The F2, F3, families and F4 lines of six soybean crosses, were selected successively under high-and low - fertility sites with the relection objective of high yield and the method of pedigree was used. Two best F4 - d...The F2, F3, families and F4 lines of six soybean crosses, were selected successively under high-and low - fertility sites with the relection objective of high yield and the method of pedigree was used. Two best F4 - derived lines were chosen from each of the six crosses under both high-and low-fertility for use in this study. In 1995, the total 24 lines were tested in high, medium and low fertility sites with the same experimental design (CRB) to study the selcctoin effects of high and low - fertility. The results suggested that high- and low-fertility had different selection effects. High fertility was more effective for selecting lines, which had higher yield under high-fertility and lower yield under low-fertility; low-fertility was better for selecting lines, which had higher yield under low-fertility and lower yield under low-fertility, and high fertility was somewhat better than low fertility for selecting lines, which had higher yield under both high and low-fertility. It revealed that the lines selected from high-fertility had superior yield potential. The lines selected from high-fertility had shorter plant height, more nodes on main stem, fewer branches, higher seed-stem ratio. The reverse was true for the lines selected from low-fertility . The lodging-resistance of the lines selected from highfertility was greater than that of the lines from low-fertility. The soil fertility level of breeding nursery should be chosen according to the breeding objective.展开更多
The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste g...The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste gas but also recover clean energy H_(2),which has significant socio-economic and ecological advantages.However,the highly effective decomposition of H_(2)S at low temperatures is still a great challenge,because of the stringent thermodynamic equilibrium constraints(only 20% even at high temperature of 1010℃).Conventional microwave catalysts exhibit unsatisfactory performance at low temperatures(below 600℃).Herein,Mo_(2)C@CeO_(2) catalysts with a core-shell structure were successfully developed for robust microwave catalytic decomposition of H_(2)S at low temperatures.Two carbon precursors,para-phenylenediamine(Mo_(2)C-p)and meta-phenylenediamine(Mo_(2)C-m),were employed to tailor Mo_(2)C configurations.Remarkably,the H_(2)S conversion of Mo_(2)C-p@CeO_(2) catalyst at a low temperature of 550℃ is as high as 92.1%,which is much higher than the H_(2)S equilibrium conversion under the conventional thermal conditions(2.6% at 550℃).To our knowledge,this represents the most active catalyst for microwave catalytic decomposition of H_(2)S at low temperature of 550℃.Notably,Mo_(2)C-p demonstrated superior intrinsic activity(84%)compared to Mo_(2)C-m(6.4%),with XPS analysis revealing that its enhanced performance stems from a higher concentration of Mo_(2+)active sites.This work presents a substitute approach for the efficient utilization of H_(2)S waste gas and opens up a novel avenue for the rational design of microwave catalysts for microwave catalytic reaction at low-temperature.展开更多
文摘The F2, F3, families and F4 lines of six soybean crosses, were selected successively under high-and low - fertility sites with the relection objective of high yield and the method of pedigree was used. Two best F4 - derived lines were chosen from each of the six crosses under both high-and low-fertility for use in this study. In 1995, the total 24 lines were tested in high, medium and low fertility sites with the same experimental design (CRB) to study the selcctoin effects of high and low - fertility. The results suggested that high- and low-fertility had different selection effects. High fertility was more effective for selecting lines, which had higher yield under high-fertility and lower yield under low-fertility; low-fertility was better for selecting lines, which had higher yield under low-fertility and lower yield under low-fertility, and high fertility was somewhat better than low fertility for selecting lines, which had higher yield under both high and low-fertility. It revealed that the lines selected from high-fertility had superior yield potential. The lines selected from high-fertility had shorter plant height, more nodes on main stem, fewer branches, higher seed-stem ratio. The reverse was true for the lines selected from low-fertility . The lodging-resistance of the lines selected from highfertility was greater than that of the lines from low-fertility. The soil fertility level of breeding nursery should be chosen according to the breeding objective.
基金supported by the National Natural Science Foundation of China(22178295,21706225)Natural Science Foundation of Hunan Province(2025JJ50085)Hunan Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization.
文摘The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste gas but also recover clean energy H_(2),which has significant socio-economic and ecological advantages.However,the highly effective decomposition of H_(2)S at low temperatures is still a great challenge,because of the stringent thermodynamic equilibrium constraints(only 20% even at high temperature of 1010℃).Conventional microwave catalysts exhibit unsatisfactory performance at low temperatures(below 600℃).Herein,Mo_(2)C@CeO_(2) catalysts with a core-shell structure were successfully developed for robust microwave catalytic decomposition of H_(2)S at low temperatures.Two carbon precursors,para-phenylenediamine(Mo_(2)C-p)and meta-phenylenediamine(Mo_(2)C-m),were employed to tailor Mo_(2)C configurations.Remarkably,the H_(2)S conversion of Mo_(2)C-p@CeO_(2) catalyst at a low temperature of 550℃ is as high as 92.1%,which is much higher than the H_(2)S equilibrium conversion under the conventional thermal conditions(2.6% at 550℃).To our knowledge,this represents the most active catalyst for microwave catalytic decomposition of H_(2)S at low temperature of 550℃.Notably,Mo_(2)C-p demonstrated superior intrinsic activity(84%)compared to Mo_(2)C-m(6.4%),with XPS analysis revealing that its enhanced performance stems from a higher concentration of Mo_(2+)active sites.This work presents a substitute approach for the efficient utilization of H_(2)S waste gas and opens up a novel avenue for the rational design of microwave catalysts for microwave catalytic reaction at low-temperature.
