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Controllable Synthesis of Few⁃layer Graphene/Cu Powders by Additives
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作者 MA Yu YANG Jun FU Jinliang 《材料导报》 北大核心 2025年第S1期441-447,共7页
Cu suffers from oxidation and corrosion during application due to its active chemical properties.Graphene⁃modified Cu can significantly improve its stability during application.However,copper is easily sintered at hig... Cu suffers from oxidation and corrosion during application due to its active chemical properties.Graphene⁃modified Cu can significantly improve its stability during application.However,copper is easily sintered at high temperatures,so that graphene cannot be grown inside.We demonstrate two kinds of spacers,graphite and SiO_(2),which are effective in preventing the sintering of copper and are used to assist in the growth of graphene.In the Cu⁃C system,the nucleation of graphene is scarce,and it tends to nucleate and grow on the concave surface of copper first,and then grow epitaxially to the convex surface of copper.Eventually,the obtained graphene is relatively thick.In the Cu⁃SiO_(2) system,due to the oxygen released by SiO_(2) at high temperatures,the surface of copper becomes rough.This leads to an increase in the number of graphene nucleation sites without preferred orientation,and relatively thin graphene is obtained.Two different growth mechanisms have been established for spacerseffects on graphene growth.It provides insights for graphene engineering for further applications. 展开更多
关键词 graphene/Cu powder silicon dioxides graphite antisintering chemical vapor deposition(CVD)
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High-temperature stability and mechanical property optimization of laser powder bed fusion 316L steel after controlled annealing
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作者 LI Wen-qi MENG Li-xin +3 位作者 ZHANG Qian-fen LU Hui-hu NIU Xiao-feng HOU Hua 《Journal of Central South University》 2025年第4期1179-1193,共15页
The research demonstrated that laser powder bed fusion(LPBF)coupled with controlled annealing at 1200°C,could significantly increase the proportion of coincidence site lattice(CSL)grain boundary,thereby achieving... The research demonstrated that laser powder bed fusion(LPBF)coupled with controlled annealing at 1200°C,could significantly increase the proportion of coincidence site lattice(CSL)grain boundary,thereby achieving an outstanding synergy of enhanced strength and exceptional ductility.The plastic deformation behavior,strain hardening behavior,and fracture behavior of LPBF 316L steel annealing at 1200℃for 20 h were studied through quasi-in-situ tensile process.It was found that LPBF 316L steel formed a certain proportion of deformation twins during the tensile process,and the formation of twins changed the crystal orientation,thus promoting further slip and crystal deformation.The synergistic effect of slip and twin promoted higher plasticity.LPBF process coupled with controlled annealing at 1200°C for 20 h leads to a ultimate tensile strength of 613 MPa and total elongation of 73.8%. 展开更多
关键词 laser powder bed fusion heat treatment microstructural evolution mechanical behavior plastic deformation behavior
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Process optimization for treatment of methyltin mercaptide effluents using modified semi-coke 被引量:1
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作者 王欣 C.Srinivasakannan +4 位作者 曲雯雯 彭金辉 张利波 段昕辉 卢帅丹 《Journal of Central South University》 SCIE EI CAS 2013年第12期3633-3640,共8页
The central composite process optimization was performed by response surface methodology technique using a design for the treatment of methyltin mercaptide with modified semi-coke. The semi-coke from the coal industry... The central composite process optimization was performed by response surface methodology technique using a design for the treatment of methyltin mercaptide with modified semi-coke. The semi-coke from the coal industry was suitably modified by treating it with phosphoric acid, with a thermal activation process. The objective of the process optimization is to reduce the chemical oxygen demand (COD) and NH4+-N in the methyltin mercaptide industrial effluent. The process variables considered for process optimization are the semi-coke dosage, adsorption time and effluent pH. The optimized process conditions are identified to be a semi-coke dosage of 80 g/L, adsorption time of 90 min and a pH value of 8.34. The ANOVA results indicate that the adsorbent dosage and pH are the significant parameters, while the adsorption time is insignificant, possibly owing to the large range of adsorption time chosen. The textural characteristics of modified semi-coke were analyzed using scanning electron microscopy and nitrogen adsorption isotherm. The average BET surface area of modified semi-coke is estimated to be 915 mE/g, with the average pore volume of 0.71 cm3/g and a average pore diameter of 3.09 nm, with micropore volume contributing to 52.36%. 展开更多
关键词 modified semi-coke semi-coke optimization water treatment chemical oxygen demand (COD) NH4+-N
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Fabrication and characterization of multi-scale coated boron powders with improved combustion performance:A brief review 被引量:5
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作者 Rui Liu Danfeng Yang +2 位作者 Kunyu Xiong Ying-Lei Wang Qi-Long Yan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期27-40,共14页
Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,whic... Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,which include coatings of boron by using fluoride compounds,energetic composites,metal fuels,and metal oxides.Coating techniques include recrystallization,dual-solvent,phase transfer,electrospinning,etc.As one of the effective coating agents,the fluorine compounds can react with the oxide shell of boron powder.In comparison,the energetic composites can effectively improve the flame temperature of boron powder and enhance the evaporation efficiency of oxide film as a condensed product.Metals and metal oxides would react with boron powder to form metal borides with a lower ignition point,which could reduce its ignition temperature. 展开更多
关键词 Boron powder coating Structure and morphology Condensed phase thermal reaction Ignition and combustion
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Characterization of semi-coke generated by coal-based direct reduction process of siderite
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作者 朱德庆 罗艳红 +1 位作者 潘建 周仙霖 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第8期2914-2921,共8页
Solid wastes derived from metallurgical industries pose a significant threat to environment. The utilization and disposal of these solid wastes are the major concern in the world. Semi-coke generated in coal-based dir... Solid wastes derived from metallurgical industries pose a significant threat to environment. The utilization and disposal of these solid wastes are the major concern in the world. Semi-coke generated in coal-based direct reduction process of iron ore is a by-product and its suitable utilization is not available so far. In order to handle it properly, the characteristics of this by-product were comprehensively investigated. A series of analysis methods were used to demonstrate its mineral compositions, petrography and physico-chemical properties. The results reveal that the semi-coke has poor washability. The fixed carbon content of semi-coke reaches 76.11% and the gross calorific value is 28.10 MJ/kg, both of which are similar to those of traditional sinter coke breeze. Also, semi-coke ash possesses lower content of SiO2, Al2O3, S and higher content of CaO and MgO, which could improve the strength of sinter ore when partially substituting for coke breeze in sintering. Semi-coke features well-development porous structure and higher reaction activity, which predicts that the sintering speed could be elevated to some extent when employing it as a partial replacement of coke breeze, so the studies further suggest that the potential adverse effect of the high reactivity on sintering process could be weakened by adequately coarsening the semi-coke's particle size. 展开更多
关键词 semi-coke coal-based direct reduction non-magnetic product sinter fuel
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Effect of process parameters on microstructure and mechanical properties of a nickel-aluminum-bronze alloy fabricated by laser powder bed fusion 被引量:1
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作者 HAN Chang-jun ZOU Yu-jin +7 位作者 HU Gao-ling DONG Zhi LI Kai HUANG Jin-miao LI Bo-yuan ZHOU Kun YANG Yong-qiang WANG Di 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2944-2960,共17页
This work investigated the effect of process parameters on densification,microstructure,and mechanical properties of a nickel-aluminum-bronze(NAB)alloy fabricated by laser powder bed fusion(LPBF)additive manufacturing... This work investigated the effect of process parameters on densification,microstructure,and mechanical properties of a nickel-aluminum-bronze(NAB)alloy fabricated by laser powder bed fusion(LPBF)additive manufacturing.The LPBF-printed NAB alloy samples with relative densities of over 98.5%were obtained under the volumetric energy density range of 200−250 J/mm^(3).The microstructure of the NAB alloy printed in both horizontal and vertical planes primarily consisted ofβ'martensitic phase and bandedαphase.In particular,a coarser-columnar grain structure and stronger crystallographic texture were achieved in the vertical plane,where the maximum texture intensity was 30.56 times greater than that of random textures at the(100)plane.Increasing the volumetric energy density resulted in a decrease in the columnar grain size,while increasing the amount ofαphase.Notably,β_(1)'martensitic structures with nanotwins and nanoscaleκ-phase precipitates were identified in the microstructure of LPBF-printed NAB samples with a volumetric energy density of 250 J/mm^(3).Furthermore,under optimal process parameters with a laser power of 350 W and scanning speed of 800 mm/s,significant improvements were observed in the microhardness(HV 386)and ultimate tensile strength(671 MPa),which was attributed to an increase in refined acicular martensite. 展开更多
关键词 copper alloy nickel-aluminum-bronze alloy laser powder bed fusion additive manufacturing
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Micro-aluminum powder with bi-or tri-component alloy coating as a promising catalyst:Boosting pyrolysis and combustion of ammonium perchlorate 被引量:1
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作者 Chao Wang Ying Liu +6 位作者 Mingze Wu Jia Li Ying Feng Xianjin Ning Hong Li Ningfei Wang Baolu Shi 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期100-113,共14页
A novel design of micro-aluminum(μAl)powder coated with bi-/tri-component alloy layer,such as:Ni-P and Ni-P-Cu(namely,Al@Ni-P,Al@Ni-P-Cu,respectively),as combustion catalysts,were introduced to release its huge energ... A novel design of micro-aluminum(μAl)powder coated with bi-/tri-component alloy layer,such as:Ni-P and Ni-P-Cu(namely,Al@Ni-P,Al@Ni-P-Cu,respectively),as combustion catalysts,were introduced to release its huge energy inside Al-core and promote rapid pyrolysis of ammonium perchlorate(AP)at a lower temperature in aluminized propellants.The microstructure of Al@Ni-P-Cu demonstrates that a three-layer Ni-P-Cu shell,with the thickness of~100 nm,is uniformly supported byμAl carrier(fuel unit),which has an amorphous surface with a thickness of~2.3 nm(catalytic unit).The peak temperature of AP with the addition of Al@Ni-P-Cu(3.5%)could significantly drop to 316.2℃ at high-temperature thermal decomposition,reduced by 124.3℃,in comparison to that of pure AP with 440.5℃.It illustrated that the introduction of Al@Ni-P-Cu could weaken or even eliminate the obstacle of AP pyrolysis due to its reduction of activation energy with 118.28 kJ/mol.The laser ignition results showed that the ignition delay time of Al@Ni-P-Cu/AP mixture with 78 ms in air is shorter than that of Al@Ni-P/AP(118 ms),decreased by 33.90%.Those astonishing breakthroughs were attributed to the synergistic effects of adequate active sites on amorphous surface and oxidation exothermic reactions(7597.7 J/g)of Al@Ni-P-Cu,resulting in accelerated mass and/or heat transfer rate to catalyze AP pyrolysis and combustion.Moreover,it is believed to provide an alternative Al-based combustion catalyst for propellant designer,to promote the development the propellants toward a higher energy. 展开更多
关键词 Micro-aluminum powder(μAl) Nano-sized alloy coating Combustion catalyst Ammonium perchlorate Pyrolysis behavior Ignition and combustion
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Ballistic performance of titanium-based layered composites made using blended elemental powder metallurgy and hot isostatic pressing
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作者 Pavlo Markovsky Jacek Janiszewski +5 位作者 Dmytro Savvakin Oleksandr Stasyuk Bartosz Fikus Victor Samarov Vianey Ellison Sergey V.Prikhodko 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第9期1-14,共14页
Metal matrix composites tiles based on Ti-6Al-4V(Ti64)alloy,reinforced with 10,20,and 40(vol%)of either TiC or TiB particles were made using press-and-sinter blended elemental powder metallurgy(BEPM)and then bonded to... Metal matrix composites tiles based on Ti-6Al-4V(Ti64)alloy,reinforced with 10,20,and 40(vol%)of either TiC or TiB particles were made using press-and-sinter blended elemental powder metallurgy(BEPM)and then bonded together into 3-layer laminated plates using hot isostatic pressing(HIP).The laminates were ballistically tested and demonstrated superior performance.The microstructure and properties of the laminates were analyzed to determine the effect of the BEPM and HIP processing on the ballistic properties of the layered plates.The effect of porosity in sintered composites on further diffusion bonding of the plates during HIP is analyzed to understand the bonding features at the interfaces between different adjacent layers in the laminate.Exceptional ballistic performance of fabricated structures was explained by a significant reduction in the residual porosity of the BEPM products by their additional processing using HIP,which provides an unprecedented increase in the hardness of the layered composites.It is argued that the combination of the used two technologies,BEPM and HIP is principally complimentary for the materials in question with the abilities to solve the essential problems of each used individually. 展开更多
关键词 Metal matrix composites powder metallurgy Titanium hydride powder Master alloy Titanium carbide Titanium boride Hot isostatic pressing Ballistic tests
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Shock Raman spectra and structural transformation of powdered TKX-50 by the plate impact experiments combined with real-time Raman detection
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作者 Xue Yang Qijun Liu +3 位作者 Yundan Gan Lei Yang Zhengtang Liu Fusheng Liu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期158-162,共5页
As an energetic material of great interest,the work capacity of dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate(TKX-50)has been questioned recently.Although some research groups have explored the reasons for the l... As an energetic material of great interest,the work capacity of dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate(TKX-50)has been questioned recently.Although some research groups have explored the reasons for the low working ability of TKX-50,the plane impact experiment on powdered TKX-50 is obviously closer to the practical application,and the conclusions based on this are more guiding.Hence,we performed shock Hugoniot measurements of powdered TKX-50 between 5.65 and 16.29 GPa.The plane impact experiments of powdered TKX-50 were carried out and the shocked Raman spectra were collected.By Raman spectroscopy analysis,a new peak of powdered TKX-50 was found between19.47 GPa and 24.96 GPa,which may be caused by decomposition/phase transition and was related with the low work capacity. 展开更多
关键词 powdered TKX-50 HUGONIOT RAMAN DECOMPOSITION Phase transition
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Effect of silica fume and glass powder for enhanced impact resistance in GGBFS-based ultra high-performance geopolymer fibrous concrete:An experimental and statistical analysis
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作者 G.Murali Anoop Kallamalayil Nassar +2 位作者 Madhumitha Swaminathan Parthiban Kathirvel Leong Sing Wong 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第11期59-81,共23页
Solid waste recycling is an economically sound strategy for preserving the environment,safeguarding natural resources,and diminishing the reliance on raw material consumption.Geopolymer technology offers a significant... Solid waste recycling is an economically sound strategy for preserving the environment,safeguarding natural resources,and diminishing the reliance on raw material consumption.Geopolymer technology offers a significant advantage by enabling the reuse and recycling of diverse materials.This research assesses how including silica fume and glass powder enhances the impact resistance of ultra-high-performance geopolymer concrete(UHPGC).In total,18 distinct mixtures were formulated by substituting ground granulated blast furnace slag with varying proportions of silica fume and glass powder,ranging from 10%to 40%.Similarly,for each of the mixtures above,steel fibre was added at a dosage of 1.5%to address the inherent brittleness of UHPGC.The mixtures were activated by combining sodium hydroxide and sodium silicate solution to generate geopolymer binders.The specimens were subjected to drop-weight impact testing,wherein an examination was carried out to evaluate various parameters,including flowability,density at fresh and hardened state,compressive strength,impact numbers indicative of cracking and failure occurrences,ductility index,and analysis of failure modes.Additionally,the variations in the impact test outcomes were analyzed using the Weibull distribution,and the findings corresponding to survival probability were offered.Furthermore,the microstructure of UHPGC was scrutinized through scanning electron microscopy.Findings reveal that the specimens incorporating glass powder exhibited lower cracking impact number values than those utilizing silica fume,with reductions ranging from 18.63%to 34.31%.Similarly,failure impact number values decreased from 8.26%to 28.46%across glass powder contents.The maximum compressive and impact strength was recorded in UHPGC,comprising 10%silica fume with fibres. 展开更多
关键词 Silica fume Glass powder Impact strength Steel fibre GGBFS Weibull analysis Microstructure
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Effect of fractures on mechanical behavior of sand powder 3D printing rock analogue under triaxial compression
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作者 LI Pi-mao JIANG Li-shuai +5 位作者 WEN Zhi-jie WU Chao-lei YANG Yi-ming PENG Xiao-han WU Quan-sen WU Quan-lin 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2703-2716,共14页
In practical engineering applications,rock mass are often found to be subjected to a triaxial stress state.Concurrently,defects like joints and fractures have a notable impact on the mechanical behavior of rock mass.S... In practical engineering applications,rock mass are often found to be subjected to a triaxial stress state.Concurrently,defects like joints and fractures have a notable impact on the mechanical behavior of rock mass.Such defects are identified as crucial contributors to the failure and instability of the surrounding rock,subsequently impacting the engineering stability.The study aimed to investigate the impact of fracture geometry and confining pressure on the deformation,failure characteristics,and strength of specimens using sand powder 3D printing technology and conventional triaxial compression tests.The results indicate that the number of fractures present considerably influences the peak strength,axial peak strain and elastic modulus of the specimens.Confining pressure is an important factor affecting the failure pattern of the specimen,under which the specimen is more prone to shear failure,but the initiation,expansion and penetration processes of secondary cracks in different fracture specimens are different.This study confirmed the feasibility of using sand powder 3D printing specimens as soft rock analogs for triaxial compression research.The insights from this research are deemed essential for a deeper understanding of the mechanical behavior of fractured surrounding rocks when under triaxial stress state. 展开更多
关键词 sand powder 3D printing triaxial compression confining pressure fracture geometry mechanical behavior
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物理激发后再生砖粉ECC的力学性能及微观结构 被引量:1
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作者 楚留声 杜飞翔 +2 位作者 田野 元成方 程站起 《硅酸盐通报》 北大核心 2025年第1期253-263,共11页
废弃黏土砖中含有大量SiO_(2)和Al_(2)O_(3)等活性矿物成分,将其破碎、研磨加工后可制得再生砖粉(RBP)。通过有效的激发方式提高RBP火山灰活性,可将RBP运用到工程水泥基复合材料(ECC)中充当部分胶凝材料,具有极大的经济效益和环境效益... 废弃黏土砖中含有大量SiO_(2)和Al_(2)O_(3)等活性矿物成分,将其破碎、研磨加工后可制得再生砖粉(RBP)。通过有效的激发方式提高RBP火山灰活性,可将RBP运用到工程水泥基复合材料(ECC)中充当部分胶凝材料,具有极大的经济效益和环境效益。试验通过对物理激发后RBP的活性指标、微观结构和XRD谱进行分析,确定了RBP的最佳物理激发时间。在此基础上利用活性激发后RBP制备再生砖粉工程水泥基复合材料(RBP-ECC),对RBP-ECC进行抗折、抗压、单轴拉伸和四点弯曲试验,研究RBP取代率对RBP-ECC力学性能的影响。结果表明,随着物理激发后RBP取代率的增加,RBP-ECC各强度指标均有所下降,而极限拉应变和弯曲跨中挠度逐渐增大,最大分别可达5.22%和55.53 mm。RBP取代率为20%(质量分数)时,RBP-ECC弯曲韧性指标提升最大,较基准ECC提高约59%,各强度指标下降幅度较低,RBP-ECC仍能保持较高的强度和韧性。综合考虑RBP-ECC的强度、韧性与可持续性指标,选取20%为RBP-ECC最佳砖粉取代率,并对该取代率下RBP-ECC纤维-基体界面进行了微观分析,结果表明20%的RBP取代率下RBP-ECC中存在纤维拔出破坏模式和纤维拉断破坏模式,相较于基准ECC,RBP-ECC仍能表现出较高的拉伸韧性和适宜的抗拉强度。 展开更多
关键词 ECC 再生砖粉 活性激发 砖粉取代率 力学性能 破坏模式
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石粉含量对机制砂混凝土拌和性能及力学性能的影响 被引量:2
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作者 陈峰宾 刘济广 +4 位作者 焦华喆 杨柳华 牛豪爽 申宏栋 徐雨 《混凝土》 北大核心 2025年第3期177-180,共4页
随着基础建设的大力发展,天然砂的存量存在供不应求的现象,随着环境友好型等可持续发展观念的提出,机制砂在当前环境下逐步占据主导地位.但因机制砂的生产工艺所限,相对于天然砂,机制砂的石粉含量较高,石粉会影响混凝土的力学性能.采用... 随着基础建设的大力发展,天然砂的存量存在供不应求的现象,随着环境友好型等可持续发展观念的提出,机制砂在当前环境下逐步占据主导地位.但因机制砂的生产工艺所限,相对于天然砂,机制砂的石粉含量较高,石粉会影响混凝土的力学性能.采用单因素变量试验,采用不同石粉含量的机制砂替代天然砂,研究石粉含量对机制砂混凝土的拌和性能与力学性能的影响,讨论了C20强度等级混凝土的最佳石粉含量.试验结果表明:当石粉含量为10%~15%,可以显著提高混凝土的拌和性能,减小离析泌水,增强黏聚性,降低骨料间的摩擦力.石粉可以填充混凝土中的孔隙,完善机制砂混凝土的整体级配,改善其工作性能,有利于提高机制砂混凝土的力学强度,28 d单轴抗压强度可达41.6 MPa,抗折强度达9.4 MPa,抗拉强度达3.7 MPa。 展开更多
关键词 石粉 机制砂 混凝土 拌和性能 力学性能
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碳化硅原料粉体制备的研究进展
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作者 冯东 刘悦 +3 位作者 丁国强 茹红强 罗旭东 游杰刚 《航空制造技术》 北大核心 2025年第3期92-101,共10页
碳化硅(SiC)材料因具有优异的物理化学性能,已被广泛应用于航空航天、工程陶瓷和半导体等领域。目前,SiC粉体的合成方法众多,其中碳热还原法是工业生产SiC粉体的主要方法,但在生产过程中,SiC粉体的颗粒度和杂质含量均会影响最终产物的... 碳化硅(SiC)材料因具有优异的物理化学性能,已被广泛应用于航空航天、工程陶瓷和半导体等领域。目前,SiC粉体的合成方法众多,其中碳热还原法是工业生产SiC粉体的主要方法,但在生产过程中,SiC粉体的颗粒度和杂质含量均会影响最终产物的各项性能。因此,如何对SiC粉体进行细化和纯化处理成为制备高性能SiC材料需要探索的问题。本文首先介绍了SiC粉体合成技术的种类、原理和特点;然后,详细阐述了近年来SiC粉体细化技术的研究进展,并对SiC粉体中无定形碳和金属及金属氧化物的纯化技术进行重点介绍;最后分析了目前制备SiC粉体需要解决的问题,并对其发展前景进行展望。 展开更多
关键词 碳化硅(SiC)粉体 SiC合成 碳热还原法 粉体细化 粉体纯化
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橡胶玻璃粉再生混凝土力学及抗冲击性能研究 被引量:2
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作者 赵毅 李宇 +4 位作者 侯东昌 蒋明旭 冯奥中 孙玉周 闵志宇 《硅酸盐通报》 北大核心 2025年第2期550-560,578,共12页
为提高固废在混凝土中的综合利用率,制备一种具备高效消纳固废能力的新型混凝土,通过原材料优选和L_(16)(4^(3))正交试验设计,采用极差分析和方差分析研究了橡胶颗粒(RP)取代砂、玻璃粉(GP)取代水泥、再生粗骨料(RCA)取代天然粗骨料(NCA... 为提高固废在混凝土中的综合利用率,制备一种具备高效消纳固废能力的新型混凝土,通过原材料优选和L_(16)(4^(3))正交试验设计,采用极差分析和方差分析研究了橡胶颗粒(RP)取代砂、玻璃粉(GP)取代水泥、再生粗骨料(RCA)取代天然粗骨料(NCA)时,三者取代率对混凝土力学及抗冲击性能的影响,并采用Weibull分布模型对冲击试验结果进行拟合和失效概率预测。结果表明:各因素对混凝土力学性能影响的主次顺序为RP、RCA、GP,各因素对混凝土抗冲击性能影响的主次顺序为RP、GP、RCA;当RP掺量为20%(体积分数)时,与RP掺量为0%时相比,抗冲击性能提高81.8%,抗压强度和劈拉强度分别降低21.63%、12.65%;当GP掺量为10%(质量分数)时,与GP掺量为0%时相比,抗压强度、劈拉强度和抗冲击性能分别提高2.87%、2.35%、15.0%;当RCA掺量为70%(体积分数)时,与RCA掺量为0%时相比,抗压强度、劈拉强度和抗冲击性能分别降低11.01%、10.77%、10.5%。Weibull分布模型可准确描述橡胶玻璃粉再生混凝土试样的抗冲击次数的概率分布。 展开更多
关键词 橡胶颗粒 玻璃粉 再生混凝土 力学性能 抗冲击性能 WEIBULL分布
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表面改性硼及硼铝复合粉的制备和性能
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作者 伍俊英 王健宇 +4 位作者 刘新航 胡良 尚伊平 刘丹阳 陈朗 《含能材料》 北大核心 2025年第6期581-588,共8页
硼粉因其较高的质量热值、体积热值和洁净的燃烧产物,常被用作可燃剂,然而硼粉表面的氧化层使硼粉点火困难且燃烧效率低。为此,研究利用氧化硼在乙腈溶剂中易溶解的特性,以热乙腈为控制剂湿法球磨硼粉,去除其表面氧化膜得到活性较高的... 硼粉因其较高的质量热值、体积热值和洁净的燃烧产物,常被用作可燃剂,然而硼粉表面的氧化层使硼粉点火困难且燃烧效率低。为此,研究利用氧化硼在乙腈溶剂中易溶解的特性,以热乙腈为控制剂湿法球磨硼粉,去除其表面氧化膜得到活性较高的预处理硼粉;再以乙腈-正己烷为双控制剂,将其与高活性金属铝二次球磨得到硼铝质量比分别为10/90,20/80,30/70,40/60的硼铝复合粉。对预处理硼及硼铝复合粉的形貌特征、热重、点火与燃烧特性进行了测试。结果表明:预处理硼粉的表面氧化硼含量降低,在空气中加热时更容易与氧气反应,质量增加百分数比未处理的硼粉多25.6%;所得硼铝复合粉的表面氧化硼的含量降低,活性硼含量增高,点火燃烧性能显著得以改善,其中硼铝质量比例为60/40的复合粉在空气中加热质量增加93%,低加热速率下点火温度为738.1℃,颗粒燃烧时间为11.2 ms。 展开更多
关键词 改性硼粉 硼铝复合粉 预处理 点火 燃烧
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基于煤体卸压钻孔钻屑的冲击危险性检测方法及应用
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作者 赵同彬 尹延春 +3 位作者 任文涛 张庆志 高久国 赵志刚 《煤炭学报》 北大核心 2025年第5期2384-2393,共10页
钻屑法是煤矿常用的冲击地压危险性检测方法,而大直径卸压钻孔的施工方法与钻屑法类似,但由于缺少相应的大直径卸压钻孔的钻粉率指数以及高效便捷的称重方法,大直径卸压钻孔钻屑法未能得到广泛应用。文中基于标准孔径钻屑法的钻粉率指数... 钻屑法是煤矿常用的冲击地压危险性检测方法,而大直径卸压钻孔的施工方法与钻屑法类似,但由于缺少相应的大直径卸压钻孔的钻粉率指数以及高效便捷的称重方法,大直径卸压钻孔钻屑法未能得到广泛应用。文中基于标准孔径钻屑法的钻粉率指数,提出考虑卸压扰动的大直径卸压钻孔钻粉率指数及临界煤粉量确定方法;通过开展室内煤样钻孔卸压-煤粉测量试验,探究钻孔孔径、煤粉量、煤样初始应力及卸压后应力间的函数关系,进而给出孔距为1、2和3 m条件下孔径为150 mm的卸压钻孔钻粉率指数及临界煤粉量的建议值;并结合研发的煤粉自动测量装置,在井下冲击危险巷道开展大直径卸压钻孔钻屑检测应用。结果表明:煤样钻孔煤粉量与钻孔孔径、煤样应力呈正相关关系,钻孔卸压后煤样应力降低率与钻孔孔径-孔距比呈正相关性;孔径为150 mm的卸压钻孔的钻粉率指数大于孔径为44 mm的钻孔的钻粉率指数,且随着钻孔间距的减小而逐渐增大;山东唐口矿6310工作面孔径为150 mm的卸压钻孔的煤粉量为25~93 kg/m,在巷帮12~14和18~20 m深处存在高应力区,沿空巷道煤粉量明显大于实体煤巷道。通过大直径卸压钻孔钻粉率指数确定方法和煤粉自动测量装置相结合,形成了基于煤体卸压钻孔钻屑的冲击危险性检测方法,为巷道高应力危险区“卸压-检测”同步作业提供了一种实用技术途径。 展开更多
关键词 冲击地压 卸压钻孔 钻屑法 钻粉率指数 临界煤粉量
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高寒环境下橡胶粉掺入对水泥砂浆的抗冻性能影响 被引量:2
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作者 张静 张新宇 +1 位作者 李婷婷 朱楠 《空军工程大学学报》 北大核心 2025年第1期111-118,共8页
研究掺入橡胶粉的水泥砂浆作为高寒地区破损道面修复材料时,其抗冻性能否适配我国高寒地区机场对破损道面修补材料的要求。通过冻融循环试验研究橡胶粉水泥砂浆中橡胶粉目数和掺量对抗冻性能以及力学性能的影响,采用两因素方差分析和极... 研究掺入橡胶粉的水泥砂浆作为高寒地区破损道面修复材料时,其抗冻性能否适配我国高寒地区机场对破损道面修补材料的要求。通过冻融循环试验研究橡胶粉水泥砂浆中橡胶粉目数和掺量对抗冻性能以及力学性能的影响,采用两因素方差分析和极差分析确定其影响效果,通过SEM和XRD从微观角度揭示橡胶粉在水泥砂浆水化过程中对其微观结构及产物的影响。结果表明,橡胶粉水泥砂浆中目数和掺量均对抗冻性能及抗压强度有显著性影响,两者之间的交互影响不显著;确定当橡胶粉目数为30目,掺量为50%时其抗冻性能最优;SEM形貌像显示橡胶粉掺入可阻断微裂缝发展,XRD结果显示30目橡胶粉更能保证橡胶粉水泥砂浆的水化反应高效进行。 展开更多
关键词 高寒环境 橡胶粉水泥砂浆 抗冻性能 力学特性 微观结构
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发酵桑叶粉对黄羽肉鸡生长性能、抗氧化和免疫能力及肠道菌群结构的影响 被引量:1
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作者 邢东旭 符兵 +6 位作者 王君雁 李庆荣 周东来 叶金玲 廖森泰 阮栋 邹宇晓 《中国畜牧兽医》 北大核心 2025年第1期169-181,共13页
[目的]试验旨在研究饲料中添加发酵桑叶粉(FML)对黄羽肉鸡生长性能、抗氧化和免疫能力及肠道菌群结构的影响。[方法]选取初始体重为(40.07±0.05)g的1日龄黄羽肉鸡540只,随机分为3组,每组6个重复,每个重复30只鸡。在育雏期、生长期... [目的]试验旨在研究饲料中添加发酵桑叶粉(FML)对黄羽肉鸡生长性能、抗氧化和免疫能力及肠道菌群结构的影响。[方法]选取初始体重为(40.07±0.05)g的1日龄黄羽肉鸡540只,随机分为3组,每组6个重复,每个重复30只鸡。在育雏期、生长期和育成期分别投喂添加0(对照组)、4.5%FMLP(FML45组)和9.0%FMLP(FML90组)的3种等氮等能试验饲料,试验期为50 d。于21、42和50日龄以重复为单位对试验鸡空腹称重并统计采食量,计算生长性能;于50日龄每重复选取3只接近平均体重的试验鸡采血和屠宰,测定血清抗氧化指标;取回肠黏膜评价抗氧化和免疫功能,取回肠内容物测定肠道菌群结构。[结果]与对照组相比,(1)FML90组试验鸡体重(BW)和平均日增重(ADG)均显著降低(P<0.05),料重比(F/G)显著升高(P<0.05),平均日采食量(ADFI)呈升高趋势(P=0.084),各组间死亡率无显著差异(P>0.05)。(2)FML45和FML90组试验鸡血清中超氧化物歧化酶(SOD)活性显著升高(P<0.05),各组间血清中丙二醛(MDA)含量、谷胱甘肽过氧化物酶(GSH-Px)活性和总抗氧化能力(T-AOC)无显著差异(P>0.05);FML45组试验鸡回肠T-AOC显著高于对照组和FML90组,各组间回肠中MDA含量、GSH-Px和SOD活性无显著差异(P>0.05)。(3)FML90组试验鸡回肠中分泌型免疫球蛋白A(SIgA)含量显著增加(P<0.05),各组间白介素1β(IL-1β)、IL-10、肿瘤坏死因子α(TNF-α)、转化生长因子β(TGF-β)和补体3(C3)含量均无显著差异(P>0.05)。(4)各组间回肠菌群在门水平相对丰度无显著差异(P>0.05);FML45和FML90组回肠普拉梭菌(Faecalibacterium)相对丰度显著升高(P<0.05),真细菌未分类属(unclassified_o_Eubacteriales)和颤螺菌未分类属(unclassified_o_Oscillospiraceae)相对丰度显著降低(P<0.05),考拉杆菌属(Phascolarctobacterium)相对丰度呈升高趋势(P=0.067);Ace指数和Chao1指数显著降低(P<0.05)。[结论]饲粮中添加发酵桑叶粉能增强肉鸡的免疫和抗氧化能力,提高肠道有益菌群的相对丰度,但过量添加会降低其生长性能,建议黄羽肉鸡饲粮中发酵桑叶粉的添加量为4.5%。 展开更多
关键词 发酵桑叶粉 黄羽肉鸡 生长性能 抗氧化能力 肠道免疫 肠道菌群
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乙丙胶粉基聚丙烯热塑性弹性体的绿色制备及其高值化性能分析
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作者 王艳秋 张明 +3 位作者 柳峰 李杰 卢猛 李晓娟 《化工新型材料》 北大核心 2025年第1期243-249,共7页
为了响应国家“双碳”战略,绿色制备了高强伸耐老化的乙丙胶粉基聚丙烯热塑性弹性体,优化了乙丙胶粉与聚丙烯的橡塑比,确定了相容剂的品种、用量,优化了乙丙胶粉与聚丙烯的化学接枝工艺。结果表明:环保相容剂2,4-二叔丁基过氧化异丙苯(B... 为了响应国家“双碳”战略,绿色制备了高强伸耐老化的乙丙胶粉基聚丙烯热塑性弹性体,优化了乙丙胶粉与聚丙烯的橡塑比,确定了相容剂的品种、用量,优化了乙丙胶粉与聚丙烯的化学接枝工艺。结果表明:环保相容剂2,4-二叔丁基过氧化异丙苯(BIBP)与硫磺S_(8)并用,乙丙胶粉基聚丙烯热塑性弹性体的力学和耐老化性能优异,拉伸强度达20MPa,扯断伸长率达800%以上,可用于耐老化汽车配件、码头缓冲器、各种胶管胶板等产品的负碳制备。 展开更多
关键词 乙丙胶粉 聚丙烯 相容剂 生胶 胶粉基热塑性弹性体 高值化性能
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