Step ladder-structured nitrocellulose(LNC)is a novel energetic binder prepared by chemically modifying nitrocellulose(NC)with the introduction of flexible polyethylene glycol(PEG-400)chain segments,with a regular stru...Step ladder-structured nitrocellulose(LNC)is a novel energetic binder prepared by chemically modifying nitrocellulose(NC)with the introduction of flexible polyethylene glycol(PEG-400)chain segments,with a regular structure and good performance of bonding.The step ladder-structured addresses critical limitations of NC-based propellants,including low-temperature brittleness and high sensitivity,while enhancing process safety.Although the structural,thermal,and other properties of LNC have been investigated in our previous research,there is a lack of systematic studies on the rheological properties during solution and gelatinization.The study of the relationship between the structural features and rheological properties of LNC is a key factor in guiding its gelatinization and improving the properties of LNC-based propellants.Steady-state rheology flow experiments revealed that LNC exhibited shear thinning in different solutions,which decreased with increasing concentration.It has desirable solu-bility and dispersion in N,N-dimethylformamide(DMF)solvent.The effect of solvents on the entan-glement or orientation of LNC molecular chains may be reduced.These results can be quantitatively demonstrated using the Herschel-Bulkley model.Dynamic viscoelastic studies identified a critical point of concentration-frequency of 2.5 rad/s.This particular frequency point is a turning point in the law of the effect of concentration on the loss factor(tanδ).For gelatinized systems,increasing the solvent content reduces the temperature sensitivity of the gelatinized materials.The viscosity-temperature correlation based on the Arrhenius equation allowed the optimization of the solvent content through the derived equilibrium relationship.These structure-rheological performance relationships establish basic guidelines for the precision gelatinization of LNC-based propellant,provide theoretical support for the replacement of conventional NC by LNC,and guide the gelatinization process to improve the performance of gun propellants.展开更多
Taking a C1x motor with a backward-facing step which can generate a typical corner vortex as a reference,a numerical methodology using large eddy simulation was established in this study.Based on this methodology,the ...Taking a C1x motor with a backward-facing step which can generate a typical corner vortex as a reference,a numerical methodology using large eddy simulation was established in this study.Based on this methodology,the position of the backward-facing step of the motor was computed and analyzed to determine a basic configuration.Two key geometrical parameters,the head cavity angle and submerged nozzle cavity height,were subsequently introduced.Their effects on the corner vortex motion and their interactions with the acoustic pressure downstream of the backward-facing step were analyzed.The phenomena of vortex acoustic coupling and characteristics of pressure oscillations were further explored.The results show that the maximum error between the simulations and experimental data on the dominant frequency of pressure oscillations is 5.23%,which indicates that the numerical methodology built in this study is highly accurate.When the step is located at less than 5/8 of the total length of the combustion chamber,vortex acoustic coupling occurs,which can increase the pressure oscillations in the motor.Both the vorticity and the scale of vortices in the downstream step increase when the head cavity angle is greater than 24°,which increases the amplitude of the pressure oscillation by maximum 63.0%.The submerged nozzle cavity mainly affects the vortices in the cavity itself rather than those in the downstream step.When the height of the cavity increases from 10 to 20 mm,the pressure oscillation amplitude under the main frequency increases by 39.1%.As this height continues to increase,the amplitude of pressure oscillations increases but the primary frequency decreases.展开更多
In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefo...In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks.展开更多
基金supported by the National Natural Science Foundation of China(No.22475100 and 22075146).
文摘Step ladder-structured nitrocellulose(LNC)is a novel energetic binder prepared by chemically modifying nitrocellulose(NC)with the introduction of flexible polyethylene glycol(PEG-400)chain segments,with a regular structure and good performance of bonding.The step ladder-structured addresses critical limitations of NC-based propellants,including low-temperature brittleness and high sensitivity,while enhancing process safety.Although the structural,thermal,and other properties of LNC have been investigated in our previous research,there is a lack of systematic studies on the rheological properties during solution and gelatinization.The study of the relationship between the structural features and rheological properties of LNC is a key factor in guiding its gelatinization and improving the properties of LNC-based propellants.Steady-state rheology flow experiments revealed that LNC exhibited shear thinning in different solutions,which decreased with increasing concentration.It has desirable solu-bility and dispersion in N,N-dimethylformamide(DMF)solvent.The effect of solvents on the entan-glement or orientation of LNC molecular chains may be reduced.These results can be quantitatively demonstrated using the Herschel-Bulkley model.Dynamic viscoelastic studies identified a critical point of concentration-frequency of 2.5 rad/s.This particular frequency point is a turning point in the law of the effect of concentration on the loss factor(tanδ).For gelatinized systems,increasing the solvent content reduces the temperature sensitivity of the gelatinized materials.The viscosity-temperature correlation based on the Arrhenius equation allowed the optimization of the solvent content through the derived equilibrium relationship.These structure-rheological performance relationships establish basic guidelines for the precision gelatinization of LNC-based propellant,provide theoretical support for the replacement of conventional NC by LNC,and guide the gelatinization process to improve the performance of gun propellants.
基金Sponsored by the Natural Science Foundation of Shaanxi Province (Grant No. S2025-JC-YB-0532)the Practice and Innovation Funds for Graduate Students of Northwestern Polytechnical University (PF2024044)
文摘Taking a C1x motor with a backward-facing step which can generate a typical corner vortex as a reference,a numerical methodology using large eddy simulation was established in this study.Based on this methodology,the position of the backward-facing step of the motor was computed and analyzed to determine a basic configuration.Two key geometrical parameters,the head cavity angle and submerged nozzle cavity height,were subsequently introduced.Their effects on the corner vortex motion and their interactions with the acoustic pressure downstream of the backward-facing step were analyzed.The phenomena of vortex acoustic coupling and characteristics of pressure oscillations were further explored.The results show that the maximum error between the simulations and experimental data on the dominant frequency of pressure oscillations is 5.23%,which indicates that the numerical methodology built in this study is highly accurate.When the step is located at less than 5/8 of the total length of the combustion chamber,vortex acoustic coupling occurs,which can increase the pressure oscillations in the motor.Both the vorticity and the scale of vortices in the downstream step increase when the head cavity angle is greater than 24°,which increases the amplitude of the pressure oscillation by maximum 63.0%.The submerged nozzle cavity mainly affects the vortices in the cavity itself rather than those in the downstream step.When the height of the cavity increases from 10 to 20 mm,the pressure oscillation amplitude under the main frequency increases by 39.1%.As this height continues to increase,the amplitude of pressure oscillations increases but the primary frequency decreases.
基金Projects(52208369,52309138,52108320)supported by the National Natural Science Foundation of ChinaProjects(2023NSFSC0284,2025ZNSFSC0409)supported by the Sichuan Science and Technology Program,ChinaProject(U22468214)supported by the Joint Fund Project for Railway Basic Research by the National Natural Science Foundation of China and China State Railway Group Co.,Ltd.
文摘In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks.
