The kinetics of the thermal decomposition for a naturally ageing ammonium perchlorate(AP) and hydroxyl-terminated-polybutadiene(HTPB) base bleed composite propellant were investigated using a differential scanning cal...The kinetics of the thermal decomposition for a naturally ageing ammonium perchlorate(AP) and hydroxyl-terminated-polybutadiene(HTPB) base bleed composite propellant were investigated using a differential scanning calorimetry(DSC). The naturally ageing AP/HTPB base bleed propellant samples have been stored in a sealed plastic bag at room temperature(5-25 ℃) for more than 20 years. The experimental DSC results were obtained by placing samples(each about 1.5 mg) in a sealed pan under non-isothermal condition under different heating rates, 5.0, 10.0, 15.0, 20.0 and 30.0 ℃·min^(-1). The activation energy and pre-exponential factor were estimated based on the relationship between the exothermic peak temperature and the heating rate by Ozawa and Kissinger methods, respectively. The decomposition kinetic parameters is lower the values under laboratorial aging condition.展开更多
Low maturity coal samples were taken from the Ordos Basin to conduct gold tube thermal simulation experiment in a closed system,and the characteristics of the products were analyzed to find out the fractionation mecha...Low maturity coal samples were taken from the Ordos Basin to conduct gold tube thermal simulation experiment in a closed system,and the characteristics of the products were analyzed to find out the fractionation mechanism of carbon isotopes and the causes of abnormal carbon isotopic compositions of natural gas.At the heating rates of 2℃/h(slow)and 20℃/h(rapid),the low maturity coal samples of the Ordos Basin had the maximum yields of alkane gas of 302.74 mL/g and 230.16 mL/g,theδ13C1 ranges of-34.8‰to-23.6‰and-35.5‰to-24.0‰;δ13C2 ranges of-28.0‰to-9.0‰and-28.9‰to-8.3‰;andδ13C3 ranges of-25.8‰to-14.7‰and-26.4‰to-13.2‰,respectively.Alkane gas in the thermal simulation products of rapid temperature rise process showed obvious partial reversal of carbon isotope series at 550℃,and at other temperatures showed positive carbon isotope series.In the two heating processes,theδ13C1 turned lighter first and then heavier,and the non-monotonic variation of theδ13C1 values is because the early CH4 is from different parent materials resulted from heterogeneity of organic matter or the carbon isotope fractionation formed by activation energy difference of early enriched 12CH4 and late enriched 13CH4.The reversal of carbon isotope values of heavy hydrocarbon gas can occur not only in high to over mature shale gas(oil-type gas),but also in coal-derived gas.Through thermal simulation experiment of toluene,it is confirmed that the carbon isotope value of heavy hydrocarbon gas can be reversed and inversed at high to over mature stage.The isotope fractionation effect caused by demethylation and methyl linkage of aromatic hydrocarbons may be an important reason for carbon isotope inversion and reversal of alkane gas at the high to over mature stage.展开更多
Since childhood,William Wordsworth and John Ruskin have developed a very natural love for landscape and scenery.Although they have different ways to interpret what they see and how they feel,they both stick to their g...Since childhood,William Wordsworth and John Ruskin have developed a very natural love for landscape and scenery.Although they have different ways to interpret what they see and how they feel,they both stick to their genuine feelings without pre⁃tension in their poems.Those unpretentious feelings and behaviors,which are crucial to their later development to be remarkable artists,come from their original habit and attitude towards Nature as a child.All their life,they preserved this innocence in their work as a memory of childhood.展开更多
Combining disk springs having negative stiffness with a rolling-ball in parallel is proposed in this paper. It is used to reduce the system stiffness and the positioning error in a non-ideal environment.The characteri...Combining disk springs having negative stiffness with a rolling-ball in parallel is proposed in this paper. It is used to reduce the system stiffness and the positioning error in a non-ideal environment.The characteristics of a disk spring are analyzed. The dynamic equation of its motion has been obtained based on Newton＇s second law. After definition of a error margin,the dynamic equation of the motion can be treated as a Duffing oscillator,and the influences of non-dimensional parameters on the stiffness and transmissibility are studied. The natural frequency and transmissibility are achieved in a linearization range,where the ratio of linear to nonlinear items is small enough.The influence of mass ratio and non-dimensional parameters on natural frequency are analyzed. Finally,a comparison of numerical example demonstrates that the QZS system can realize a lower stiffness within an increased range.展开更多
文摘The kinetics of the thermal decomposition for a naturally ageing ammonium perchlorate(AP) and hydroxyl-terminated-polybutadiene(HTPB) base bleed composite propellant were investigated using a differential scanning calorimetry(DSC). The naturally ageing AP/HTPB base bleed propellant samples have been stored in a sealed plastic bag at room temperature(5-25 ℃) for more than 20 years. The experimental DSC results were obtained by placing samples(each about 1.5 mg) in a sealed pan under non-isothermal condition under different heating rates, 5.0, 10.0, 15.0, 20.0 and 30.0 ℃·min^(-1). The activation energy and pre-exponential factor were estimated based on the relationship between the exothermic peak temperature and the heating rate by Ozawa and Kissinger methods, respectively. The decomposition kinetic parameters is lower the values under laboratorial aging condition.
基金Supported by the National Natural Science Foundation of China(41902160,41625009)the China Postdoctoral Science Foundation(2019M650967,2020T130721)the China National Science and Technology Major Project(2016ZX05007-001)
文摘Low maturity coal samples were taken from the Ordos Basin to conduct gold tube thermal simulation experiment in a closed system,and the characteristics of the products were analyzed to find out the fractionation mechanism of carbon isotopes and the causes of abnormal carbon isotopic compositions of natural gas.At the heating rates of 2℃/h(slow)and 20℃/h(rapid),the low maturity coal samples of the Ordos Basin had the maximum yields of alkane gas of 302.74 mL/g and 230.16 mL/g,theδ13C1 ranges of-34.8‰to-23.6‰and-35.5‰to-24.0‰;δ13C2 ranges of-28.0‰to-9.0‰and-28.9‰to-8.3‰;andδ13C3 ranges of-25.8‰to-14.7‰and-26.4‰to-13.2‰,respectively.Alkane gas in the thermal simulation products of rapid temperature rise process showed obvious partial reversal of carbon isotope series at 550℃,and at other temperatures showed positive carbon isotope series.In the two heating processes,theδ13C1 turned lighter first and then heavier,and the non-monotonic variation of theδ13C1 values is because the early CH4 is from different parent materials resulted from heterogeneity of organic matter or the carbon isotope fractionation formed by activation energy difference of early enriched 12CH4 and late enriched 13CH4.The reversal of carbon isotope values of heavy hydrocarbon gas can occur not only in high to over mature shale gas(oil-type gas),but also in coal-derived gas.Through thermal simulation experiment of toluene,it is confirmed that the carbon isotope value of heavy hydrocarbon gas can be reversed and inversed at high to over mature stage.The isotope fractionation effect caused by demethylation and methyl linkage of aromatic hydrocarbons may be an important reason for carbon isotope inversion and reversal of alkane gas at the high to over mature stage.
文摘Since childhood,William Wordsworth and John Ruskin have developed a very natural love for landscape and scenery.Although they have different ways to interpret what they see and how they feel,they both stick to their genuine feelings without pre⁃tension in their poems.Those unpretentious feelings and behaviors,which are crucial to their later development to be remarkable artists,come from their original habit and attitude towards Nature as a child.All their life,they preserved this innocence in their work as a memory of childhood.
基金Supported by National Science and Technology Major Project(2013ZX02104003)
文摘Combining disk springs having negative stiffness with a rolling-ball in parallel is proposed in this paper. It is used to reduce the system stiffness and the positioning error in a non-ideal environment.The characteristics of a disk spring are analyzed. The dynamic equation of its motion has been obtained based on Newton＇s second law. After definition of a error margin,the dynamic equation of the motion can be treated as a Duffing oscillator,and the influences of non-dimensional parameters on the stiffness and transmissibility are studied. The natural frequency and transmissibility are achieved in a linearization range,where the ratio of linear to nonlinear items is small enough.The influence of mass ratio and non-dimensional parameters on natural frequency are analyzed. Finally,a comparison of numerical example demonstrates that the QZS system can realize a lower stiffness within an increased range.
