Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In ...Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In order to obtain high-quality HMX@PDA-based PBX explosives with high sphericity and a narrow particle size distribution,composite microspheres were prepared using co-axial droplet microfluidic technology.The formation mechanism,thermal behavior,mechanical sensitivity,electrostatic spark sensitivity,compressive strength,and combustion performance of the microspheres were investigated.The results show that PDA can effectively enhance the interfacial interaction between the explosive particles and the binder under the synergistic effect of chemical bonds and the physical"mechanical interlocking"structure.Interface reinforcement causes the thermal decomposition temperature of the sample microspheres to move to a higher temperature,with the sensitivity to impact,friction,and electrostatic sparks(for S-1)increasing by 12.5%,31.3%,and 81.5%respectively,and the compressive strength also increased by 30.7%,effectively enhancing the safety performance of the microspheres.Therefore,this study provides an effective and universal strategy for preparing high-quality functional explosives,and also provides some reference for the safe use of energetic materials in practical applications.展开更多
To examine the similarities and differences in the evolution of cavity,wetting and dynamics of a highspeed,oblique water-entry projectile with different positive angles of attack,a comparative analysis has been conduc...To examine the similarities and differences in the evolution of cavity,wetting and dynamics of a highspeed,oblique water-entry projectile with different positive angles of attack,a comparative analysis has been conducted based on the numerical results of two mathematical models,the rigid-body model and fluid-structure interaction model.In addition,the applicable scope of the above two methods,and the structural response characteristics of the projectile have also been investigated.Our results demonstrate that:(1) The impact loads and angular motion of the projectile of the rigid-body method are more likely to exhibit periodic variations due to the periodic tail slap,its range of positive angles of attack is about α<2°.(2) When the projectile undergone significant wetting,a strong coupling effect is observed among wetting,structural deformation,and projectile motion.With the applied projectile shape,it is observed that,when the projectile bends,the final wetting position is that of Part B(cylinder of body).With the occu rrence of this phenomenon,the projectile ballistics beco me completely unstable.(3) The force exerted on the lower surface of the projectile induced by wetting is the primary reason of the destabilization of the projectile traj ectory and structu ral deformation failure.Bending deformation is most likely to appear at the junction of Part C(cone of body) and Part D(tail).The safe angles of attack of the projectile stability are found to be about α≤2°.展开更多
Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and equipment.Accurate prediction of the distribution pattern of explosive loads ...Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and equipment.Accurate prediction of the distribution pattern of explosive loads and shock wave propagation process in semi-enclosed structures at various altitude environment is key research focus in the fields of explosion shock and fluid dynamics.The effect of altitude on the propagation of shock waves in tunnels was investigated by conducting explosion test and numerical simulation.Based on the experimental and numerical simulation results,a prediction model for the attenuation of the peak overpressure of tunnel shock waves at different altitudes was established.The results showed that the peak overpressure decreased at the same measurement points in the tunnel entrance under the high altitude condition.In contrast,an increase in altitude accelerated the propagation speed of the shock wave in the tunnel.The average error between the peak shock wave overpressure obtained using the overpressure prediction formula and the measured test data was less than15%,the average error between the propagation velocity of shock waves predicted values and the test data is less than 10%.The method can effectively predict the overpressure attenuation of blast wave in tunnel at various altitudes.展开更多
Objective:In recent years,the incidence and detection rate of pancreatic cystic lesions(PCLs)have increased significantly.Endoscopic ultrasound(EUS)plays an indispensable role in the diagnosis and differential diagnos...Objective:In recent years,the incidence and detection rate of pancreatic cystic lesions(PCLs)have increased significantly.Endoscopic ultrasound(EUS)plays an indispensable role in the diagnosis and differential diagnosis of PCLs.However,evidence comparing the diagnostic performance of EUS-guided fine-needle aspiration(EUS-FNA)and fine-needle biopsy(FNB)remains limited.This study aims to compare the diagnostic yield,adequacy of tissue acquisition,and safety between EUS-FNA and EUS-FNB in evaluating PCLs to inform clinical practice.Methods:A retrospective review was conducted on patients with PCLs who underwent either EUS-FNA or EUS-FNB between January 2014 and August 2021.The diagnostic yield,tissue acquisition adequacy,and incidence of adverse events were compared between the 2 groups.Results:A total of 90 patients with PCLs were included(52 in the FNA group and 38 in the FNB group).The diagnostic yield was similar between the FNA and FNB groups(94.2%vs 94.7%,P>0.05).The adequacy of tissue acquisition was 71.2%in the FNA group and 81.6%in the FNB group(P>0.05).No statistically significant difference was observed in the incidence of adverse events between the 2 groups(P>0.05).Conclusion:Both EUS-FNA and EUS-FNB demonstrate equally high diagnostic yields and tissue adequacy in PCLs,with excellent safety profiles.Both methods are safe and effective diagnostic tools for evaluating PCLs.展开更多
Sea-based rocket launches encounter significant challenges stemming from dynamic marine environmental interactions.During the hot launch phase,characterized by low-velocity ascent,the departure of the rocket from the ...Sea-based rocket launches encounter significant challenges stemming from dynamic marine environmental interactions.During the hot launch phase,characterized by low-velocity ascent,the departure of the rocket from the oscillatory platform exhibits heightened sensitivity to external disturbances.In the development stage,assessing the launch dynamics and the clearance between the rocket and framed launcher are crucial for improving the reliability of sea-based rocket launches in rough sea conditions.This study presents a high-fidelity dynamic model of maritime hot launch system,demonstrating 3.21%prediction error through rigorous validation against experimental datasets from comprehensive modal analyses and the full-scale rocket flight test.To mitigate collision risks,we develop a computational method employing spatial vector analysis for dynamic measurement of rocket-launcher clearance during departure.Systematic investigations reveal that in rough sea conditions,optimal departure dynamics are achieved at θ_(thrust)=270°nozzle azimuth configuration,reducing failure probability compared to conventional orientations.The developed assessment framework not only resolves critical safety challenges in current sea launch systems but also establishes foundational principles for optimizing adapter axial configuration patterns in future designs.展开更多
The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experim...The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.展开更多
The impact safety of explosive charges has been focused in these decades. The fragment impact is widely used to evaluate the response of explosive charges. In our work, the explosive detonation driving technique was u...The impact safety of explosive charges has been focused in these decades. The fragment impact is widely used to evaluate the response of explosive charges. In our work, the explosive detonation driving technique was used to generate a high velocity fragment with large mass. When the fragment masses are10 g, 16 g, 25 g, and 50 g, the highest velocity of fragments can reach 2400 m/s, 2100 m/s, 1900 m/s, and1400 m/s, respectively. The high velocity fragment with large mass was used to evaluate the safety of two kinds of CL-20 based explosive charges. The effects of the fragment mass and velocity were analyzed.Especially, the reaction extent was obtained based on visible phenomenon. The CL-20-based explosive charge containing Al had a higher safety level than that without Al. It was because Al had good ductility,and further improved the mechanical property of the material. Also, the numerical simulation was conducted to understand the reaction characteristics of the CL-20-based explosive charge. The results showed that as the fragment mass and velocity increased, the reaction became more violent.展开更多
The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricat...The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricated to address the above issues.The coordination complexes which consist of natural polyphenol tannic acid(TA) and Fe~Ⅲ were chosen to construct the inner shell,while the graphene sheets were used to build the outer shell.The resulting CL-20/TA-Fe~Ⅲ/graphene composites exhibited simultaneously improved thermal stability and safety performance with only 1 wt% double-shell content,which should be ascribed to the intense physical encapsulation effect from inner shell combined with the desensitization effect of carbon nano-materials from outer shell.The phase transition(ε to γ) temperature increased from 173.70 ℃ of pure CL-20 to 191.87℃ of CL-20/TA-Fe~Ⅲ/graphene composites.Meanwhile,the characteristic drop height(H_(50)) dramatically increased from 14.7 cm of pure CL-20 to112.8 cm of CL-20/TA-Fe~Ⅲ/graphene composites,indicating much superior safety performance after the construction of the double-shell structure.In general,this work has provided an effective and versatile strategy to conquer the thermal stability and safety issues of CL-20 and contributes to the future application of high energy density energetic materials.展开更多
Sudden earthquakes pose a threat to the running safety of trains on high-speed railway bridges,and the stiffness of piers is one of the factors affecting the dynamic response of train-track-bridge system.In this paper...Sudden earthquakes pose a threat to the running safety of trains on high-speed railway bridges,and the stiffness of piers is one of the factors affecting the dynamic response of train-track-bridge system.In this paper,a experiment of a train running on a high-speed railway bridge is performed based on a dynamic experiment system,and the corresponding numerical model is established.The reliability of the numerical model is verified by experiments.Then,the experiment and numerical data are analyzed to reveal the pier height effects on the running safety of trains on bridges.The results show that when the pier height changes,the frequency of the bridge below the 30 m pier height changes greater;the increase of pier height causes the transverse fundamental frequency of the bridge close to that of the train,and the shaking angle and lateral displacement of the train are the largest for bridge with 50 m pier,which increases the risk of derailment;with the pier height increases from 8 m to 50 m,the derailment coefficient obtained by numerical simulations increases by 75% on average,and the spectral intensity obtained by experiments increases by 120% on average,two indicators exhibit logarithmic variation.展开更多
Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can b...Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can be well characterized based on various stochastic excitations.A three-dimensional refined spatial random vibration analysis model of high-speed maglev train-bridge coupled system is established in this paper,in which multi-source uncertainty excitation can be considered simultaneously,and the probability density evolution method(PDEM)is adopted to reveal the system-specific uncertainty dynamic characteristic.The motion equation of the maglev vehicle model is composed of multi-rigid bodies with a total 210-degrees of freedom for each vehicle,and a refined electromagnetic force-air gap model is used to account for the interaction and coupling effect between the moving train and track beam bridges,which are directly established by using finite element method.The model is proven to be applicable by comparing with Monte Carlo simulation.By applying the proposed stochastic framework to the high maglev line,the random dynamic responses of maglev vehicles running on the bridges are studied for running safety and stability assessment.Moreover,the effects of track irregularity wavelength range under different amplitude and running speeds on the coupled system are investigated.The results show that the augmentation of train speed will move backward the sensitive wavelength interval,and track irregularity amplitude influences the response remarkably in the sensitive interval.展开更多
A multistage assessment index set is chosen based on the analysis of building fire safety system, whereby the weight of each index is determined through an analy tie.hierarchy process; a fuzzy synthetic assessment mod...A multistage assessment index set is chosen based on the analysis of building fire safety system, whereby the weight of each index is determined through an analy tie.hierarchy process; a fuzzy synthetic assessment model for the building fire safety system is constructed, and the quantified result was obtained by using hierarchy parameter judgment. This fuzzy synthetic assessment method can quantify assessment result of the building fire safety system, so thatthe fire precautions may be accurately adopted, and the serious potential risk may be avoided. The application shows that this method possesses both objectivity and feasibility.展开更多
Based on the tunnel shape, span and depth, the previous elliptical plate model and clamped beam model were modified.The modified model was applied to different situations. For the elliptical plate model, the water eff...Based on the tunnel shape, span and depth, the previous elliptical plate model and clamped beam model were modified.The modified model was applied to different situations. For the elliptical plate model, the water effects were considered. For the clamped beam model, water and horizontal stress were considered. Corresponding potential functions and cusp catastrophe models of rock system were established based on the catastrophe theory. The expressions of critical safety thickness were derived with necessary and sufficient conditions. The method was applied to the practical engineering. Some parameters related to the stability were discussed. The results show that elastic modulus and thickness are advantageous to the floor stability, and that the load, span,horizontal stress and water are disadvantageous to the floor stability.展开更多
Bridges crossing active faults are more likely to suffer serious damage or even collapse due to the wreck capabilities of near-fault pulses and surface ruptures under earthquakes.Taking a high-speed railway simply-sup...Bridges crossing active faults are more likely to suffer serious damage or even collapse due to the wreck capabilities of near-fault pulses and surface ruptures under earthquakes.Taking a high-speed railway simply-supported girder bridge with eight spans crossing an active strike-slip fault as the research object,a refined coupling dynamic model of the high-speed train-CRTS III slab ballastless track-bridge system was established based on ABAQUS.The rationality of the established model was thoroughly discussed.The horizontal ground motions in a fault rupture zone were simulated and transient dynamic analyses of the high-speed train-track-bridge coupling system under 3-dimensional seismic excitations were subsequently performed.The safe running speed limits of a high-speed train under different earthquake levels(frequent occurrence,design and rare occurrence)were assessed based on wheel-rail dynamic(lateral wheel-rail force,derailment coefficient and wheel-load reduction rate)and rail deformation(rail dislocation,parallel turning angle and turning angle)indicators.Parameter optimization was then investigated in terms of the rail fastener stiffness and isolation layer friction coefficient.Results of the wheel-rail dynamic indicators demonstrate the safe running speed limits for the high-speed train to be approximately 200 km/h and 80 km/h under frequent and design earthquakes,while the train is unable to run safely under rare earthquakes.In addition,the rail deformations under frequent,design and rare earthquakes meet the safe running requirements of the high-speed train for the speeds of 250,100 and 50 km/h,respectively.The speed limits determined for the wheel-rail dynamic indicators are lower due to the complex coupling effect of the train-track-bridge system under track irregularity.The running safety of the train was improved by increasing the fastener stiffness and isolation layer friction coefficient.At the rail fastener lateral stiffness of 60 kN/mm and isolation layer friction coefficients of 0.9 and 0.8,respectively,the safe running speed limits of the high-speed train increased to 250 km/h and 100 km/h under frequent and design earthquakes,respectively.展开更多
The transient pressures induced by trains passing through a tunnel and their impact on the structural safety of the tunnel lining were numerically analyzed.The results show that the pressure change increases rapidly a...The transient pressures induced by trains passing through a tunnel and their impact on the structural safety of the tunnel lining were numerically analyzed.The results show that the pressure change increases rapidly along the tunnel length,and the maximum value is observed at around 200 m from the entrance,while the maximum pressure amplitude is detected at 250 m from the entrance when two trains meeting in a double-track tunnel.The maximum peak pressure on the tunnel induced by a train passing through a 70 m^(2) single-track tunnel,100 m^(2) double-track tunnel and two trains meeting in the 100 m^(2) double-track tunnel at 350 km/h,are−4544 Pa,−3137 Pa and−5909 Pa,respectively.The aerodynamic pressure induced axial forces acting on the tunnel lining are only 8%,5%and 9%,respectively,of those generated by the earth pressure.It seems that the aerodynamic loads exert little underlying influence on the static strength safety of the tunnel lining providing that the existing cracks and defects are not considered.展开更多
3-nitro-1,2,4-triazol-5-one(NTO)is the main component of insensitive munitions(IM)formulation because of its outstanding insensitive properties.In this paper,a series of NTO/HMX-based compositeexplosives were prepared...3-nitro-1,2,4-triazol-5-one(NTO)is the main component of insensitive munitions(IM)formulation because of its outstanding insensitive properties.In this paper,a series of NTO/HMX-based compositeexplosives were prepared and characterized.The study focuses on the effect of NTO on the perfommance of the formulations,especially the safety performance.The results revealed that the mechanical sensi-tivity of fomulations was associated with NTO content,as well as the thermal conductivity,specific heat capacity and Arrhenius parameters.Then,the high amount of NTO using in formulation was proved to be helpful for NTO/HMX-based formulation to exhibit good thermal safety.Besides,by accelerating rate calorimeter(ARC)and a modified cook-off equipment,the pressure and pressure rise rate were proved as the important indicator for judging the thermal safety performance in confined spaces.Finally,the numerical simulation was used as a credible method for predicting the respond temperature of cook-off experiment.展开更多
The thermal behavior,non-isothermal thermal decomposition reaction kinetics and specific heat capacity of hexanitro-hexaazaisowurtzitane(HNIW)were studied by differential scanning calorimeter(DSC)and Micro-DSCIapparat...The thermal behavior,non-isothermal thermal decomposition reaction kinetics and specific heat capacity of hexanitro-hexaazaisowurtzitane(HNIW)were studied by differential scanning calorimeter(DSC)and Micro-DSCIapparatus,The kinetic parameters of the thermal decomposition reaction(the apparent activation energy(E,)and pre-exponential factor(A))were calcu-lated by non-isothermal DSC curves.The results show that the differential mlechanism function and values of E,and A of the ther-mal decomposition reaction of HNIW are 3(1-a)[-ln(1-a)]"·,155.04 kJ·mol^(-1)and 10""s^(-1),respectively.The critical tem-perature of thermal explosion of the title compound is 226.60℃.The entropy of activation(AS·),enthalpy of activation(AH·)and free energy of activation(AG·)of this reaction are 11.60J·mol·K^(-1),152.04 kJ·mol^(-1)and 146.29 kJ·mol^(-1),respec-tively.The equation of specific heat capacity of HNIW with temperature is C,=0.2472+0.002705992Tin the temperature range of 283 K to 343K.The values of self-accelerating decomposition temperature,adiabatic time-to-maximum decomposition rate and adiabatic time-to-explosion are 486.5K,54.81s and 54.31s,respectively.Thermal sensitivity probability density distribution curve of HNIW is constructed.展开更多
Thermal safety of modular charge which is fed into and retained in the chamber after gun fires consecutively is first investigated with cook-off method,A two-dimensional cook-off model of modular charge in gun chamber...Thermal safety of modular charge which is fed into and retained in the chamber after gun fires consecutively is first investigated with cook-off method,A two-dimensional cook-off model of modular charge in gun chamber is established and the cook-off process of modular charge in gun chamber is numerically simulated.Then the effects of module number and firing condition on charge thermal safety are evaluated by researching the cook-off response characteristics of modules.The results show that under conditions of different module numbers the cook-off responses all occur on the module closest to the boundary of missile,and the single-base propellants located at the inner surface of cartridge ignite first.When the number of loaded module changes from 1 to 6,the cook-off response temperatures vary little,only in a small range of 478.1 K-482.4 K.The cook-off response times decrease logarithmically in the range of 211.25-166.7 s with the increasing length of residual air gap in gun chamber.The simulation results are well matched with the experimental data.Furthermore,different firing conditions have greatinfluence on the cook-off response time,minor influence on the initial response position and little in-fluence on the response temperature.Under the three conditions of consecutive 32 launches with 5 rounds/min,43 launches with 1 round/min,and 41 launches with different firing frequencies,the cook off response temperatures are 479.2 K,481.1 K and 479.9 K respectively and the response times are 709.25,211.2 s and 214.4 s respectively.The response position is near the middle area of the inner cartridge surface in the former condition and near the right area in the latter two conditions.展开更多
Fault prediction technology of running state of electromechanical systems is one of the key technologies that ensure safe and reliable operation of electromechanical equipment in health state. For multiple types of mo...Fault prediction technology of running state of electromechanical systems is one of the key technologies that ensure safe and reliable operation of electromechanical equipment in health state. For multiple types of modern, high-end and key electromechanical equipment, this paper will describe the early faults prediction method for multi-type electromechanical systems, which is favorable for predicting early faults of complex electromechanical systems in non-stationary, nonlinear, variable working conditions and long-time running state; the paper shall introduce the reconfigurable integration technology of series safety monitoring systems based on which the integrated development platform of series safety monitoring systems is built. This platform can adapt to integrated R&D of series safety monitoring systems characterized by high technology, multiple species and low volume. With the help of this platform, series safety monitoring systems were developed, and the Remote Network Security Monitoring Center for Facility Groups was built. Experimental research and engineering applications show that: this new fault prediction method has realized the development trend features extraction of typical electromechanical systems, multi-information fusion, intelligent information decision-making and so on, improving the processing accuracy, relevance and applicability of information; new reconfigurable integration technologies have improved the integration level and R&D efficiency of series safety monitoring systems as well as expanded the scope of application; the series safety monitoring systems developed based on reconfigurable integration platform has already played an important role in many aspects including ensuring safety operation of equipment, stabilizing product quality, optimizing running state, saving energy consumption, reducing environmental pollution, improving working conditions, carrying out scientific maintenance, advancing equipment utilization, saving maintenance charge and enhancing the level of information management.展开更多
The wheel brake system safety is a complex problem which refers to its technical state, operating environment, human factors, etc., in aircraft landing taxiing process. Usually, professors consider system safety with ...The wheel brake system safety is a complex problem which refers to its technical state, operating environment, human factors, etc., in aircraft landing taxiing process. Usually, professors consider system safety with traditional probability techniques based on the linear chain of events. However, it could not comprehensively analyze system safety problems, especially in operating environment, interaction of subsystems, and human factors. Thus,we consider system safety as a control problem based on the system-theoretic accident model, the processes(STAMP) model and the system theoretic process analysis(STPA) technique to compensate the deficiency of traditional techniques. Meanwhile,system safety simulation is considered as system control simulation, and Monte Carlo methods are used which consider the range of uncertain parameters and operation deviation to quantitatively study system safety influence factors in control simulation. Firstly,we construct the STAMP model and STPA feedback control loop of the wheel brake system based on the system functional requirement. Then four unsafe control actions are identified, and causes of them are analyzed. Finally, we construct the Monte Carlo simulation model to analyze different scenarios under disturbance. The results provide a basis for choosing corresponding process model variables in constructing the context table and show that appropriate brake strategies could prevent hazards in aircraft landing taxiing.展开更多
The emergence of TKX-50,an energetic ionic salt with a high enthalpy of formation and low sensitivity,has opened a new path for the development of high-energetic,insensitive composite explosives.However,due to the poo...The emergence of TKX-50,an energetic ionic salt with a high enthalpy of formation and low sensitivity,has opened a new path for the development of high-energetic,insensitive composite explosives.However,due to the poor interfacial binding properties of TKX-50 with conventional binders,there is a lack of effective guidance for the design of TKX-50 based composite explosives.To address the above issues,the interactions between carboxymethyl cellulose acetate butyrate(CMCAB)and other binders with explosives TKX-50/HMX were compared using the molecular dynamics method.Based on the simulations,TKX-50/HMX/CMCAB-based polymer-bonded explosives(PBXs)were prepared with CMCAB as binder,which displays a high binding energy(Ebind)with TKX-50 and high cohesive energy density(CED),and the effect of TKX-50 content on the performance of PBXs was investigated.The physical properties of PBXs,specifically the morphology,mechanical sensitivity,and thermal conductivity,were analyzed by SEM,sensitivity apparatus,and thermal conductivity meter,respectively.The specific heat capacity(Cp)and non-isothermal decomposition temperature of PBXs were tested by DSC,and then the corresponding thermal kinetic parameters were analyzed to evaluate their thermal safety.The adiabatic thermal decomposition processes of PBXs were tested using an ARC instrument.The decomposition mechanism and kinetics were also explored to further analyze their thermal stability and thermal safety under adiabatic conditions.The computer code EXPLO5 was used to predict the detonation parameters of PBXs.The results showed that CMCAB and TKX-50 displayed favorable interfacial bonding properties,and TKX-50 can be bonded with HMX to form a molding powder with a desirable morphology and safety profile.The TKX-50 in PBXs effectively improves the mechanical sensitivity and thermal safety of PBX and has a significant effect on the detonation performance of PBX.This research demonstrates a novel method suitable for screening and investigating high-energetic insensitive explosive systems compatible with TKX-50.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.22005275).
文摘Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In order to obtain high-quality HMX@PDA-based PBX explosives with high sphericity and a narrow particle size distribution,composite microspheres were prepared using co-axial droplet microfluidic technology.The formation mechanism,thermal behavior,mechanical sensitivity,electrostatic spark sensitivity,compressive strength,and combustion performance of the microspheres were investigated.The results show that PDA can effectively enhance the interfacial interaction between the explosive particles and the binder under the synergistic effect of chemical bonds and the physical"mechanical interlocking"structure.Interface reinforcement causes the thermal decomposition temperature of the sample microspheres to move to a higher temperature,with the sensitivity to impact,friction,and electrostatic sparks(for S-1)increasing by 12.5%,31.3%,and 81.5%respectively,and the compressive strength also increased by 30.7%,effectively enhancing the safety performance of the microspheres.Therefore,this study provides an effective and universal strategy for preparing high-quality functional explosives,and also provides some reference for the safe use of energetic materials in practical applications.
基金supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX24_0714).
文摘To examine the similarities and differences in the evolution of cavity,wetting and dynamics of a highspeed,oblique water-entry projectile with different positive angles of attack,a comparative analysis has been conducted based on the numerical results of two mathematical models,the rigid-body model and fluid-structure interaction model.In addition,the applicable scope of the above two methods,and the structural response characteristics of the projectile have also been investigated.Our results demonstrate that:(1) The impact loads and angular motion of the projectile of the rigid-body method are more likely to exhibit periodic variations due to the periodic tail slap,its range of positive angles of attack is about α<2°.(2) When the projectile undergone significant wetting,a strong coupling effect is observed among wetting,structural deformation,and projectile motion.With the applied projectile shape,it is observed that,when the projectile bends,the final wetting position is that of Part B(cylinder of body).With the occu rrence of this phenomenon,the projectile ballistics beco me completely unstable.(3) The force exerted on the lower surface of the projectile induced by wetting is the primary reason of the destabilization of the projectile traj ectory and structu ral deformation failure.Bending deformation is most likely to appear at the junction of Part C(cone of body) and Part D(tail).The safe angles of attack of the projectile stability are found to be about α≤2°.
基金financially supported by National Natural Science Foundation of China(Grant Nos.52378401,52278504)the Fundamental Research Funds for the Central Universities(Grant No.30922010918)。
文摘Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and equipment.Accurate prediction of the distribution pattern of explosive loads and shock wave propagation process in semi-enclosed structures at various altitude environment is key research focus in the fields of explosion shock and fluid dynamics.The effect of altitude on the propagation of shock waves in tunnels was investigated by conducting explosion test and numerical simulation.Based on the experimental and numerical simulation results,a prediction model for the attenuation of the peak overpressure of tunnel shock waves at different altitudes was established.The results showed that the peak overpressure decreased at the same measurement points in the tunnel entrance under the high altitude condition.In contrast,an increase in altitude accelerated the propagation speed of the shock wave in the tunnel.The average error between the peak shock wave overpressure obtained using the overpressure prediction formula and the measured test data was less than15%,the average error between the propagation velocity of shock waves predicted values and the test data is less than 10%.The method can effectively predict the overpressure attenuation of blast wave in tunnel at various altitudes.
基金supported by the Special Project for the Construction of Innovative Provinces in Hunan Province,China(2020SK2013)。
文摘Objective:In recent years,the incidence and detection rate of pancreatic cystic lesions(PCLs)have increased significantly.Endoscopic ultrasound(EUS)plays an indispensable role in the diagnosis and differential diagnosis of PCLs.However,evidence comparing the diagnostic performance of EUS-guided fine-needle aspiration(EUS-FNA)and fine-needle biopsy(FNB)remains limited.This study aims to compare the diagnostic yield,adequacy of tissue acquisition,and safety between EUS-FNA and EUS-FNB in evaluating PCLs to inform clinical practice.Methods:A retrospective review was conducted on patients with PCLs who underwent either EUS-FNA or EUS-FNB between January 2014 and August 2021.The diagnostic yield,tissue acquisition adequacy,and incidence of adverse events were compared between the 2 groups.Results:A total of 90 patients with PCLs were included(52 in the FNA group and 38 in the FNB group).The diagnostic yield was similar between the FNA and FNB groups(94.2%vs 94.7%,P>0.05).The adequacy of tissue acquisition was 71.2%in the FNA group and 81.6%in the FNB group(P>0.05).No statistically significant difference was observed in the incidence of adverse events between the 2 groups(P>0.05).Conclusion:Both EUS-FNA and EUS-FNB demonstrate equally high diagnostic yields and tissue adequacy in PCLs,with excellent safety profiles.Both methods are safe and effective diagnostic tools for evaluating PCLs.
基金the experimental technology support provided by the China Academy of Launch Vehicle Technology
文摘Sea-based rocket launches encounter significant challenges stemming from dynamic marine environmental interactions.During the hot launch phase,characterized by low-velocity ascent,the departure of the rocket from the oscillatory platform exhibits heightened sensitivity to external disturbances.In the development stage,assessing the launch dynamics and the clearance between the rocket and framed launcher are crucial for improving the reliability of sea-based rocket launches in rough sea conditions.This study presents a high-fidelity dynamic model of maritime hot launch system,demonstrating 3.21%prediction error through rigorous validation against experimental datasets from comprehensive modal analyses and the full-scale rocket flight test.To mitigate collision risks,we develop a computational method employing spatial vector analysis for dynamic measurement of rocket-launcher clearance during departure.Systematic investigations reveal that in rough sea conditions,optimal departure dynamics are achieved at θ_(thrust)=270°nozzle azimuth configuration,reducing failure probability compared to conventional orientations.The developed assessment framework not only resolves critical safety challenges in current sea launch systems but also establishes foundational principles for optimizing adapter axial configuration patterns in future designs.
基金financially supported by the Fundamental Research Funds for the Central Universities(Grant No.30923011018)。
文摘The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.
文摘The impact safety of explosive charges has been focused in these decades. The fragment impact is widely used to evaluate the response of explosive charges. In our work, the explosive detonation driving technique was used to generate a high velocity fragment with large mass. When the fragment masses are10 g, 16 g, 25 g, and 50 g, the highest velocity of fragments can reach 2400 m/s, 2100 m/s, 1900 m/s, and1400 m/s, respectively. The high velocity fragment with large mass was used to evaluate the safety of two kinds of CL-20 based explosive charges. The effects of the fragment mass and velocity were analyzed.Especially, the reaction extent was obtained based on visible phenomenon. The CL-20-based explosive charge containing Al had a higher safety level than that without Al. It was because Al had good ductility,and further improved the mechanical property of the material. Also, the numerical simulation was conducted to understand the reaction characteristics of the CL-20-based explosive charge. The results showed that as the fragment mass and velocity increased, the reaction became more violent.
基金financially supported by the National Natural Science Foundation of China (Grant No. 22275173)the Open Project of State Key Laboratory of Environment-friendly Energy Materials (Grant No. 22kfhg10)。
文摘The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricated to address the above issues.The coordination complexes which consist of natural polyphenol tannic acid(TA) and Fe~Ⅲ were chosen to construct the inner shell,while the graphene sheets were used to build the outer shell.The resulting CL-20/TA-Fe~Ⅲ/graphene composites exhibited simultaneously improved thermal stability and safety performance with only 1 wt% double-shell content,which should be ascribed to the intense physical encapsulation effect from inner shell combined with the desensitization effect of carbon nano-materials from outer shell.The phase transition(ε to γ) temperature increased from 173.70 ℃ of pure CL-20 to 191.87℃ of CL-20/TA-Fe~Ⅲ/graphene composites.Meanwhile,the characteristic drop height(H_(50)) dramatically increased from 14.7 cm of pure CL-20 to112.8 cm of CL-20/TA-Fe~Ⅲ/graphene composites,indicating much superior safety performance after the construction of the double-shell structure.In general,this work has provided an effective and versatile strategy to conquer the thermal stability and safety issues of CL-20 and contributes to the future application of high energy density energetic materials.
基金Projects(52022113,52278546)supported by the National Natural Science Foundation of ChinaProject(2020EEEVL0403)supported by the China Earthquake Administration。
文摘Sudden earthquakes pose a threat to the running safety of trains on high-speed railway bridges,and the stiffness of piers is one of the factors affecting the dynamic response of train-track-bridge system.In this paper,a experiment of a train running on a high-speed railway bridge is performed based on a dynamic experiment system,and the corresponding numerical model is established.The reliability of the numerical model is verified by experiments.Then,the experiment and numerical data are analyzed to reveal the pier height effects on the running safety of trains on bridges.The results show that when the pier height changes,the frequency of the bridge below the 30 m pier height changes greater;the increase of pier height causes the transverse fundamental frequency of the bridge close to that of the train,and the shaking angle and lateral displacement of the train are the largest for bridge with 50 m pier,which increases the risk of derailment;with the pier height increases from 8 m to 50 m,the derailment coefficient obtained by numerical simulations increases by 75% on average,and the spectral intensity obtained by experiments increases by 120% on average,two indicators exhibit logarithmic variation.
基金Project(2023YFB4302500)supported by the National Key R&D Program of ChinaProject(52078485)supported by the National Natural Science Foundation of ChinaProjects(2021-Major-16,2021-Special-08)supported by the Science and Technology Research and Development Program Project of China Railway Group Limited。
文摘Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can be well characterized based on various stochastic excitations.A three-dimensional refined spatial random vibration analysis model of high-speed maglev train-bridge coupled system is established in this paper,in which multi-source uncertainty excitation can be considered simultaneously,and the probability density evolution method(PDEM)is adopted to reveal the system-specific uncertainty dynamic characteristic.The motion equation of the maglev vehicle model is composed of multi-rigid bodies with a total 210-degrees of freedom for each vehicle,and a refined electromagnetic force-air gap model is used to account for the interaction and coupling effect between the moving train and track beam bridges,which are directly established by using finite element method.The model is proven to be applicable by comparing with Monte Carlo simulation.By applying the proposed stochastic framework to the high maglev line,the random dynamic responses of maglev vehicles running on the bridges are studied for running safety and stability assessment.Moreover,the effects of track irregularity wavelength range under different amplitude and running speeds on the coupled system are investigated.The results show that the augmentation of train speed will move backward the sensitive wavelength interval,and track irregularity amplitude influences the response remarkably in the sensitive interval.
文摘A multistage assessment index set is chosen based on the analysis of building fire safety system, whereby the weight of each index is determined through an analy tie.hierarchy process; a fuzzy synthetic assessment model for the building fire safety system is constructed, and the quantified result was obtained by using hierarchy parameter judgment. This fuzzy synthetic assessment method can quantify assessment result of the building fire safety system, so thatthe fire precautions may be accurately adopted, and the serious potential risk may be avoided. The application shows that this method possesses both objectivity and feasibility.
基金Project(2013CB036004)supported by the National Basic Research Program of ChinaProject(51378510)supported by the National Natural Science Foundation of China
文摘Based on the tunnel shape, span and depth, the previous elliptical plate model and clamped beam model were modified.The modified model was applied to different situations. For the elliptical plate model, the water effects were considered. For the clamped beam model, water and horizontal stress were considered. Corresponding potential functions and cusp catastrophe models of rock system were established based on the catastrophe theory. The expressions of critical safety thickness were derived with necessary and sufficient conditions. The method was applied to the practical engineering. Some parameters related to the stability were discussed. The results show that elastic modulus and thickness are advantageous to the floor stability, and that the load, span,horizontal stress and water are disadvantageous to the floor stability.
基金Project(51378050) supported by the National Natural Science Foundation of ChinaProject(B13002) supported by the “111” Project,China+2 种基金Project (8192035) supported by the Beijing Municipal Natural Science Foundation,ChinaProject(P2019G002) supported by the Science and Technology Research and Development Program of China RailwayProject(2019YJ193) supported by the State Key Laboratory for Track Technology of High-speed Railway,China。
文摘Bridges crossing active faults are more likely to suffer serious damage or even collapse due to the wreck capabilities of near-fault pulses and surface ruptures under earthquakes.Taking a high-speed railway simply-supported girder bridge with eight spans crossing an active strike-slip fault as the research object,a refined coupling dynamic model of the high-speed train-CRTS III slab ballastless track-bridge system was established based on ABAQUS.The rationality of the established model was thoroughly discussed.The horizontal ground motions in a fault rupture zone were simulated and transient dynamic analyses of the high-speed train-track-bridge coupling system under 3-dimensional seismic excitations were subsequently performed.The safe running speed limits of a high-speed train under different earthquake levels(frequent occurrence,design and rare occurrence)were assessed based on wheel-rail dynamic(lateral wheel-rail force,derailment coefficient and wheel-load reduction rate)and rail deformation(rail dislocation,parallel turning angle and turning angle)indicators.Parameter optimization was then investigated in terms of the rail fastener stiffness and isolation layer friction coefficient.Results of the wheel-rail dynamic indicators demonstrate the safe running speed limits for the high-speed train to be approximately 200 km/h and 80 km/h under frequent and design earthquakes,while the train is unable to run safely under rare earthquakes.In addition,the rail deformations under frequent,design and rare earthquakes meet the safe running requirements of the high-speed train for the speeds of 250,100 and 50 km/h,respectively.The speed limits determined for the wheel-rail dynamic indicators are lower due to the complex coupling effect of the train-track-bridge system under track irregularity.The running safety of the train was improved by increasing the fastener stiffness and isolation layer friction coefficient.At the rail fastener lateral stiffness of 60 kN/mm and isolation layer friction coefficients of 0.9 and 0.8,respectively,the safe running speed limits of the high-speed train increased to 250 km/h and 100 km/h under frequent and design earthquakes,respectively.
基金Project(51975591)supported by the National Natural Science Foundation of ChinaProject(P2018J003)supported by the Technology Research and Development Program of China Railway。
文摘The transient pressures induced by trains passing through a tunnel and their impact on the structural safety of the tunnel lining were numerically analyzed.The results show that the pressure change increases rapidly along the tunnel length,and the maximum value is observed at around 200 m from the entrance,while the maximum pressure amplitude is detected at 250 m from the entrance when two trains meeting in a double-track tunnel.The maximum peak pressure on the tunnel induced by a train passing through a 70 m^(2) single-track tunnel,100 m^(2) double-track tunnel and two trains meeting in the 100 m^(2) double-track tunnel at 350 km/h,are−4544 Pa,−3137 Pa and−5909 Pa,respectively.The aerodynamic pressure induced axial forces acting on the tunnel lining are only 8%,5%and 9%,respectively,of those generated by the earth pressure.It seems that the aerodynamic loads exert little underlying influence on the static strength safety of the tunnel lining providing that the existing cracks and defects are not considered.
基金The authors are grateful to the National Defense Foundation of China(3090021322001,3090020221912,3090021211903.)for financial support of this work.
文摘3-nitro-1,2,4-triazol-5-one(NTO)is the main component of insensitive munitions(IM)formulation because of its outstanding insensitive properties.In this paper,a series of NTO/HMX-based compositeexplosives were prepared and characterized.The study focuses on the effect of NTO on the perfommance of the formulations,especially the safety performance.The results revealed that the mechanical sensi-tivity of fomulations was associated with NTO content,as well as the thermal conductivity,specific heat capacity and Arrhenius parameters.Then,the high amount of NTO using in formulation was proved to be helpful for NTO/HMX-based formulation to exhibit good thermal safety.Besides,by accelerating rate calorimeter(ARC)and a modified cook-off equipment,the pressure and pressure rise rate were proved as the important indicator for judging the thermal safety performance in confined spaces.Finally,the numerical simulation was used as a credible method for predicting the respond temperature of cook-off experiment.
基金The National Nature Science Foundation of China(21173163)
文摘The thermal behavior,non-isothermal thermal decomposition reaction kinetics and specific heat capacity of hexanitro-hexaazaisowurtzitane(HNIW)were studied by differential scanning calorimeter(DSC)and Micro-DSCIapparatus,The kinetic parameters of the thermal decomposition reaction(the apparent activation energy(E,)and pre-exponential factor(A))were calcu-lated by non-isothermal DSC curves.The results show that the differential mlechanism function and values of E,and A of the ther-mal decomposition reaction of HNIW are 3(1-a)[-ln(1-a)]"·,155.04 kJ·mol^(-1)and 10""s^(-1),respectively.The critical tem-perature of thermal explosion of the title compound is 226.60℃.The entropy of activation(AS·),enthalpy of activation(AH·)and free energy of activation(AG·)of this reaction are 11.60J·mol·K^(-1),152.04 kJ·mol^(-1)and 146.29 kJ·mol^(-1),respec-tively.The equation of specific heat capacity of HNIW with temperature is C,=0.2472+0.002705992Tin the temperature range of 283 K to 343K.The values of self-accelerating decomposition temperature,adiabatic time-to-maximum decomposition rate and adiabatic time-to-explosion are 486.5K,54.81s and 54.31s,respectively.Thermal sensitivity probability density distribution curve of HNIW is constructed.
文摘Thermal safety of modular charge which is fed into and retained in the chamber after gun fires consecutively is first investigated with cook-off method,A two-dimensional cook-off model of modular charge in gun chamber is established and the cook-off process of modular charge in gun chamber is numerically simulated.Then the effects of module number and firing condition on charge thermal safety are evaluated by researching the cook-off response characteristics of modules.The results show that under conditions of different module numbers the cook-off responses all occur on the module closest to the boundary of missile,and the single-base propellants located at the inner surface of cartridge ignite first.When the number of loaded module changes from 1 to 6,the cook-off response temperatures vary little,only in a small range of 478.1 K-482.4 K.The cook-off response times decrease logarithmically in the range of 211.25-166.7 s with the increasing length of residual air gap in gun chamber.The simulation results are well matched with the experimental data.Furthermore,different firing conditions have greatinfluence on the cook-off response time,minor influence on the initial response position and little in-fluence on the response temperature.Under the three conditions of consecutive 32 launches with 5 rounds/min,43 launches with 1 round/min,and 41 launches with different firing frequencies,the cook off response temperatures are 479.2 K,481.1 K and 479.9 K respectively and the response times are 709.25,211.2 s and 214.4 s respectively.The response position is near the middle area of the inner cartridge surface in the former condition and near the right area in the latter two conditions.
基金Supported by National Natural Science Fund Project(51275052)Key project supported by Beijing Municipal Natural Science Foundation(3131002)Open topic of Key Laboratory of Key Laboratory of Modern Measurement & Control Technology,Ministry of Education(KF20141123202,KF20111123201)
文摘Fault prediction technology of running state of electromechanical systems is one of the key technologies that ensure safe and reliable operation of electromechanical equipment in health state. For multiple types of modern, high-end and key electromechanical equipment, this paper will describe the early faults prediction method for multi-type electromechanical systems, which is favorable for predicting early faults of complex electromechanical systems in non-stationary, nonlinear, variable working conditions and long-time running state; the paper shall introduce the reconfigurable integration technology of series safety monitoring systems based on which the integrated development platform of series safety monitoring systems is built. This platform can adapt to integrated R&D of series safety monitoring systems characterized by high technology, multiple species and low volume. With the help of this platform, series safety monitoring systems were developed, and the Remote Network Security Monitoring Center for Facility Groups was built. Experimental research and engineering applications show that: this new fault prediction method has realized the development trend features extraction of typical electromechanical systems, multi-information fusion, intelligent information decision-making and so on, improving the processing accuracy, relevance and applicability of information; new reconfigurable integration technologies have improved the integration level and R&D efficiency of series safety monitoring systems as well as expanded the scope of application; the series safety monitoring systems developed based on reconfigurable integration platform has already played an important role in many aspects including ensuring safety operation of equipment, stabilizing product quality, optimizing running state, saving energy consumption, reducing environmental pollution, improving working conditions, carrying out scientific maintenance, advancing equipment utilization, saving maintenance charge and enhancing the level of information management.
文摘The wheel brake system safety is a complex problem which refers to its technical state, operating environment, human factors, etc., in aircraft landing taxiing process. Usually, professors consider system safety with traditional probability techniques based on the linear chain of events. However, it could not comprehensively analyze system safety problems, especially in operating environment, interaction of subsystems, and human factors. Thus,we consider system safety as a control problem based on the system-theoretic accident model, the processes(STAMP) model and the system theoretic process analysis(STPA) technique to compensate the deficiency of traditional techniques. Meanwhile,system safety simulation is considered as system control simulation, and Monte Carlo methods are used which consider the range of uncertain parameters and operation deviation to quantitatively study system safety influence factors in control simulation. Firstly,we construct the STAMP model and STPA feedback control loop of the wheel brake system based on the system functional requirement. Then four unsafe control actions are identified, and causes of them are analyzed. Finally, we construct the Monte Carlo simulation model to analyze different scenarios under disturbance. The results provide a basis for choosing corresponding process model variables in constructing the context table and show that appropriate brake strategies could prevent hazards in aircraft landing taxiing.
基金supported by“the Fundamental Research Funds for the Central Universities”.
文摘The emergence of TKX-50,an energetic ionic salt with a high enthalpy of formation and low sensitivity,has opened a new path for the development of high-energetic,insensitive composite explosives.However,due to the poor interfacial binding properties of TKX-50 with conventional binders,there is a lack of effective guidance for the design of TKX-50 based composite explosives.To address the above issues,the interactions between carboxymethyl cellulose acetate butyrate(CMCAB)and other binders with explosives TKX-50/HMX were compared using the molecular dynamics method.Based on the simulations,TKX-50/HMX/CMCAB-based polymer-bonded explosives(PBXs)were prepared with CMCAB as binder,which displays a high binding energy(Ebind)with TKX-50 and high cohesive energy density(CED),and the effect of TKX-50 content on the performance of PBXs was investigated.The physical properties of PBXs,specifically the morphology,mechanical sensitivity,and thermal conductivity,were analyzed by SEM,sensitivity apparatus,and thermal conductivity meter,respectively.The specific heat capacity(Cp)and non-isothermal decomposition temperature of PBXs were tested by DSC,and then the corresponding thermal kinetic parameters were analyzed to evaluate their thermal safety.The adiabatic thermal decomposition processes of PBXs were tested using an ARC instrument.The decomposition mechanism and kinetics were also explored to further analyze their thermal stability and thermal safety under adiabatic conditions.The computer code EXPLO5 was used to predict the detonation parameters of PBXs.The results showed that CMCAB and TKX-50 displayed favorable interfacial bonding properties,and TKX-50 can be bonded with HMX to form a molding powder with a desirable morphology and safety profile.The TKX-50 in PBXs effectively improves the mechanical sensitivity and thermal safety of PBX and has a significant effect on the detonation performance of PBX.This research demonstrates a novel method suitable for screening and investigating high-energetic insensitive explosive systems compatible with TKX-50.
