Automatic modulation classification(AMC) technology is one of the cutting-edge technologies in cognitive radio communications. AMC based on deep learning has recently attracted much attention due to its superior perfo...Automatic modulation classification(AMC) technology is one of the cutting-edge technologies in cognitive radio communications. AMC based on deep learning has recently attracted much attention due to its superior performances in classification accuracy and robustness. In this paper, we propose a novel, high resolution and multi-scale feature fusion convolutional neural network model with a squeeze-excitation block, referred to as HRSENet,to classify different kinds of modulation signals.The proposed model establishes a parallel computing mechanism of multi-resolution feature maps through the multi-layer convolution operation, which effectively reduces the information loss caused by downsampling convolution. Moreover, through dense skipconnecting at the same resolution and up-sampling or down-sampling connection at different resolutions, the low resolution representation of the deep feature maps and the high resolution representation of the shallow feature maps are simultaneously extracted and fully integrated, which is benificial to mine signal multilevel features. Finally, the feature squeeze and excitation module embedded in the decoder is used to adjust the response weights between channels, further improving classification accuracy of proposed model.The proposed HRSENet significantly outperforms existing methods in terms of classification accuracy on the public dataset “Over the Air” in signal-to-noise(SNR) ranging from-2dB to 20dB. The classification accuracy in the proposed model achieves 85.36% and97.30% at 4dB and 10dB, respectively, with the improvement by 9.71% and 5.82% compared to LWNet.Furthermore, the model also has a moderate computation complexity compared with several state-of-the-art methods.展开更多
Deep learning techniques are revolutionizing the developmentof medical image segmentation.With the advancement of Transformer models,especially ViT and Swin-Transformer,which enhances the remote-dependent modeling cap...Deep learning techniques are revolutionizing the developmentof medical image segmentation.With the advancement of Transformer models,especially ViT and Swin-Transformer,which enhances the remote-dependent modeling capability of the model through the self-attention mechanism,better segmentation performance can be achieve.Moreover,the high computational cost of Transformer has motivated researchers to explore more efficient models,such as the Mamba model based on state-space modeling(SSM),and for the field of medical segmentation,reducing the number of model parameters is also necessary.In this study,a novel asymmetric model called LA-UMamba was proposed,which integrates visual Mamba module to efficiently capture complex visual features and remote dependencies.The classical design of U-Net was adopted in the upsampling phase to help reduce the number of references and recover more details.To mitigate the information loss problem,an auxiliary U-Net downsampling layer was designed to focus on sizing without extracting features,thus enhancing the protection of input information while maintaining the efficiency of the model.The experiments were conducted on the ACDC MRI cardiac segmentation dataset,and the results showed that the proposed LA-UMamba achieves proved performance compared to the baseline model in several evaluation metrics,such as IoU,Accuracy,Precision,HD and ASD,which improved that the model is successful in optimizing the detail processing and reducing the complexity of the model,providing a new perspective for further optimization of medical image segmentation techniques.展开更多
A considerable efficiency gap exists between large-area perovskite solar modules and small-area perovskite solar cells.The control of forming uniform and large-area film and perovskite crystallization is still the mai...A considerable efficiency gap exists between large-area perovskite solar modules and small-area perovskite solar cells.The control of forming uniform and large-area film and perovskite crystallization is still the main obstacle restricting the efficiency of PSMs.In this work,we adopted a solid-liquid two-step film formation technique,which involved the evaporation of a lead iodide film and blade coating of an organic ammonium halide solution to prepare perovskite films.This method possesses the advantages of integrating vapor deposition and solution methods,which could apply to substrates with different roughness and avoid using toxic solvents to achieve a more uniform,large-area perovskite film.Furthermore,modification of the NiO_(x)/perovskite buried interface and introduction of Urea additives were utilized to reduce interface recombination and regulate perovskite crystallization.As a result,a large-area perovskite film possessing larger grains,fewer pinholes,and reduced defects could be achieved.The inverted PSM with an active area of 61.56 cm^(2)(10×10 cm^(2)substrate)achieved a champion power conversion efficiency of 20.56%and significantly improved stability.This method suggests an innovative approach to resolving the uniformity issue associated with large-area film fabrication.展开更多
All-season thermal management with zero energy consumption and emissions is more crucial to global decarbonization over traditional energy-intensive cooling/heating systems.However,the static single thermal management...All-season thermal management with zero energy consumption and emissions is more crucial to global decarbonization over traditional energy-intensive cooling/heating systems.However,the static single thermal management for cooling or heating fails to self-regulate the temperature in dynamic seasonal temperature condition.Herein,inspired by the dual-temperature regulation function of the fur color changes on the backs and abdomens of penguins,a smart thermal management composite hydrogel(PNA@H-PM Gel)system was subtly created though an"on-demand"dual-layer structure design strategy.The PNA@H-PM Gel system features synchronous solar and thermal radiation modulation as well as tunable phase transition temperatures to meet the variable seasonal thermal requirements and energy-saving demands via self-adaptive radiative cooling and solar heating regulation.Furthermore,this system demonstrates superb modulations of both the solar reflectance(ΔR=0.74)and thermal emissivity(ΔE=0.52)in response to ambient temperature changes,highlighting efficient temperature regulation with average radiative cooling and solar heating effects of 9.6℃in summer and 6.1℃in winter,respectively.Moreover,compared to standard building baselines,the PNA@H-PM Gel presents a more substantial energy-saving cooling/heating potentials for energy-efficient buildings across various regions and climates.This novel solution,inspired by penguins in the real world,will offer a fresh approach for producing intelligent,energy-saving thermal management materials,and serve for temperature regulation under dynamic climate conditions and even throughout all seasons.展开更多
High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,inclu...High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments.展开更多
Two-terminal(2-T)perovskite(PVK)/CuIn(Ga)Se_(2)(CIGS)tandem solar cells(TSCs)have been considered as an ideal tandem cell because of their best bandgap matching regarding to Shockley–Queisser(S–Q)limits.However,the ...Two-terminal(2-T)perovskite(PVK)/CuIn(Ga)Se_(2)(CIGS)tandem solar cells(TSCs)have been considered as an ideal tandem cell because of their best bandgap matching regarding to Shockley–Queisser(S–Q)limits.However,the nature of the irregular rough morphology of commercial CIGS prevents people from improving tandem device performances.In this paper,D-homoserine lactone hydrochloride is proven to improve coverage of PVK materials on irregular rough CIGS surfaces and also passivate bulk defects by modulating the growth of PVK crystals.In addition,the minority carriers near the PVK/C60 interface and the incompletely passivated trap states caused interface recombination.A surface reconstruction with 2-thiopheneethylammonium iodide and N,N-dimethylformamide assisted passivates the defect sites located at the surface and grain boundaries.Meanwhile,LiF is used to create this field effect,repelling hole carriers away from the PVK and C60 interface and thus reducing recombination.As a result,a 2-T PVK/CIGS tandem yielded a power conversion efficiency of 24.6%(0.16 cm^(2)),one of the highest results for 2-T PVK/CIGS TSCs to our knowledge.This validation underscores the potential of our methodology in achieving superior performance in PVK/CIGS tandem solar cells.展开更多
In this paper,we introduce the notions of_((m,n))-coherent rings and FP_((m,n))-projective modules for nonnegative integers m,n.We prove that(FP_((m,n))-Proj,(FPn-id)_(≤m))is a complete cotorsion pair for any m,n≥0 ...In this paper,we introduce the notions of_((m,n))-coherent rings and FP_((m,n))-projective modules for nonnegative integers m,n.We prove that(FP_((m,n))-Proj,(FPn-id)_(≤m))is a complete cotorsion pair for any m,n≥0 and it is hereditary if and only if the ring R is a left n-coherent ring for all m≥0 and n≥1.Moreover,we study the existence of FP_((m,n))-Proj covers and envelopes and obtain that if FP_((m,n))-Proj is closed under pure quotients,then FP_((m,n))-Proj is covering for any n≥2.As applications,we obtain that every R-module has an epic FP_((m,n))-Proj-envelope if and only if the left FP_((m,n))-global dimension of R is at most 1 and FP_((m,n))-Proj is closed under direct products.展开更多
Multilevel coding(MLC)is a commonly used polar coded modulation scheme,but challenging to implement in engineering due to its high complexity and long decoding delay for high-order modulations.To address these limitat...Multilevel coding(MLC)is a commonly used polar coded modulation scheme,but challenging to implement in engineering due to its high complexity and long decoding delay for high-order modulations.To address these limitations,a novel two-level serially concatenated MLC scheme,in which the bitlevels with similar reliability are bundled and transmitted together,is proposed.The proposed scheme hierarchically protects the two bit-level sets:the bitlevel sets at the higher level are sufficiently reliable and do not require excessive resources for protection,whereas only the bit-level sets at the lower level are encoded by polar codes.The proposed scheme has the advantages of low power consumption,low delay and high reliability.Moreover,an optimized constellation signal labeling rule that can enhance the performance is proposed.Finally,the superiority of the proposed scheme is validated through the theoretical analysis and simulation results.Compared with the bit interleaving coding modulation(BICM)scheme,under 256-quadrature amplitude modulation(QAM),the proposed scheme attains a performance gain of 1.0 dB while reducing the decoding complexity by 54.55%.展开更多
Under submerged conditions, compared with traditional self-excited oscillating pulsed waterjets(SOPWs), annular fluid-enhanced self-excited oscillating pulsed waterjets(AFESOPWs) exhibit a higher surge pressure throug...Under submerged conditions, compared with traditional self-excited oscillating pulsed waterjets(SOPWs), annular fluid-enhanced self-excited oscillating pulsed waterjets(AFESOPWs) exhibit a higher surge pressure through self-priming. However, their pressure frequency and cavitation characteristics remain unclear, resulting in an inability to fully utilize resonance and cavitation erosion to break coal and rock. In this study, high-frequency pressure testing, high-speed photography, and large eddy simulation(LES) are used to investigate the distribution of the pressure frequency band, evolution law of the cavitation cloud, and its regulation mechanism of a continuous waterjet, SOPW, and AFESOPW. The results indicated that the excitation of the plunger pump, shearing layer vortex, and bubble collapse corresponded to the three high-amplitude frequency bands of the waterjet pressure. AFESOPWs have an additional self-priming frequency that can produce a larger amplitude under a synergistic effect with the second high-amplitude frequency band. A better cavitation effect was produced after self-priming the annulus fluid, and the shedding frequency of the cavitation clouds of the three types of waterjets was linearly related to the cavitation number. The peak pressure of the waterjet and cavitation erosion effect can be improved by modulating the waterjet pressure oscillation frequency and cavitation shedding frequency.展开更多
Two-dimensional(2D)superconductors have attracted significant research interest due to their promising potential applications in optoelectronic and microelectronic devices.Herein,we employ first-principles calculation...Two-dimensional(2D)superconductors have attracted significant research interest due to their promising potential applications in optoelectronic and microelectronic devices.Herein,we employ first-principles calculations to predicted a new 2D conventional superconductor,Tc_(2)B_(2),demonstrating its stable structural configuration.Remarkably,under biaxial strain,the superconducting transition temperature(T_(c))of Tc_(2)B_(2)demonstrates a significant enhancement,achieving 19.5 K under 3%compressive strain and 9.2 K under 11%tensile strain.Our study reveals that strain-induced modifications in Fermi surface topology significantly enhance the Fermi surface nesting effect,which amplifies electron–phonon coupling interactions and consequently elevates Tc.Additionally,the presence of the Lifshitz transition results in a more pronounced rise in Tc under compressive strain compared to tensile strain.These insights offer important theoretical guidance for designing 2D superconductors with high-Tc through strain modulation.展开更多
The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches...The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches between the parameters of the received amplitude modulation(AM) signals and the system's linear workspace and demodulation operating points can cause severe distortion in the demodulated signals. To address this, the article proposes a method for determining the operational parameters based on the mean square error(MSE) and total harmonic distortion(THD) assessments and presents strategies for optimizing the system's operational parameters focusing on linear response characteristics(LRC) and linear dynamic range(LDR). Specifically, we employ a method that minimizes the MSE to define the system's linear workspace, thereby ensuring the system has a good LRC while maximizing the LDR. To ensure that the signal always operates within the linear workspace, an appropriate carrier amplitude is set as the demodulation operating point. By calculating the THD at different operating points, the LRC performance within different regions of the linear workspace is evaluated, and corresponding optimization strategies based on the range of signal strengths are proposed. Moreover, to more accurately restore the baseband signal, we establish a mapping relationship between the carrier Rabi frequency and the transmitted power of the probe light, and optimize the slope of the linear demodulation function to reduce the MSE to less than 0.8×10^(-4). Finally, based on these methods for determining the operational parameters, we explore the effects of different laser Rabi frequencies on the system performance, and provide optimization recommendations. This research provides robust support for the design of high-performance Rydberg atom-based AM receivers.展开更多
Na_(3)V_(2)(PO_(4))_(2)O_(2)F (VP) is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific capacity.Density functional theory (DFT) and finite el...Na_(3)V_(2)(PO_(4))_(2)O_(2)F (VP) is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific capacity.Density functional theory (DFT) and finite element simulations show that incorporating SO_(4)^(2-)into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge cycles.Consequently,the average Na+diffusion coefficient of Na_(3)V_(2)(PO_(4))_(1.95)(SO_(4))_(0.05)O_(2)F(VPS-1) is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g^(-1)) and cycling stability (111.0 mAh g^(-1)capacity after 1000 cycles at 10 C current density) for VPS-1.VPS-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 min.The assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.展开更多
Solid-state batteries(SSBs) with high safety are promising for the energy fields,but the development has long been limited by machinability and interfacial problems.Hence,self-supporting,flexible Nano LLZO CSEs are pr...Solid-state batteries(SSBs) with high safety are promising for the energy fields,but the development has long been limited by machinability and interfacial problems.Hence,self-supporting,flexible Nano LLZO CSEs are prepared with a solvent-free method at 25℃.The 99.8 wt% contents of Nano LLZO particles enable the Nano LLZO CSEs to maintain good thermal stability while exhibiting a wide electrochemical window of 5.0 V and a high Li~+ transfer number of 0.8.The mean modulus reaches 4376 MPa.Benefiting from the interfacial modulation,the Li|Li symmetric batteries based on the Nano LLZO CSEs show benign stability with lithium at the current densities of 0.1 mA cm^(-2),0.2 mA cm^(-2),and 0.5 mA cm^(-2).In addition,the Li|LiFePO_(4)(LFP) SSBs achieve favorable cycling performance:the specific capacity reaches128.1 mAh g^(-1) at 0.5 C rate,with a capacity retention of about 80% after 600 cycles.In the further tests of the LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811) cathodes with higher energy density,the Nano LLZO CSEs also demonstrate good compatibility:the specific capacities of NCM811-based SSBs reach 177.9 mAh g^(-1) at 0.5 C rate,while the capacity retention is over 96% after 150 cycles.Furthermore,the Li|LFP soft-pack SSBs verify the safety characteristics and the potential for application,which have a desirable prospect.展开更多
Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involv...Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.展开更多
The presence of SnZn-related defects in Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)absorber results in large irreversible energy loss and extra irreversible electron-hole non-radiative recombination,thus hindering the efficiency enh...The presence of SnZn-related defects in Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)absorber results in large irreversible energy loss and extra irreversible electron-hole non-radiative recombination,thus hindering the efficiency enhancement of CZTSSe devices.Although the incorporation of Ag in CZTSSe can effectively suppress the SnZn-related defects and significantly improve the resulting cell performance,an excellent efficiency has not been achieved to date primarily owing to the poor electrical-conductivity and the low carrier density of the CZTSSe film induced by Ag substitution.Herein,this study exquisitely devises an Ag/H co-doping strategy in CZTSSe absorber via Ag substitution programs followed by hydrogen-plasma treatment procedure to suppress SnZn defects for achieving efficient CZTSSe devices.In-depth investigation results demonstrate that the incorporation of H in Ag-based CZTSSe absorber is expected to improve the poor electrical-conductivity and the low carrier density caused by Ag substitution.Importantly,the C=O and O-H functional groups induced by hydrogen incorporation,serving as an electron donor,can interact with under-coordinated cations in CZTSSe material,effectively passivating the SnZn-related defects.Consequently,the incorporation of an appropriate amount of Ag/H in CZTSSe mitigates carrier non-radiative recombination,prolongs minority carrier lifetime,and thus yields a champion efficiency of 14.74%,showing its promising application in kesterite-based CZTSSe devices.展开更多
The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus...The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus,the ability to manipulate its degrees of freedom is highly desirable.In this paper,the full-domain polarization modulation of BlVVB within a hot atomic ensemble has been investigated.We begin with the theoretical analysis of the resonant magneto-optical effect of atoms with a horizontal linear-polarized beam and experimentally demonstrate precise manipulation of the polarization state across the entire domain of the BlVVB,achieving an error margin of less than 3°at various cross-sectional points.Our study provides a novel approach for the modulation of BlVVB based on atomic media,which holds potential applications in sensitive vector magnetometers,optical communications,and signal processing.展开更多
The utilization of millimeter-wave frequencies and cognitive radio(CR)are promising ways to increase the spectral efficiency of wireless communication systems.However,conventional CR spectrum sensing techniques entail...The utilization of millimeter-wave frequencies and cognitive radio(CR)are promising ways to increase the spectral efficiency of wireless communication systems.However,conventional CR spectrum sensing techniques entail sampling the received signal at a Nyquist rate,and they are not viable for wideband signals due to their high cost.This paper expounds on how sub-Nyquist sampling in conjunction with deep learning can be leveraged to remove this limitation.To this end,we propose a multi-task learning(MTL)framework using convolutional neural networks for the joint inference of the underlying narrowband signal number,their modulation scheme,and their location in a wideband spectrum.We demonstrate the effectiveness of the proposed framework for real-world millimeter-wave wideband signals collected by physical devices,exhibiting a 91.7% accuracy in the joint inference task when considering up to two narrowband signals over a wideband spectrum.Ultimately,the proposed data-driven approach enables on-the-fly wideband spectrum sensing,combining accuracy,and computational efficiency,which are indispensable for CR and opportunistic networking.展开更多
In this work,we propose a comprehensive theoretical framework for the multilevel NAND(NOT AND logic)flash memory,built upon the modified Student’s t distribution where the distortion of the threshold voltage caused b...In this work,we propose a comprehensive theoretical framework for the multilevel NAND(NOT AND logic)flash memory,built upon the modified Student’s t distribution where the distortion of the threshold voltage caused by the random telegraph noise,cell-to-cell interference and data retention noise are jointly considered.Based on the superposition modulation,we build a non-orthogonal multiuser communication model where a linear mapping is conducted between the verify voltages and binary antipodal symbols.Aimed at improving the storage efficiency,we propose an unequal amplitude mapping(UAM)solution by optimizing the weighting coefficients of verify voltages to intelligently adjust the width of each state.Moreover,the uniform storage efficiency region and sum storage efficiency of different labelings with various decoding schemes are discussed.Simulation results validate the effectiveness of our proposed UAM solution where an up to 20.9%storage efficiency gain can be achieved compared to the current used benchmark scheme.In addition,analytical and simulation results also demonstrate that the successive cancellation decoding outperforms other decoding schemes for all labelings.展开更多
In high-speed railway(HSR)wireless communication,the rapid channel changes and limited high-capacity access cause significant impact on the link performance.Meanwhile,the Doppler shift caused by high mobility leads to...In high-speed railway(HSR)wireless communication,the rapid channel changes and limited high-capacity access cause significant impact on the link performance.Meanwhile,the Doppler shift caused by high mobility leads to the inter-carrier interference.In this paper,we propose a reconfigurable intelligent surface(RIS)-assisted receive spatial modulation(SM)scheme based on the spatial-temporal correlated HSR Rician channel.The characteristics of SM and the phase shift adjustment of RIS are used to mitigate the performance degradation in high mobility scenarios.Considering the influence of channel spatial-temporal correlation and Doppler shift,the effects of different parameters on average bit error rate(BER)performance and upper bound of ergodic capacity are analyzed.Therefore,a joint antenna and RIS-unit selection algorithm based on the antenna removal method is proposed to increase the capacity performance of communication links.Numerical results show that the proposed RIS-assisted receive SM scheme can maintain high transmission capacity compared to the conventional HSR-SM scheme,whereas the degradation of BER performance can be compensated by arranging a large number of RIS-units.In addition,selecting more RIS-units has better capacity performance than activating more antennas in the low signal-to-noise ratio regions.展开更多
Electronic-state modulation strategy offers great potential in designing RuO_(2)-based bifunctionalelectrocatalysts for rechargeable Zn-air batteries(ZABs).Various three-dimensional(3D)transition metal oxides are atte...Electronic-state modulation strategy offers great potential in designing RuO_(2)-based bifunctionalelectrocatalysts for rechargeable Zn-air batteries(ZABs).Various three-dimensional(3D)transition metal oxides are attempted to couple with RuO_(2)for constructing an appropriate Ru—O—M interface.This work aims to construct Co_(3)O_(4)-RuO_(2)heterostructures on carbon sheets(Co_(3)O_(4)/RuO_(2)/NCNS)for boosting electronic transfer and regulation.Experiments and theoretical calculations identify the electronic transfer from Co_(3)O_(4)to RuO_(2)that modulates the electronic structure of metal surfaces/interfaces.Specifically,it leads to the increase in Co3+content,electron-rich state at RuO_(2)surface and electronic accumulation at interfaces.Moreover,this electronic-state modulation optimizes the d-band center in Co_(3)O_(4)/RuO_(2)that lowers the reaction barriers and endows interfaces as the biggest contributor to oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)performance,The Co_(3)O_(4)/RuO_(2)/NCNS shows a quite low potential difference of 0.62 V and remarkable durability for ORR/OER.Co_(3)O_(4)/RuO_(2)/NCNS-assembled ZABs exhibit an excellent specific capacity of 818.3 mA h g^(-1)and a superior lifespan over 750 h.展开更多
基金supported by the Beijing Natural Science Foundation (L202003)National Natural Science Foundation of China (No. 31700479)。
文摘Automatic modulation classification(AMC) technology is one of the cutting-edge technologies in cognitive radio communications. AMC based on deep learning has recently attracted much attention due to its superior performances in classification accuracy and robustness. In this paper, we propose a novel, high resolution and multi-scale feature fusion convolutional neural network model with a squeeze-excitation block, referred to as HRSENet,to classify different kinds of modulation signals.The proposed model establishes a parallel computing mechanism of multi-resolution feature maps through the multi-layer convolution operation, which effectively reduces the information loss caused by downsampling convolution. Moreover, through dense skipconnecting at the same resolution and up-sampling or down-sampling connection at different resolutions, the low resolution representation of the deep feature maps and the high resolution representation of the shallow feature maps are simultaneously extracted and fully integrated, which is benificial to mine signal multilevel features. Finally, the feature squeeze and excitation module embedded in the decoder is used to adjust the response weights between channels, further improving classification accuracy of proposed model.The proposed HRSENet significantly outperforms existing methods in terms of classification accuracy on the public dataset “Over the Air” in signal-to-noise(SNR) ranging from-2dB to 20dB. The classification accuracy in the proposed model achieves 85.36% and97.30% at 4dB and 10dB, respectively, with the improvement by 9.71% and 5.82% compared to LWNet.Furthermore, the model also has a moderate computation complexity compared with several state-of-the-art methods.
文摘Deep learning techniques are revolutionizing the developmentof medical image segmentation.With the advancement of Transformer models,especially ViT and Swin-Transformer,which enhances the remote-dependent modeling capability of the model through the self-attention mechanism,better segmentation performance can be achieve.Moreover,the high computational cost of Transformer has motivated researchers to explore more efficient models,such as the Mamba model based on state-space modeling(SSM),and for the field of medical segmentation,reducing the number of model parameters is also necessary.In this study,a novel asymmetric model called LA-UMamba was proposed,which integrates visual Mamba module to efficiently capture complex visual features and remote dependencies.The classical design of U-Net was adopted in the upsampling phase to help reduce the number of references and recover more details.To mitigate the information loss problem,an auxiliary U-Net downsampling layer was designed to focus on sizing without extracting features,thus enhancing the protection of input information while maintaining the efficiency of the model.The experiments were conducted on the ACDC MRI cardiac segmentation dataset,and the results showed that the proposed LA-UMamba achieves proved performance compared to the baseline model in several evaluation metrics,such as IoU,Accuracy,Precision,HD and ASD,which improved that the model is successful in optimizing the detail processing and reducing the complexity of the model,providing a new perspective for further optimization of medical image segmentation techniques.
基金the financial support from Shanxi Province Science and Technology Department(20201101012,202101060301016)the support from the APRC Grant of the City University of Hong Kong(9380086)+5 种基金the TCFS Grant(GHP/018/20SZ)MRP Grant(MRP/040/21X)from the Innovation and Technology Commission of Hong Kongthe Green Tech Fund(202020164)from the Environment and Ecology Bureau of Hong Kongthe GRF grants(11307621,11316422)from the Research Grants Council of Hong KongGuangdong Major Project of Basic and Applied Basic Research(2019B030302007)Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials(2019B121205002).
文摘A considerable efficiency gap exists between large-area perovskite solar modules and small-area perovskite solar cells.The control of forming uniform and large-area film and perovskite crystallization is still the main obstacle restricting the efficiency of PSMs.In this work,we adopted a solid-liquid two-step film formation technique,which involved the evaporation of a lead iodide film and blade coating of an organic ammonium halide solution to prepare perovskite films.This method possesses the advantages of integrating vapor deposition and solution methods,which could apply to substrates with different roughness and avoid using toxic solvents to achieve a more uniform,large-area perovskite film.Furthermore,modification of the NiO_(x)/perovskite buried interface and introduction of Urea additives were utilized to reduce interface recombination and regulate perovskite crystallization.As a result,a large-area perovskite film possessing larger grains,fewer pinholes,and reduced defects could be achieved.The inverted PSM with an active area of 61.56 cm^(2)(10×10 cm^(2)substrate)achieved a champion power conversion efficiency of 20.56%and significantly improved stability.This method suggests an innovative approach to resolving the uniformity issue associated with large-area film fabrication.
基金the funding and generous support of the National Natural Science Foundation of China(52103263,52271249)the Key Project of International Science&Technology Cooperation of Shaanxi Province(2023-GHZD-09)+5 种基金the Key Project of Science Foundation of Education Department of Shaanxi Province(22JY011)the Key Project of Scientific Research and Development of Shaanxi Province(2023GXLH-070)the Qinchuangyuan"Scientist+Engineer"Team of Shaanxi Province(2023KXJ-069)the Key Research and Development Program of Shaanxi(2023-YBGY-488)the Sci-tech Innovation Team of Shaanxi Province(2024RS-CXTD-46)the Key Research and Development Program of Shaanxi Province(2020ZDLGY13-11).
文摘All-season thermal management with zero energy consumption and emissions is more crucial to global decarbonization over traditional energy-intensive cooling/heating systems.However,the static single thermal management for cooling or heating fails to self-regulate the temperature in dynamic seasonal temperature condition.Herein,inspired by the dual-temperature regulation function of the fur color changes on the backs and abdomens of penguins,a smart thermal management composite hydrogel(PNA@H-PM Gel)system was subtly created though an"on-demand"dual-layer structure design strategy.The PNA@H-PM Gel system features synchronous solar and thermal radiation modulation as well as tunable phase transition temperatures to meet the variable seasonal thermal requirements and energy-saving demands via self-adaptive radiative cooling and solar heating regulation.Furthermore,this system demonstrates superb modulations of both the solar reflectance(ΔR=0.74)and thermal emissivity(ΔE=0.52)in response to ambient temperature changes,highlighting efficient temperature regulation with average radiative cooling and solar heating effects of 9.6℃in summer and 6.1℃in winter,respectively.Moreover,compared to standard building baselines,the PNA@H-PM Gel presents a more substantial energy-saving cooling/heating potentials for energy-efficient buildings across various regions and climates.This novel solution,inspired by penguins in the real world,will offer a fresh approach for producing intelligent,energy-saving thermal management materials,and serve for temperature regulation under dynamic climate conditions and even throughout all seasons.
基金supported by the National Natural Science Foundation of China(Grant Nos.52272103 and 52072010)Beijing Natural Science Foundation(Grant Nos.2242029 and JL23004).
文摘High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments.
基金supported by“National Natural Science Foundation of China(U21A20171,U20A20245)”“Hubei Provincial Natural Science Foundation of China(2023AFA010)”+1 种基金“Independent Innovation Projects of the Hubei Longzhong Laboratory(2022ZZ-09)”“Social Public Welfare and Basic Research Special Project of Zhongshan(2020B2015).”。
文摘Two-terminal(2-T)perovskite(PVK)/CuIn(Ga)Se_(2)(CIGS)tandem solar cells(TSCs)have been considered as an ideal tandem cell because of their best bandgap matching regarding to Shockley–Queisser(S–Q)limits.However,the nature of the irregular rough morphology of commercial CIGS prevents people from improving tandem device performances.In this paper,D-homoserine lactone hydrochloride is proven to improve coverage of PVK materials on irregular rough CIGS surfaces and also passivate bulk defects by modulating the growth of PVK crystals.In addition,the minority carriers near the PVK/C60 interface and the incompletely passivated trap states caused interface recombination.A surface reconstruction with 2-thiopheneethylammonium iodide and N,N-dimethylformamide assisted passivates the defect sites located at the surface and grain boundaries.Meanwhile,LiF is used to create this field effect,repelling hole carriers away from the PVK and C60 interface and thus reducing recombination.As a result,a 2-T PVK/CIGS tandem yielded a power conversion efficiency of 24.6%(0.16 cm^(2)),one of the highest results for 2-T PVK/CIGS TSCs to our knowledge.This validation underscores the potential of our methodology in achieving superior performance in PVK/CIGS tandem solar cells.
基金supported by the National Natural Science Foundation of China(No.12471036),the project of Young and Middle-Aged Talents of Hubei Province(No.Q20234405),and the Scientific Research Fund of Hunan Provincial Education Department(No.24A0221)。
文摘In this paper,we introduce the notions of_((m,n))-coherent rings and FP_((m,n))-projective modules for nonnegative integers m,n.We prove that(FP_((m,n))-Proj,(FPn-id)_(≤m))is a complete cotorsion pair for any m,n≥0 and it is hereditary if and only if the ring R is a left n-coherent ring for all m≥0 and n≥1.Moreover,we study the existence of FP_((m,n))-Proj covers and envelopes and obtain that if FP_((m,n))-Proj is closed under pure quotients,then FP_((m,n))-Proj is covering for any n≥2.As applications,we obtain that every R-module has an epic FP_((m,n))-Proj-envelope if and only if the left FP_((m,n))-global dimension of R is at most 1 and FP_((m,n))-Proj is closed under direct products.
基金supported by the External Cooperation Program of Science and Technology of Fujian Province,China(2024I0016)the Fundamental Research Funds for the Central Universities(ZQN-1005).
文摘Multilevel coding(MLC)is a commonly used polar coded modulation scheme,but challenging to implement in engineering due to its high complexity and long decoding delay for high-order modulations.To address these limitations,a novel two-level serially concatenated MLC scheme,in which the bitlevels with similar reliability are bundled and transmitted together,is proposed.The proposed scheme hierarchically protects the two bit-level sets:the bitlevel sets at the higher level are sufficiently reliable and do not require excessive resources for protection,whereas only the bit-level sets at the lower level are encoded by polar codes.The proposed scheme has the advantages of low power consumption,low delay and high reliability.Moreover,an optimized constellation signal labeling rule that can enhance the performance is proposed.Finally,the superiority of the proposed scheme is validated through the theoretical analysis and simulation results.Compared with the bit interleaving coding modulation(BICM)scheme,under 256-quadrature amplitude modulation(QAM),the proposed scheme attains a performance gain of 1.0 dB while reducing the decoding complexity by 54.55%.
基金supported by the program for National Natural Science Foundation of China (Nos. 52174173, 52274188, and 52104190)the Joint Funds of the National Natural Science Foundation of China (No. U24A2091)+1 种基金The Natural Science Foundation of Henan Polytechnic University (No. B2021-2)Double FirstClass Initiative of Safety and Energy Engineering (Henan Polytechnic University) (Nos. AQ20240703 and AQ20230304)。
文摘Under submerged conditions, compared with traditional self-excited oscillating pulsed waterjets(SOPWs), annular fluid-enhanced self-excited oscillating pulsed waterjets(AFESOPWs) exhibit a higher surge pressure through self-priming. However, their pressure frequency and cavitation characteristics remain unclear, resulting in an inability to fully utilize resonance and cavitation erosion to break coal and rock. In this study, high-frequency pressure testing, high-speed photography, and large eddy simulation(LES) are used to investigate the distribution of the pressure frequency band, evolution law of the cavitation cloud, and its regulation mechanism of a continuous waterjet, SOPW, and AFESOPW. The results indicated that the excitation of the plunger pump, shearing layer vortex, and bubble collapse corresponded to the three high-amplitude frequency bands of the waterjet pressure. AFESOPWs have an additional self-priming frequency that can produce a larger amplitude under a synergistic effect with the second high-amplitude frequency band. A better cavitation effect was produced after self-priming the annulus fluid, and the shedding frequency of the cavitation clouds of the three types of waterjets was linearly related to the cavitation number. The peak pressure of the waterjet and cavitation erosion effect can be improved by modulating the waterjet pressure oscillation frequency and cavitation shedding frequency.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12274169,12122405,and 52072188)the National Key Research and Development Program of China(Grant No.2022YFA1402304)+1 种基金the Program for Science and Technology Innovation Team in Zhejiang Province,China(Grant No.2021R01004)the Fundamental Research Funds for the Central Universities.
文摘Two-dimensional(2D)superconductors have attracted significant research interest due to their promising potential applications in optoelectronic and microelectronic devices.Herein,we employ first-principles calculations to predicted a new 2D conventional superconductor,Tc_(2)B_(2),demonstrating its stable structural configuration.Remarkably,under biaxial strain,the superconducting transition temperature(T_(c))of Tc_(2)B_(2)demonstrates a significant enhancement,achieving 19.5 K under 3%compressive strain and 9.2 K under 11%tensile strain.Our study reveals that strain-induced modifications in Fermi surface topology significantly enhance the Fermi surface nesting effect,which amplifies electron–phonon coupling interactions and consequently elevates Tc.Additionally,the presence of the Lifshitz transition results in a more pronounced rise in Tc under compressive strain compared to tensile strain.These insights offer important theoretical guidance for designing 2D superconductors with high-Tc through strain modulation.
基金Project supported by the National Natural Science Foundation of China (Grant No. U22B2095)the Civil Aerospace Technology Research Project (Grant No. D010103)。
文摘The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches between the parameters of the received amplitude modulation(AM) signals and the system's linear workspace and demodulation operating points can cause severe distortion in the demodulated signals. To address this, the article proposes a method for determining the operational parameters based on the mean square error(MSE) and total harmonic distortion(THD) assessments and presents strategies for optimizing the system's operational parameters focusing on linear response characteristics(LRC) and linear dynamic range(LDR). Specifically, we employ a method that minimizes the MSE to define the system's linear workspace, thereby ensuring the system has a good LRC while maximizing the LDR. To ensure that the signal always operates within the linear workspace, an appropriate carrier amplitude is set as the demodulation operating point. By calculating the THD at different operating points, the LRC performance within different regions of the linear workspace is evaluated, and corresponding optimization strategies based on the range of signal strengths are proposed. Moreover, to more accurately restore the baseband signal, we establish a mapping relationship between the carrier Rabi frequency and the transmitted power of the probe light, and optimize the slope of the linear demodulation function to reduce the MSE to less than 0.8×10^(-4). Finally, based on these methods for determining the operational parameters, we explore the effects of different laser Rabi frequencies on the system performance, and provide optimization recommendations. This research provides robust support for the design of high-performance Rydberg atom-based AM receivers.
基金National Natural Science Foundation of China (52372224 and 52072299)Major Project of Shaanxi Coal Joint Fund of Shaanxi Provincial Science and Technology Department (2019JLZ-07)。
文摘Na_(3)V_(2)(PO_(4))_(2)O_(2)F (VP) is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific capacity.Density functional theory (DFT) and finite element simulations show that incorporating SO_(4)^(2-)into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge cycles.Consequently,the average Na+diffusion coefficient of Na_(3)V_(2)(PO_(4))_(1.95)(SO_(4))_(0.05)O_(2)F(VPS-1) is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g^(-1)) and cycling stability (111.0 mAh g^(-1)capacity after 1000 cycles at 10 C current density) for VPS-1.VPS-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 min.The assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.
基金supported by Science and Technology Project of China Southern Power Grid (SZKJXM20230049/090000KC23010038)。
文摘Solid-state batteries(SSBs) with high safety are promising for the energy fields,but the development has long been limited by machinability and interfacial problems.Hence,self-supporting,flexible Nano LLZO CSEs are prepared with a solvent-free method at 25℃.The 99.8 wt% contents of Nano LLZO particles enable the Nano LLZO CSEs to maintain good thermal stability while exhibiting a wide electrochemical window of 5.0 V and a high Li~+ transfer number of 0.8.The mean modulus reaches 4376 MPa.Benefiting from the interfacial modulation,the Li|Li symmetric batteries based on the Nano LLZO CSEs show benign stability with lithium at the current densities of 0.1 mA cm^(-2),0.2 mA cm^(-2),and 0.5 mA cm^(-2).In addition,the Li|LiFePO_(4)(LFP) SSBs achieve favorable cycling performance:the specific capacity reaches128.1 mAh g^(-1) at 0.5 C rate,with a capacity retention of about 80% after 600 cycles.In the further tests of the LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811) cathodes with higher energy density,the Nano LLZO CSEs also demonstrate good compatibility:the specific capacities of NCM811-based SSBs reach 177.9 mAh g^(-1) at 0.5 C rate,while the capacity retention is over 96% after 150 cycles.Furthermore,the Li|LFP soft-pack SSBs verify the safety characteristics and the potential for application,which have a desirable prospect.
基金supported by the National Natural Science Foundation of China(No.22375021,22235003,22261132516&22205021)the BIT Research and Innovation 265 Promoting Project(Grant No.2023YCXZ017)。
文摘Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.
基金supported by the National Natural Science Foundation of China(51802081,62074052,and 62104061)the Natural Science Foundation of Henan Province(232300420145).
文摘The presence of SnZn-related defects in Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)absorber results in large irreversible energy loss and extra irreversible electron-hole non-radiative recombination,thus hindering the efficiency enhancement of CZTSSe devices.Although the incorporation of Ag in CZTSSe can effectively suppress the SnZn-related defects and significantly improve the resulting cell performance,an excellent efficiency has not been achieved to date primarily owing to the poor electrical-conductivity and the low carrier density of the CZTSSe film induced by Ag substitution.Herein,this study exquisitely devises an Ag/H co-doping strategy in CZTSSe absorber via Ag substitution programs followed by hydrogen-plasma treatment procedure to suppress SnZn defects for achieving efficient CZTSSe devices.In-depth investigation results demonstrate that the incorporation of H in Ag-based CZTSSe absorber is expected to improve the poor electrical-conductivity and the low carrier density caused by Ag substitution.Importantly,the C=O and O-H functional groups induced by hydrogen incorporation,serving as an electron donor,can interact with under-coordinated cations in CZTSSe material,effectively passivating the SnZn-related defects.Consequently,the incorporation of an appropriate amount of Ag/H in CZTSSe mitigates carrier non-radiative recombination,prolongs minority carrier lifetime,and thus yields a champion efficiency of 14.74%,showing its promising application in kesterite-based CZTSSe devices.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12033007,61801458,12103058,12203058,12074309,and 61875205)the Key Project of Frontier Science Research of the Chinese Academy of Sciences(Grant No.QYZDB-SSW-SLH007)+2 种基金the Strategic Priority Research Program of CAS(Grant No.XDC07020200)the Youth Innovation Promotion Association,CAS(Grant Nos.2021408,2022413,and 2023425)the Research on Highly Sensitive Long-Wave Receiver Based on Rydberg Atoms(Grant No.1P2024000059)。
文摘The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus,the ability to manipulate its degrees of freedom is highly desirable.In this paper,the full-domain polarization modulation of BlVVB within a hot atomic ensemble has been investigated.We begin with the theoretical analysis of the resonant magneto-optical effect of atoms with a horizontal linear-polarized beam and experimentally demonstrate precise manipulation of the polarization state across the entire domain of the BlVVB,achieving an error margin of less than 3°at various cross-sectional points.Our study provides a novel approach for the modulation of BlVVB based on atomic media,which holds potential applications in sensitive vector magnetometers,optical communications,and signal processing.
文摘The utilization of millimeter-wave frequencies and cognitive radio(CR)are promising ways to increase the spectral efficiency of wireless communication systems.However,conventional CR spectrum sensing techniques entail sampling the received signal at a Nyquist rate,and they are not viable for wideband signals due to their high cost.This paper expounds on how sub-Nyquist sampling in conjunction with deep learning can be leveraged to remove this limitation.To this end,we propose a multi-task learning(MTL)framework using convolutional neural networks for the joint inference of the underlying narrowband signal number,their modulation scheme,and their location in a wideband spectrum.We demonstrate the effectiveness of the proposed framework for real-world millimeter-wave wideband signals collected by physical devices,exhibiting a 91.7% accuracy in the joint inference task when considering up to two narrowband signals over a wideband spectrum.Ultimately,the proposed data-driven approach enables on-the-fly wideband spectrum sensing,combining accuracy,and computational efficiency,which are indispensable for CR and opportunistic networking.
基金supported by Key Project of Sichuan Provincial Natural Science Foundation(No.2022NSFSC0043).
文摘In this work,we propose a comprehensive theoretical framework for the multilevel NAND(NOT AND logic)flash memory,built upon the modified Student’s t distribution where the distortion of the threshold voltage caused by the random telegraph noise,cell-to-cell interference and data retention noise are jointly considered.Based on the superposition modulation,we build a non-orthogonal multiuser communication model where a linear mapping is conducted between the verify voltages and binary antipodal symbols.Aimed at improving the storage efficiency,we propose an unequal amplitude mapping(UAM)solution by optimizing the weighting coefficients of verify voltages to intelligently adjust the width of each state.Moreover,the uniform storage efficiency region and sum storage efficiency of different labelings with various decoding schemes are discussed.Simulation results validate the effectiveness of our proposed UAM solution where an up to 20.9%storage efficiency gain can be achieved compared to the current used benchmark scheme.In addition,analytical and simulation results also demonstrate that the successive cancellation decoding outperforms other decoding schemes for all labelings.
基金supported in part by National Natural Science Foundation of China under Grant 62461024Jiangxi Provincial Natural Science Foundation of China under Grant 20224ACB202001.
文摘In high-speed railway(HSR)wireless communication,the rapid channel changes and limited high-capacity access cause significant impact on the link performance.Meanwhile,the Doppler shift caused by high mobility leads to the inter-carrier interference.In this paper,we propose a reconfigurable intelligent surface(RIS)-assisted receive spatial modulation(SM)scheme based on the spatial-temporal correlated HSR Rician channel.The characteristics of SM and the phase shift adjustment of RIS are used to mitigate the performance degradation in high mobility scenarios.Considering the influence of channel spatial-temporal correlation and Doppler shift,the effects of different parameters on average bit error rate(BER)performance and upper bound of ergodic capacity are analyzed.Therefore,a joint antenna and RIS-unit selection algorithm based on the antenna removal method is proposed to increase the capacity performance of communication links.Numerical results show that the proposed RIS-assisted receive SM scheme can maintain high transmission capacity compared to the conventional HSR-SM scheme,whereas the degradation of BER performance can be compensated by arranging a large number of RIS-units.In addition,selecting more RIS-units has better capacity performance than activating more antennas in the low signal-to-noise ratio regions.
基金supported by the National Natural Science Foundation of China(52273264)the Outstanding Youth Fund of Heilongjiang Province(JQ 2020B002).
文摘Electronic-state modulation strategy offers great potential in designing RuO_(2)-based bifunctionalelectrocatalysts for rechargeable Zn-air batteries(ZABs).Various three-dimensional(3D)transition metal oxides are attempted to couple with RuO_(2)for constructing an appropriate Ru—O—M interface.This work aims to construct Co_(3)O_(4)-RuO_(2)heterostructures on carbon sheets(Co_(3)O_(4)/RuO_(2)/NCNS)for boosting electronic transfer and regulation.Experiments and theoretical calculations identify the electronic transfer from Co_(3)O_(4)to RuO_(2)that modulates the electronic structure of metal surfaces/interfaces.Specifically,it leads to the increase in Co3+content,electron-rich state at RuO_(2)surface and electronic accumulation at interfaces.Moreover,this electronic-state modulation optimizes the d-band center in Co_(3)O_(4)/RuO_(2)that lowers the reaction barriers and endows interfaces as the biggest contributor to oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)performance,The Co_(3)O_(4)/RuO_(2)/NCNS shows a quite low potential difference of 0.62 V and remarkable durability for ORR/OER.Co_(3)O_(4)/RuO_(2)/NCNS-assembled ZABs exhibit an excellent specific capacity of 818.3 mA h g^(-1)and a superior lifespan over 750 h.
