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采用反吹、微流控技术分析原油中的轻烃组分 被引量:4
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作者 朱翠山 赵红 +2 位作者 王培荣 张敏 徐冠军 《色谱》 CAS CSCD 北大核心 2007年第3期449-450,共2页
利用程序升温蒸发进样器、反吹技术和微流控装置分析原油中的C5-C13轻烃组分,用一根HPPONA色谱柱分离,同时得到保留时间相同的火焰离子化检测信号和质谱检测信号,为原油中轻烃组分的色谱定性提供了新的有力工具。该方法中所用的色谱... 利用程序升温蒸发进样器、反吹技术和微流控装置分析原油中的C5-C13轻烃组分,用一根HPPONA色谱柱分离,同时得到保留时间相同的火焰离子化检测信号和质谱检测信号,为原油中轻烃组分的色谱定性提供了新的有力工具。该方法中所用的色谱柱使用寿命长,分离效果好,对平湖4井油样中C5~C13馏分的分离得到了可用质谱定性的峰约290个(尚有不少混合峰存在),较难分离的物质对t-1,2-二甲基环戊烷与2-乙基戊烷得到了较好的分离,2-乙基戊烷峰得到非常好的质谱图,是目前研究原油中轻烃组分分析的有效手段。同时应用微流控装置后可在质谱仪不停机的条件下更换色谱柱。 展开更多
关键词 程序升温蒸发进样器(programmed temperature VAPORIZER injector) 反吹技术(backflushing technique) 微流控装置(micro—fluidic splitter) 气相色谱(GC) 气相色谱-质谱(GC—MS) 轻烃组分(light hydrocarbons) 定性(qualification) 原油(crude oil)
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Dynamic grey model of verification cycle and lifecycle of measuring instrument and its application 被引量:4
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作者 苏海涛 杨世元 +1 位作者 董华 沈毛虎 《Journal of Central South University》 SCIE EI CAS 2005年第S2期86-89,共4页
Two dynamic grey models DGM (1, 1) for the verification cycle and the lifecycle of measuring instrument based on time sequence and frequency sequence were set up, according to the statistical feature of examination da... Two dynamic grey models DGM (1, 1) for the verification cycle and the lifecycle of measuring instrument based on time sequence and frequency sequence were set up, according to the statistical feature of examination data and weighting method. By a specific case, i.e. vernier caliper, it is proved that the fit precision and forecast precision of the models are much higher, the cycles are obviously different under different working conditions, and the forecast result of the frequency sequence model is better than that of the time sequence model. Combining dynamic grey model and auto-manufacturing case the controlling and information subsystems of verification cycle and the lifecycle based on information integration, multi-sensor controlling and management controlling were given. The models can be used in production process to help enterprise reduce error, cost and flaw. 展开更多
关键词 measuring equipment verification cycle LIFECYCLE dynamic grey model qualification rate information system
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