The electron configuration of the active sites can be effectively modulated by regulating the inherent nanostructure of the electrocatalysts,thereby enhancing their electrocatalytic performance.To tackle the unexplore...The electron configuration of the active sites can be effectively modulated by regulating the inherent nanostructure of the electrocatalysts,thereby enhancing their electrocatalytic performance.To tackle the unexplored challenge of substantial electrochemical overpotential,surface reconstruction has emerged as a necessary strategy.Focusing on key aspects such as Janus structures,overflow effects,the d-band center displacement hypothesis,and interface coupling related to electrochemical reactions is essential for water electrolysis.Emerging as frontrunners among next-generation electrocatalysts,Mott-Schottky(M-S)catalysts feature a heterojunction formed between a metal and a semiconductor,offering customizable and predictable interfacial synergy.This review offers an in-depth examination of the processes driving the hydrogen and oxygen evolution reactions(HER and OER),highlighting the benefits of employing nanoscale transition metal nitrides,carbides,oxides,and phosphides in M-S heterointerface catalysts.Furthermore,the challenges,limitations,and future prospects of employing M-S heterostructured catalysts for water splitting are thoroughly discussed.展开更多
Developing efficient,durable,and precious metal-free electrocatalysts is currently a huge challenge.In this article,through a simple one-step high-temperature pyrolysis method,by incorporating various non-metallic ele...Developing efficient,durable,and precious metal-free electrocatalysts is currently a huge challenge.In this article,through a simple one-step high-temperature pyrolysis method,by incorporating various non-metallic element atoms,we prepared four different NiX(X=Cl_(2),(CH_(3)COO)_(2),(NO_(3))2,SO_(4))@CNT catalysts.Additionally,by adjusting the temperature,these four materials were expanded into twelve catalyst materials for comparative optimization of hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)activity.Ultimately,Ni(NO_(3))2@CNT-900 typically exhibits superior OER and HER activity.In 1 mol/L KOH solution with a current density of 10 mA/cm^(2),the overpotentials of HER and OER of Ni(NO_(3))2@CNT-900 are only 145 mV and 300 mV,respectively.Furthermore,the Ni(NO_(3))2@CNT-900 shows excellent durability in both HER and OER.展开更多
Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as ...Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.展开更多
Using seismic waveform data recorded at station YK (Yingkou) of Liaoning Telemetry Digital Seismic Network, this paper studied the characteristics of shear-wave splitting before and after the Xiuyan MS5.9 (ML5.3) eart...Using seismic waveform data recorded at station YK (Yingkou) of Liaoning Telemetry Digital Seismic Network, this paper studied the characteristics of shear-wave splitting before and after the Xiuyan MS5.9 (ML5.3) earthquake in November 29, 1999 with SAM method. The results show that the predominant polarizations of fast shear-waves at YK is in direction of ENE-WSW, consistent with the direction of regional principal compressive stress and also consistent with the direction of the regional tectonic stress field in North China; time-delays increasing before Xiuyan earthquake may shows accumulation of stress before earthquake. The predominant polarizations of fast shear-waves at YK are also related to the spatial distribution of small earthquakes and correlate with the fault strike. The histogram of monthly average polarizations of fast shear-waves shows that polarizations of fast shear-waves also seems to change from two months before the earthquake, but it still needs more data for verification.展开更多
In 2001 three earthquakes occurred in Shidian in Yunnan Province, which were the MS=5.2 on April 10, the MS=5.9 on April 12 and the MS=5.3 on June 8. Based on the data from the station Baoshan of Yunnan Telemetry Digi...In 2001 three earthquakes occurred in Shidian in Yunnan Province, which were the MS=5.2 on April 10, the MS=5.9 on April 12 and the MS=5.3 on June 8. Based on the data from the station Baoshan of Yunnan Telemetry Digital Seismograph Network, the variational characteristics of shear-wave splitting on these series of strong earthquakes has been studied by using the systematic analysis method (SAM) of shear-wave splitting. The result shows the time delays of shear-wave splitting basically increase with earthquake activity intensifying. However the time delays abruptly decrease immediately before strong aftershocks. It accords with the stress relaxation before earthquakes, which was found recently in study on shear-wave splitting. The result suggests it is significant for reducing the harm degree of earthquakes to develop the stress-forecasting on earthquake in strong active tectonic zones and economic developed regions or big cities under the danger of strong earthquakes.展开更多
In the re-entry phase of a ballistic missile,decoys can be deployed as a mean to overburden enemy defenses.This results in a single track being split into multiple track-lets.Tracking of these track-lets is a critical...In the re-entry phase of a ballistic missile,decoys can be deployed as a mean to overburden enemy defenses.This results in a single track being split into multiple track-lets.Tracking of these track-lets is a critical task as any miss in the tracking procedure can become a cause of a major threat.The tracking process becomes more complicated in the presence of clutter.The low detection rate is one of the factors that may contribute to increasing the difficulty level in terms of tracking in the cluttered environment.This work introduces a new algorithm for the split event detection and target tracking under the framework of the joint integrated probabilistic data association(JIPDA)algorithm.The proposed algorithm is termed as split event-JIPDA(SE-JIPDA).This work establishes the mathematical foundation for the split target detection and tracking mechanism.The performance analysis is made under different simulation conditions to provide a clear insight into the merits of the proposed algorithm.The performance parameters in these simulations are the root mean square error(RMSE),confirmed true track rate(CTTR)and confirmed split true track rate(CSTTR).展开更多
基金supported by the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2021L574)the Guizhou Provincial Science and Technology Foundation([2024]ZK General 425 and 438)+1 种基金the National Natural Science Foundation of China(22309033)the Academic Young Talent Foundation of Guizhou Normal University([2022]B05 and B06)。
文摘The electron configuration of the active sites can be effectively modulated by regulating the inherent nanostructure of the electrocatalysts,thereby enhancing their electrocatalytic performance.To tackle the unexplored challenge of substantial electrochemical overpotential,surface reconstruction has emerged as a necessary strategy.Focusing on key aspects such as Janus structures,overflow effects,the d-band center displacement hypothesis,and interface coupling related to electrochemical reactions is essential for water electrolysis.Emerging as frontrunners among next-generation electrocatalysts,Mott-Schottky(M-S)catalysts feature a heterojunction formed between a metal and a semiconductor,offering customizable and predictable interfacial synergy.This review offers an in-depth examination of the processes driving the hydrogen and oxygen evolution reactions(HER and OER),highlighting the benefits of employing nanoscale transition metal nitrides,carbides,oxides,and phosphides in M-S heterointerface catalysts.Furthermore,the challenges,limitations,and future prospects of employing M-S heterostructured catalysts for water splitting are thoroughly discussed.
基金Project(145209113)supported by the Basic Research Expenses of Department of Education of Heilongjiang Province,China。
文摘Developing efficient,durable,and precious metal-free electrocatalysts is currently a huge challenge.In this article,through a simple one-step high-temperature pyrolysis method,by incorporating various non-metallic element atoms,we prepared four different NiX(X=Cl_(2),(CH_(3)COO)_(2),(NO_(3))2,SO_(4))@CNT catalysts.Additionally,by adjusting the temperature,these four materials were expanded into twelve catalyst materials for comparative optimization of hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)activity.Ultimately,Ni(NO_(3))2@CNT-900 typically exhibits superior OER and HER activity.In 1 mol/L KOH solution with a current density of 10 mA/cm^(2),the overpotentials of HER and OER of Ni(NO_(3))2@CNT-900 are only 145 mV and 300 mV,respectively.Furthermore,the Ni(NO_(3))2@CNT-900 shows excellent durability in both HER and OER.
基金the National Basic Research Development of China(2011CB936003)the National Natural Science Foundation of China(50971116)。
文摘Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.
基金Basis and Special Research Foundation, Institute of Earthquake Science, China Earthquake Administration (2007-24)
文摘Using seismic waveform data recorded at station YK (Yingkou) of Liaoning Telemetry Digital Seismic Network, this paper studied the characteristics of shear-wave splitting before and after the Xiuyan MS5.9 (ML5.3) earthquake in November 29, 1999 with SAM method. The results show that the predominant polarizations of fast shear-waves at YK is in direction of ENE-WSW, consistent with the direction of regional principal compressive stress and also consistent with the direction of the regional tectonic stress field in North China; time-delays increasing before Xiuyan earthquake may shows accumulation of stress before earthquake. The predominant polarizations of fast shear-waves at YK are also related to the spatial distribution of small earthquakes and correlate with the fault strike. The histogram of monthly average polarizations of fast shear-waves shows that polarizations of fast shear-waves also seems to change from two months before the earthquake, but it still needs more data for verification.
基金National Natural Science Foundation of China (40274011 40074020) MOST (2001BA601B02) and Joint Seis-mological Science Foundation of China (102068).
文摘In 2001 three earthquakes occurred in Shidian in Yunnan Province, which were the MS=5.2 on April 10, the MS=5.9 on April 12 and the MS=5.3 on June 8. Based on the data from the station Baoshan of Yunnan Telemetry Digital Seismograph Network, the variational characteristics of shear-wave splitting on these series of strong earthquakes has been studied by using the systematic analysis method (SAM) of shear-wave splitting. The result shows the time delays of shear-wave splitting basically increase with earthquake activity intensifying. However the time delays abruptly decrease immediately before strong aftershocks. It accords with the stress relaxation before earthquakes, which was found recently in study on shear-wave splitting. The result suggests it is significant for reducing the harm degree of earthquakes to develop the stress-forecasting on earthquake in strong active tectonic zones and economic developed regions or big cities under the danger of strong earthquakes.
文摘In the re-entry phase of a ballistic missile,decoys can be deployed as a mean to overburden enemy defenses.This results in a single track being split into multiple track-lets.Tracking of these track-lets is a critical task as any miss in the tracking procedure can become a cause of a major threat.The tracking process becomes more complicated in the presence of clutter.The low detection rate is one of the factors that may contribute to increasing the difficulty level in terms of tracking in the cluttered environment.This work introduces a new algorithm for the split event detection and target tracking under the framework of the joint integrated probabilistic data association(JIPDA)algorithm.The proposed algorithm is termed as split event-JIPDA(SE-JIPDA).This work establishes the mathematical foundation for the split target detection and tracking mechanism.The performance analysis is made under different simulation conditions to provide a clear insight into the merits of the proposed algorithm.The performance parameters in these simulations are the root mean square error(RMSE),confirmed true track rate(CTTR)and confirmed split true track rate(CSTTR).
