Solid-state electrolyte Li_(10)GeP_(2)S_(12)(LGPS)has a high lithium ion conductivity of 12 mS cm^(-1)at room temperature,but its inferior chemical stability against lithium metal anode impedes its practical applicati...Solid-state electrolyte Li_(10)GeP_(2)S_(12)(LGPS)has a high lithium ion conductivity of 12 mS cm^(-1)at room temperature,but its inferior chemical stability against lithium metal anode impedes its practical application.Among all solutions,Ge atom substitution of the solid-state electrolyte LGPS stands out as the most promising solution to this interface problem.A systematic screening framework for Ge atom substitution including ionic conductivity,thermodynamic stability,electronic and mechanical properties is utilized to solve it.For fast screening,an enhanced model Dop Net FC using chemical formulas for the dataset is adopted to predict ionic conductivity.Finally,Li_(10)SrP_(2)S_(12)(LSrPS)is screened out,which has high lithium ion conductivity(12.58 mS cm^(-1)).In addition,an enhanced migration of lithium ion across the LSr PS/Li interface is found.Meanwhile,compared to the LGPS/Li interface,LSrPS/Li interface exhibits a larger Schottky barrier(0.134 eV),smaller electron transfer region(3.103?),and enhanced ability to block additional electrons,all of which contribute to the stabilized interface.The applied theoretical atom substitution screening framework with the aid of machine learning can be extended to rapid determination of modified specific material schemes.展开更多
Fiber is highly escapable in conventional slickwater,making it difficult to form fiber-proppant agglomerate with proppant and exhibit limited effectiveness.To solve these problems,a novel structure stabilizer(SS)is de...Fiber is highly escapable in conventional slickwater,making it difficult to form fiber-proppant agglomerate with proppant and exhibit limited effectiveness.To solve these problems,a novel structure stabilizer(SS)is developed.Through microscopic structural observations and performance evaluations in indoor experiments,the mechanism of proppant placement under the action of the SS and the effects of the SS on proppant placement dimensions and fracture conductivity were elucidated.The SS facilitates the formation of robust fiber-proppant agglomerates by polymer,fiber,and quartz sand.Compared to bare proppants,these agglomerates exhibit reduced density,increased volume,and enlarged contact area with the fluid during settlement,leading to heightened buoyancy and drag forces,ultimately resulting in slower settling velocities and enhanced transportability into deeper regions of the fracture.Co-injecting the fiber and the SS alongside the proppant into the reservoir effectively reduces the fiber escape rate,increases the proppant volume in the slickwater,and boosts the proppant placement height,conveyance distance and fracture conductivity,while also decreasing the proppant backflow.Experimental results indicate an optimal SS mass fraction of 0.3%.The application of this SS in over 80 wells targeting tight gas,shale oil,and shale gas reservoirs has substantiated its strong adaptability and general suitability for meeting the production enhancement,cost reduction,and sand control requirements of such wells.展开更多
The capture and characterization of oligomers are extremely important in the studies of amyloid aggregation of proteins and peptides.Oligomers are critical intermediates that can impact the structures of amyloid fibri...The capture and characterization of oligomers are extremely important in the studies of amyloid aggregation of proteins and peptides.Oligomers are critical intermediates that can impact the structures of amyloid fibrils.Moreover,it is widely accepted that oligomers are the most toxic species along the aggregation pathway[1e4].The studies of oligomers are believed to shed light on the molecular mechanism of amyloid fibrillation and probably the medical clues for related diseases.In vitro investigations of amyloid oligomers are challenging due to their transient and polymorphic nature[5].This is particularly evident in the case of human type-2 diabetes-associated islet amyloid polypeptide(hIAPP),which tends to rapidly form polymorphic fibrils within minutes[6].Notably,hIAPP demonstrates a higher propensity for rapid aggregation compared to other amyloid proteins such as a-synuclein[7].展开更多
Single-crystal Nickel-rich layered oxides has been recognized as one of the promising cathodes for nextgeneration lithium batteries on account of their high capacity,while its practical application was hindered by str...Single-crystal Nickel-rich layered oxides has been recognized as one of the promising cathodes for nextgeneration lithium batteries on account of their high capacity,while its practical application was hindered by structural instability and slow Li^(+) transfer kinetics.Herein,a surface-to-bulk engineered single-crystal LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2)(Ni90) cathode,which features W-doped bulk and Li_(2)WO_(4) surface layer,was successfully achieved by a one-step high-valence W^(6+) modification.The as-obtained W-modified Ni90 delivers excellent cycling stability(89.8% capacity retention after 300 cycles at 0.5 C)and rate capability.The enhanced electrochemical performance was ascribed to the doped-W induced stabilized lattice oxygen,reduced Li^(+)/Ni^(2+) mixing and inhibited H2-H3 phase transition in the bulk,and Li_(2)WO_(4) layer generated stabilized cathode/electrolyte interface.In addition,the thinner LiF-rich cathode electrolyte interphase(CEI) on surface and smaller grain size for W-modified Ni90 benefit to its Li^(+) diffusion dynamics.The effect of high-valence W^(6+)on single-crystal Ni-rich cathode was firstly revealed in detail,which deepens the understanding of electrochemical behavior of Ni-rich cathode with high-valence cations modification,and provides clues for design of high-performance layered cathodes.展开更多
Ultra-high nickel cobalt-free lithium layered oxides are promising cathode material for lithium-ion batteries(LIBs)because of their relatively high capacity and low cost.Nevertheless,the high nickel content would indu...Ultra-high nickel cobalt-free lithium layered oxides are promising cathode material for lithium-ion batteries(LIBs)because of their relatively high capacity and low cost.Nevertheless,the high nickel content would induce bulk structure degradation and interfacial environment deterioration,and the absence of Co element reduces the lithium diffusion kinetics,severely limiting the performance liberation of this kind of cathodes.Herein,a multifunctional Ti/Zr dual cation co-doping strategy has been employed to improve the lithium storage performance of LiNi_(0.9)Mn_(0.1)O_(2)(NM91)cathode.On the one hand,the Ti/Zr co-doping weakens the Li^(+)/Ni^(2+)mixing through magnetic interactions due to the inexistence of unpaired electrons for Ti^(4+)and Zr^(4+),increasing the lithium diffusion rate and suppressing the harmful coexistence of H1 and H2 phases.On the other hand,they enhance the lattice oxygen stability because of the strong Ti-O and Zr-O bonds,inhibiting the undesired H3 phase transition and lattice oxygen loss,improving the bulk structure and cathode-electrolyte interface stability.As a result,the Ti/Zr co-doped NM91(NMTZ)exhibits a 91.2%capacity retention rate after 100 cycles,while that of NM91 is only82.9%.Also,the NMTZ displays better rate performance than NM91 with output capacities of 115 and93 mA h g^(-1)at a high current density of 5 C,respectively.Moreover,the designed NMTZ could enable the full battery to deliver an energy density up to 263 W h kg^(-1),making the ultra-high nickel cobaltfree lithium layered oxide cathode closer to practical applications.展开更多
Aim To study the effect of aerodynamically stabilized seeker dynamics on guided bomb system analysis. Methods A thorough analysis of aerodynamically stabilized seeker dynamics was made to show that because of the mu...Aim To study the effect of aerodynamically stabilized seeker dynamics on guided bomb system analysis. Methods A thorough analysis of aerodynamically stabilized seeker dynamics was made to show that because of the much smaller time constant, its dynamic model can be greatly simplified. Results and Conclusion In guided bomb guidance/control digital simulation, with the use of the simplified seeker model, simulation time can be reduced without the loss of simulation accuracy.展开更多
The high-temperature β-phase NaMnO2 is a promising material for Na-ion batteries（NIBs） due to its high capacity and abundant resources. However, the synthesis of phase-pure -NaMnO2 is burdensome and costineffective...The high-temperature β-phase NaMnO2 is a promising material for Na-ion batteries（NIBs） due to its high capacity and abundant resources. However, the synthesis of phase-pure -NaMnO2 is burdensome and costineffective because it needs to be sintered under oxygen atmosphere at high temperature and followed by a quenching procedure. Here we first report that the pure β phase can be stabilized by Cu-doping and easily synthesized by replacing a proportion of Mn with Cu via a simplified process including sintering in air and cooling to room temperature naturally. Based on the first-principle calculations, the band gap decreases from 0.7 eV to 0.3 eV, which indicates that the electronic conductivity can be improved by Cu-doping. The designed -NaCu（0.1）Mn（0.9）O2 is applied as cathode in NIBs, exhibiting an energy density of 419 Wh/kg and better performance in terms of rate capability and cycling stability than those in the undoped case.展开更多
Cu-based materials are ideal catalysts for CO_(2) electrocatalytic reduction reaction(CO_(2)RR) into multicarbon products.However,such reactions require stringent conditions on local environments of catalyst surfaces,...Cu-based materials are ideal catalysts for CO_(2) electrocatalytic reduction reaction(CO_(2)RR) into multicarbon products.However,such reactions require stringent conditions on local environments of catalyst surfaces,which currently are the global pressing challenges.Here,a stabilized activation of Cu^(0)/Cu^(+)-onAg interface by N_(2) cold plasma treatment was developed for improving Faradaic efficiency(FE) of CO_(2)RR into C2 products.The resultant Ag@Cu-CuN_x exhibits a C2 FE of 72% with a partial current density of-14.9 mA cm^(-2) at-1.0 V vs.RHE(reversible hydrogen electrode).Combining density functional theory(DFT) and experimental investigations,we unveiled that Cu^(0)/Cu^(+) species can be co ntrollably tu ned by the incorporation of nitrogen to form CuN_x on Ag surface,i.e.,Ag@Cu-CuN_x.This strategy enhances ^(*)CO intermediates generation and accelerates C-C coupling both thermodynamically and kinetically.The intermediates O^(*)C^(*)CO,^(*)COOH,and ^(*)CO were detected by in-situ attenuated total internal reflection surface enhanced infrared absorption spectroscopy(ATR-SEIRAS).The uncovered CO_(2)RR-into-C2 products were carried out along CO_(2)→^(*)COOH→^(*)CO→O^(*)C^(*)CO→^(*)C_(2)H_(3)O→^(*)C_(2)H_(4)O→ C_(2)H_(5)OH(or ^(*)C_(2)H_(3)O→^(*)O+C_(2)H_(4)) paths over Ag@Cu-CuN_x electrocatalyst.This work provides a new approach to design Cu-based electrocatalysts with high-efficiency,mild condition,and stable CO_(2)RR to C2 products.展开更多
A low-cost eco-friendly aqueous foam,especially the robust foam with great tolerance to high salinity and high temperature,is in great demand in the oil industry,e.g.,oil and gas well or geothermal well drilling.Herei...A low-cost eco-friendly aqueous foam,especially the robust foam with great tolerance to high salinity and high temperature,is in great demand in the oil industry,e.g.,oil and gas well or geothermal well drilling.Herein,an ultra-stable aqueous foam was developed using the biodegradable cellulose microfiber(CMF)as a foam stabilizer.The foam stabilized by CMF shows excellent tolerance to the high concentration of NaCl(6.0 wt%)and CaCl_(2)(0.25 wt%)and the related drainage half-life times(T_(0.5))reach 1750 and 2340 s respectively.By contrast,the foams without CMF are completely drained(T_(0.5)=0 s)when NaCl concentration is greater than 6.0 wt%or CaCl_(2) concentration is greater than 0.20 wt%.Notably,T0.5 of the foams stabilized by CMF at these saline concentrations still can maintain above 1000 s even after aging at 120℃ for 16 h,exhibiting an outstanding foam-stabilizing performance at high temperature.Experimental results suggest that the salt and high-temperature tolerance of CMF in foam stabilization is attributed to the electrically uncharged surfaces,the formation of a gel-like structure and the excellent thermal stability.This work not only provides a promising candidate of aqueous foam stabilizer to deal with high temperature and high salinity but also presents a natural-based solution for an environmentally friendly drilling industry in the future.展开更多
Aimed at requirements, a kind of radar stabilized platform with external rotor and orthogonal shafts is designed. Its dynamic characters are analyzed by using finite element theory and ANSYS software. Also, a traditio...Aimed at requirements, a kind of radar stabilized platform with external rotor and orthogonal shafts is designed. Its dynamic characters are analyzed by using finite element theory and ANSYS software. Also, a traditional stabilized platform with inner rotor is designed for comparison. It is shown that the new platform reduces two transmission links and 20% of precise components, its weight decreases by 20%, its natural frequency and rigidity are enlarged, the operating accuracy and stationary are increased. The new stabilized platform is more superiority and practicability. Its design method and analysis results have already been used in development mission. It provides helpful reference for similar structure designs.展开更多
Compact accelerator-based neutron source facilities are garnering attention and play an important and expanding role in material and engineering sciences,as well as in neutron science education and training.Neutrons a...Compact accelerator-based neutron source facilities are garnering attention and play an important and expanding role in material and engineering sciences,as well as in neutron science education and training.Neutrons are produced by bombarding a low-energy proton beam onto a beryllium or lithium target.In such an acceleratorbased neutron source,a radio frequency quadrupole(RFQ)is usually utilized to accelerate a high-intensity proton beam to a few MeV.This study mainly covers the highfrequency structure design optimizations of a 4-vane RFQ with pi-mode stabilizer loops(PISLs)and its RF stability analysis.A 176 MHz RFQ accelerator is designed to operate at a 10%duty factor and could accelerate an80 mA proton beam from 65 keV to 2.5 MeV within a length of 5.3 m.The adoption of PISLs ensures high RF stability,eases the operation of the accelerator,and implies less stringent alignment and machining tolerances.展开更多
In order to overcome serious instability prob- lems in hydratable shale formations, a novel electropositive wellbore stabilizer （EPWS） was prepared by a new approach. It has good colloidal stability, particle size d...In order to overcome serious instability prob- lems in hydratable shale formations, a novel electropositive wellbore stabilizer （EPWS） was prepared by a new approach. It has good colloidal stability, particle size dis- tribution, compatibility, sealing property, and flexible adaptability. A variety of methods including measurements of particle size, Zeta potential, colloidal stability, contact angle, shale stability index, shale dispersion, shale swelling, and plugging experiments were adopted to characterize the EPWS and evaluate its anti-sloughing capacity and flexible adaptability. Results show that the EPWS has advantages over the conventional wellbore stabilizer （ZX-3） in particle size distribution, colloidal stability, inhibition, compatibil- ity, and flexible adaptability. The EPWS with an average particle size of 507 nm and an average Zeta potential of 54 mV could be stable for 147 days and be compatible with salt tolerant or positive charged additives, and it also exhibited preferable anti-sloughing performance to hydrat- able shales at 77, 100, and 120 ~C, and better compatibility with sodium bentonite than ZX-3 and KC1. The EPWS can plug micro-fractures and pores by forming a tight external mud cake and an internal sealing belt to retard pressure transmission and prevent filtrate invasion, enhancing hydrophobicity of shale surfaces by adsorption to inhibithydration. The EPWS with flexible adaptability to tem- perature for inhibition and sealing capacity is available for long open-hole sections during drilling.展开更多
An optimized workspace calculation method is proposed for parallel stabilized platform testing systems.This method refines the searched space progressively in order to approach the boundary of the workspace from both ...An optimized workspace calculation method is proposed for parallel stabilized platform testing systems.This method refines the searched space progressively in order to approach the boundary of the workspace from both the inside and the outside of it.The orientation density is defined and used as an evaluation index to calculate the orientation workspace.The algorithm of the orientation density is embedded into the computer program of the workspace calculation.Then the workspaces of the testing system are solved.In the solution,the orientation density is regarded as a discrete function of the reachable workspace.As a result,the reachable workspace and the orientation workspace are represented in the same multidimensional graphs.Finally the useful workspace of the testing system is determined based on these results.This case study indicates that the calculation efficiency is enhanced by adopting the optimized method and the practicability of workspace study is improved by proposing the orientation density.展开更多
Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics a...Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics and isotherms pertaining to Longmaxi shale,an experimental setup was designed based on the volumetric method.The objective was to conduct experiments on methane adsorption and desorption kinetics and isotherms before and after clay stabilizer treatments.The experimental data were a good fit for both the intraparticle diffusion model and the Freundlich isotherm model.We analyzed the effect of the clay stabilizer on desorption kinetics and isotherms.Results show that clay stabilizer can obviously improve the diffusion rate constant and reduce the methane adsorption amount.Moreover,we analyzed the desorption efficiency before and after treatment as well as the adsorbed methane content.The results show that a higher desorption efficiency after treatment can be observed when the pressure is higher than 6.84 MPa.Meanwhile,the adsorbed methane content before and after treatment all increase when the pressure decreases,and clay stabilizer can obviously promote the adsorbed methane to free gas when the pressure is lower than 19 MPa.This can also be applied to the optimization formulation of slickwater and the design of gas well production.展开更多
The production of the poloidally sheared flow during electron cyclotron resonant heating(ECRH)in the collisional tokamak plasmas,which refers to the edge region,is studied.Based on the linearized kinetic drift equatio...The production of the poloidally sheared flow during electron cyclotron resonant heating(ECRH)in the collisional tokamak plasmas,which refers to the edge region,is studied.Based on the linearized kinetic drift equation and the fluid equations including the density perturbation term driven by rf waves,the criterion of the destabilization of the poloidal plasma rotation is analytically derived.It is shown that the edge poloidal plasma rotation can be destabilized during ECRH in the present rf power level.展开更多
Backlash nonlinearity inevitably exists in the actuator of tank horizontal stabilizer and has adverse effect on the system control performance,however,how to effectively eliminate its effect remains a pending issue.To...Backlash nonlinearity inevitably exists in the actuator of tank horizontal stabilizer and has adverse effect on the system control performance,however,how to effectively eliminate its effect remains a pending issue.To solve this problem,a robust adaptive precision motion controller is presented in this paper to address uncertainties and unknown actuator backlash of tank horizontal actuator.The controller handles the modeling uncertainties including parameter uncertainties and unmodeled disturbances by integrating adaptive feedforward compensation and continuous nonlinear robust law.Based on the backstepping method,a smooth backlash inverse model is constructed by combining the adaptive idea.Meanwhile,the unknown backlash parameters of the system can be approximated through the parameter adaptation,and the impact of the actuator backlash nonlinearity is effectively compensated via the inverse operation,which can availably improve the tracking performance.Moreover,the adaptive law can update the disturbance ranges of tank horizontal stabilizer online in real time,which enhances the feasibility in practical engineering applications.Furthermore,the stability analysis based on Lyapunov function shows that with the existence of unmodeled disturbances and unknown actuator backlash,the designed controller guarantees excellent asymptotic output tracking performance.Extensive comparative results verify the effectiveness of the proposed control strategy.展开更多
In this paper,we develop a novel hybrid automatic-repeat-request(ARQ)protocol for the quantum communication system using quantum stabilizer codes.The quantum information is encoded by stabilizer codes to against the c...In this paper,we develop a novel hybrid automatic-repeat-request(ARQ)protocol for the quantum communication system using quantum stabilizer codes.The quantum information is encoded by stabilizer codes to against the channel noise.The twophoton entangled state is prepared for codeword secure transmission.Hybrid ARQ protocol rules the recognition and retransmission of error codewords.In this protocol,the property of quantum entangled state ensures the security of information,the theory of hybrid ARQ system improves the reliability of transmission,the theory of quantum stabilizer codes corrects the flipping errors of codewords.Finally,we verify the security and throughput efficiency of this protocol.展开更多
Motivated by the need of quantum measurement of Majorana qubits and surface-code stabilizers, we analyze the performance of a double-dot interferometer under the influence of environment noise. The double-dot setup de...Motivated by the need of quantum measurement of Majorana qubits and surface-code stabilizers, we analyze the performance of a double-dot interferometer under the influence of environment noise. The double-dot setup design allows accounting for the full multiple tunneling process between the dots through the Majorana island, within a master equation approach. In the co-tunneling regime, which results in a Majorana-mediated effective coupling between the dots, the master equation approach allows us to obtain analytic solutions for the measurement currents. The measurement quality,characterized by figures of merit such as the visibility of measurement signals, is carried out in regard to the unusual decoherence effect rather than ‘which-path’ dephasing. The results obtained in this work are expected to be useful for future experiments of Majorana qubit and stabilizer measurements.展开更多
In this study, we employ mixed finite element （MFE） method, two local Gauss integrals, and parameter-free to establish a stabilized MFE formulation for the non-stationary incompressible Boussinesq equations. We also...In this study, we employ mixed finite element （MFE） method, two local Gauss integrals, and parameter-free to establish a stabilized MFE formulation for the non-stationary incompressible Boussinesq equations. We also provide the theoretical analysis of the existence, uniqueness, stability, and convergence of the stabilized MFE solutions for the stabilized MFE formulation.展开更多
基金support from the National Natural Science Foundation of China (No.51806072)。
文摘Solid-state electrolyte Li_(10)GeP_(2)S_(12)(LGPS)has a high lithium ion conductivity of 12 mS cm^(-1)at room temperature,but its inferior chemical stability against lithium metal anode impedes its practical application.Among all solutions,Ge atom substitution of the solid-state electrolyte LGPS stands out as the most promising solution to this interface problem.A systematic screening framework for Ge atom substitution including ionic conductivity,thermodynamic stability,electronic and mechanical properties is utilized to solve it.For fast screening,an enhanced model Dop Net FC using chemical formulas for the dataset is adopted to predict ionic conductivity.Finally,Li_(10)SrP_(2)S_(12)(LSrPS)is screened out,which has high lithium ion conductivity(12.58 mS cm^(-1)).In addition,an enhanced migration of lithium ion across the LSr PS/Li interface is found.Meanwhile,compared to the LGPS/Li interface,LSrPS/Li interface exhibits a larger Schottky barrier(0.134 eV),smaller electron transfer region(3.103?),and enhanced ability to block additional electrons,all of which contribute to the stabilized interface.The applied theoretical atom substitution screening framework with the aid of machine learning can be extended to rapid determination of modified specific material schemes.
文摘Fiber is highly escapable in conventional slickwater,making it difficult to form fiber-proppant agglomerate with proppant and exhibit limited effectiveness.To solve these problems,a novel structure stabilizer(SS)is developed.Through microscopic structural observations and performance evaluations in indoor experiments,the mechanism of proppant placement under the action of the SS and the effects of the SS on proppant placement dimensions and fracture conductivity were elucidated.The SS facilitates the formation of robust fiber-proppant agglomerates by polymer,fiber,and quartz sand.Compared to bare proppants,these agglomerates exhibit reduced density,increased volume,and enlarged contact area with the fluid during settlement,leading to heightened buoyancy and drag forces,ultimately resulting in slower settling velocities and enhanced transportability into deeper regions of the fracture.Co-injecting the fiber and the SS alongside the proppant into the reservoir effectively reduces the fiber escape rate,increases the proppant volume in the slickwater,and boosts the proppant placement height,conveyance distance and fracture conductivity,while also decreasing the proppant backflow.Experimental results indicate an optimal SS mass fraction of 0.3%.The application of this SS in over 80 wells targeting tight gas,shale oil,and shale gas reservoirs has substantiated its strong adaptability and general suitability for meeting the production enhancement,cost reduction,and sand control requirements of such wells.
文摘The capture and characterization of oligomers are extremely important in the studies of amyloid aggregation of proteins and peptides.Oligomers are critical intermediates that can impact the structures of amyloid fibrils.Moreover,it is widely accepted that oligomers are the most toxic species along the aggregation pathway[1e4].The studies of oligomers are believed to shed light on the molecular mechanism of amyloid fibrillation and probably the medical clues for related diseases.In vitro investigations of amyloid oligomers are challenging due to their transient and polymorphic nature[5].This is particularly evident in the case of human type-2 diabetes-associated islet amyloid polypeptide(hIAPP),which tends to rapidly form polymorphic fibrils within minutes[6].Notably,hIAPP demonstrates a higher propensity for rapid aggregation compared to other amyloid proteins such as a-synuclein[7].
基金National Key Research and Development Program of China (2022YFB2502103)National Natural Science Foundation of China (22279107, 22309153)Fundamental Research Funds for the Central Universities (20720230039)。
文摘Single-crystal Nickel-rich layered oxides has been recognized as one of the promising cathodes for nextgeneration lithium batteries on account of their high capacity,while its practical application was hindered by structural instability and slow Li^(+) transfer kinetics.Herein,a surface-to-bulk engineered single-crystal LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2)(Ni90) cathode,which features W-doped bulk and Li_(2)WO_(4) surface layer,was successfully achieved by a one-step high-valence W^(6+) modification.The as-obtained W-modified Ni90 delivers excellent cycling stability(89.8% capacity retention after 300 cycles at 0.5 C)and rate capability.The enhanced electrochemical performance was ascribed to the doped-W induced stabilized lattice oxygen,reduced Li^(+)/Ni^(2+) mixing and inhibited H2-H3 phase transition in the bulk,and Li_(2)WO_(4) layer generated stabilized cathode/electrolyte interface.In addition,the thinner LiF-rich cathode electrolyte interphase(CEI) on surface and smaller grain size for W-modified Ni90 benefit to its Li^(+) diffusion dynamics.The effect of high-valence W^(6+)on single-crystal Ni-rich cathode was firstly revealed in detail,which deepens the understanding of electrochemical behavior of Ni-rich cathode with high-valence cations modification,and provides clues for design of high-performance layered cathodes.
基金funded by the Key R&D Program of Jilin Province(20220201132GX)the Key R&D Program of Hubei Province(2022BAA084)the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization(RERU2023008)。
文摘Ultra-high nickel cobalt-free lithium layered oxides are promising cathode material for lithium-ion batteries(LIBs)because of their relatively high capacity and low cost.Nevertheless,the high nickel content would induce bulk structure degradation and interfacial environment deterioration,and the absence of Co element reduces the lithium diffusion kinetics,severely limiting the performance liberation of this kind of cathodes.Herein,a multifunctional Ti/Zr dual cation co-doping strategy has been employed to improve the lithium storage performance of LiNi_(0.9)Mn_(0.1)O_(2)(NM91)cathode.On the one hand,the Ti/Zr co-doping weakens the Li^(+)/Ni^(2+)mixing through magnetic interactions due to the inexistence of unpaired electrons for Ti^(4+)and Zr^(4+),increasing the lithium diffusion rate and suppressing the harmful coexistence of H1 and H2 phases.On the other hand,they enhance the lattice oxygen stability because of the strong Ti-O and Zr-O bonds,inhibiting the undesired H3 phase transition and lattice oxygen loss,improving the bulk structure and cathode-electrolyte interface stability.As a result,the Ti/Zr co-doped NM91(NMTZ)exhibits a 91.2%capacity retention rate after 100 cycles,while that of NM91 is only82.9%.Also,the NMTZ displays better rate performance than NM91 with output capacities of 115 and93 mA h g^(-1)at a high current density of 5 C,respectively.Moreover,the designed NMTZ could enable the full battery to deliver an energy density up to 263 W h kg^(-1),making the ultra-high nickel cobaltfree lithium layered oxide cathode closer to practical applications.
文摘Aim To study the effect of aerodynamically stabilized seeker dynamics on guided bomb system analysis. Methods A thorough analysis of aerodynamically stabilized seeker dynamics was made to show that because of the much smaller time constant, its dynamic model can be greatly simplified. Results and Conclusion In guided bomb guidance/control digital simulation, with the use of the simplified seeker model, simulation time can be reduced without the loss of simulation accuracy.
基金Supported by the National Key Technologies R&D Program of China under Grant No 2016YFB0901500the National Nature Science Foundation of China under Grant Nos 51725206 and 51421002
文摘The high-temperature β-phase NaMnO2 is a promising material for Na-ion batteries（NIBs） due to its high capacity and abundant resources. However, the synthesis of phase-pure -NaMnO2 is burdensome and costineffective because it needs to be sintered under oxygen atmosphere at high temperature and followed by a quenching procedure. Here we first report that the pure β phase can be stabilized by Cu-doping and easily synthesized by replacing a proportion of Mn with Cu via a simplified process including sintering in air and cooling to room temperature naturally. Based on the first-principle calculations, the band gap decreases from 0.7 eV to 0.3 eV, which indicates that the electronic conductivity can be improved by Cu-doping. The designed -NaCu（0.1）Mn（0.9）O2 is applied as cathode in NIBs, exhibiting an energy density of 419 Wh/kg and better performance in terms of rate capability and cycling stability than those in the undoped case.
基金the National Natural Science Foundation of China (21902017)the Foundation of technological innovation and application development of Chongqing (cstc2021jscxmsxm X0308, CSTB2022BSXM-JCX0132)+1 种基金the Youth project of science and technology research program of Chongqing Education Commission of China (KJQN20211107)the Scientific Research Foundation of Chongqing University of Technology (2020ZDZ022, 2021PYZ13)。
文摘Cu-based materials are ideal catalysts for CO_(2) electrocatalytic reduction reaction(CO_(2)RR) into multicarbon products.However,such reactions require stringent conditions on local environments of catalyst surfaces,which currently are the global pressing challenges.Here,a stabilized activation of Cu^(0)/Cu^(+)-onAg interface by N_(2) cold plasma treatment was developed for improving Faradaic efficiency(FE) of CO_(2)RR into C2 products.The resultant Ag@Cu-CuN_x exhibits a C2 FE of 72% with a partial current density of-14.9 mA cm^(-2) at-1.0 V vs.RHE(reversible hydrogen electrode).Combining density functional theory(DFT) and experimental investigations,we unveiled that Cu^(0)/Cu^(+) species can be co ntrollably tu ned by the incorporation of nitrogen to form CuN_x on Ag surface,i.e.,Ag@Cu-CuN_x.This strategy enhances ^(*)CO intermediates generation and accelerates C-C coupling both thermodynamically and kinetically.The intermediates O^(*)C^(*)CO,^(*)COOH,and ^(*)CO were detected by in-situ attenuated total internal reflection surface enhanced infrared absorption spectroscopy(ATR-SEIRAS).The uncovered CO_(2)RR-into-C2 products were carried out along CO_(2)→^(*)COOH→^(*)CO→O^(*)C^(*)CO→^(*)C_(2)H_(3)O→^(*)C_(2)H_(4)O→ C_(2)H_(5)OH(or ^(*)C_(2)H_(3)O→^(*)O+C_(2)H_(4)) paths over Ag@Cu-CuN_x electrocatalyst.This work provides a new approach to design Cu-based electrocatalysts with high-efficiency,mild condition,and stable CO_(2)RR to C2 products.
基金This work was supported by the National Natural Science Foundation of China(Grant No.51991361 and Grant No.51991362)the foundation of China University of Petroleum(Beijing)(Grant No.2462021YXZZ002).
文摘A low-cost eco-friendly aqueous foam,especially the robust foam with great tolerance to high salinity and high temperature,is in great demand in the oil industry,e.g.,oil and gas well or geothermal well drilling.Herein,an ultra-stable aqueous foam was developed using the biodegradable cellulose microfiber(CMF)as a foam stabilizer.The foam stabilized by CMF shows excellent tolerance to the high concentration of NaCl(6.0 wt%)and CaCl_(2)(0.25 wt%)and the related drainage half-life times(T_(0.5))reach 1750 and 2340 s respectively.By contrast,the foams without CMF are completely drained(T_(0.5)=0 s)when NaCl concentration is greater than 6.0 wt%or CaCl_(2) concentration is greater than 0.20 wt%.Notably,T0.5 of the foams stabilized by CMF at these saline concentrations still can maintain above 1000 s even after aging at 120℃ for 16 h,exhibiting an outstanding foam-stabilizing performance at high temperature.Experimental results suggest that the salt and high-temperature tolerance of CMF in foam stabilization is attributed to the electrically uncharged surfaces,the formation of a gel-like structure and the excellent thermal stability.This work not only provides a promising candidate of aqueous foam stabilizer to deal with high temperature and high salinity but also presents a natural-based solution for an environmentally friendly drilling industry in the future.
基金Sponsored by Optic-mechanical Integration Research and Design Technology Innovation Platform(20082108)
文摘Aimed at requirements, a kind of radar stabilized platform with external rotor and orthogonal shafts is designed. Its dynamic characters are analyzed by using finite element theory and ANSYS software. Also, a traditional stabilized platform with inner rotor is designed for comparison. It is shown that the new platform reduces two transmission links and 20% of precise components, its weight decreases by 20%, its natural frequency and rigidity are enlarged, the operating accuracy and stationary are increased. The new stabilized platform is more superiority and practicability. Its design method and analysis results have already been used in development mission. It provides helpful reference for similar structure designs.
文摘Compact accelerator-based neutron source facilities are garnering attention and play an important and expanding role in material and engineering sciences,as well as in neutron science education and training.Neutrons are produced by bombarding a low-energy proton beam onto a beryllium or lithium target.In such an acceleratorbased neutron source,a radio frequency quadrupole(RFQ)is usually utilized to accelerate a high-intensity proton beam to a few MeV.This study mainly covers the highfrequency structure design optimizations of a 4-vane RFQ with pi-mode stabilizer loops(PISLs)and its RF stability analysis.A 176 MHz RFQ accelerator is designed to operate at a 10%duty factor and could accelerate an80 mA proton beam from 65 keV to 2.5 MeV within a length of 5.3 m.The adoption of PISLs ensures high RF stability,eases the operation of the accelerator,and implies less stringent alignment and machining tolerances.
基金financially supported by the National Science Foundation of China (No.51374233)Shandong Province Science Foundation (No.ZR2013EEM032)+1 种基金the Fundamental Research Funds for the Central Universities (No.13CX02044A)the Project of China Scholarship Council (201306455021)
文摘In order to overcome serious instability prob- lems in hydratable shale formations, a novel electropositive wellbore stabilizer （EPWS） was prepared by a new approach. It has good colloidal stability, particle size dis- tribution, compatibility, sealing property, and flexible adaptability. A variety of methods including measurements of particle size, Zeta potential, colloidal stability, contact angle, shale stability index, shale dispersion, shale swelling, and plugging experiments were adopted to characterize the EPWS and evaluate its anti-sloughing capacity and flexible adaptability. Results show that the EPWS has advantages over the conventional wellbore stabilizer （ZX-3） in particle size distribution, colloidal stability, inhibition, compatibil- ity, and flexible adaptability. The EPWS with an average particle size of 507 nm and an average Zeta potential of 54 mV could be stable for 147 days and be compatible with salt tolerant or positive charged additives, and it also exhibited preferable anti-sloughing performance to hydrat- able shales at 77, 100, and 120 ~C, and better compatibility with sodium bentonite than ZX-3 and KC1. The EPWS can plug micro-fractures and pores by forming a tight external mud cake and an internal sealing belt to retard pressure transmission and prevent filtrate invasion, enhancing hydrophobicity of shale surfaces by adsorption to inhibithydration. The EPWS with flexible adaptability to tem- perature for inhibition and sealing capacity is available for long open-hole sections during drilling.
基金Supported by the Ministerial Level Advanced Research Foundation (870102056)
文摘An optimized workspace calculation method is proposed for parallel stabilized platform testing systems.This method refines the searched space progressively in order to approach the boundary of the workspace from both the inside and the outside of it.The orientation density is defined and used as an evaluation index to calculate the orientation workspace.The algorithm of the orientation density is embedded into the computer program of the workspace calculation.Then the workspaces of the testing system are solved.In the solution,the orientation density is regarded as a discrete function of the reachable workspace.As a result,the reachable workspace and the orientation workspace are represented in the same multidimensional graphs.Finally the useful workspace of the testing system is determined based on these results.This case study indicates that the calculation efficiency is enhanced by adopting the optimized method and the practicability of workspace study is improved by proposing the orientation density.
基金supported by the China Scholarship Council(No.201908505143)the Chongqing Research Program of Basic Research and Frontier Technology(No.cstc2017jcyj AX0290/No.cstc2018jcyj AX0563)。
文摘Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics and isotherms pertaining to Longmaxi shale,an experimental setup was designed based on the volumetric method.The objective was to conduct experiments on methane adsorption and desorption kinetics and isotherms before and after clay stabilizer treatments.The experimental data were a good fit for both the intraparticle diffusion model and the Freundlich isotherm model.We analyzed the effect of the clay stabilizer on desorption kinetics and isotherms.Results show that clay stabilizer can obviously improve the diffusion rate constant and reduce the methane adsorption amount.Moreover,we analyzed the desorption efficiency before and after treatment as well as the adsorbed methane content.The results show that a higher desorption efficiency after treatment can be observed when the pressure is higher than 6.84 MPa.Meanwhile,the adsorbed methane content before and after treatment all increase when the pressure decreases,and clay stabilizer can obviously promote the adsorbed methane to free gas when the pressure is lower than 19 MPa.This can also be applied to the optimization formulation of slickwater and the design of gas well production.
基金Supported by the China Nuclear Science Foundation under Grant No.H7196C0305。
文摘The production of the poloidally sheared flow during electron cyclotron resonant heating(ECRH)in the collisional tokamak plasmas,which refers to the edge region,is studied.Based on the linearized kinetic drift equation and the fluid equations including the density perturbation term driven by rf waves,the criterion of the destabilization of the poloidal plasma rotation is analytically derived.It is shown that the edge poloidal plasma rotation can be destabilized during ECRH in the present rf power level.
基金supported in part by the National Natural Science Foundation of China under Grant 51905271,Grant No.52275062and Grant No.52075262。
文摘Backlash nonlinearity inevitably exists in the actuator of tank horizontal stabilizer and has adverse effect on the system control performance,however,how to effectively eliminate its effect remains a pending issue.To solve this problem,a robust adaptive precision motion controller is presented in this paper to address uncertainties and unknown actuator backlash of tank horizontal actuator.The controller handles the modeling uncertainties including parameter uncertainties and unmodeled disturbances by integrating adaptive feedforward compensation and continuous nonlinear robust law.Based on the backstepping method,a smooth backlash inverse model is constructed by combining the adaptive idea.Meanwhile,the unknown backlash parameters of the system can be approximated through the parameter adaptation,and the impact of the actuator backlash nonlinearity is effectively compensated via the inverse operation,which can availably improve the tracking performance.Moreover,the adaptive law can update the disturbance ranges of tank horizontal stabilizer online in real time,which enhances the feasibility in practical engineering applications.Furthermore,the stability analysis based on Lyapunov function shows that with the existence of unmodeled disturbances and unknown actuator backlash,the designed controller guarantees excellent asymptotic output tracking performance.Extensive comparative results verify the effectiveness of the proposed control strategy.
基金The work is supported by was supported by the Shandong Province Higher Educational Science and Technology Program(Grant No.J18KZ012)the National Natural Science Foundation of China(Grant No.11975132,61772295)the Shandong Provincial Natural Science Foundation,China(Grant No.ZR2019YQ01).
文摘In this paper,we develop a novel hybrid automatic-repeat-request(ARQ)protocol for the quantum communication system using quantum stabilizer codes.The quantum information is encoded by stabilizer codes to against the channel noise.The twophoton entangled state is prepared for codeword secure transmission.Hybrid ARQ protocol rules the recognition and retransmission of error codewords.In this protocol,the property of quantum entangled state ensures the security of information,the theory of hybrid ARQ system improves the reliability of transmission,the theory of quantum stabilizer codes corrects the flipping errors of codewords.Finally,we verify the security and throughput efficiency of this protocol.
基金Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0303304)the National Natural Science Foundation of China (Grant Nos. 11675016, 11974011, and 61905174)。
文摘Motivated by the need of quantum measurement of Majorana qubits and surface-code stabilizers, we analyze the performance of a double-dot interferometer under the influence of environment noise. The double-dot setup design allows accounting for the full multiple tunneling process between the dots through the Majorana island, within a master equation approach. In the co-tunneling regime, which results in a Majorana-mediated effective coupling between the dots, the master equation approach allows us to obtain analytic solutions for the measurement currents. The measurement quality,characterized by figures of merit such as the visibility of measurement signals, is carried out in regard to the unusual decoherence effect rather than ‘which-path’ dephasing. The results obtained in this work are expected to be useful for future experiments of Majorana qubit and stabilizer measurements.
基金supported by the National Science Foundation of China(11271127)Science Research Project of Guizhou Province Education Department(QJHKYZ[2013]207)
文摘In this study, we employ mixed finite element （MFE） method, two local Gauss integrals, and parameter-free to establish a stabilized MFE formulation for the non-stationary incompressible Boussinesq equations. We also provide the theoretical analysis of the existence, uniqueness, stability, and convergence of the stabilized MFE solutions for the stabilized MFE formulation.
