The regulation of the burning rate pressure exponent for the ammonium perchlorate/hydroxylterminated polybutadiene/aluminum(AP/HTPB/Al)composite propellants under high pressures is a crucial step for its application i...The regulation of the burning rate pressure exponent for the ammonium perchlorate/hydroxylterminated polybutadiene/aluminum(AP/HTPB/Al)composite propellants under high pressures is a crucial step for its application in high-pressure solid rocket motors.In this work,the combustion characteristics of AP/HTPB/Al composite propellants containing ferrocene-based catalysts were investigated,including the burning rate,thermal behavior,the local heat transfer,and temperature profile in the range of 7-28 MPa.The results showed that the exponent breaks were still observed in the propellants after the addition of positive catalysts(Ce-Fc-MOF),the burning rate inhibitor((Ferrocenylmethyl)trimethylammonium bromide,Fc Br)and the mixture of Fc Br/catocene(GFP).However,the characteristic pressure has increased,and the exponent decreased from 1.14 to 0.66,0.55,and 0.48 when the addition of Ce-FcMOF,Fc Br and Fc Br/GFP in the propellants.In addition,the temperature in the first decomposition stage was increased by 7.50℃ and 11.40℃ for the AP/Fc Br mixture and the AP/Fc Br/GFP mixture,respectively,compared to the pure AP.On the other hand,the temperature in the second decomposition stage decreased by 48.30℃ and 81.70℃ for AP/Fc Br and AP/Fc Br/GFP mixtures,respectively.It was also found that Fc Br might generate ammonia to cover the AP surface.In this case,a reaction between the methyl in Fc Br and perchloric acid caused more ammonia to appear at the AP surface,resulting in the suppression of ammonia desorption.In addition,the coarse AP particles on the quenched surface were of a concave shape relative to the binder matrix under low and high pressures when the catalysts were added.In the process,the decline at the AP/HTPB interface was only exhibited in the propellant with the addition of Ce-Fc-MOF.The ratio of the gas-phase temperature gradient of the propellants containing catalysts was reduced significantly below and above the characteristic pressure,rather than 3.6 times of the difference in the blank propellant.Overall,the obtained results demonstrated that the pressure exponent could be effectively regulated and controlled by adjusting the propellant local heat and mass transfer under high and low pressures.展开更多
An experimental investigation on the boiling heat transfer and frictional pressure drop of R245fa in a 7 mm horizontal micro-fin tube was performed.The results show that in terms of flow boiling heat transfer characte...An experimental investigation on the boiling heat transfer and frictional pressure drop of R245fa in a 7 mm horizontal micro-fin tube was performed.The results show that in terms of flow boiling heat transfer characteristics,boiling heat transfer coefficient(HTC)increases with mass velocity of R245fa,while it decreases with the increment of saturation temperature and heat flux.With the increase of vapor quality,HTC has a maximum and the corresponding vapor quality is about 0.4,which varies with the operating conditions.When vapor quality is larger than the transition point,HTC can be promoted more remarkably at higher mass velocity or lower saturation temperature.Among the four selected correlations,KANDLIKAR correlation matches with 91.6%of experimental data within the deviation range of±25%,and the absolute mean deviation is 11.2%.Also,in terms of frictional pressure drop characteristics of flow boiling,the results of this study show that frictional pressure drop increases with mass velocity and heat flux of R245fa,while it decreases with the increment of saturation temperature.MULLER-STEINHAGEN-HECK correlation shows the best prediction accuracy for frictional pressure drop among the four widely used correlations.It covers 84.1%of experimental data within the deviation range of±20%,and the absolute mean deviation is 10.1%.展开更多
A five steps pressure swing adsorption process was designed for acetone and toluene mixtures separation and recovery. Dynamic distributions of gas phase content and temperature were investigated. Based on the theory o...A five steps pressure swing adsorption process was designed for acetone and toluene mixtures separation and recovery. Dynamic distributions of gas phase content and temperature were investigated. Based on the theory of Soret and Dufour, a non-isothermal mathematical model was developed to simulate the PSA process. Effects of heat and mass transfer coefficients were studied. The coupled Soret and Dufour effects were also evaluated. It is found that the heat transfer coefficient has little effect on mass transfer in adsorption stage. However, it has some impacts in desorption stage. The maximum value of C/C0 increases by about 25% as heat transfer coefficient decreases. The temperature variation is less than 0.05 K with the change of mass transfer coefficient, so that the effect of mass transfer coefficient on heat transfer can be ignored. It is also concluded that the Soret and Dufour coupled effects are not obvious in pressure swing adsorption compared with fixed-bed adsorption.展开更多
Numerical computation models of air cooling heat transfer and flow behaviors in triangular wavy fin channels(TWFC) were established with structural parameters of fins considered.The air side properties of heat transfe...Numerical computation models of air cooling heat transfer and flow behaviors in triangular wavy fin channels(TWFC) were established with structural parameters of fins considered.The air side properties of heat transfer coefficient and pressure drop are displayed with variable structural parameters of fins and inlet velocities of cooling air.Within the range of simulation,TWFC has the best comprehensive performance when inlet velocity vin=4-10 m/s.Compared with those of straight fins,the simulation results reveal that the triangular wavy fin channels are of higher heat transfer performances especially with the fin structural parameters of fin-height Fh=9.0 mm,fin-pitch Fp=2.5-3.0 mm,fin-wavelength λ=14.0-17.5 mm and fin-wave-amplitude A=1.0-1.2 mm.The correlations of both heat transfer factor and friction factor are presented,and the deviations from the experimental measurements are within 20%.展开更多
Convection heat transfer coefficient and air pressure drop in sinter layer are important factors for the design of sinter cooling craft. Due to the lack of necessary data, the two parameters are studied by experimenta...Convection heat transfer coefficient and air pressure drop in sinter layer are important factors for the design of sinter cooling craft. Due to the lack of necessary data, the two parameters are studied by experimental method. The experimental results show that heat conduction of sinter impacts the measurement of convection heat transfer coefficient. Convection heat transfer increases with the increase of air volumetric flow rate. Sinter layer without small particles(sample I) gives higher convection heat transfer coefficient than that with small particles(sample II). Under the considered conditions, volumetric convection heat transfer coefficient is in the range of 400-1800 W/(m3·°C). Air pressure drop in sinter layer increases with the increase of normal superficial velocity, as well as with the rise of air temperature. Additionally, air pressure drop also depends on sinter particle size distribution. In considered experimental conditions, pressure drop in sinter sample II is 2-3 times that in sinter sample I, which resulted from 17% small scale particles in sinter sample II.展开更多
基金the support of the National Natural Science Foundation of China grant number 51776175。
文摘The regulation of the burning rate pressure exponent for the ammonium perchlorate/hydroxylterminated polybutadiene/aluminum(AP/HTPB/Al)composite propellants under high pressures is a crucial step for its application in high-pressure solid rocket motors.In this work,the combustion characteristics of AP/HTPB/Al composite propellants containing ferrocene-based catalysts were investigated,including the burning rate,thermal behavior,the local heat transfer,and temperature profile in the range of 7-28 MPa.The results showed that the exponent breaks were still observed in the propellants after the addition of positive catalysts(Ce-Fc-MOF),the burning rate inhibitor((Ferrocenylmethyl)trimethylammonium bromide,Fc Br)and the mixture of Fc Br/catocene(GFP).However,the characteristic pressure has increased,and the exponent decreased from 1.14 to 0.66,0.55,and 0.48 when the addition of Ce-FcMOF,Fc Br and Fc Br/GFP in the propellants.In addition,the temperature in the first decomposition stage was increased by 7.50℃ and 11.40℃ for the AP/Fc Br mixture and the AP/Fc Br/GFP mixture,respectively,compared to the pure AP.On the other hand,the temperature in the second decomposition stage decreased by 48.30℃ and 81.70℃ for AP/Fc Br and AP/Fc Br/GFP mixtures,respectively.It was also found that Fc Br might generate ammonia to cover the AP surface.In this case,a reaction between the methyl in Fc Br and perchloric acid caused more ammonia to appear at the AP surface,resulting in the suppression of ammonia desorption.In addition,the coarse AP particles on the quenched surface were of a concave shape relative to the binder matrix under low and high pressures when the catalysts were added.In the process,the decline at the AP/HTPB interface was only exhibited in the propellant with the addition of Ce-Fc-MOF.The ratio of the gas-phase temperature gradient of the propellants containing catalysts was reduced significantly below and above the characteristic pressure,rather than 3.6 times of the difference in the blank propellant.Overall,the obtained results demonstrated that the pressure exponent could be effectively regulated and controlled by adjusting the propellant local heat and mass transfer under high and low pressures.
基金Project(51606162)supported by the National Natural Science Foundation of ChinaProject(2018JJ2399)supported by the Natural Science Foundation of Hunan Province,China
文摘An experimental investigation on the boiling heat transfer and frictional pressure drop of R245fa in a 7 mm horizontal micro-fin tube was performed.The results show that in terms of flow boiling heat transfer characteristics,boiling heat transfer coefficient(HTC)increases with mass velocity of R245fa,while it decreases with the increment of saturation temperature and heat flux.With the increase of vapor quality,HTC has a maximum and the corresponding vapor quality is about 0.4,which varies with the operating conditions.When vapor quality is larger than the transition point,HTC can be promoted more remarkably at higher mass velocity or lower saturation temperature.Among the four selected correlations,KANDLIKAR correlation matches with 91.6%of experimental data within the deviation range of±25%,and the absolute mean deviation is 11.2%.Also,in terms of frictional pressure drop characteristics of flow boiling,the results of this study show that frictional pressure drop increases with mass velocity and heat flux of R245fa,while it decreases with the increment of saturation temperature.MULLER-STEINHAGEN-HECK correlation shows the best prediction accuracy for frictional pressure drop among the four widely used correlations.It covers 84.1%of experimental data within the deviation range of±20%,and the absolute mean deviation is 10.1%.
基金Projects(20976200,20676154) supported by the National Natural Science Foundation of China
文摘A five steps pressure swing adsorption process was designed for acetone and toluene mixtures separation and recovery. Dynamic distributions of gas phase content and temperature were investigated. Based on the theory of Soret and Dufour, a non-isothermal mathematical model was developed to simulate the PSA process. Effects of heat and mass transfer coefficients were studied. The coupled Soret and Dufour effects were also evaluated. It is found that the heat transfer coefficient has little effect on mass transfer in adsorption stage. However, it has some impacts in desorption stage. The maximum value of C/C0 increases by about 25% as heat transfer coefficient decreases. The temperature variation is less than 0.05 K with the change of mass transfer coefficient, so that the effect of mass transfer coefficient on heat transfer can be ignored. It is also concluded that the Soret and Dufour coupled effects are not obvious in pressure swing adsorption compared with fixed-bed adsorption.
基金Project(50976022) supported by the National Natural Science Foundation of ChinaProject(BY2011155) supported by the Provincial Science and Technology Innovation and Transformation of Achievements of Special Fund Project of Jiangsu Province,China
文摘Numerical computation models of air cooling heat transfer and flow behaviors in triangular wavy fin channels(TWFC) were established with structural parameters of fins considered.The air side properties of heat transfer coefficient and pressure drop are displayed with variable structural parameters of fins and inlet velocities of cooling air.Within the range of simulation,TWFC has the best comprehensive performance when inlet velocity vin=4-10 m/s.Compared with those of straight fins,the simulation results reveal that the triangular wavy fin channels are of higher heat transfer performances especially with the fin structural parameters of fin-height Fh=9.0 mm,fin-pitch Fp=2.5-3.0 mm,fin-wavelength λ=14.0-17.5 mm and fin-wave-amplitude A=1.0-1.2 mm.The correlations of both heat transfer factor and friction factor are presented,and the deviations from the experimental measurements are within 20%.
基金Project(51306198)supported by the National Natural Science Foundation of China
文摘Convection heat transfer coefficient and air pressure drop in sinter layer are important factors for the design of sinter cooling craft. Due to the lack of necessary data, the two parameters are studied by experimental method. The experimental results show that heat conduction of sinter impacts the measurement of convection heat transfer coefficient. Convection heat transfer increases with the increase of air volumetric flow rate. Sinter layer without small particles(sample I) gives higher convection heat transfer coefficient than that with small particles(sample II). Under the considered conditions, volumetric convection heat transfer coefficient is in the range of 400-1800 W/(m3·°C). Air pressure drop in sinter layer increases with the increase of normal superficial velocity, as well as with the rise of air temperature. Additionally, air pressure drop also depends on sinter particle size distribution. In considered experimental conditions, pressure drop in sinter sample II is 2-3 times that in sinter sample I, which resulted from 17% small scale particles in sinter sample II.
