z value reduces grain size and enhances flow stress of the processed samples,while the experiment with the highest Z value refines initial microstructure from 40 to 8μm and increases flow stress by 5 times.
基金supported by Poongsan-KAIST Future Research Center Projectthe fund support provided by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(Grant No.2023R1A2C2005661)。
文摘This study presents a machine learning-based method for predicting fragment velocity distribution in warhead fragmentation under explosive loading condition.The fragment resultant velocities are correlated with key design parameters including casing dimensions and detonation positions.The paper details the finite element analysis for fragmentation,the characterizations of the dynamic hardening and fracture models,the generation of comprehensive datasets,and the training of the ANN model.The results show the influence of casing dimensions on fragment velocity distributions,with the tendencies indicating increased resultant velocity with reduced thickness,increased length and diameter.The model's predictive capability is demonstrated through the accurate predictions for both training and testing datasets,showing its potential for the real-time prediction of fragmentation performance.
基金Natural Science Foundation of Shanghai(24ZR1400800)he Natural Science Foundation of China(U23A20685,52073058,91963204)+1 种基金the National Key R&D Program of China(2021YFB3701400)Shanghai Sailing Program(23YF1400200)。
文摘High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.
文摘1)Bifidobacterium longum subsp.iuvenis(Modesto et al.IJSEM.2023,73:6013;Type strain:NCC 5000 T=CCOS 2034 T=LMG 32752^(T))Etymology:iu’ve.nis.L.gen.masc./fem.n.iuvenis,of child,because the type strain was isolated from a 2 year old Bangladeshi child.长双歧杆菌幼儿亚种.
基金the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 101034425 for the project titled A2M2TECHThe Scientific and Technological Research Council of Türkiye (TUBITAK) with grant No 120C158 for the same A2M2TECH project under the TUBITAK's 2236/B program
文摘Recent advances in additive manufacturing have enabled the construction of metallic lattice structures with tailored mechanical and functional properties.One potential application of metallic lattice struc-tures is in the impact load mitigation where an external kinetic energy is absorbed by the deformation/crushing of lattice cells.This has motivated a growing number of experimental and numerical studies,recently,on the crushing behavior of additively produced lattice structures.The present study overviews the dynamic and quasi-static crushing behavior of additively produced Ti64,316L,and AlSiMg alloy lattice structures.The first part of the study summarizes the main features of two most commonly used additive processing techniques for lattice structures,namely selective-laser-melt(SLM)and electro-beam-melt(EBM),along with a description of commonly observed process induced defects.In the second part,the deformation and strain rate sensitivities of the selected alloy lattices are outlined together with the most widely used dynamic test methods,followed by a part on the observed micro-structures of the SLM and EBM-processed Ti64,316L and AlSiMg alloys.Finally,the experimental and numerical studies on the quasi-static and dynamic compression behavior of the additively processed Ti64,316L,and AlSiMg alloy lattices are reviewed.The results of the experimental and numerical studies of the dynamic properties of various types of lattices,including graded,non-uniform strut size,hollow,non-uniform cell size,and bio-inspired,were tabulated together with the used dynamic testing methods.The dynamic tests have been noted to be mostly conducted in compression Split Hopkinson Pressure Bar(SHPB)or Taylor-and direct-impact tests using the SHPB set-up,in all of which relatively small-size test specimens were tested.The test specimen size effect on the compression behavior of the lattices was further emphasized.It has also been shown that the lattices of Ti64 and AlSiMg alloys are relatively brittle as compared with the lattices of 316L alloy.Finally,the challenges associated with modelling lattice structures were explained and the micro tension tests and multi-scale modeling techniques combining microstructural characteristics with macroscopic lattice dynamics were recommended to improve the accuracy of the numerical simulations of the dynamic compression deformations of metallic lattice structures.
基金Project(52005362) supported by the National Natural Science Foundation of ChinaProjects(202303021221005,202303021211045) supported by the Natural Science Foundation of Shanxi Province,China+1 种基金Project(202402003) supported by the Patent Commercialization Program of Shanxi Province,ChinaProject supported by the Key Research and Development Plan of Xinzhou City,China。
文摘The deformation behavior of hot-rolled AZ31 magnesium(Mg)alloy sheet was analyzed when subjected to uniaxial tension along its normal direction at temperatures ranging from 100 to 400℃and strain rates ranging from 0.5 to 100 mm/min.Based on the stress−strain curves and the dynamic material model,the hot processing map was established,which demonstrates that the power dissipation factor(η)is the most sensitive to strain rate at 400℃via absorption of dislocations.At 400℃,sample at 0.5 mm/min possessesηof 0.89 because of its lower kernel average misorientation(KAM)value of 0.51,while sample at 100 mm/min possessesηof 0.46 with a higher KAM value of 1.147.In addition,the flow stress presents a slight decrease of 25.94 MPa at 10 mm/min compared to that at 100 mm/min and 100℃.The reasons are twofold:a special~34°texture component during 100℃-100 mm/min favoring the activation of basal slip,and dynamic recrystallization(DRX)also providing softening effect to some extent by absorbing dislocations.Difference in activation of basal slip among twin laminas during 100℃-100 mm/min results in deformation inhomogeneity within the grains,which generates stress that helps matrix grains tilt to a direction favorable to basal slip,forming the special~34°texture component.
基金supported by the National Natural Science Foundation of China(Grant No.12302437)Natural Science Foundation of Jiangsu Province(Grant No.SBK2023045424)。
文摘Waveform regulator in charge is a method that can realize multi-source detonation wave superposition through a single point detonation.The method does not need to weaken the strength of shell,and relies on the high stress generated by superposition to cut shell into regular fragments.Additionally,it can be combined with different initiation methods to alter the fragmentation outcomes.In this study,aiming at the fracture strain of metal cylindrical shell driven by explosive charge with waveform regulator,theoretical analysis was first adopted to obtain the prediction model of the fracture strain of cylindrical shell with waveform regulator and the model of the axial distribution of the stress concentration factor.On this basis,both theoretical analysis and numerical models were utilized to investigate the effect of waveform regulator on the initial velocity of fragments.Finally,experiments were conducted to validate the fracture strain prediction model for cylindrical shell with waveform regulator.The research results show that the collision angles of the detonation waves at different axial positions are different,which leads to the stress concentration factor on the shell presenting a trend of gradually decreasing,then sharply increasing,and then rapidly decreasing along the axial direction.Additionally,the changes in the slot spacing and the thickness of outer charge will also affect the stress concentration factor,and the influence of outer charge thickness is relatively large.The smaller the ratio of charge volume to waveform regulator volume,the larger the axial sparse wave intensity and the more the fragment initial velocity decrease.From the initiation end to the non-initiation end,the failure modes of the shell sequentially change from pure shear,to mixed tensile-shear,and finally to pure tensile failure.The experimental results are in good agreement with the calculated results of the fracture strain model,and the maximum relative error is less than 10%,which indicates that the fracture strain prediction model of the cylindrical shell with waveform regulator established in this paper by considering the increase of elastic energy per unit volume caused by stress concentration on the shell is reliable.
基金Projects(52174092,42472338,51904290)supported by the National Natural Science Foundation of ChinaProject(BK20220157)supported by the Natural Science Foundation of Jiangsu Province,ChinaProject(2022YCPY0202)supported by the Fundamental Research Funds for the Central Universities,China。
文摘This study investigates the shear mechanical responses and debonding failure mechanisms of anchoring systems comprising three anisotropic media and two anisotropic interfaces under controlled boundary conditions of constant normal load(F_(s)),constant normal stiffness(K),and shear rate(v).A systematic analysis of shear mechanical properties,the evolution of maximum principal strain field,and damage characteristics along shear failure surface is presented.Results from direct shear tests demonstrate that initial shear slip diminishes with increasing F_(s)and K,attributed to the normal constraint strengthening effect,while an increase in v enhances initial shear slip due to attenuated deformation coordination and stress transfer.As F_(s)increases from 7.5 to 120 kN,K from 0 to 12 MPa/mm,and v from 0.1 to 2 mm/min,the peak shear load increases by 210.32%and 80.16%with rising F_(s)and K,respectively,while decreases by 38.57%with increasing v.Correspondingly,the shear modulus exhibits,respectively,a 135.29%and 177.06%increase with rising F_(s)and K,and a 37.03%decrease with larger v.Initial shear dilation is identified as marking the formation of shear failure surface along anisotropic interfaces,resulting from the combined shear actions at the resin bolt interface,where resin undergoes shear by bolt surface protrusions,and the resin-rock interface,where mutual shear occurs between resin and rock.With increasing F_(s)and K and decreasing v,the location of the shear failure surface shifts from the resin-rock interface to the resin-bolt interface,accompanied by a transition in failure mode from tensile rupture of resin to shear off at the resin surface.
基金Project(52074299)supported by the National Natural Science Foundation of ChinaProjects(2023JCCXSB02,BBJ2024083)supported by the Fundamental Research Funds for the Central Universities,China。
文摘This study proposed a new and more flexible S-shaped rock damage evolution model from a phenomenological perspective based on an improved Logistic function to describe the characteristics of the rock strain softening and damage process.Simultaneously,it established a constitutive model capable of describing the entire process of rock pre-peak compaction and post-peak strain softening deformation,considering the nonlinear effects of the initial compaction stage of rocks,combined with damage mechanics theory and effective medium theory.In addition,this research verified the rationality of the constructed damage constitutive model using results from uniaxial and conventional triaxial compression tests on Miluo granite,yellow sandstone,mudstone,and glutenite.The results indicate that based on the improved Logistic function,the theoretical damage model accurately describes the entire evolution of damage characteristics during rock compression deformation,from maintenance through gradual onset,accelerated development to deceleration and termination,in a simple and unified expression.At the same time,the constructed constitutive model can accurately simulate the stress-strain process of different rock types under uniaxial and conventional triaxial compression,and the theoretical model curve closely aligns with experimental data.Compared to existing constitutive models,the proposed model has significant advantages.The damage model parameters a,r and β have clear physical meanings and interact competitively,where the three parameters collectively determine the shape of the theoretical stress−strain curve.
基金Project(BZ2024023)supported by the Jiangsu Province International Collaboration Program-Key National Industrial Technology Research and Development Cooperation,China。
文摘Dynamic compression experiments were conducted on red sandstone utilizing a split Hopkinson pressure bar(SHPB)to study the loading rate and high temperatures on their mechanically deformed properties and ultimate failure modes,and to analyze the correlation between the strain rate,temperature,peak strength,and ultimate failure modes.The results show that the mass decreases with the increase of treatment temperature,and the pattern of the stress−strain curves is not impacted by the increase of impact velocity.Under a fixed temperature,the higher the impact velocity,the higher the strain rate and dynamical compression strength,indicating a strain rate hardening effect for red sandstone.With an increasing treatment temperature,the strain rate gradually increases when the impact loading remains unchanged,suggesting a rise in the deformability of red sandstone under high-temperature environment.Raise in both impact velocity and treatment temperature leads to an intensification of the damage features of the red sandstone.Similarly,higher strain rates lead to the intensification of the final damage mode of red sandstone regardless of the change in treatment temperature.Moreover,a dynamic damage constitutive model that considers the impacts of strain rate and temperature is proposed based on experimental results.
基金Project(2023YFC2907400)by the National Key Research and Development Program of China-2023 Key Special ProjectProject(51974043)supported by the National Natural Science Foundation of China+2 种基金Project(SKLCRKF1908)supported by the Open Fund of the State Key Laboratory of Coal Resources in Western China,Xi’an University of Science and Technology,ChinaProject(2023JJ10072)suupported by the Hunan Provincial Natural Science Foundation for Distinguished Young ScholarsProject(2022RC1173)supported by the Science and Technology Innovation Program of Hunan Province,China。
文摘The geostress and rock blasting in underground engineering may greatly affect the stress thresholds of surrounding rock.In this study,pre-damage impact tests were first conducted on granite under varying confining pressures(5,10 and 15 MPa)and numbers of impacts(1,5,10 and 15 impacts).Then,uniaxial compression tests were undertaken on the pre-damaged granite to study the evolution of stress thresholds using the crack volume strain method and acoustic emission method.The crack damage stresses determined by the two methods were compared.Additionally,based on the rise time amplitude and average frequency,the evolution law of microcracks inside rock specimens was revealed,and an improved acoustic emission method was proposed.The results indicated that as the number of impacts increased,the crack closure stress,crack damage stress,and peak stress of granite specimens initially rose and then declined,while they continuously increased with the confining pressure.The proportion of shear cracks first declined and then rose with greater number of impacts and decreased with higher confining pressure,and that of tensile cracks showed the opposite trend.The improved acoustic emission method was more accurate in identifying the crack damage stress.
基金Projects(52174096, 52304110) supported by the National Natural Science Foundation of China。
文摘Water is a critical factor affecting the mechanical properties of rocks, leading to their degradation. Understanding the creep mechanical behavior of deep roadway surrounding rock under the influence of underground water is of great significance. Compression and creep experiments on sandstone with varying water contents were conducted using a deep soft rock five-linked rheological experiment system. The experimental conditions, including water content (0%, 0.8%, 1.6%, 2.4% and 3.3%) and confining pressure (0, 6, 9 and 12 MPa), were determined based on pressure-free water absorption tests and in-situ stress measurements. The experimental results show that the compressive strength, creep failure stress, and dilatancy stress of sandstone decrease exponentially with increasing water content, while they increase exponentially with confining pressure. The ratio of lateral to axial instantaneous strain increases nearly linearly with the increase of stress, and the lateral creep strain characteristics of the sample are more significant than the axial ones. The duration of the attenuation creep stage of sandstone decreases with increasing water content and increases with increasing confining pressure. The lateral strain enters the steady-state creep stage before the axial strain, and the onset time of the accelerated creep stage of lateral strain under the failure stress is earlier than that of axial strain. The long-term strength of sandstone was determined based on the lateral steady-state creep rate curve, showing a negative exponential relationship with water content and a positive exponential relationship with confining pressure. A method for determining the long-term strength of rocks based on the ratio of lateral strain to axial strain (μc) is proposed, which is independent of water content. The research results provide a reliable theoretical basis for the analysis of the long-term stability of roadways under the influence of groundwater and the early prediction of creep failure.
基金National Natural Science Foundation of China-NSAF(Grant No.U2330202)the National Natural Science Foundation of China(Grant Nos.52175162 and 51805086)+1 种基金Fujian Provincial Technological Innovation Key Research and Industrialization Projects(Grant Nos.2023XQ005 and 2024XQ010)The National Independent Innovation Demonstration Platform Project of Fujian Province(2024QZFX07)。
文摘Flexible microporous metal rubber(FMP-MR)is widely used in national defense applications,yet its mechanical behavior under high-speed impact conditions remains insufficiently explored.In this study,dynamic and static experiments were conducted to systematically investigate the mechanical response of metal-wrapped microporous materials under impact loading that spanned 10~6 orders of magnitude.By combining a high-precision numerical model with a spatial contact point search algorithm,the spatio–temporal contact characteristics of the complex network structure in FMP-MR were systematically analyzed.Furthermore,the mapping mechanism from turn topology and mesoscopic friction behavior to macroscopic mechanical properties was comprehensively explored.The results showed that compared with quasi-static loading,FMP-MR under high-speed impact exhibited higher energy absorption efficiency due to high-strain-rate inertia effect.Therefore,the peak stress increased by 141%,and the maximum energy dissipation increased by 300%.Consequently,the theory of dynamic friction locking effect was innovatively proposed.The theory explains that the close synergistic effect of sliding friction and plastic dissipation promoted by the stable interturn-locked embedded structure is the essential reason for the excellent dynamic mechanical properties of FMP-MR under dynamic loading conditions.Briefly,based on the in-depth investigation of the mechanical response and energy dissipation mechanism of FMP-MR under impact loads,this study provides a solid theoretical basis for further expanding the application range of FMP-MR and optimizing its performance.
基金Projects(51871243,51574290)supported by the National Natural Science Foundation of ChinaProject(ASSIKFJJ202304001)supported by the Open Fund of the National Key Laboratory of Strength and Structural Integrity,China+3 种基金Project(HT-CSNS-DG-CD-0092/2021)supported by the Guangdong-Hong Kong-Macao Joint Laboratory for Neutron Scattering Science and Technology,ChinaProject(2022KF-08)supported by the Hubei Longzhong Laboratory,ChinaProject(22kfgk06)supported by the Shock and Vibration of Engineering Materials and Structures Key Laboratory of Sichuan Province,ChinaProject(PBSKL2022C01)supported by the State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering,China。
文摘The commercial ZK 60 magnesium alloy with extruded state experienced aging heat treatment(T 6)was dynamically loaded at strain rate of 3000 s−1 by means of the split Hopkinson pressure bar(SHPB)in this paper.Transmission electron microscopy(TEM)observations showed that the precipitatedβ′_(1) phases partially dissolved(spheroidized)with blurred interfaces within 160μs at 3000 s^(−1).The average length and diameter of the rod-shapedβ′_(1) phase particles were 48.5 and 9.8 nm after the T 6 heat treatment;while the average diameter of the sphericalβ′_(1) phases changed to 8.8 nm after loading.The deformedβ′_(1) phase generated larger lattice distortion energy than Mg matrix under high strain rate loading.Therefore,the difference of free energy(the driving force of dissolution)between theβ′_(1) phase and the matrix increased,making the instantaneous dissolution of theβ′_(1) phase thermodynamically feasible.The dissolution(spheroidization)of theβ′_(1) phase particles was kinetically promoted because the diffusion rate of the solute Zn atoms was accelerated by combined actions of adiabatic temperature rise,high density of dislocations(vacancies)and high deviatoric stresses during high strain rate loading.The increase in hardness of ZK 60-T 6 alloy could be attributed to solid solution strengthening,dislocation strengthening and second phase particle strengthening.
基金Projects(52175373,52005516)supported by the National Natural Science Foundation of ChinaProject(2018YFA0702800)supported by the National Key Basic Research Program,ChinaProject(ZZYJKT2021-03)supported by the State Key Laboratory of High Performance Complex Manufacturing,Central South University,China。
文摘The vibration pretreatment-microwave curing process is an efficient,low energy consumption,and high-quality out-of-autoclave curing process for carbon fiber resin matrix composites.This study aims to investigate the impact of vibration pretreatment temperature on the fiber weight content,microscopic morphology and mechanical properties of the composite laminates by using optical digital microscopy,universal tensile testing machine and thermo-gravimetric analyzer.Additionally,the combined mode of Bragg fiber grating sensor and temperature measurement fiber was employed to explore the effect of vibration pretreatment on the strain process during microwave curing.The study results revealed that the change in vibration pretreatment temperature had a slight impact on the fiber weight content when the vibration acceleration remained constant.The metallographic and interlaminar strength of the specimen formed at a vibration pretreatment temperature of 80℃ demonstrated a porosity of 0.414% and a 10.69% decrease in interlaminar shear strength compared to autoclave curing.Moreover,the introduction of the vibration energy field during the microwave curing process led to a significant reduction in residual strain in both the 0°and 90°fiber directions,when the laminate was cooled to 60℃.
基金Project(52227901)supported by the National Natural Science Foundation of ChinaProject(2308085ME153)supported by the Anhui Provincial Natural Science Foundation,China+2 种基金Project(2022AH030088)supported by the University Natural Science Foundation of Anhui Province,ChinaProject(EC2022011)supported by the Foundation of Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining,ChinaProject(GXXT-2022-020)supported by the University Synergy Innovation Program of Anhui Province,China。
文摘In recent years,rockburst have gained significant attention as a crucial topic in rock engineering.Strain andfault-slip rockburst are two common types that occur frequently and cause substantial damage.The objective of thisreview is to conduct a comprehensive study on the experiments and failure mechanisms of strain and fault-slip rockburst.Firstly,the article analyzes the evolving trends in experimental research on rockburst in the past decade,highlightingmechanical properties and failure modes as the primary research focuses in understanding rockburst mechanisms.Subsequently,it provides an overview of the experimental techniques and methods employed for studying both types ofrockburst.Then,with a focus on the mechanical properties and failure modes,the article conducts an extensive analysisof the failure mechanisms associated with strain and fault-slip rockburst.By analyzing experimental data and observingthe failure characteristics of samples,it discusses the variations and common features exhibited by these two types ofrockburst under various test conditions.This analysis is of paramount importance in revealing the causes of rockburstformation and development,as well as in predicting rockburst trends and assessing associated risks.Lastly,thelimitations of current rockburst experiments and future research directions are discussed,followed by a comprehensivesummary of the entire article.
基金National Natural Science Foundation of China (Grant No. U2141246)。
文摘In order to investigate the mechanical response behavior of the gas obturator of the breech mechanism,made of polychloroprene rubber(PCR), uniaxial compression experiments were carried out by using a universal testing machine and a split Hopkinson pressure bar(SHPB), obtaining stress-strain responses at different temperatures and strain rates. The results revealed that, in comparison to other polymers, the gas obturator material exhibited inconspicuous strain softening and hardening effects;meanwhile, the mechanical response was more affected by the strain rate than by temperature. Subsequently, a succinct viscoelastic damage constitutive model was developed based on the ZWT model, including ten undetermined parameters, formulated with incorporating three parallel components to capture the viscoelastic response at high strain rate and further enhanced by integrating a three-parameter Weibull function to describe the damage. Compared to the ZWT model, the modified model could effectively describe the mechanical response behavior of the gas obturator material at high strain rates. This research laid a theoretical foundation for further investigation into the influence of chamber sealing issues on artillery firing.
基金Science and Technology Commission of Shanghai Municipality(21ZR1472900,22ZR1471600)。
文摘Platinum(Pt)-based noble metal catalysts(PGMs)are the most widely used commercial catalysts,but they have the problems of high cost,low reserves,and susceptibility to small-molecule toxicity.Transition metal oxides(TMOs)are regarded as potential substitutes for PGMs because of their stability in oxidizing environments and excellent catalytic performance.In this study,comprehensive investigation into the influence of elastic strains on the adsorption energies of carbon(C),hydrogen(H)and oxygen(O)on TMOs was conducted.Based on density functional theory(DFT)calculations,these effects in both tetragonal structures(PtO_(2),PdO_(2))and hexagonal structures(ZnO,CdO),along with their respective transition metals were systematically explored.It was identified that the optimal adsorption sites on metal oxides pinpointed the top of oxygen or the top of metal atom,while face-centered cubic(FCC)and hexagonal close-packed(HCP)holes were preferred for the transition metals.Furthermore,under the influence of elastic strains,the results demonstrated significant disparities in the adsorption energies of H and O between oxides and transition metals.Despite these differences,the effect of elastic strains on the adsorption energies of C,H and O on TMOs mirrored those on transition metals:adsorption energies increased under compressive strains,indicating weaker adsorption,and decreased under tension strains,indicating stronger adsorption.This behavior was rationalized based on the d-band model for adsorption atop a metallic atom or the p-band model for adsorption atop an oxygen atom.Consequently,elastic strains present a promising avenue for tailoring the catalytic properties of TMOs.
文摘借助扫描电镜和透射电镜对尼罗罗非鱼(Oreochromis niloticus)、奥利亚罗非鱼(O.aureus)、奥尼罗非鱼(O.niloticus×O.aureus)和吉富罗非鱼(GIFT Strain in Nile Tilapia,O.niloticus)成熟精子的超微结构进行了比较研究。结果显示,4种罗非鱼精子均为有鞭毛精子,无顶体,尾部轴丝9±2型。尼罗罗非鱼精子植入窝陷入核深度最浅,线粒体个数和平均直径分别为5-9个、(0.36±0.10)μm,鞭毛侧鳍平均翼长为(0.29±0.11)μm;奥利亚罗非鱼精子核内染色质着色程度最深,植入窝陷入核深度约1/3,线粒体个数和平均直径分别为3-10个、(0.40±0.17)μm,鞭毛侧鳍平均翼长为(0.32±0.12)μm;奥尼罗非鱼精子核内染色质着色程度较浅,植入窝陷入核深度约1/3,线粒体个数和平均直径分别为5-7个、(0.32±0.09)μm,鞭毛侧鳍平均翼长(0.26±0.09)μm;吉富罗非鱼精子核内染色质着色最浅,植入窝陷入核最深,约占2/3,线粒体个数和平均直径分别为5-10个、(0.37±0.08)μm,中段存在大量中空囊泡,鞭毛侧鳍平均翼长为(0.15±0.03)μm,与其它三种罗非鱼精子鞭毛平均侧鳍翼长比较具显著性差异(P〈0.05)。