The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated operation.Here,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by...The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated operation.Here,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by self-crosslinking encapsulation method.MNMGH achieved high selectivity(K_(d)=23.31 mL/g)in the acidic range,and exhibited ultrahigh silver recovery capacity(1604.8 mg/g),which greatly improved by 66%with the assistance of in-situ magnetic field.The recovered silver crystals could be directly physically exfoliated,without acid/base additions.The selective sieving effect of adsorption,MNMGH preferentially adsorbed Ag(I),and then selectively reduced to Ag(0),realizing dual-selective recovery.The in-situ magnetic field enhanced selective adsorption by enhancing mass transfer,reactivity of oxygen-containing functional groups.Furthermore,density function theory simulations demonstrated that the in-situ magnetic field could lower the silver reduction reaction energy barrier to enhance the selective reduction.Three-drive synergy system(reduction drive,adsorption drive and magnetic drive)achieved ultrahigh silver recovery performance.This study pioneered an in-situ magnetic field assisted enhancement strategy for dual-selective(adsorption/reduction)recovery of precious metal silver,which provided new idea for low-carbon recovery of noble metal from industrial waste liquids.展开更多
Infrared detection technology has greatly expanded the ability of mankind to study the earth and the universe. In recent years, the demand for long-wavelength infrared detectors is increasing for their advantages in e...Infrared detection technology has greatly expanded the ability of mankind to study the earth and the universe. In recent years, the demand for long-wavelength infrared detectors is increasing for their advantages in exploring the earth and the universe. A variety of long-wavelength infrared detectors have been made based on thermal resistive effect, photoelectric effect, etc., in the past few decades. Remarkable achievements have been made in infrared materials, device fabrication,readout circuit, and device package. However, high performance long-wavelength infrared detectors, especially those for large format long-wavelength infrared detector focus plane array, are still unsatisfactory. Low noise, high detectivity, and large format long-wavelength infrared detector is necessary to satisfy space-based application requirements.展开更多
With the development of satellite communications,the number of satellite nodes is constantly increasing,which undoubtedly increases the difficulty of maintaining network security.Combining software defined network(SDN...With the development of satellite communications,the number of satellite nodes is constantly increasing,which undoubtedly increases the difficulty of maintaining network security.Combining software defined network(SDN) with traditional space-based networks provides a new class of ideas for solving this problem.However,because of the highly centralized network management of the SDN controller,once the SDN controller is destroyed by network attacks,the network it manages will be paralyzed due to loss of control.One of the main security threats to SDN controllers is Distributed Denial of Service(DDoS) attacks,so how to detect DDoS attacks scientifically has become a hot topic among SDN security management.This paper proposes a DDoS attack detection method for space-based networks based on SDN architecture.This attack detection method combines the optimized Long Short-Term Memory(LSTM) deep learning model and Support Vector Machine(SVM),which can not only make classification judgments on the time series,but also achieve the purpose of detecting and judging through the flow characteristics of a period of time.In addition,it can reduce the detection time as well as the system burden.展开更多
In space-based Automatic Identification Systems(AIS), due to high satellite orbits, several Ad Hoc cells within the observation range of the satellite are vulnerable to interference by an external signal.To increase e...In space-based Automatic Identification Systems(AIS), due to high satellite orbits, several Ad Hoc cells within the observation range of the satellite are vulnerable to interference by an external signal.To increase efficiency in target detection and improve system security, a blind source separation method is adopted for processing the conflicting signals received by satellites. Compared to traditional methods, we formulate the separation problem as a clustering problem. Since our algorithm is affected by the sparseness of source signals, to get satisfactory results, our algorithm assumes that the distance between two arbitrary mixed-signal vectors is less than the doubled sum of variances of distribution of the corresponding mixtures. Signal sparsity is overcome by computing the Short-Time Fourier Transform, and the mixed source signals are separated using the improved PSO clustering. We evaluated the performance and the robustness of the proposed network architecture by several simulations. The experimental results demonstrate the effectiveness of the proposed method in not only improving satellite signal receiving ability but also in enhancing space-based AIS security.展开更多
This paper reviews the basic research means for oilfield development and also the researches and tests of enhanced oil recovery(EOR)methods for mature oilfields and continental shale oil development,analyzes the probl...This paper reviews the basic research means for oilfield development and also the researches and tests of enhanced oil recovery(EOR)methods for mature oilfields and continental shale oil development,analyzes the problems of EOR methods,and proposes the relevant research prospects.The basic research means for oilfield development include in-situ acquisition of formation rock/fluid samples and non-destructive testing.The EOR methods for conventional and shale oil development are classified as improved water flooding(e.g.nano-water flooding),chemical flooding(e.g.low-concentration middle-phase micro-emulsion flooding),gas flooding(e.g.micro/nano bubble flooding),thermal recovery(e.g.air injection thermal-aided miscible flooding),and multi-cluster uniform fracturing/water-free fracturing,which are discussed in this paper for their mechanisms,approaches,and key technique researches and field tests.These methods have been studied with remarkable progress,and some achieved ideal results in field tests.Nonetheless,some problems still exist,such as inadequate research on mechanisms,imperfect matching technologies,and incomplete industrial chains.It is proposed to further strengthen the basic researches and expand the field tests,thereby driving the formation,promotion and application of new technologies.展开更多
Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant...Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs.展开更多
Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displa...Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displacement mechanisms of shale oil extraction by CO_(2)injection,and the influences of CO_(2)pre-pad on shale mechanical properties.Numerical simulations were performed about influences of CO_(2)pre-pad fracturing and puff-n-huff for energy replenishment on the recovery efficiency.The findings obtained were applied to the field tests of CO_(2)pre-pad fracturing and single well puff-n-huff.The results show that the efficiency of CO_(2)puff-n-huff is affected by micro-and nano-scale effect,kerogen,adsorbed oil and so on,and a longer soaking time in a reasonable range leads to a higher exploitation degree of shale oil.In the"injection+soaking"stage,the exploitation degree of heavy hydrocarbons is enhanced by CO_(2)through its effects of solubility-diffusion and mass-transfer.In the"huff"stage,crude oil in large pores is displaced by CO_(2)to surrounding larger pores or bedding fractures and finally flows to the production well.The injection of CO_(2)pre-pad is conducive to keeping the rock brittle and reducing the fracture breakdown pressure,and the CO_(2)is liable to filter along the bedding surface,thereby creating a more complex fracture.Increasing the volume of CO_(2)pre-pad can improve the energizing effect,and enhance the replenishment of formation energy.Moreover,the oil recovery is more enhanced by CO_(2)huff-n-puff with the lower shale matrix permeability,the lower formation pressure,and the larger heavy hydrocarbon content.The field tests demonstrate a good performance with the pressure maintained well after CO_(2)pre-pad fracturing,the formation energy replenished effectively after CO_(2)huff-n-puff in a single well,and the well productivity improved.展开更多
With the rise of artificial intelligence(AI)in mineral processing,predicting the flotation indexes has attracted significant research attention.Nevertheless,current prediction models suffer from low accuracy and high ...With the rise of artificial intelligence(AI)in mineral processing,predicting the flotation indexes has attracted significant research attention.Nevertheless,current prediction models suffer from low accuracy and high prediction errors.Therefore,this paper utilizes a two-step procedure.First,the outliers are pro-cessed using the box chart method and filtering algorithm.Then,the decision tree(DT),support vector regression(SVR),random forest(RF),and the bagging,boosting,and stacking integration algorithms are employed to construct a flotation recovery prediction model.Extensive experiments compared the prediction accuracy of six modeling methods on flotation recovery and delved into the impact of diverse base model combinations on the stacking model’s prediction accuracy.In addition,field data have veri-fied the model’s effectiveness.This study demonstrates that the stacking ensemble approaches,which uses ten variables to predict flotation recovery,yields a more favorable prediction effect than the bagging ensemble approach and single models,achieving MAE,RMSE,R2,and MRE scores of 0.929,1.370,0.843,and 1.229%,respectively.The hit rates,within an error range of±2%and±4%,are 82.4%and 94.6%.Consequently,the prediction effect is relatively precise and offers significant value in the context of actual production.展开更多
Carbonated water injection(CWI)is a promising enhanced oil recovery(EOR)technology that has received much attention in co-optimizing CO_(2) storage and oil recovery.This study provides a comprehensive review of the fl...Carbonated water injection(CWI)is a promising enhanced oil recovery(EOR)technology that has received much attention in co-optimizing CO_(2) storage and oil recovery.This study provides a comprehensive review of the fluid system properties and the underlying changes in rock-fluid interactions that drive the CWI-EOR mechanisms.Previous research has indicated that CWI can enhance oil recovery by shifting reservoir wettability towards a more water-wet state and reducing interfacial tension(IFT).However,this study reveals that there is still room for discussion in this area.Notably,the potential of CWI to alter reservoir permeability has not yet been explored.The varying operational conditions of the CWI process,namely temperature,pressure,injection rate,salinity,and ionic composition,lead to different levels of oil recovery factors.Herein,we aim to meticulously analyze their impact on oil recovery performance and outline the optimal operational conditions.Pressure,for instance,positively influences oil recovery rate and CWI efficiency.On one hand,higher operating pressures enhance the effectiveness of CW due to increased CO_(2)solubility.On the other hand,gas exsolution events in depleted reservoirs provide additional energy for oil movement along gas growth pathways.However,CWI at high carbonation levels does not offer significant benefits over lower carbonation levels.Additionally,lower temperatures and injection rates correlate with higher recovery rates.Further optimization of solution chemistry is necessary to determine the maximum recovery rates under optimal conditions.Moreover,this review comprehensively covers laboratory experiments,numerical simulations,and field applications involving the CWI process.However,challenges such as pipeline corrosion,potential reservoir damage,and produced water treatment impact the further application of CWI in EOR technologies.These issues can affect the expected oil recovery rates,thereby reducing the economic returns of EOR projects.Finally,this review introduces current research trends and future development prospects based on recently published studies in the field of CWI.The conclusions of this study aid readers in better understanding the latest advancements in CWI technology and the strengths and limitations of the techniques used,providing directions for further development and application of CWI.展开更多
The recycling of spent lithium-ion batteries(LIBs) is crucial for environmental protection and resource sustainability.However,the economic recovery of spent LIBs remains challenging due to low Li recovery efficiency ...The recycling of spent lithium-ion batteries(LIBs) is crucial for environmental protection and resource sustainability.However,the economic recovery of spent LIBs remains challenging due to low Li recovery efficiency and the need for multiple separation operations.Here,we propose a process involving mixed HCl-H_(2)SO_(4) leaching-spray pyrolysis for recycling spent ternary LIBs,achieving both selective Li recovery and the preparation of a ternary oxide precursor.Specifically,the process transforms spent ternary cathode(LiNi_(x)Co_yMn_(2)O_(2),NCM) powder into Li_(2)SO_(4) solution and ternary oxide,which can be directly used for synthesizing battery-grade Li_(2)CO_(3) and NCM cathode,respectively.Notably,SO_(4)^(2-) selectively precipitates with Li^(+) to form thermostable Li_(2)SO_(4) during the spray pyrolysis,which substantially improves the Li recovery efficiency by inhibiting Li evaporation and intercalation.Besides,SO_(2) emissions are avoided by controlling the molar ratio of Li^(+)/SO_(4)^(2-)(≥2:1),The mechanism of the preferential formation of Li_(2)SO_(4) is interpreted from its reverse solubility variation with temperature.During the recycling of spent NCM811,92% of Li is selectively recovered,and the regenerated NCM811 exhibits excellent cycling stability with a capacity retention of 81.7% after 300 cycles at 1 C.This work offers a simple and robust process for the recycling of spent NCM cathodes.展开更多
Polymerflooding is an effective method widely applied for enhancing oil recovery(EOR)by reducing the mobility ratio between theinjected water and crude oil.However,traditional polymers encounter challenges in high sali...Polymerflooding is an effective method widely applied for enhancing oil recovery(EOR)by reducing the mobility ratio between theinjected water and crude oil.However,traditional polymers encounter challenges in high salinity reservoirs due to their salt sensitivity.Toovercome this challenge,we synthesized a zwitterion polymer(PAMNS)with salt-induced tackifying property through copolymerization ofacrylamide and a zwitterion monomer,methylacrylamide propyl-N,N-dimethylbutylsulfonate(NS).NS monomer is obtained from thereaction between 1,4-butanesultone and dimethylamino propyl methylacrylamide.In this study,the rheological properties,salt responsiveness,and EOR efficiency of PAMNS were evaluated.Results demonstrate that PAMNS exhibits desirable salt-induced tackifyingcharacteristics,with viscosity increasing up to 2.4 times as the NaCl concentration reaches a salinity of 30×10^(4)mg L^(-1).Furthermore,highvalence ions possess a much stronger effect on enhancing viscosity,manifested as Mg^(2+)>Ca^(2+)>Na^(+).Molecular dynamics simulations(MD)andfluid dynamics experiment results demonstrate that PAMNS molecules exhibit a more stretched state and enhanced intermolecularassociations in high-salinity environments.It is because of the salt-induced tackifying,PAMNS demonstrates superior performance inpolymerflooding experiments under salinity ranges from 5×10^(4)mg L^(-1)to 20×10^(4)mg L^(-1),leading to 10.38–19.83%higher EOR thantraditional polymers.展开更多
The intensive development of tight reservoirs has positioned them as a strategic alternative to conventional oil and gas resources. Existing enhanced oil recovery(EOR) methods struggle to effectively exploring reservo...The intensive development of tight reservoirs has positioned them as a strategic alternative to conventional oil and gas resources. Existing enhanced oil recovery(EOR) methods struggle to effectively exploring reservoir oil, resulting in low recovery rates. Novel and effective means of developing tight reservoirs are urgently needed. Nanomaterials have shown promising applications in improving water flooding efficiency, with in-depth research into mechanisms that lower injection pressure and increase water injection volumes. However, the extent of improvement remains limited. In this study, a silicon quantum dots(Si-QDs) material was synthesized via a hydrothermal synthesis method and used to prepare a nanofluid for the efficient recovery of tight reservoir. The Si-QDs, with an approximate diameter of 3 nm and a spherical structure, were surface functionalized with benzenesulfonic acid groups to enhance the performance. The developed nanofluid demonstrated stability without aggregation at 120℃ and a salinity of 60000 mg/L. Core flooding experiments have demonstrated the attractive EOR capabilities of Si-QDs, shedding light of the EOR mechanisms. Si-QDs effectively improve the wettability of rocks, enhancing the sweeping coefficient of injected fluids and expanding sweeping area.Within this sweeping region, Si-QDs efficiently stripping adsorbed oil from the matrix, thus increasing sweeping efficiency. Furthermore, Si-QDs could modify the state of pore-confined crude oil, breaking it down into smaller particles that are easier to displacement in subsequent stages. Si-QDs exhibit compelling EOR potential, positioning them as a promising approach for effectively developing tight oil reservoirs.展开更多
This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume i...This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume in horizontal well fracturing.A numerical model is established to investigate the production rate,reservoir pressure field,and CO_(2)saturation distribution corresponding to changing time of CO_(2)flooding with radial borehole fracturing.A sensitivity analysis on the influence of CO_(2)injection location,layer spacing,pressure difference,borehole number,and hydraulic fractures on oil production and CO_(2)storage is conducted.The CO_(2)flooding process is divided into four stages.Reductions in layer spacing will significantly improve oil production rate and gas storage capacity.However,serious gas channeling can occur when the spacing is lower than 20 m.Increasing the pressure difference between the producer and injector,the borehole number,the hydraulic fracture height,and the fracture width can also increase the oil production rate and gas storage rate.Sensitivity analysis shows that layer spacing and fracture height greatly influence gas storage and oil production.Research outcomes are expected to provide a theoretical basis for the efficient development of shale oil reservoirs in the vertical direction.展开更多
The load-bearing performance(LBP)of pumpable supports(PPS)is crucial for the stability of longwall pre-driven recovery room(PRR)surrounding rock.However,the unbalanced bearing coefficient(UBC)of the PPS(undertaking un...The load-bearing performance(LBP)of pumpable supports(PPS)is crucial for the stability of longwall pre-driven recovery room(PRR)surrounding rock.However,the unbalanced bearing coefficient(UBC)of the PPS(undertaking unequal load along the mining direction)has not been investigated.A mechanical model of the PRR was established,considering the main roof cantilever beam structure,to derive an assessment formula for the load,the failure criteria,and the UBC of the PPS.Subsequently,the generation mechanisms,and influencing factors of the UBC were revealed.Global sensitivity analysis shows that the main roof hanging length(l_(2))and the spacing between the PPS(r)significantly impact the UBC.A novel design of the PPS and the coupling control technology were proposed and applied to reduce the UBC of the PPS in the adjacent longwall PRR.Monitor results showed no failure of the PPS at the test site,with the UBC(ζ)reduced to 1.1 consistent with the design value(1.15)basically,fully utilizing the collaborative LBP of the PPS.Finally,the maximum roof-to-floor convergence of the PRR was 234 mm,effectively controlling the stability of the surrounding rock of the PRR and ensuring the mining equipment recovery.展开更多
Once a satellite experiences extreme abnormal conditions,it may face serious consequences such as structural damages,material low-temperature failures,propellant freezing,and even whole satellite failures if it is not...Once a satellite experiences extreme abnormal conditions,it may face serious consequences such as structural damages,material low-temperature failures,propellant freezing,and even whole satellite failures if it is not rescued in time.Therefore,it is significantly important to study emergency recovery technologies for satellites.The research progress on attitude determination and control technologies during satellite emergency recovery is reviewed in detail.Moreover,the research achievements in the design and implementation of satellite emergency modes are summarized.By synthesizing and analyzing relevant literature,this paper aims to provide reference and guidance for emergency recovery technologies in response to extremely abnormal satellite states.展开更多
CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fractio...CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fraction),while CO_(2) emulsion with high water cut has been rarely researched.In this paper,we carried out a comprehensive experimental study of using high water cut CO_(2)/H_(2)O emulsion for enhancing oil recovery.Firstly,a nonionic surfactant,alkyl glycosides(APG),was selected to stabilize CO_(2)/H_(2)O emulsion,and the corresponding morphology and stability were evaluated with a transparent PVT cell.Subsequently,plugging capacity and apparent viscosity of CO_(2)/H_(2)O emulsion were measured systematically by a sand pack displacement apparatus connected with a 1.95-m long capillary tube.Furthermore,a high water cut(40 vol%) CO_(2)/H_(2)O emulsion was selected for flooding experiments in a long sand pack and a core sample,and the oil recovery,the rate of oil recovery,and the pressure gradients were analyzed.The results indicated that APG had a good performance on emulsifying and stabilizing CO_(2) emulsion.An inversion from H_(2)O/CO_(2) emulsion to CO_(2)/H_(2)O emulsion with the increase in water cut was confirmed.CO_(2)/H_(2)O emulsions with lower water cuts presented higher apparent viscosity,while the optimal plugging capacity of CO_(2)/H_(2)O emulsion occurred at a certain water cut.Eventually,the displacement using CO_(2)/H_(2)O emulsion provided 18.98% and 13.36% additional oil recovery than that using pure CO_(2) in long sand pack and core tests,respectively.This work may provide guidelines for EOR using CO_(2) emulsions with high water cut.展开更多
Injecting CO_(2)when the gas reservoir of tight sandstone is depleted can achieve the dual purposes of greenhouse gas storage and enhanced gas recovery(CS-EGR).To evaluate the feasibility of CO_(2)injection to enhance...Injecting CO_(2)when the gas reservoir of tight sandstone is depleted can achieve the dual purposes of greenhouse gas storage and enhanced gas recovery(CS-EGR).To evaluate the feasibility of CO_(2)injection to enhance gas recovery and understand the production mechanism,a numerical simulation model of CS-EGR in multi-stage fracturing horizontal wells is established.The behavior of gas production and CO_(2)sequestration is then analyzed through numerical simulation,and the impact of fracture parameters on production performance is examined.Simulation results show that the production rate increases significantly and a large amount of CO_(2)is stored in the reservoir,proving the technical potential.However,hydraulic fractures accelerate CO_(2)breakthrough,resulting in lower gas recovery and lower CO_(2)storage than in gas reservoirs without fracturing.Increasing the length of hydraulic fractures can significantly increase CH4production,but CO_(2)breakthrough will advance.Staggered and spaced perforation of hydraulic fractures in injection wells and production wells changes the fluid flow path,which can delay CO_(2)breakthrough and benefit production efficiency.The fracture network of massive hydraulic fracturing has a positive effect on the CS-EGR.As a result,CH4production,gas recovery,and CO_(2)storage increase with the increase in stimulated reservoir volume.展开更多
基金supported by The National Natural Science Foundation of China(52170087,22276137).
文摘The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated operation.Here,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by self-crosslinking encapsulation method.MNMGH achieved high selectivity(K_(d)=23.31 mL/g)in the acidic range,and exhibited ultrahigh silver recovery capacity(1604.8 mg/g),which greatly improved by 66%with the assistance of in-situ magnetic field.The recovered silver crystals could be directly physically exfoliated,without acid/base additions.The selective sieving effect of adsorption,MNMGH preferentially adsorbed Ag(I),and then selectively reduced to Ag(0),realizing dual-selective recovery.The in-situ magnetic field enhanced selective adsorption by enhancing mass transfer,reactivity of oxygen-containing functional groups.Furthermore,density function theory simulations demonstrated that the in-situ magnetic field could lower the silver reduction reaction energy barrier to enhance the selective reduction.Three-drive synergy system(reduction drive,adsorption drive and magnetic drive)achieved ultrahigh silver recovery performance.This study pioneered an in-situ magnetic field assisted enhancement strategy for dual-selective(adsorption/reduction)recovery of precious metal silver,which provided new idea for low-carbon recovery of noble metal from industrial waste liquids.
基金Project supported by the Young Scientists Fund of the National Natural Science Foundation of China(Grant No.51502337)the Fund from China Academy of Space Technology
文摘Infrared detection technology has greatly expanded the ability of mankind to study the earth and the universe. In recent years, the demand for long-wavelength infrared detectors is increasing for their advantages in exploring the earth and the universe. A variety of long-wavelength infrared detectors have been made based on thermal resistive effect, photoelectric effect, etc., in the past few decades. Remarkable achievements have been made in infrared materials, device fabrication,readout circuit, and device package. However, high performance long-wavelength infrared detectors, especially those for large format long-wavelength infrared detector focus plane array, are still unsatisfactory. Low noise, high detectivity, and large format long-wavelength infrared detector is necessary to satisfy space-based application requirements.
基金the National Natural Science Foundation of Chi⁃na under Grant Nos.61671183 and 61771163.
文摘With the development of satellite communications,the number of satellite nodes is constantly increasing,which undoubtedly increases the difficulty of maintaining network security.Combining software defined network(SDN) with traditional space-based networks provides a new class of ideas for solving this problem.However,because of the highly centralized network management of the SDN controller,once the SDN controller is destroyed by network attacks,the network it manages will be paralyzed due to loss of control.One of the main security threats to SDN controllers is Distributed Denial of Service(DDoS) attacks,so how to detect DDoS attacks scientifically has become a hot topic among SDN security management.This paper proposes a DDoS attack detection method for space-based networks based on SDN architecture.This attack detection method combines the optimized Long Short-Term Memory(LSTM) deep learning model and Support Vector Machine(SVM),which can not only make classification judgments on the time series,but also achieve the purpose of detecting and judging through the flow characteristics of a period of time.In addition,it can reduce the detection time as well as the system burden.
基金supported by National Natural Science Foundation of China (No. 61821001)fully supported by Natural Science Foundation of China Project (61871422)+5 种基金Science and Technology Program of Sichuan Province (2020YFH0071)National Natural Science Foundation of China under Grant (61801319)in part by Sichuan Science and Technology Program under Grant (2020JDJQ0061), (2021YFG0099)in part by the Sichuan University of Science and Engineering Talent Introduction Project under Grant (2020RC33)Innovation Fund of Chinese Universities under Grant (2020HYA04001)Technology Key Project of Guangdong Province, China (2019B010157001)。
文摘In space-based Automatic Identification Systems(AIS), due to high satellite orbits, several Ad Hoc cells within the observation range of the satellite are vulnerable to interference by an external signal.To increase efficiency in target detection and improve system security, a blind source separation method is adopted for processing the conflicting signals received by satellites. Compared to traditional methods, we formulate the separation problem as a clustering problem. Since our algorithm is affected by the sparseness of source signals, to get satisfactory results, our algorithm assumes that the distance between two arbitrary mixed-signal vectors is less than the doubled sum of variances of distribution of the corresponding mixtures. Signal sparsity is overcome by computing the Short-Time Fourier Transform, and the mixed source signals are separated using the improved PSO clustering. We evaluated the performance and the robustness of the proposed network architecture by several simulations. The experimental results demonstrate the effectiveness of the proposed method in not only improving satellite signal receiving ability but also in enhancing space-based AIS security.
基金Supported by the PetroChina Science and Technology Major Project(2023ZZ04,2023ZZ08)。
文摘This paper reviews the basic research means for oilfield development and also the researches and tests of enhanced oil recovery(EOR)methods for mature oilfields and continental shale oil development,analyzes the problems of EOR methods,and proposes the relevant research prospects.The basic research means for oilfield development include in-situ acquisition of formation rock/fluid samples and non-destructive testing.The EOR methods for conventional and shale oil development are classified as improved water flooding(e.g.nano-water flooding),chemical flooding(e.g.low-concentration middle-phase micro-emulsion flooding),gas flooding(e.g.micro/nano bubble flooding),thermal recovery(e.g.air injection thermal-aided miscible flooding),and multi-cluster uniform fracturing/water-free fracturing,which are discussed in this paper for their mechanisms,approaches,and key technique researches and field tests.These methods have been studied with remarkable progress,and some achieved ideal results in field tests.Nonetheless,some problems still exist,such as inadequate research on mechanisms,imperfect matching technologies,and incomplete industrial chains.It is proposed to further strengthen the basic researches and expand the field tests,thereby driving the formation,promotion and application of new technologies.
基金financially supported by National Natural Science Foundation of China(No.22302229)Beijing Municipal Excellent Talent Training Funds Youth Advanced Individual Project(No.2018000020124G163)。
文摘Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs.
基金Supported by Basic and Forward-Looking Project of the Science and Technology Department of SINOPEC(P22213-4)。
文摘Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displacement mechanisms of shale oil extraction by CO_(2)injection,and the influences of CO_(2)pre-pad on shale mechanical properties.Numerical simulations were performed about influences of CO_(2)pre-pad fracturing and puff-n-huff for energy replenishment on the recovery efficiency.The findings obtained were applied to the field tests of CO_(2)pre-pad fracturing and single well puff-n-huff.The results show that the efficiency of CO_(2)puff-n-huff is affected by micro-and nano-scale effect,kerogen,adsorbed oil and so on,and a longer soaking time in a reasonable range leads to a higher exploitation degree of shale oil.In the"injection+soaking"stage,the exploitation degree of heavy hydrocarbons is enhanced by CO_(2)through its effects of solubility-diffusion and mass-transfer.In the"huff"stage,crude oil in large pores is displaced by CO_(2)to surrounding larger pores or bedding fractures and finally flows to the production well.The injection of CO_(2)pre-pad is conducive to keeping the rock brittle and reducing the fracture breakdown pressure,and the CO_(2)is liable to filter along the bedding surface,thereby creating a more complex fracture.Increasing the volume of CO_(2)pre-pad can improve the energizing effect,and enhance the replenishment of formation energy.Moreover,the oil recovery is more enhanced by CO_(2)huff-n-puff with the lower shale matrix permeability,the lower formation pressure,and the larger heavy hydrocarbon content.The field tests demonstrate a good performance with the pressure maintained well after CO_(2)pre-pad fracturing,the formation energy replenished effectively after CO_(2)huff-n-puff in a single well,and the well productivity improved.
基金supported by the National Key R&D Program of China(No.2023YFC2908200)National Natural Science Foundation of China(No.52174249)Key Research and Development Program of Jiangxi Province(No.20203BBGL73231).
文摘With the rise of artificial intelligence(AI)in mineral processing,predicting the flotation indexes has attracted significant research attention.Nevertheless,current prediction models suffer from low accuracy and high prediction errors.Therefore,this paper utilizes a two-step procedure.First,the outliers are pro-cessed using the box chart method and filtering algorithm.Then,the decision tree(DT),support vector regression(SVR),random forest(RF),and the bagging,boosting,and stacking integration algorithms are employed to construct a flotation recovery prediction model.Extensive experiments compared the prediction accuracy of six modeling methods on flotation recovery and delved into the impact of diverse base model combinations on the stacking model’s prediction accuracy.In addition,field data have veri-fied the model’s effectiveness.This study demonstrates that the stacking ensemble approaches,which uses ten variables to predict flotation recovery,yields a more favorable prediction effect than the bagging ensemble approach and single models,achieving MAE,RMSE,R2,and MRE scores of 0.929,1.370,0.843,and 1.229%,respectively.The hit rates,within an error range of±2%and±4%,are 82.4%and 94.6%.Consequently,the prediction effect is relatively precise and offers significant value in the context of actual production.
基金supported by National Key Research and Development Program of China(Grant No.2023YFB4104200)Liaoning Foundation Research Projects for Application(Grant No.2023JH2/101300005)National Natural Science Foundation of China(Grant No.51976024,52076030)。
文摘Carbonated water injection(CWI)is a promising enhanced oil recovery(EOR)technology that has received much attention in co-optimizing CO_(2) storage and oil recovery.This study provides a comprehensive review of the fluid system properties and the underlying changes in rock-fluid interactions that drive the CWI-EOR mechanisms.Previous research has indicated that CWI can enhance oil recovery by shifting reservoir wettability towards a more water-wet state and reducing interfacial tension(IFT).However,this study reveals that there is still room for discussion in this area.Notably,the potential of CWI to alter reservoir permeability has not yet been explored.The varying operational conditions of the CWI process,namely temperature,pressure,injection rate,salinity,and ionic composition,lead to different levels of oil recovery factors.Herein,we aim to meticulously analyze their impact on oil recovery performance and outline the optimal operational conditions.Pressure,for instance,positively influences oil recovery rate and CWI efficiency.On one hand,higher operating pressures enhance the effectiveness of CW due to increased CO_(2)solubility.On the other hand,gas exsolution events in depleted reservoirs provide additional energy for oil movement along gas growth pathways.However,CWI at high carbonation levels does not offer significant benefits over lower carbonation levels.Additionally,lower temperatures and injection rates correlate with higher recovery rates.Further optimization of solution chemistry is necessary to determine the maximum recovery rates under optimal conditions.Moreover,this review comprehensively covers laboratory experiments,numerical simulations,and field applications involving the CWI process.However,challenges such as pipeline corrosion,potential reservoir damage,and produced water treatment impact the further application of CWI in EOR technologies.These issues can affect the expected oil recovery rates,thereby reducing the economic returns of EOR projects.Finally,this review introduces current research trends and future development prospects based on recently published studies in the field of CWI.The conclusions of this study aid readers in better understanding the latest advancements in CWI technology and the strengths and limitations of the techniques used,providing directions for further development and application of CWI.
基金Fund of University of South China (201RGC013 and 200XQD052)。
文摘The recycling of spent lithium-ion batteries(LIBs) is crucial for environmental protection and resource sustainability.However,the economic recovery of spent LIBs remains challenging due to low Li recovery efficiency and the need for multiple separation operations.Here,we propose a process involving mixed HCl-H_(2)SO_(4) leaching-spray pyrolysis for recycling spent ternary LIBs,achieving both selective Li recovery and the preparation of a ternary oxide precursor.Specifically,the process transforms spent ternary cathode(LiNi_(x)Co_yMn_(2)O_(2),NCM) powder into Li_(2)SO_(4) solution and ternary oxide,which can be directly used for synthesizing battery-grade Li_(2)CO_(3) and NCM cathode,respectively.Notably,SO_(4)^(2-) selectively precipitates with Li^(+) to form thermostable Li_(2)SO_(4) during the spray pyrolysis,which substantially improves the Li recovery efficiency by inhibiting Li evaporation and intercalation.Besides,SO_(2) emissions are avoided by controlling the molar ratio of Li^(+)/SO_(4)^(2-)(≥2:1),The mechanism of the preferential formation of Li_(2)SO_(4) is interpreted from its reverse solubility variation with temperature.During the recycling of spent NCM811,92% of Li is selectively recovered,and the regenerated NCM811 exhibits excellent cycling stability with a capacity retention of 81.7% after 300 cycles at 1 C.This work offers a simple and robust process for the recycling of spent NCM cathodes.
基金support of the National Natural Science Foundation of China(No.52120105007)the National Key Research and Development Program of China(2019Y FA0708700)are gratefully acknowledged.
文摘Polymerflooding is an effective method widely applied for enhancing oil recovery(EOR)by reducing the mobility ratio between theinjected water and crude oil.However,traditional polymers encounter challenges in high salinity reservoirs due to their salt sensitivity.Toovercome this challenge,we synthesized a zwitterion polymer(PAMNS)with salt-induced tackifying property through copolymerization ofacrylamide and a zwitterion monomer,methylacrylamide propyl-N,N-dimethylbutylsulfonate(NS).NS monomer is obtained from thereaction between 1,4-butanesultone and dimethylamino propyl methylacrylamide.In this study,the rheological properties,salt responsiveness,and EOR efficiency of PAMNS were evaluated.Results demonstrate that PAMNS exhibits desirable salt-induced tackifyingcharacteristics,with viscosity increasing up to 2.4 times as the NaCl concentration reaches a salinity of 30×10^(4)mg L^(-1).Furthermore,highvalence ions possess a much stronger effect on enhancing viscosity,manifested as Mg^(2+)>Ca^(2+)>Na^(+).Molecular dynamics simulations(MD)andfluid dynamics experiment results demonstrate that PAMNS molecules exhibit a more stretched state and enhanced intermolecularassociations in high-salinity environments.It is because of the salt-induced tackifying,PAMNS demonstrates superior performance inpolymerflooding experiments under salinity ranges from 5×10^(4)mg L^(-1)to 20×10^(4)mg L^(-1),leading to 10.38–19.83%higher EOR thantraditional polymers.
基金the financial support from the National Natural Science Foundation of China (Nos. 52074249, 51874261, 52304011)。
文摘The intensive development of tight reservoirs has positioned them as a strategic alternative to conventional oil and gas resources. Existing enhanced oil recovery(EOR) methods struggle to effectively exploring reservoir oil, resulting in low recovery rates. Novel and effective means of developing tight reservoirs are urgently needed. Nanomaterials have shown promising applications in improving water flooding efficiency, with in-depth research into mechanisms that lower injection pressure and increase water injection volumes. However, the extent of improvement remains limited. In this study, a silicon quantum dots(Si-QDs) material was synthesized via a hydrothermal synthesis method and used to prepare a nanofluid for the efficient recovery of tight reservoir. The Si-QDs, with an approximate diameter of 3 nm and a spherical structure, were surface functionalized with benzenesulfonic acid groups to enhance the performance. The developed nanofluid demonstrated stability without aggregation at 120℃ and a salinity of 60000 mg/L. Core flooding experiments have demonstrated the attractive EOR capabilities of Si-QDs, shedding light of the EOR mechanisms. Si-QDs effectively improve the wettability of rocks, enhancing the sweeping coefficient of injected fluids and expanding sweeping area.Within this sweeping region, Si-QDs efficiently stripping adsorbed oil from the matrix, thus increasing sweeping efficiency. Furthermore, Si-QDs could modify the state of pore-confined crude oil, breaking it down into smaller particles that are easier to displacement in subsequent stages. Si-QDs exhibit compelling EOR potential, positioning them as a promising approach for effectively developing tight oil reservoirs.
基金This study has been funded by the National Science Fund for Distinguished Young Scholars(No.52204063)Science Foundation of China University of Petroleum,Beijing(No.2462023BJRC025).Moreover,we would like to express our heartfelt appreciation to the Computational Geosciences group in the Department of Mathematics and Cybernetics at SINTEF Digital for developing and providing the free open-source MATLAB Reservoir Simulation Toolbox(MRST)used in this research.
文摘This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume in horizontal well fracturing.A numerical model is established to investigate the production rate,reservoir pressure field,and CO_(2)saturation distribution corresponding to changing time of CO_(2)flooding with radial borehole fracturing.A sensitivity analysis on the influence of CO_(2)injection location,layer spacing,pressure difference,borehole number,and hydraulic fractures on oil production and CO_(2)storage is conducted.The CO_(2)flooding process is divided into four stages.Reductions in layer spacing will significantly improve oil production rate and gas storage capacity.However,serious gas channeling can occur when the spacing is lower than 20 m.Increasing the pressure difference between the producer and injector,the borehole number,the hydraulic fracture height,and the fracture width can also increase the oil production rate and gas storage rate.Sensitivity analysis shows that layer spacing and fracture height greatly influence gas storage and oil production.Research outcomes are expected to provide a theoretical basis for the efficient development of shale oil reservoirs in the vertical direction.
基金financial support provided by the Xinjiang Uygur Autonomous Region Key R&D Project Task Special-Department and Department Linkage Project(No.2022B01051)Major Project of Regional Joint Foundation of China(No.U21A20107)+1 种基金Hunan Provincial Natural Science Foundation of China(No.2024JJ4021)the Xinjiang Uygur Autonomous Region Tianchi Introduction Plan(No.2024XGYTCYC03)。
文摘The load-bearing performance(LBP)of pumpable supports(PPS)is crucial for the stability of longwall pre-driven recovery room(PRR)surrounding rock.However,the unbalanced bearing coefficient(UBC)of the PPS(undertaking unequal load along the mining direction)has not been investigated.A mechanical model of the PRR was established,considering the main roof cantilever beam structure,to derive an assessment formula for the load,the failure criteria,and the UBC of the PPS.Subsequently,the generation mechanisms,and influencing factors of the UBC were revealed.Global sensitivity analysis shows that the main roof hanging length(l_(2))and the spacing between the PPS(r)significantly impact the UBC.A novel design of the PPS and the coupling control technology were proposed and applied to reduce the UBC of the PPS in the adjacent longwall PRR.Monitor results showed no failure of the PPS at the test site,with the UBC(ζ)reduced to 1.1 consistent with the design value(1.15)basically,fully utilizing the collaborative LBP of the PPS.Finally,the maximum roof-to-floor convergence of the PRR was 234 mm,effectively controlling the stability of the surrounding rock of the PRR and ensuring the mining equipment recovery.
基金supported by the Na⁃tional Natural Science Foundation of China(No.62373125).
文摘Once a satellite experiences extreme abnormal conditions,it may face serious consequences such as structural damages,material low-temperature failures,propellant freezing,and even whole satellite failures if it is not rescued in time.Therefore,it is significantly important to study emergency recovery technologies for satellites.The research progress on attitude determination and control technologies during satellite emergency recovery is reviewed in detail.Moreover,the research achievements in the design and implementation of satellite emergency modes are summarized.By synthesizing and analyzing relevant literature,this paper aims to provide reference and guidance for emergency recovery technologies in response to extremely abnormal satellite states.
基金The financial supports received from the National Natural Science Foundation of China(Nos.22178378,22127812)。
文摘CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fraction),while CO_(2) emulsion with high water cut has been rarely researched.In this paper,we carried out a comprehensive experimental study of using high water cut CO_(2)/H_(2)O emulsion for enhancing oil recovery.Firstly,a nonionic surfactant,alkyl glycosides(APG),was selected to stabilize CO_(2)/H_(2)O emulsion,and the corresponding morphology and stability were evaluated with a transparent PVT cell.Subsequently,plugging capacity and apparent viscosity of CO_(2)/H_(2)O emulsion were measured systematically by a sand pack displacement apparatus connected with a 1.95-m long capillary tube.Furthermore,a high water cut(40 vol%) CO_(2)/H_(2)O emulsion was selected for flooding experiments in a long sand pack and a core sample,and the oil recovery,the rate of oil recovery,and the pressure gradients were analyzed.The results indicated that APG had a good performance on emulsifying and stabilizing CO_(2) emulsion.An inversion from H_(2)O/CO_(2) emulsion to CO_(2)/H_(2)O emulsion with the increase in water cut was confirmed.CO_(2)/H_(2)O emulsions with lower water cuts presented higher apparent viscosity,while the optimal plugging capacity of CO_(2)/H_(2)O emulsion occurred at a certain water cut.Eventually,the displacement using CO_(2)/H_(2)O emulsion provided 18.98% and 13.36% additional oil recovery than that using pure CO_(2) in long sand pack and core tests,respectively.This work may provide guidelines for EOR using CO_(2) emulsions with high water cut.
基金the financial support of the National Natural Science Foundation of China(Grant No.52304018)China Postdoctoral Science Foundation(Grant No.2023TQ0014,Grant No.2023M730088)。
文摘Injecting CO_(2)when the gas reservoir of tight sandstone is depleted can achieve the dual purposes of greenhouse gas storage and enhanced gas recovery(CS-EGR).To evaluate the feasibility of CO_(2)injection to enhance gas recovery and understand the production mechanism,a numerical simulation model of CS-EGR in multi-stage fracturing horizontal wells is established.The behavior of gas production and CO_(2)sequestration is then analyzed through numerical simulation,and the impact of fracture parameters on production performance is examined.Simulation results show that the production rate increases significantly and a large amount of CO_(2)is stored in the reservoir,proving the technical potential.However,hydraulic fractures accelerate CO_(2)breakthrough,resulting in lower gas recovery and lower CO_(2)storage than in gas reservoirs without fracturing.Increasing the length of hydraulic fractures can significantly increase CH4production,but CO_(2)breakthrough will advance.Staggered and spaced perforation of hydraulic fractures in injection wells and production wells changes the fluid flow path,which can delay CO_(2)breakthrough and benefit production efficiency.The fracture network of massive hydraulic fracturing has a positive effect on the CS-EGR.As a result,CH4production,gas recovery,and CO_(2)storage increase with the increase in stimulated reservoir volume.
