Photoinduced[2+2]cycloaddition of biomass-derived cycloolefin is a promising approach to synthesize high-energy bio-fuels,however,the conversion efficiency and selectivity are still low.Herein,we provide an acid-promo...Photoinduced[2+2]cycloaddition of biomass-derived cycloolefin is a promising approach to synthesize high-energy bio-fuels,however,the conversion efficiency and selectivity are still low.Herein,we provide an acid-promoted photocycloaddition approach to synthesize a new kind of spiral fuel from biomass-derived cyclohexanone (CHOE) and camphene (CPE).Bronsted acids show higher catalytic activity than Lewis acids,and acetic acid (HOAc) possesses the best catalytic performance,with CHOE conversion up to 99.1%.Meanwhile,the HOAc-catalytic effect has been confirmed for[2+2]photocycloaddition of other biomass-derived ketenes and olefins.The catalytic mechanism and dynamics have been investigated,and show that HOAc can bond with C=O groups of CHOE to form H–CHOE complex,which leads to higher light adsorption and longer triplet lifetime.Meanwhile,H–CHOE complex reduces the energy gap between CHOE LUMO and CPE HOMO,shortens the distance of ring-forming atoms,and then decreases the energy barrier (from 103.3 kcal mol^(-1)to 95.8 kcal mol^(-1)) of rate-limiting step.After hydrodeoxygenation,the targeted bio-spiral fuel shows high density of 0.992 g cm^(-3),high neat heat of combustion of 41.89 MJ L^(-1),low kinetic viscosity of 5.69 mm^(2)s^(-1)at 20℃,which is very promising to serve as high-performance aerospace fuel.展开更多
Optical vortices generated by the conventional vortex lens are usually disturbed by the undesired higher-order foci,which may lead to additional artifacts and thus degrade the contrast sensitivity. In this work, we pr...Optical vortices generated by the conventional vortex lens are usually disturbed by the undesired higher-order foci,which may lead to additional artifacts and thus degrade the contrast sensitivity. In this work, we propose an efficient methodology to combine the merit of elliptical reflective zone plates(ERZPs) and the advantage of spiral zone plates(SZPs) in establishing a specific single optical element, termed elliptical reflective annulus quadrangle-element coded spiral zone plates(ERAQSZPs) to generate single-focus phase singularity. Differing from the abrupt reflectance of the ERZPs, a series of randomly distributed nanometer apertures are adopted to realize the sinusoidal reflectance. Typically, according to our physical design, the ERAQSZPs are fabricated on a bulk substrate;therefore, the new idea can significantly reduce the difficulty in the fabrication process. Based on the Kirchhoff diffraction theory and convolution theorem, the focusing performance of ERAQSZPs is calculated. The results reveal that apart from the capability of generating optical vortices,ERAQSZPs can also integrate the function of focusing, energy selection, higher-order foci elimination, as well as high spectral resolution together. In addition, the focusing properties can be further improved by appropriately adjusting the parameters, such as zone number and the size of the consisted primitives. These findings are expected to direct a new direction toward improving the performance of optical capture, x-ray fluorescence spectra, and forbidden transition.展开更多
Multistage fracturing of horizontal wells is a critical technology for unconventional oil and gas reservoir stimulation. Ball-throwing temporary plugging fracturing is a new method for realizing uniform fracturing alo...Multistage fracturing of horizontal wells is a critical technology for unconventional oil and gas reservoir stimulation. Ball-throwing temporary plugging fracturing is a new method for realizing uniform fracturing along horizontal wells and plays an important role in increasing oil and gas production. However,the transportation and sealing law of temporary plugging balls(TPBs) in the perforation section of horizontal wells is still unclear. Using COMSOL computational fluid dynamics and a particle tracking module, we simulate the transportation process of TPBs in a horizontal wellbore and analyse the effects of the ball density, ball diameter, ball number, fracturing fluid injection rate, and viscosity on the plugging efficiency of TPB transportation. This study reveals that when the density of TPBs is close to that of the fracturing fluid and a moderate diameter of the TPB is used, the plugging efficiency can be substantially enhanced. The plugging efficiency is greater when the TPB number is close to twice the number of perforations and is lower when the number of TPBs is three times the number of perforations.Adjusting the fracturing fluid injection rate from low to high can control the position of the TPBs,improving plugging efficiency. As the viscosity of the fracturing fluid increases, the plugging efficiency of the perforations decreases near the borehole heel and increases near the borehole toe. In contrast, the plugging efficiency of the central perforation is almost unaffected by the fracturing fluid viscosity. This study can serve as a valuable reference for establishing the parameters for temporary plugging and fracturing.展开更多
We propose a new method to generate terahertz perfect vortex beam with integer-order and fractional-order. A new optical diffractive element composed of the phase combination of a spherical harmonic axicon and a spira...We propose a new method to generate terahertz perfect vortex beam with integer-order and fractional-order. A new optical diffractive element composed of the phase combination of a spherical harmonic axicon and a spiral phase plate is designed and called spiral spherical harmonic axicon. A terahertz Gaussian beam passes through the spiral spherical harmonic axicon to generate a terahertz vortex beam. When only the topological charge number carried by spiral spherical harmonic axicon increases, the ring radius of terahertz vortex beam increases slightly, so the beam is shaped into a terahertz quasi-perfect vortex beam. Importantly, the terahertz quasi-perfect vortex beam can carry not only integer-order topological charge number but also fractional-order topological charge number. This is the first time that vortex beam and quasi-perfect vortex beam with fractional-order have been successfully realized in terahertz domain and experiment.展开更多
A geometric modeling method for generating-manufactured spiral bevel gears（SBGs） is proposed. It consists of two steps： （1） creating a reference model by simulating the process of cutting spiral bevel gear,（2） ...A geometric modeling method for generating-manufactured spiral bevel gears（SBGs） is proposed. It consists of two steps： （1） creating a reference model by simulating the process of cutting spiral bevel gear,（2） reconstructing the final solid model by collecting data points from the reference model and fitting these points into NURBS surfaces. In this method,cutting simulation avoids abstruse mathematical theories and complex methods,thus making it convenient to obtain data points on the complex tooth surface before the gear is manufactured and efficient to increase the accuracy of the solid model. Also,the representations of tooth surfaces of the final model is unified as a NURBS surface function. The NURBS surface is continuous and smooth,thus it is available for wide applications in CAD/CAE. The experiment proves that the method can be used to establish an accurate pair of SBG models,thus providing a feasible and effective way for CAD/CAE modeling.展开更多
The generating motion of the generating gear and the work gear on spiral bevel gear NC machining is analyzed. The mathematical model of the tooth surface of spiral bevel gear is presented. A direct interpolation algor...The generating motion of the generating gear and the work gear on spiral bevel gear NC machining is analyzed. The mathematical model of the tooth surface of spiral bevel gear is presented. A direct interpolation algorithm of spiral bevel gear NC machining is proposed, thus establishing the relationship between the motion of the cutter-head center and the rotation of the work gear. The interpolation algorithm is implemented to control the gear cutting on self-developed spiral bevel gear NC cutting machine. An example is given to verify the mathematical model and the interpolation algorithm.展开更多
基金the support from National Key R&D Program of China (2021YFC2103704)the National Natural Science Foundation of China (22222808)+4 种基金the Natural Science Foundation of Shandong Province (ZR2023QB152)the Youth Innovation Team Plan of Shandong Province (2022KJ270)the China National Postdoctoral Program for Innovative Talents (BX20240251)the Aeronautical Science Foundation of China (2023Z073048003)the Haihe Laboratory of Sustainable Chemical Transformations。
文摘Photoinduced[2+2]cycloaddition of biomass-derived cycloolefin is a promising approach to synthesize high-energy bio-fuels,however,the conversion efficiency and selectivity are still low.Herein,we provide an acid-promoted photocycloaddition approach to synthesize a new kind of spiral fuel from biomass-derived cyclohexanone (CHOE) and camphene (CPE).Bronsted acids show higher catalytic activity than Lewis acids,and acetic acid (HOAc) possesses the best catalytic performance,with CHOE conversion up to 99.1%.Meanwhile,the HOAc-catalytic effect has been confirmed for[2+2]photocycloaddition of other biomass-derived ketenes and olefins.The catalytic mechanism and dynamics have been investigated,and show that HOAc can bond with C=O groups of CHOE to form H–CHOE complex,which leads to higher light adsorption and longer triplet lifetime.Meanwhile,H–CHOE complex reduces the energy gap between CHOE LUMO and CPE HOMO,shortens the distance of ring-forming atoms,and then decreases the energy barrier (from 103.3 kcal mol^(-1)to 95.8 kcal mol^(-1)) of rate-limiting step.After hydrodeoxygenation,the targeted bio-spiral fuel shows high density of 0.992 g cm^(-3),high neat heat of combustion of 41.89 MJ L^(-1),low kinetic viscosity of 5.69 mm^(2)s^(-1)at 20℃,which is very promising to serve as high-performance aerospace fuel.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.12174350,12275253,and 12275250)the Program of Science and Technology on Plasma Physics Laboratory,China Academy of Engineering Physics (Grant No.6142A04200107)the National Natural Science Foundation,Youth Fund (Grant No.12105268)。
文摘Optical vortices generated by the conventional vortex lens are usually disturbed by the undesired higher-order foci,which may lead to additional artifacts and thus degrade the contrast sensitivity. In this work, we propose an efficient methodology to combine the merit of elliptical reflective zone plates(ERZPs) and the advantage of spiral zone plates(SZPs) in establishing a specific single optical element, termed elliptical reflective annulus quadrangle-element coded spiral zone plates(ERAQSZPs) to generate single-focus phase singularity. Differing from the abrupt reflectance of the ERZPs, a series of randomly distributed nanometer apertures are adopted to realize the sinusoidal reflectance. Typically, according to our physical design, the ERAQSZPs are fabricated on a bulk substrate;therefore, the new idea can significantly reduce the difficulty in the fabrication process. Based on the Kirchhoff diffraction theory and convolution theorem, the focusing performance of ERAQSZPs is calculated. The results reveal that apart from the capability of generating optical vortices,ERAQSZPs can also integrate the function of focusing, energy selection, higher-order foci elimination, as well as high spectral resolution together. In addition, the focusing properties can be further improved by appropriately adjusting the parameters, such as zone number and the size of the consisted primitives. These findings are expected to direct a new direction toward improving the performance of optical capture, x-ray fluorescence spectra, and forbidden transition.
基金supported by the National Natural Science Foundation of China (No. 52074250)。
文摘Multistage fracturing of horizontal wells is a critical technology for unconventional oil and gas reservoir stimulation. Ball-throwing temporary plugging fracturing is a new method for realizing uniform fracturing along horizontal wells and plays an important role in increasing oil and gas production. However,the transportation and sealing law of temporary plugging balls(TPBs) in the perforation section of horizontal wells is still unclear. Using COMSOL computational fluid dynamics and a particle tracking module, we simulate the transportation process of TPBs in a horizontal wellbore and analyse the effects of the ball density, ball diameter, ball number, fracturing fluid injection rate, and viscosity on the plugging efficiency of TPB transportation. This study reveals that when the density of TPBs is close to that of the fracturing fluid and a moderate diameter of the TPB is used, the plugging efficiency can be substantially enhanced. The plugging efficiency is greater when the TPB number is close to twice the number of perforations and is lower when the number of TPBs is three times the number of perforations.Adjusting the fracturing fluid injection rate from low to high can control the position of the TPBs,improving plugging efficiency. As the viscosity of the fracturing fluid increases, the plugging efficiency of the perforations decreases near the borehole heel and increases near the borehole toe. In contrast, the plugging efficiency of the central perforation is almost unaffected by the fracturing fluid viscosity. This study can serve as a valuable reference for establishing the parameters for temporary plugging and fracturing.
基金Project supported by the Fundamental Research Funds for the Central Universities,China (Grant No.2017KFYXJJ029)。
文摘We propose a new method to generate terahertz perfect vortex beam with integer-order and fractional-order. A new optical diffractive element composed of the phase combination of a spherical harmonic axicon and a spiral phase plate is designed and called spiral spherical harmonic axicon. A terahertz Gaussian beam passes through the spiral spherical harmonic axicon to generate a terahertz vortex beam. When only the topological charge number carried by spiral spherical harmonic axicon increases, the ring radius of terahertz vortex beam increases slightly, so the beam is shaped into a terahertz quasi-perfect vortex beam. Importantly, the terahertz quasi-perfect vortex beam can carry not only integer-order topological charge number but also fractional-order topological charge number. This is the first time that vortex beam and quasi-perfect vortex beam with fractional-order have been successfully realized in terahertz domain and experiment.
文摘A geometric modeling method for generating-manufactured spiral bevel gears（SBGs） is proposed. It consists of two steps： （1） creating a reference model by simulating the process of cutting spiral bevel gear,（2） reconstructing the final solid model by collecting data points from the reference model and fitting these points into NURBS surfaces. In this method,cutting simulation avoids abstruse mathematical theories and complex methods,thus making it convenient to obtain data points on the complex tooth surface before the gear is manufactured and efficient to increase the accuracy of the solid model. Also,the representations of tooth surfaces of the final model is unified as a NURBS surface function. The NURBS surface is continuous and smooth,thus it is available for wide applications in CAD/CAE. The experiment proves that the method can be used to establish an accurate pair of SBG models,thus providing a feasible and effective way for CAD/CAE modeling.
文摘The generating motion of the generating gear and the work gear on spiral bevel gear NC machining is analyzed. The mathematical model of the tooth surface of spiral bevel gear is presented. A direct interpolation algorithm of spiral bevel gear NC machining is proposed, thus establishing the relationship between the motion of the cutter-head center and the rotation of the work gear. The interpolation algorithm is implemented to control the gear cutting on self-developed spiral bevel gear NC cutting machine. An example is given to verify the mathematical model and the interpolation algorithm.
