Metal-free organic emitters,characterized by their thermally activated delayed fluorescence(TADF)properties,offer considerable promise for the creation of highly efficient organic light-emitting diodes(OLEDs).Recently...Metal-free organic emitters,characterized by their thermally activated delayed fluorescence(TADF)properties,offer considerable promise for the creation of highly efficient organic light-emitting diodes(OLEDs).Recently,Shao et al.presented a novel excited state intramolecular proton transfer(ESIPT)system BrA-HBI,demonstrating an emission quantum yield of up to 50%[Adv.Funct.Mater.32,2201256(2022)].However,many open issues cannot be answered solely by experimental means only and require detailed theoretical investigations.For instance,what causes the activation of TADF from the Keto^(*) tautomer and leads to fluorescence quenching in the Enol^(*)form?Herein,we provide a theoretical investigation on the TADF mechanism of the BrA-HBI molecule by optimally tuned range-separated functionals.Our findings reveal that ESIPT occurs in the BrA-HBI molecule.Moreover,we have disclosed the reason for the fluorescence quenching of the Enol^(*)form and determined that the T_(2)state plays a dominant role in the TADF phenomenon.In addition,double hybrid density functionals method was utilized to verify the reliability of optimally tuned range separation functionals on the calculation of the TADF mechanism in BrA-HBI.These findings not only provide a theoretical reference for development of highly efficient organic light-emitting diodes,but also demonstrate the effectiveness of the optimally tuned range-separated functionals in predicting the luminescence properties of TADF molecules.展开更多
Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic...Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.展开更多
By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ODE method is developed for solving the mKdV-sinh-Gordon equation. As a result, many explicit and exact sol...By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ODE method is developed for solving the mKdV-sinh-Gordon equation. As a result, many explicit and exact solutions including some new formal solutions are successfully picked up for the mKdV-sinh-Gordon equation by this approach.展开更多
This article outlines the development of downhole monitoring and data transmission technology for separated zone water injection in China.According to the development stages,the principles,operation processes,adaptabi...This article outlines the development of downhole monitoring and data transmission technology for separated zone water injection in China.According to the development stages,the principles,operation processes,adaptability and application status of traditional downhole data acquisition method,cable communications and testing technology,cable-controlled downhole parameter real-time monitoring communication method and downhole wireless communication technology are introduced in detail.Problems and challenges of existing technologies in downhole monitoring and data transmission technology are pointed out.According to the production requirement,the future development direction of the downhole monitoring and data transmission technology for separated zone water injection is proposed.For the large number of wells adopting cable measuring and adjustment technology,the key is to realize the digitalization of downhole plug.For the key monitoring wells,cable-controlled communication technology needs to be improved,and downhole monitoring and data transmission technology based on composite coiled tubing needs to be developed to make the operation more convenient and reliable.For large-scale application in oil fields,downhole wireless communication technology should be developed to realize automation of measurement and adjustment.In line with ground mobile communication network,a digital communication network covering the control center,water distribution station and oil reservoir should be built quickly to provide technical support for the digitization of reservoir development.展开更多
An investigation of the decoupled thermal–hydraulic analysis of a separated heat pipe spent fuel pool passive cooling system(SFS)is essential for practical engineering applications.Based on the principles of thermal ...An investigation of the decoupled thermal–hydraulic analysis of a separated heat pipe spent fuel pool passive cooling system(SFS)is essential for practical engineering applications.Based on the principles of thermal and mass balance,this study decoupled the heat transfer processes in the SFS.In accordance with the decoupling conditions,we modeled the spent fuel pool of the CAP1400 pressurized water reactor in Weihai and used computational fluid dynamics to explore the heat dissipation capacity of the SFS under different air temperatures and wind speeds.The results show that the air-cooled separated heat pipe radiator achieved optimal performance at an air temperature of 10℃ or wind speed of 8 m/s.Fitted equations for the equivalent thermal conductivity of the separated heat pipes with the wind speed and air temperature we obtained according to the thermal resistance network model.This study is instructive for the actual operation of an SFS.展开更多
This article outlines the development of separated zone oil production in foreign countries,and details its development in China.According to the development process,production needs,technical characteristics and adap...This article outlines the development of separated zone oil production in foreign countries,and details its development in China.According to the development process,production needs,technical characteristics and adaptability of oilfields in China,the development of separate zone oil production technology is divided into four stages:flowing well zonal oil production,mechanical recovery and water blocking,hydraulically adjustable zonal oil production,and intelligent zonal production.The principles,construction processes,adaptability,advantages and disadvantages of the technology are introduced in detail.Based on the actual production situation of the oilfields in China at present,three development directions of the technology are proposed.First,the real-time monitoring and adjustment level of separated zone oil production needs to be improved by developing downhole sensor technology and two-way communication technology between ground and downhole and enhancing full life cycle service capability and adaptability to horizontal wells.Second,an integrated platform of zonal oil production and management should be built using a digital artificial lifting system.Third,integration of injection and production should be implemented through large-scale application of zonal oil production and zonal water injection to improve matching and adjustment level between the injection and production parameters,thus making the development adjustment from"lag control"to"real-time optimization"and improving the development effect.展开更多
Endophytic fungi are widely found in almost all kinds of plants. Many endophytic fungi can produce some physio-logical active compounds, which are same to or analog to those isolated from their hosts. Producing physio...Endophytic fungi are widely found in almost all kinds of plants. Many endophytic fungi can produce some physio-logical active compounds, which are same to or analog to those isolated from their hosts. Producing physiological active com-pounds through microbial fermentation can give a new way to resolve resource limitation and to find out alternative source. Through the methods of organic solvent extraction, thin layer chromatography (TLC) and column chromatography, compound I was isolated, purified from the liquid fermentation metabolites of the taxoids-produced endophytic fungi (Alternaria. alternata var. taxi 1011 Y. Xiang et LU An-guo) that was screened from the bark of Taxus. cuspidata Sieb.et Zucc.. Compound I was identified as one kind of taxoids type III, based on the analyzing results by using the methods of ultraviolet spectroscopy (UV), infrared spectroscopy (IR), mass spectrometry (MS) and nuclear magnetic resonance spectroscopy (NMR). This study provides a com-pleted method for separation and purification of the endophytic fungi as well as structure identification of its fermentation me-tabolite展开更多
By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ordinary differential equation method is presented for solving the （2 ＋ 1）-dimensional sine-Poisson equa...By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ordinary differential equation method is presented for solving the （2 ＋ 1）-dimensional sine-Poisson equation. As a result, many explicit and exact solutions of the （2 ＋ 1）-dimensional sine-Poisson equation are derived in a simple manner by this technique.展开更多
Control of purity and entanglement of two two-qubits dispersively coupled to a field with a reservoir are investigated.Initially the qubits are entangled,while the field is either in a coherent state or a statistical ...Control of purity and entanglement of two two-qubits dispersively coupled to a field with a reservoir are investigated.Initially the qubits are entangled,while the field is either in a coherent state or a statistical mixture of two coherent states.For an alternative entanglement measure we calculate the negativity of the eigenvalues of the partially transposed density matrix.A measure related to the mutual entropy,namely the index of entropy,is employed to measure the entanglement.Its results agree well with the negativity.It is found that the entanglement and purity have strong sensitivity to phase damping.The asymptotic behaviour of the states of the field,the two two-qubits,and the total system fall into mixed states.展开更多
A recent article in the Opto-Electronic Advances(OEA)journal from Prof.Qian Chen and Prof.Chao Zuo’s group introduced a new and efficient 3D imaging system that captures high-speed images using deep learning-enabled ...A recent article in the Opto-Electronic Advances(OEA)journal from Prof.Qian Chen and Prof.Chao Zuo’s group introduced a new and efficient 3D imaging system that captures high-speed images using deep learning-enabled fringe projection profilometry(FPP).In this News&Views article,we explore potential avenues for future advancements,including expanding the measurement range through an extended number-theoretical approach,enhancing quality through the incorporation of horizontal fringes,and integrating data from other modalities to broaden the system's applications.展开更多
It is well known that -nitride semiconductors can generate the magnitude of MV/cm polarization electric field which is comparable with their ionization electric fields. To take full advantage of the polarization elect...It is well known that -nitride semiconductors can generate the magnitude of MV/cm polarization electric field which is comparable with their ionization electric fields. To take full advantage of the polarization electric field, we design an N-face AlGaN solar-blind avalanche photodiode (APD) with an Al<sub>0.45</sub>Ga<sub>0.55</sub>N/Al<sub>0.3</sub>Ga<sub>0.7</sub>N heterostructure as separate absorption and multiplication (SAM) regions. The simulation results show that the N-face APDs are more beneficial to improving the avalanche gain and reducing the avalanche breakdown voltage compared with the Ga-face APDs due to the effect of the polarization electric field. Furthermore, the Al<sub>0.45</sub>Ga<sub>0.55</sub>N/Al<sub>0.3</sub>Ga<sub>0.7</sub>N heterostructure SAM regions used in APDs instead of homogeneous Al<sub>0.45</sub>Ga<sub>0.55</sub>N SAM structure can increase significantly avalanche gain because of the increased hole ionization coefficient by using the relatively low Al-content AlGaN in the multiplication region. Meanwhile, a quarter-wave AlGaN/AlN distributed Bragg reflector structure at the bottom of the device is designed to remain a solar-blind characteristic of the heterostructure SAM-APDs.展开更多
In this paper,we discuss the separateness in topological molecular lattices (TML) by the molecular stratums given in [1] and [2],deal with the relationship between the compactness and separateness.
This paper presents experimental results of cocracking of straight-run gasoline (SRG) and light gaS oil (LGO) in an improved pulsed-micro-pyrolyzer. It is shown that there are negative opergistic effect on the yields ...This paper presents experimental results of cocracking of straight-run gasoline (SRG) and light gaS oil (LGO) in an improved pulsed-micro-pyrolyzer. It is shown that there are negative opergistic effect on the yields and selectivities of ethylene and propylene in cocracking. The difference in coking tendencies betWeen the cocracking and the separate cracking is compared as well.展开更多
The efficiency of photocatalytic overall water splitting was mainly limited by the slow reaction kinetics of water oxidation.How to design effective surface active site to overcome the slow water oxidation reaction wa...The efficiency of photocatalytic overall water splitting was mainly limited by the slow reaction kinetics of water oxidation.How to design effective surface active site to overcome the slow water oxidation reaction was a major challenge.Here,we propose a strategy to accelerate surface water oxidation through the fabrication spatially separated double active sites.FeCoPi/Bi_(4)NbO_(8)Cl-OVs photocatalyst with spatially separated double active site was prepared by hydrogen reduction photoanode deposition method.Due to the high matching of the spatial loading positions of FeCoPi and OVs with the photogenerated charge distribution of Bi_(4)NbO_(8)Cl and corresponding reaction mechanisms of substrate,the FeCoPi and OVs on the(001)and(010)crystal planes of Bi_(4)NbO_(8)Cl photocatalyst provided surface active site for water oxidation reaction and electron shuttle reaction(Fe^(3+)/Fe^(2+)),respectively.Under visible light irradiation,the evolution O_(2)rate of FeCoPi/Bi_(4)NbO_(8)Cl OVs was 16.8μmol h^(-1),as 32.9 times as Bi_(4)NbO_(8)Cl.Furthermore,a hydrogen evolution co-catalyst PtRu@Cr_(2)O_(3)was prepared by sequential photodeposition method.Due to the introduction of Ru,the Schottky barrier between PbTiO_(3)and Pt was effectively reduced,which promoted the transfer of photogenerated electrons to PtRu@Cr_(2)O_(3)thermodynamically,the evolution H_(2)rate on PtRu@Cr_(2)O_(3)/PbTiO_(3)increased to 664.8 times.On based of the synchronous enhancement of the water oxidation performance on FeCoPi/Bi_(4)NbO_(8)Cl-OVs and water reduction performance on PtRu@Cr_(2)O_(3)/PbTiO_(3),a novel Z-Scheme photocatalytic overall water splitting system(FeCoPi/Bi_(4)NbO_(8)Cl-OVs)mediated by Fe^(3+)/Fe^(2+)had successfully constructed.Under visible light irradiation,the evolution rates of H_(2)and O_(2)were 2.5 and 1.3μmol h^(-1),respectively.This work can provide some reference for the design of active site and the controllable synthesis of OVs spatial position.On the other hand,the hydrogen evolution co catalyst(PtRu@Cr_(2)O_(3))and the co catalyst FeCoPi for oxygen evolution contributed to the construction of an overall water splitting system.展开更多
Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used...Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used as a medium to separate coal bed methane by fluidifying the solid adsorbent material.The sorption equilibrium experiment of binary mixture(CH_4/N_2)and slurry was conducted.The selectivity of CH_4 to N_2 is within the range of 2-6,which proved the feasibility of the slurry separation method.The modified Langmuir equation was used to describe the gas-slurry phase equilibrium behavior,and the calculated results were in good agreement with the experimental data.A continuous absorption-adsorption and desorption process on the separation of CH_4/N_2 in slurry is proposed and its mathematical model is also developed.Sensitivity analysis is conducted to determine the operation conditions and the energy performance of the proposed process was also evaluated.Feed gas contains 30 mol%of methane and the methane concentration in product gas is 95.46 mol%with the methane recovery ratio of 90.74%.The total energy consumption for per unit volume of product gas is determined as 1.846 kWh Nm^(-3).Experimental results and process simulation provide basic data for the design and operation of pilot and industrial plant.展开更多
The concept of α-CT2 separation L-fuzzy subsets in L-fuzzy topological spaces is presented by taking the stratiform structure of L-fuzzy subsets as the point of departure,and its basic characterizations and some topo...The concept of α-CT2 separation L-fuzzy subsets in L-fuzzy topological spaces is presented by taking the stratiform structure of L-fuzzy subsets as the point of departure,and its basic characterizations and some topological properties are discussed,and the relation between it and other separateness is exposed,and the action is studied of α-CT2 separateness in N-compact spaces and N-paracompact spaces.展开更多
The locator/ID separation paradigm has been widely discussed to resolve the serious scalability issue that today's Internet is facing. Many researches have been carried on with this issue to alleviate the routing ...The locator/ID separation paradigm has been widely discussed to resolve the serious scalability issue that today's Internet is facing. Many researches have been carried on with this issue to alleviate the routing burden of the Default Free Zone (DFZ), improve the traffic engineering capabilities and support efficient mobility and multi-homing. However, in the locator/ID split networks, a third party is needed to store the identifier-to-locator pairs. How to map identifiers onto locators in a scalable and secure way is a really critical challenge. In this paper, we propose SS-MAP, a scalable and secure locator/ID mapping scheme for future Internet. First, SS-MAP uses a near-optimal DHT to map identifiers onto locators, which is able to achieve the maximal performance of the system with reasonable maintenance overhead relatively. Second, SS-MAP uses a decentralized admission control system to protect the DHT-based identifier-to-locator mapping from Sybil attacks, where a malicious mapping server creates numerous fake identities (called Sybil identifiers) to control a large fraction of the mapping system. This is the first work to discuss the Sybil attack problem in identifier-to-locator mapping mechanisms with the best knowledge of the authors. We evaluate the performance of the proposed approach in terms of scalability and security. The analysis and simulation results show that the scheme is scalable for large size networks and can resistant to Sybil attacks.展开更多
A three-terminal device based on electronic phase separated manganites is suggested to produce high performance resistive switching. Our Monte Carlo simulations reveal that the conductive filaments can be formed/annih...A three-terminal device based on electronic phase separated manganites is suggested to produce high performance resistive switching. Our Monte Carlo simulations reveal that the conductive filaments can be formed/annihilated by reshaping the ferromagnetic metal phase domains with two cross-oriented switching voltages. Besides, by controlling the high resistance state（HRS） to a stable state that just after the filament is ruptured, the resistive switching remains stable and reversible, while the switching voltage and the switching time can be greatly reduced.展开更多
The effect of nanosecond pulsed dielectric barrier discharge(NS-DBD) plasma flow separation control is closely related to the actuation frequency,because it involves the interaction between plasma-induced vortexes and...The effect of nanosecond pulsed dielectric barrier discharge(NS-DBD) plasma flow separation control is closely related to the actuation frequency,because it involves the interaction between plasma-induced vortexes and separated flow.In order to study the mechanism of NS-DBD plasma flow separation control over a swept wing,especially the influence of the actuation frequency,at first,experimental studies of the actuation frequencies at 100 Hz are conducted to validate the numerical simulation method.Then,numerical studies of different actuation frequencies which are 50 Hz,100 Hz,160 Hz,200 Hz,500 Hz,and 1000 Hz,respectively are conducted.The interaction between the plasma-induced vortexes and the separated flow is analyzed.Results show that there is a range of the actuation frequency which includes the frequency(160 Hz) calculated by the average aerodynamic chord length to make the control effect good,but when the actuation frequencies are too low(50 Hz) or too high(1000 Hz),the control effect will get worse.The former is because plasmainduced vortexes disappear in a period within an actuation cycle;the latter is because plasma-induced vortexes cannot develop completely,resulting in a weak vortex intensity.展开更多
The photoluminescence（PL） properties of a green and blue light-emitting InGaN/GaN multiple quantum well structure with a strong phase separated into quasi-quantum dots（QDs） and an InGaN matrix in the InGaN epilaye...The photoluminescence（PL） properties of a green and blue light-emitting InGaN/GaN multiple quantum well structure with a strong phase separated into quasi-quantum dots（QDs） and an InGaN matrix in the InGaN epilayer are investigated.The excitation power dependences of QD-related green emissions（PD〉） and matrix-related blue emissions（PM） in the low excitation power range of the PL peak energy and line-width indicate that at 6 K both Pm and PD are dominated by the combined action of Coulomb screening and localized state filling effect.However,at 300 K,Pm is dominated by the non-radiative recombination of the carriers in the InGaN matrix,while PD is influenced by the carriers transferred from the shallower QDs to deeper QDs by tunnelling.This is consistent with the excitation power dependence of the PL efficiency for the emission.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.12174149)。
文摘Metal-free organic emitters,characterized by their thermally activated delayed fluorescence(TADF)properties,offer considerable promise for the creation of highly efficient organic light-emitting diodes(OLEDs).Recently,Shao et al.presented a novel excited state intramolecular proton transfer(ESIPT)system BrA-HBI,demonstrating an emission quantum yield of up to 50%[Adv.Funct.Mater.32,2201256(2022)].However,many open issues cannot be answered solely by experimental means only and require detailed theoretical investigations.For instance,what causes the activation of TADF from the Keto^(*) tautomer and leads to fluorescence quenching in the Enol^(*)form?Herein,we provide a theoretical investigation on the TADF mechanism of the BrA-HBI molecule by optimally tuned range-separated functionals.Our findings reveal that ESIPT occurs in the BrA-HBI molecule.Moreover,we have disclosed the reason for the fluorescence quenching of the Enol^(*)form and determined that the T_(2)state plays a dominant role in the TADF phenomenon.In addition,double hybrid density functionals method was utilized to verify the reliability of optimally tuned range separation functionals on the calculation of the TADF mechanism in BrA-HBI.These findings not only provide a theoretical reference for development of highly efficient organic light-emitting diodes,but also demonstrate the effectiveness of the optimally tuned range-separated functionals in predicting the luminescence properties of TADF molecules.
基金Supported by the Major Science and Technology Project of CNPC(2023ZZ19-01).
文摘Based on the waterflooding development in carbonate reservoirs in the Middle East,in order to solve the problem of the poor development effects caused by commingled injection and production,taking the thick bioclastic limestone reservoirs of Cretaceous in Iran-Iraq as an example,this paper proposes a balanced waterflooding development technology for thick and complex carbonate reservoirs.This technology includes the fine division of development units by concealed baffles and barriers,the combination of multi well type and multi well pattern,and the construction of balanced water injection and recovery system.Thick carbonate reservoirs in Iran-Iraq are characterized by extremely vertical heterogeneity,development of multi-genesis ultra-high permeability zones,and highly concealed baffles and barriers.Based on the technologies of identification,characterization,and sealing evaluation for concealed baffles and barriers,the balanced waterflooding development technology is proposed,and three types of balanced waterflooding development modes/techniques are formed,namely,conventional stratigraphic framework,fine stratigraphic framework,and deepened stratigraphic framework.Numerical simulations show that this technology is able to realize a fine and efficient waterflooding development to recover,in a balanced manner,the reserves of thick and complex carbonate reservoirs in Iran and Iraq.The proposed technology provides a reference for the development optimization of similar reservoirs.
基金Project supported by the National Natural Science Foundation of China (Grant No 10672053)
文摘By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ODE method is developed for solving the mKdV-sinh-Gordon equation. As a result, many explicit and exact solutions including some new formal solutions are successfully picked up for the mKdV-sinh-Gordon equation by this approach.
基金Supported by the National Natural Science Foundation Science Center Project/Basic Science Center Project(72088101)PetroChina Scientific Research and Technology Development Project(2020B-4119,2021ZG12).
文摘This article outlines the development of downhole monitoring and data transmission technology for separated zone water injection in China.According to the development stages,the principles,operation processes,adaptability and application status of traditional downhole data acquisition method,cable communications and testing technology,cable-controlled downhole parameter real-time monitoring communication method and downhole wireless communication technology are introduced in detail.Problems and challenges of existing technologies in downhole monitoring and data transmission technology are pointed out.According to the production requirement,the future development direction of the downhole monitoring and data transmission technology for separated zone water injection is proposed.For the large number of wells adopting cable measuring and adjustment technology,the key is to realize the digitalization of downhole plug.For the key monitoring wells,cable-controlled communication technology needs to be improved,and downhole monitoring and data transmission technology based on composite coiled tubing needs to be developed to make the operation more convenient and reliable.For large-scale application in oil fields,downhole wireless communication technology should be developed to realize automation of measurement and adjustment.In line with ground mobile communication network,a digital communication network covering the control center,water distribution station and oil reservoir should be built quickly to provide technical support for the digitization of reservoir development.
文摘An investigation of the decoupled thermal–hydraulic analysis of a separated heat pipe spent fuel pool passive cooling system(SFS)is essential for practical engineering applications.Based on the principles of thermal and mass balance,this study decoupled the heat transfer processes in the SFS.In accordance with the decoupling conditions,we modeled the spent fuel pool of the CAP1400 pressurized water reactor in Weihai and used computational fluid dynamics to explore the heat dissipation capacity of the SFS under different air temperatures and wind speeds.The results show that the air-cooled separated heat pipe radiator achieved optimal performance at an air temperature of 10℃ or wind speed of 8 m/s.Fitted equations for the equivalent thermal conductivity of the separated heat pipes with the wind speed and air temperature we obtained according to the thermal resistance network model.This study is instructive for the actual operation of an SFS.
基金Supported by the National Key Research and Development Program of China(2018YFE0196000)National Science and Technology Major Project of China(2016ZX05010-006)CNPC Scientific Research and Technical Development Project(2019B-4113)
文摘This article outlines the development of separated zone oil production in foreign countries,and details its development in China.According to the development process,production needs,technical characteristics and adaptability of oilfields in China,the development of separate zone oil production technology is divided into four stages:flowing well zonal oil production,mechanical recovery and water blocking,hydraulically adjustable zonal oil production,and intelligent zonal production.The principles,construction processes,adaptability,advantages and disadvantages of the technology are introduced in detail.Based on the actual production situation of the oilfields in China at present,three development directions of the technology are proposed.First,the real-time monitoring and adjustment level of separated zone oil production needs to be improved by developing downhole sensor technology and two-way communication technology between ground and downhole and enhancing full life cycle service capability and adaptability to horizontal wells.Second,an integrated platform of zonal oil production and management should be built using a digital artificial lifting system.Third,integration of injection and production should be implemented through large-scale application of zonal oil production and zonal water injection to improve matching and adjustment level between the injection and production parameters,thus making the development adjustment from"lag control"to"real-time optimization"and improving the development effect.
文摘Endophytic fungi are widely found in almost all kinds of plants. Many endophytic fungi can produce some physio-logical active compounds, which are same to or analog to those isolated from their hosts. Producing physiological active com-pounds through microbial fermentation can give a new way to resolve resource limitation and to find out alternative source. Through the methods of organic solvent extraction, thin layer chromatography (TLC) and column chromatography, compound I was isolated, purified from the liquid fermentation metabolites of the taxoids-produced endophytic fungi (Alternaria. alternata var. taxi 1011 Y. Xiang et LU An-guo) that was screened from the bark of Taxus. cuspidata Sieb.et Zucc.. Compound I was identified as one kind of taxoids type III, based on the analyzing results by using the methods of ultraviolet spectroscopy (UV), infrared spectroscopy (IR), mass spectrometry (MS) and nuclear magnetic resonance spectroscopy (NMR). This study provides a com-pleted method for separation and purification of the endophytic fungi as well as structure identification of its fermentation me-tabolite
基金Project supported by the National Natural Science Foundation of China (Grant No. 10672053)
文摘By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ordinary differential equation method is presented for solving the （2 ＋ 1）-dimensional sine-Poisson equation. As a result, many explicit and exact solutions of the （2 ＋ 1）-dimensional sine-Poisson equation are derived in a simple manner by this technique.
文摘Control of purity and entanglement of two two-qubits dispersively coupled to a field with a reservoir are investigated.Initially the qubits are entangled,while the field is either in a coherent state or a statistical mixture of two coherent states.For an alternative entanglement measure we calculate the negativity of the eigenvalues of the partially transposed density matrix.A measure related to the mutual entropy,namely the index of entropy,is employed to measure the entanglement.Its results agree well with the negativity.It is found that the entanglement and purity have strong sensitivity to phase damping.The asymptotic behaviour of the states of the field,the two two-qubits,and the total system fall into mixed states.
文摘A recent article in the Opto-Electronic Advances(OEA)journal from Prof.Qian Chen and Prof.Chao Zuo’s group introduced a new and efficient 3D imaging system that captures high-speed images using deep learning-enabled fringe projection profilometry(FPP).In this News&Views article,we explore potential avenues for future advancements,including expanding the measurement range through an extended number-theoretical approach,enhancing quality through the incorporation of horizontal fringes,and integrating data from other modalities to broaden the system's applications.
基金Supported by the State Key Project of Research and Development Plan of China under Grant No 2016YFB0400903the National Natural Science Foundation of China under Grant Nos 61634002,61274075 and 61474060+2 种基金the Key Project of Jiangsu Province under Grant No BE2016174the Anhui University Natural Science Research Project under Grant No KJ2015A153the Open Fund of State KeyLab of Optical Technologies on Nano-fabrication and Micro-engineering
文摘It is well known that -nitride semiconductors can generate the magnitude of MV/cm polarization electric field which is comparable with their ionization electric fields. To take full advantage of the polarization electric field, we design an N-face AlGaN solar-blind avalanche photodiode (APD) with an Al<sub>0.45</sub>Ga<sub>0.55</sub>N/Al<sub>0.3</sub>Ga<sub>0.7</sub>N heterostructure as separate absorption and multiplication (SAM) regions. The simulation results show that the N-face APDs are more beneficial to improving the avalanche gain and reducing the avalanche breakdown voltage compared with the Ga-face APDs due to the effect of the polarization electric field. Furthermore, the Al<sub>0.45</sub>Ga<sub>0.55</sub>N/Al<sub>0.3</sub>Ga<sub>0.7</sub>N heterostructure SAM regions used in APDs instead of homogeneous Al<sub>0.45</sub>Ga<sub>0.55</sub>N SAM structure can increase significantly avalanche gain because of the increased hole ionization coefficient by using the relatively low Al-content AlGaN in the multiplication region. Meanwhile, a quarter-wave AlGaN/AlN distributed Bragg reflector structure at the bottom of the device is designed to remain a solar-blind characteristic of the heterostructure SAM-APDs.
文摘In this paper,we discuss the separateness in topological molecular lattices (TML) by the molecular stratums given in [1] and [2],deal with the relationship between the compactness and separateness.
文摘This paper presents experimental results of cocracking of straight-run gasoline (SRG) and light gaS oil (LGO) in an improved pulsed-micro-pyrolyzer. It is shown that there are negative opergistic effect on the yields and selectivities of ethylene and propylene in cocracking. The difference in coking tendencies betWeen the cocracking and the separate cracking is compared as well.
基金supported by National Natural Science Foundation of China(22369022)Technology Innovation Leading Program of Shaanxi(2022QFY07-03)。
文摘The efficiency of photocatalytic overall water splitting was mainly limited by the slow reaction kinetics of water oxidation.How to design effective surface active site to overcome the slow water oxidation reaction was a major challenge.Here,we propose a strategy to accelerate surface water oxidation through the fabrication spatially separated double active sites.FeCoPi/Bi_(4)NbO_(8)Cl-OVs photocatalyst with spatially separated double active site was prepared by hydrogen reduction photoanode deposition method.Due to the high matching of the spatial loading positions of FeCoPi and OVs with the photogenerated charge distribution of Bi_(4)NbO_(8)Cl and corresponding reaction mechanisms of substrate,the FeCoPi and OVs on the(001)and(010)crystal planes of Bi_(4)NbO_(8)Cl photocatalyst provided surface active site for water oxidation reaction and electron shuttle reaction(Fe^(3+)/Fe^(2+)),respectively.Under visible light irradiation,the evolution O_(2)rate of FeCoPi/Bi_(4)NbO_(8)Cl OVs was 16.8μmol h^(-1),as 32.9 times as Bi_(4)NbO_(8)Cl.Furthermore,a hydrogen evolution co-catalyst PtRu@Cr_(2)O_(3)was prepared by sequential photodeposition method.Due to the introduction of Ru,the Schottky barrier between PbTiO_(3)and Pt was effectively reduced,which promoted the transfer of photogenerated electrons to PtRu@Cr_(2)O_(3)thermodynamically,the evolution H_(2)rate on PtRu@Cr_(2)O_(3)/PbTiO_(3)increased to 664.8 times.On based of the synchronous enhancement of the water oxidation performance on FeCoPi/Bi_(4)NbO_(8)Cl-OVs and water reduction performance on PtRu@Cr_(2)O_(3)/PbTiO_(3),a novel Z-Scheme photocatalytic overall water splitting system(FeCoPi/Bi_(4)NbO_(8)Cl-OVs)mediated by Fe^(3+)/Fe^(2+)had successfully constructed.Under visible light irradiation,the evolution rates of H_(2)and O_(2)were 2.5 and 1.3μmol h^(-1),respectively.This work can provide some reference for the design of active site and the controllable synthesis of OVs spatial position.On the other hand,the hydrogen evolution co catalyst(PtRu@Cr_(2)O_(3))and the co catalyst FeCoPi for oxygen evolution contributed to the construction of an overall water splitting system.
基金The financial supports received from the National Natural Science Foundation of China(21522609,21636009 and 21878328)the National Key Research and Development Program of China(Nos.2017YFC0307302,2016YFC0304003)+1 种基金the Science Foundation of China University of Petroleum,Beijing(No.2462018BJC004)Beijing Science and Technology Program,China(No.Z181100005118010)。
文摘Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used as a medium to separate coal bed methane by fluidifying the solid adsorbent material.The sorption equilibrium experiment of binary mixture(CH_4/N_2)and slurry was conducted.The selectivity of CH_4 to N_2 is within the range of 2-6,which proved the feasibility of the slurry separation method.The modified Langmuir equation was used to describe the gas-slurry phase equilibrium behavior,and the calculated results were in good agreement with the experimental data.A continuous absorption-adsorption and desorption process on the separation of CH_4/N_2 in slurry is proposed and its mathematical model is also developed.Sensitivity analysis is conducted to determine the operation conditions and the energy performance of the proposed process was also evaluated.Feed gas contains 30 mol%of methane and the methane concentration in product gas is 95.46 mol%with the methane recovery ratio of 90.74%.The total energy consumption for per unit volume of product gas is determined as 1.846 kWh Nm^(-3).Experimental results and process simulation provide basic data for the design and operation of pilot and industrial plant.
文摘The concept of α-CT2 separation L-fuzzy subsets in L-fuzzy topological spaces is presented by taking the stratiform structure of L-fuzzy subsets as the point of departure,and its basic characterizations and some topological properties are discussed,and the relation between it and other separateness is exposed,and the action is studied of α-CT2 separateness in N-compact spaces and N-paracompact spaces.
基金supported in part by National Key Basic Research Program of China (973 program) under Grant No.2007CB307101,2007CB307106National Key Technology R&D Program under Grant No.2008BAH37B03+2 种基金Program of Introducing Talents of Discipline to Universities (111 Project) under Grant No. B08002National Natural Science Foundation of China under Grant No.60833002China Fundamental Research Funds for the Central Universities under Grant No.2009YJS016
文摘The locator/ID separation paradigm has been widely discussed to resolve the serious scalability issue that today's Internet is facing. Many researches have been carried on with this issue to alleviate the routing burden of the Default Free Zone (DFZ), improve the traffic engineering capabilities and support efficient mobility and multi-homing. However, in the locator/ID split networks, a third party is needed to store the identifier-to-locator pairs. How to map identifiers onto locators in a scalable and secure way is a really critical challenge. In this paper, we propose SS-MAP, a scalable and secure locator/ID mapping scheme for future Internet. First, SS-MAP uses a near-optimal DHT to map identifiers onto locators, which is able to achieve the maximal performance of the system with reasonable maintenance overhead relatively. Second, SS-MAP uses a decentralized admission control system to protect the DHT-based identifier-to-locator mapping from Sybil attacks, where a malicious mapping server creates numerous fake identities (called Sybil identifiers) to control a large fraction of the mapping system. This is the first work to discuss the Sybil attack problem in identifier-to-locator mapping mechanisms with the best knowledge of the authors. We evaluate the performance of the proposed approach in terms of scalability and security. The analysis and simulation results show that the scheme is scalable for large size networks and can resistant to Sybil attacks.
基金supported by the National Basic Research Program of China(Grant No.2011CB922101)the National Natural Science Foundation of China(Grant Nos.51301084 and 11234005)+1 种基金the Natural Science Foundation of Jiangsu Province,China(Grant No.BK20130576)Program for Changjiang Scholars and Innovative Research Team in University,China(Grant No.IRT1243)
文摘A three-terminal device based on electronic phase separated manganites is suggested to produce high performance resistive switching. Our Monte Carlo simulations reveal that the conductive filaments can be formed/annihilated by reshaping the ferromagnetic metal phase domains with two cross-oriented switching voltages. Besides, by controlling the high resistance state（HRS） to a stable state that just after the filament is ruptured, the resistive switching remains stable and reversible, while the switching voltage and the switching time can be greatly reduced.
基金National Science and Technology Major Project (No.J2019-Ⅱ-0014-0035)Academician Workstation Foundation of the Green Aerotechnics Research Institute of Chonging Jiaotong University (No. GATRI2020C06003)。
文摘The effect of nanosecond pulsed dielectric barrier discharge(NS-DBD) plasma flow separation control is closely related to the actuation frequency,because it involves the interaction between plasma-induced vortexes and separated flow.In order to study the mechanism of NS-DBD plasma flow separation control over a swept wing,especially the influence of the actuation frequency,at first,experimental studies of the actuation frequencies at 100 Hz are conducted to validate the numerical simulation method.Then,numerical studies of different actuation frequencies which are 50 Hz,100 Hz,160 Hz,200 Hz,500 Hz,and 1000 Hz,respectively are conducted.The interaction between the plasma-induced vortexes and the separated flow is analyzed.Results show that there is a range of the actuation frequency which includes the frequency(160 Hz) calculated by the average aerodynamic chord length to make the control effect good,but when the actuation frequencies are too low(50 Hz) or too high(1000 Hz),the control effect will get worse.The former is because plasmainduced vortexes disappear in a period within an actuation cycle;the latter is because plasma-induced vortexes cannot develop completely,resulting in a weak vortex intensity.
基金supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20120131110006)the Key Science and Technology Program of Shandong Province,China(Grant No.2013GGX10221)+2 种基金the Key Laboratory of Functional Crystal Materials and Device(Shandong University,Ministry of Education)(Grant No.JG1401)the Major Research Plan of the National Natural Science Foundation of China(Grant No.91433112)the National Natural Science Foundation of China(Grant No.61306113)
文摘The photoluminescence（PL） properties of a green and blue light-emitting InGaN/GaN multiple quantum well structure with a strong phase separated into quasi-quantum dots（QDs） and an InGaN matrix in the InGaN epilayer are investigated.The excitation power dependences of QD-related green emissions（PD〉） and matrix-related blue emissions（PM） in the low excitation power range of the PL peak energy and line-width indicate that at 6 K both Pm and PD are dominated by the combined action of Coulomb screening and localized state filling effect.However,at 300 K,Pm is dominated by the non-radiative recombination of the carriers in the InGaN matrix,while PD is influenced by the carriers transferred from the shallower QDs to deeper QDs by tunnelling.This is consistent with the excitation power dependence of the PL efficiency for the emission.
